##############################################################################
###                                                                        ###
###           Full Paper (Acta Crystallographica Section C)                ###
###                                                                        ###
##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in Acta     #
# Crystallographica Section C. It conforms to the editorial and technical    #
# requirements of Notes for Authors for Section C, and has been peer         #
# reviewed under the auspices of the IUCr Commission on Journals.            #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.1.    #
#                                                                            #
# Software is freely available for graphical display of the structure(s) in  #
# this CIF.  For information consult the CIF home page http://www.iucr.org/  #
# cif/home.html                                                              #
#                                                                            #
#            Copyright International Union of Crystallography                #
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##############################################################################
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
cis-dichlorobis(triethylarsine)platinum(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C12 H30 As2 Cl2 Pt'
_chemical_formula_sum     'C12 H30 As2 Cl2 Pt'
_chemical_formula_iupac     '[Pt Cl2 (C6 H15 As)2]'
_chemical_formula_weight     590.19
_chemical_melting_point     ?
_symmetry_cell_setting     'Monoclinic'
_symmetry_space_group_name_H-M     'P 21/n'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     8.0566(16)
_cell_length_b     17.754(4)
_cell_length_c     13.083(3)
_cell_angle_alpha     90.00
_cell_angle_beta     94.20(3)
_cell_angle_gamma     90.00
_cell_volume     1866.4(6)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     6559
_cell_measurement_theta_min     2.29
_cell_measurement_theta_max     30.87
_cell_measurement_temperature     293(2)
_exptl_crystal_description     rectangular
_exptl_crystal_colour     colourless
_exptl_crystal_size_max      .119
_exptl_crystal_size_mid      .112
_exptl_crystal_size_min      .038
_exptl_crystal_density_diffrn     2.100
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     1120
_exptl_absorpt_coefficient_mu     11.306
_exptl_absorpt_correction_type     empirical
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min      .328
_exptl_absorpt_correction_T_max      .651
_exptl_special_details
;
For both complexes, the intensity data were collected on a Siemens SMART CCD
diffractometer using an exposure time of 15 s per frame for (I) and 20
s per frame for (II). A total of 1890 frames with a frame width of 0.25\%
were collected for (I) and 2250 frames with a frame width of 0.20\% were
collected for (II).  A completeness of 98.9% was accomplished up to \q =
30.50\% for (I), while the completeness was 99.0% at \q = 30.51\% for (II).
The first 50 frames were recollected at the end of each data collection to
check for decay; no decay was found for either data collection.
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength      .71073
_diffrn_radiation_source     'rotating anode'
_diffrn_radiation_monochromator     'graphite'
_diffrn_measurement_device_type     'Siemens SMART CCD'
_diffrn_measurement_method     \w
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     19330
_diffrn_reflns_av_R_equivalents      .0708
_diffrn_reflns_av_sigmaI/netI      .0642
_diffrn_reflns_theta_min     1.94
_diffrn_reflns_theta_max     31.93
_diffrn_reflns_theta_full     31.93
_diffrn_measured_fraction_theta_max      .917
_diffrn_measured_fraction_theta_full      .917
_diffrn_reflns_limit_h_min     -11
_diffrn_reflns_limit_h_max     11
_diffrn_reflns_limit_k_min     -25
_diffrn_reflns_limit_k_max     24
_diffrn_reflns_limit_l_min     -19
_diffrn_reflns_limit_l_max     17
_diffrn_standards_number     'First 50 frames repeated after data collection.'
