data_1007136
_chemical_name_systematic
;
TELLURIUM(VI) HYDROXIDE BIS(THALLIUM DIHYDROGENPHOSPHATE)
;
_chemical_formula_structural       'TE (O H)6 (TL (H2 P O4))2'
_chemical_formula_sum              'H10 O14 P2 Te Tl2'
_publ_section_title
;
Crystal data for two new phosphate-tellurates: Te (O H)~6~ (Tl (H~2~ P
O~4~))~2~ (Tl~2~ (H P O~4~)) and Te (O H)~6~ (Tl (H~2~ P O~4~))~2~.
Crystal structure of Te (O H)~6~ (Tl (H~2~ P O~4~))~2~.
;
loop_
_publ_author_name
  'Averbuch-Pouchot, M T'
  'Durif, A'
_journal_name_full                 'Materials Research Bulletin'
_journal_coden_ASTM                MRBUAC
_journal_volume                    16
_journal_year                      1981
_journal_page_first                71
_journal_page_last                 76
_cell_length_a                     6.285(5)
_cell_length_b                     14.74(1)
_cell_length_c                     7.844(5)
_cell_angle_alpha                  90
_cell_angle_beta                   113.38(1)
_cell_angle_gamma                  90
_cell_volume                       667.0
_cell_formula_units_Z              2
_exptl_crystal_density_meas        4.14
_symmetry_space_group_name_H-M     'P 1 21/n 1'
_symmetry_Int_Tables_number        14
_symmetry_cell_setting             monoclinic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '1/2+x,1/2-y,1/2+z'
  '-x,-y,-z'
  '1/2-x,1/2+y,1/2-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  Tl1+   1.000
  Te6+   6.000
  P5+    5.000
  O2-   -2.000
  H1+    1.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  Tl1   Tl1+   4 ? 0.31173(6) 0.08193(3) 0.60412(5) 1.  0 d
  Te1   Te6+   2 ? 0. 0. 0. 1.  0 d
  P1    P5+    4 ? 0.7245(3) 0.1831(1) 0.3905(3) 1.  0 d
  O1    O2-    4 ? 0.770(1) 0.0027(4) 0.1017(8) 1.  1 d
  O2    O2-    4 ? 0.382(1) 0.3896(4) 0.3648(7) 1.  1 d
  O3    O2-    4 ? 0.202(1) 0.0693(5) 0.2078(8) 1.  1 d
  O4    O2-    4 ? 0.588(1) 0.1522(4) 0.1930(8) 1.  0 d
  O5    O2-    4 ? 0.889(1) 0.2614(5) 0.3830(9) 1.  0 d
  O6    O2-    4 ? 0.849(1) 0.1077(5) 0.5174(8) 1.  0 d
  O7    O2-    4 ? 0.559(1) 0.2248(5) 0.4775(8) 1.  0 d
  H1    H1+    4 ? -1. -1. -1. 5.  0 dum
_refine_ls_R_factor_all            0.037