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     none
_refine_special_details
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F^2^, conventional R-factors R are based
 on F, with F set to zero for negative F^2^. The threshold expression of
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F^2^ are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     5905
_reflns_number_gt     4285
_reflns_threshold_expression     I>2\s(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all      .0584
_refine_ls_R_factor_gt      .0343
_refine_ls_wR_factor_gt      .0661
_refine_ls_wR_factor_ref      .0720
_refine_ls_goodness_of_fit_ref      .930
_refine_ls_restrained_S_all      .930
_refine_ls_number_reflns     5905
_refine_ls_number_parameters     162
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
             'calc w = 1/[\s^2^(Fo^2^)+(0.0281P)^2^] where P = (Fo^2^+2Fc^2^)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max      .002
_refine_ls_shift/su_mean      .000
_refine_diff_density_max     1.139
_refine_diff_density_min     -2.048
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C'  .0033  .0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H'  .0000  .0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl'  .1484  .1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'As' 'As'  .0499 2.0058
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Siemens, 1995)'
_computing_cell_refinement     'SAINT (Siemens, 1995)'
_computing_data_reduction     'SAINT'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'DIAMOND (Brandenburg, 1999)'
_computing_publication_material     'SHELXL97'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Pt  .23175(2)  .197343(9)  .191580(13)  .02951(6) Uani d . 1 . . Pt
    As1  .34578(5)  .07684(2)  .22491(3)  .03068(10) Uani d . 1 . . As
    As2  .48241(6)  .26115(2)  .16514(4)  .03327(11) Uani d . 1 . . As
    Cl1  .08491(18)  .31085(7)  .17214(12)  .0565(4) Uani d . 1 . . Cl
    Cl2  -.01854(15)  .13713(8)  .22449(12)  .0573(4) Uani d . 1 . . Cl
    C111  .5813(6)  .0591(2)  .2122(4)  .0434(12) Uani d . 1 . . C
    H11A  .6046  .0683  .1415  .059(5) Uiso calc R 1 . . H
    H11B  .6439  .0958  .2542  .059(5) Uiso calc R 1 . . H
    C112  .6456(7)  -.0192(3)  .2422(5)  .0681(18) Uani d . 1 . . C
    H11C  .6388  -.0264  .3145  .092(5) Uiso calc R 1 . . H
    H11D  .7594  -.0238  .2258  .092(5) Uiso calc R 1 . . H
    H11E  .5792  -.0565  .2053  .092(5) Uiso calc R 1 . . H
    C121  .3091(7)  .0442(3)  .3639(4)  .0455(12) Uani d . 1 . . C
    H12A  .1903  .0427  .3717  .059(5) Uiso calc R 1 . . H
    H12B  .3520  -.0065  .3739  .059(5) Uiso calc R 1 . . H
    C122  .3904(10)  .0946(4)  .4449(4)  .081(2) Uani d . 1 . . C
    H12C  .5083  .0957  .4383  .092(5) Uiso calc R 1 . . H
    H12D  .3690  .0756  .5114  .092(5) Uiso calc R 1 . . H
    H12E  .3460  .1445  .4368  .092(5) Uiso calc R 1 . . H
    C131  .2339(7)  -.0035(3)  .1456(4)  .0482(13) Uani d . 1 . . C
    H13A  .2885  -.0509  .1636  .059(5) Uiso calc R 1 . . H
    H13B  .1199  -.0070  .1643  .059(5) Uiso calc R 1 . . H
    C132  .2333(9)  .0077(4)  .0309(5)  .0701(18) Uani d . 1 . . C
    H13C  .1811  .0549  .0125  .092(5) Uiso calc R 1 . . H
    H13D  .1727  -.0326  -.0036  .092(5) Uiso calc R 1 . . H
    H13E  .3457  .0079  .0111  .092(5) Uiso calc R 1 . . H
    C211  .4630(7)  .3668(3)  .1233(4)  .0542(14) Uani d . 1 . . C
    H21A  .3913  .3925  .1684  .059(5) Uiso calc R 1 . . H
    H21B  .5721  .3900  .1321  .059(5) Uiso calc R 1 . . H
    C212  .3950(9)  .3786(3)  .0145(5)  .0706(18) Uani d . 1 . . C
    H21C  .4748  .3615  -.0313  .092(5) Uiso calc R 1 . . H
    H21D  .3729  .4312  .0031  .092(5) Uiso calc R 1 . . H
    H21E  .2936  .3505  .0023  .092(5) Uiso calc R 1 . . H
    C221  .6271(6)  .2693(3)  .2907(4)  .0514(14) Uani d . 1 . . C
    H22A  .6623  .2193  .3128  .059(5) Uiso calc R 1 . . H
    H22B  .7257  .2977  .2766  .059(5) Uiso calc R 1 . . H
    C222  .5421(9)  .3078(3)  .3771(5)  .0688(18) Uani d . 1 . . C
    H22C  .5240  .3600  .3606  .092(5) Uiso calc R 1 . . H
    H22D  .6116  .3038  .4397  .092(5) Uiso calc R 1 . . H
    H22E  .4371  .2838  .3855  .092(5) Uiso calc R 1 . . H
    C231  .6287(6)  .2227(3)  .0649(4)  .0400(11) Uani d . 1 . . C
    H23A  .7011  .2631  .0454  .059(5) Uiso calc R 1 . . H
    H23B  .6985  .1834  .0967  .059(5) Uiso calc R 1 . . H
    C232  .5369(8)  .1912(3)  -.0309(5)  .0606(16) Uani d . 1 . . C
    H23C  .4677  .1500  -.0127  .092(5) Uiso calc R 1 . . H
    H23D  .6159  .1737  -.0770  .092(5) Uiso calc R 1 . . H
    H23E  .4690  .2299  -.0637  .092(5) Uiso calc R 1 . . H
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    Pt  .02428(9)  .03401(9)  .03033(9)  .00395(7)  .00265(6)  .00006(7)
    As1  .0277(2)  .0305(2)  .0341(2)  .00035(17)  .00402(18)  .00045(18)
    As2  .0317(2)  .0325(2)  .0359(2)  -.00120(18)  .00457(19)  -.00042(19)
    Cl1  .0492(8)  .0485(7)  .0729(10)  .0213(6)  .0117(7)  .0099(6)
    Cl2  .0249(6)  .0626(8)  .0854(10)  .0004(6)  .0094(6)  .0121(7)
    C111  .034(3)  .034(2)  .064(3)  .005(2)  .013(2)  .006(2)
    C112  .049(3)  .058(3)  .100(5)  .025(3)  .022(3)  .030(3)
    C121  .049(3)  .048(3)  .040(3)  .001(2)  .010(2)  .007(2)
    C122  .129(7)  .073(4)  .040(3)  -.008(4)  -.003(4)  -.002(3)
    C131  .048(3)  .041(3)  .055(3)  -.005(2)  -.005(2)  -.008(2)
    C132  .081(5)  .077(4)  .051(4)  -.012(4)  -.004(3)  -.016(3)
    C211  .064(4)  .036(3)  .064(4)  -.001(2)  .015(3)  .004(3)
    C212  .095(5)  .053(3)  .065(4)  .017(3)  .017(4)  .016(3)
    C221  .043(3)  .051(3)  .057(3)  -.001(2)  -.010(3)  -.004(3)
    C222  .078(5)  .084(4)  .044(3)  .002(3)  -.002(3)  -.019(3)
    C231  .034(3)  .044(2)  .044(3)  .001(2)  .013(2)  .005(2)
    C232  .071(4)  .059(3)  .053(4)  .002(3)  .019(3)  -.011(3)


data_II
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
cis-dichlorobis(triethylphosphine)platinum(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C12 H30 Cl2 P2 Pt'
_chemical_formula_sum     'C12 H30 Cl2 P2 Pt'
_chemical_formula_iupac     '[Pt Cl2 (C6 H15 P1)2]'
_chemical_formula_weight     502.29
_chemical_melting_point     ?
_symmetry_cell_setting     'Monoclinic'
_symmetry_space_group_name_H-M     'C c'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    'x, -y, z+1/2'
    'x+1/2, y+1/2, z'
    'x+1/2, -y+1/2, z+1/2'
_cell_length_a     19.773(4)
_cell_length_b     7.5310(15)
_cell_length_c     13.726(3)
_cell_angle_alpha     90.00
_cell_angle_beta     117.31(3)
_cell_angle_gamma     90.00
_cell_volume     1816.1(6)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     6951
_cell_measurement_theta_min     2.32
_cell_measurement_theta_max     31.66
_cell_measurement_temperature     293(2)
_exptl_crystal_description     rectangular
_exptl_crystal_colour     colourless
_exptl_crystal_size_max      .35
_exptl_crystal_size_mid      .30
_exptl_crystal_size_min      .18
_exptl_crystal_density_diffrn     1.837
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     976
_exptl_absorpt_coefficient_mu     8.178
_exptl_absorpt_correction_type     empirical
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min      .092
_exptl_absorpt_correction_T_max      .229
_exptl_special_details
;
For both complexes, the intensity data were collected on a Siemens SMART CCD
diffractometer using an exposure time of 15 s per frame for (I) and 20
s per frame for (II). A total of 1890 frames with a frame width of 0.25\%
were collected for (I) and 2250 frames with a frame width of 0.20\% were
collected for (II).  A completeness of 98.9% was accomplished up to \q =
30.50\% for (I), while the completeness was 99.0% at \q = 30.51\% for (II).
The first 50 frames were recollected at the end of each data collection to
check for decay; no decay was found for either data collection.
;
_diffrn_ambient_temperature     293(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength      .71073
_diffrn_radiation_source     'rotating anode'
_diffrn_radiation_monochromator     'graphite'
_diffrn_measurement_device_type     'Siemens SMART CCD'
_diffrn_measurement_method     \w
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     9281
_diffrn_reflns_av_R_equivalents      .0530
_diffrn_reflns_av_sigmaI/netI      .0425
_diffrn_reflns_theta_min     2.94
_diffrn_reflns_theta_max     32.03
_diffrn_reflns_theta_full     32.03
_diffrn_measured_fraction_theta_max      .901
_diffrn_measured_fraction_theta_full      .901
_diffrn_reflns_limit_h_min     -28
_diffrn_reflns_limit_h_max     22
_diffrn_reflns_limit_k_min     -10
_diffrn_reflns_limit_k_max     11
_diffrn_reflns_limit_l_min     -19
_diffrn_reflns_limit_l_max     17
_diffrn_standards_number     'First 50 frames repeated after data collection.'
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     none
_refine_special_details
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F^2^, conventional R-factors R are based
 on F, with F set to zero for negative F^2^. The threshold expression of
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F^2^ are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     4284
_reflns_number_gt     4059
_reflns_threshold_expression     I>2\s(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all      .0363
_refine_ls_R_factor_gt      .0341
_refine_ls_wR_factor_gt      .0906
_refine_ls_wR_factor_ref      .0921
_refine_ls_goodness_of_fit_ref     1.020
_refine_ls_restrained_S_all     1.020
_refine_ls_number_reflns     4284
_refine_ls_number_parameters     162
_refine_ls_number_restraints     2
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
             'calc w = 1/[\s^2^(Fo^2^)+(0.0648P)^2^] where P = (Fo^2^+2Fc^2^)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     <0.001
_refine_ls_shift/su_mean      .000
_refine_diff_density_max      .978
_refine_diff_density_min     -2.063
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
_refine_ls_abs_structure_details     'Flack (1983)'
_refine_ls_abs_structure_Flack     '0.035(10), 1109 Friedel pairs'
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C'  .0033  .0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H'  .0000  .0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P'  .1023  .0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl'  .1484  .1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Pt' 'Pt' -1.7033 8.3905
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Siemens, 1995)'
_computing_cell_refinement     'SAINT (Siemens, 1995)'
_computing_data_reduction     'SAINT'
_computing_structure_solution     'SHELXS97 (Sheldrick, 1997)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 1997)'
_computing_molecular_graphics     'DIAMOND (Brandenburg, 1999)'
_computing_publication_material     'SHELXL97'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
    Pt  .08960(2)  .33029(2)  .14145(2)  .02873(7) Uani d . 1 . . Pt
    P1  -.03044(11)  .3783(3)  .00820(15)  .0323(3) Uani d . 1 . . P
    P2  .15326(11)  .4669(2)  .06151(15)  .0310(3) Uani d . 1 . . P
    Cl1  .20485(12)  .2581(3)  .29721(16)  .0456(4) Uani d . 1 . . Cl
    Cl2  .02913(17)  .1786(3)  .2319(2)  .0523(6) Uani d . 1 . . Cl
    C111  -.0511(5)  .5107(13)  -.1136(8)  .049(2) Uani d . 1 . . C
    H11A  -.0258  .6245  -.0897  .056(6) Uiso calc R 1 . . H
    H11B  -.0285  .4517  -.1544  .056(6) Uiso calc R 1 . . H
    C112  -.1338(6)  .5451(17)  -.1910(10)  .064(3) Uani d . 1 . . C
    H11C  -.1584  .4353  -.2235  .113(11) Uiso calc R 1 . . H
    H11D  -.1375  .6256  -.2475  .113(11) Uiso calc R 1 . . H
    H11E  -.1582  .5966  -.1511  .113(11) Uiso calc R 1 . . H
    C121  -.0784(6)  .1672(9)  -.0468(9)  .0429(19) Uani d . 1 . . C
    H12A  -.0771  .0963  .0130  .056(6) Uiso calc R 1 . . H
    H12B  -.1313  .1907  -.0971  .056(6) Uiso calc R 1 . . H
    C122  -.0438(7)  .0607(13)  -.1061(10)  .064(3) Uani d . 1 . . C
    H12C  -.0488  .1254  -.1694  .113(11) Uiso calc R 1 . . H
    H12D  -.0697  -.0510  -.1288  .113(11) Uiso calc R 1 . . H
    H12E  .0091  .0402  -.0579  .113(11) Uiso calc R 1 . . H
    C131  -.0886(6)  .4812(12)  .0646(8)  .0488(19) Uani d . 1 . . C
    H13A  -.1410  .4856  .0079  .056(6) Uiso calc R 1 . . H
    H13B  -.0869  .4073  .1235  .056(6) Uiso calc R 1 . . H
    C132  -.0632(11)  .6688(13)  .1085(15)  .073(4) Uani d . 1 . . C
    H13C  -.0113  .6661  .1645  .113(11) Uiso calc R 1 . . H
    H13D  -.0950  .7134  .1389  .113(11) Uiso calc R 1 . . H
    H13E  -.0674  .7448  .0498  .113(11) Uiso calc R 1 . . H
    C211  .2563(5)  .4640(12)  .1434(7)  .0455(17) Uani d . 1 . . C
    H21A  .2693  .5226  .2127  .056(6) Uiso calc R 1 . . H
    H21B  .2729  .3415  .1594  .056(6) Uiso calc R 1 . . H
    C212  .3006(6)  .5532(15)  .0900(9)  .055(2) Uani d . 1 . . C
    H21C  .2826  .5093  .0166  .113(11) Uiso calc R 1 . . H
    H21D  .3538  .5269  .1318  .113(11) Uiso calc R 1 . . H
    H21E  .2931  .6794  .0880  .113(11) Uiso calc R 1 . . H
    C221  .1378(6)  .3677(13)  -.0688(8)  .0455(18) Uani d . 1 . . C
    H22A  .0836  .3611  -.1175  .056(6) Uiso calc R 1 . . H
    H22B  .1606  .4430  -.1032  .056(6) Uiso calc R 1 . . H
    C222  .1726(11)  .1801(12)  -.0526(13)  .071(4) Uani d . 1 . . C
    H22C  .2267  .1893  -.0251  .113(11) Uiso calc R 1 . . H
    H22D  .1510  .1184  -.1214  .113(11) Uiso calc R 1 . . H
    H22E  .1617  .1159  -.0010  .113(11) Uiso calc R 1 . . H
    C231  .1332(6)  .7041(11)  .0355(9)  .047(2) Uani d . 1 . . C
    H23A  .1643  .7531  .0042  .056(6) Uiso calc R 1 . . H
    H23B  .0802  .7204  -.0172  .056(6) Uiso calc R 1 . . H
    C232  .1498(10)  .8042(15)  .1424(14)  .074(4) Uani d . 1 . . C
    H23C  .1326  .7344  .1852  .113(11) Uiso calc R 1 . . H
    H23D  .1236  .9161  .1247  .113(11) Uiso calc R 1 . . H
    H23E  .2036  .8244  .1836  .113(11) Uiso calc R 1 . . H
loop_
    _atom_site_aniso_label
    _atom_site_aniso_U_11
    _atom_site_aniso_U_22
    _atom_site_aniso_U_33
    _atom_site_aniso_U_12
    _atom_site_aniso_U_13
    _atom_site_aniso_U_23
    Pt  .02999(12)  .03011(10)  .02696(10)  .00048(11)  .01382(8)  .00179(11)
    P1  .0290(9)  .0342(7)  .0346(8)  .0027(7)  .0154(7)  .0041(7)
    P2  .0317(8)  .0308(7)  .0311(8)  -.0016(6)  .0150(7)  .0018(6)
    Cl1  .0347(9)  .0601(12)  .0355(9)  .0036(8)  .0104(7)  .0104(8)
    Cl2  .0498(14)  .0678(14)  .0450(12)  -.0028(9)  .0265(11)  .0167(8)
    C111  .032(4)  .065(5)  .048(5)  .007(4)  .016(3)  .022(4)
    C112  .043(5)  .083(6)  .060(6)  .015(5)  .018(4)  .033(5)
    C121  .029(4)  .044(4)  .047(5)  -.007(3)  .010(4)  -.003(3)
    C122  .073(7)  .040(4)  .079(7)  -.004(4)  .034(6)  -.015(4)
    C131  .047(5)  .059(5)  .047(5)  .012(4)  .027(4)  .003(3)
    C132  .096(12)  .057(7)  .083(10)  .015(5)  .054(10)  -.006(4)
    C211  .037(4)  .056(4)  .042(4)  -.001(3)  .017(3)  .009(3)
    C212  .042(5)  .071(6)  .053(5)  -.016(4)  .023(4)  .002(4)
    C221  .048(5)  .049(4)  .044(4)  .001(4)  .025(4)  -.005(3)
    C222  .106(13)  .053(6)  .074(9)  -.007(5)  .057(9)  -.022(4)
    C231  .048(5)  .034(3)  .058(5)  -.008(3)  .025(4)  .001(3)
    C232  .096(11)  .046(5)  .091(10)  -.010(5)  .052(9)  -.016(5)
data_global
_journal_date_recd_electronic     2001-09-03
_journal_date_accepted     2001-09-28
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     2001
_journal_volume     57
_journal_issue     12
_journal_page_first     1405
_journal_page_last     1407
_journal_paper_category     FM
_publ_contact_author_name     'Stefanus Otto'
_publ_contact_author_address
;
      Inorganic Chemistry 1
      Centre for Chemistry and Chemical Engineering
      University of Lund
      PO Box 124
      SE-221 00 Lund
      Sweden
;
_publ_contact_author_email     stefanus.otto@inorg.lu.se
_publ_contact_author_fax     'Intl-46-46-2224439'
_publ_contact_author_phone     'Intl-46-46-2228634'
_publ_section_title
;
cis-Dichlorobis(triethylarsine)platinum(II) and
cis-dichlorobis(triethylphosphine)platinum(II)
;
loop_
    _publ_author_name
    _publ_author_address
    'Otto, Stefanus'
;     Inorganic Chemistry 1
      Centre for Chemistry and Chemical Engineering
      University of Lund
      PO Box 124
      SE-221 00 Lund
      Sweden
;
    'Muller, Alfred Johannes'
;     Department of Chemistry
      University of the Free State
      Bloemfontein 9300
      South Africa
;