#------------------------------------------------------------------------------
#$Date: 2011-09-10 04:16:28 +0100 (Sat, 10 Sep 2011) $
#$Revision: 25271 $
#$URL: svn://www.crystallography.net/cod/cif/2/2000570.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000570
loop_
_publ_author_name
'Morooka, M.'
'Ohba, S.'
'Nakashima, M.'
'Tokii, T.'
'Muto, Y.'
'Kato, M.'
'Steward, O. W.'
_publ_section_title
;
 Dimeric nickel(II) carboxylates and a silanecarboxylate:
 [Ni(Me~3~CCOO)~2~(2,5-lutidine)]~2~,
 [Ni(MePh~2~CCOO)~2~(quinoline)]~2~.2CHCl~3~,
 [Ni(Me~2~PhCCOO)~2~(quinoline)]~2~,
 [Ni(Me~3~CCOO)~2~(2-ethylpyridine)]~2~,
 [Ni(Me~3~CCOO)~2~(2-picoline)]~2~ and [Ni(MePh~2~SiCOO)~2~(Ph~3~P)]~2~
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1888
_journal_page_last               1894
_journal_volume                  48
_journal_year                    1992
_chemical_formula_moiety         'C92 H82 Ni2 O8 P2 Si4'
_chemical_formula_structural
'(Ni ((C H3) (C6 H5)2 Si C O2)2 (P (C6 H5)3))2'
_chemical_formula_sum            'C92 H82 Ni2 O8 P2 Si4'
_chemical_formula_weight         1607.3
_chemical_name_systematic
; tetrakis(\m-methyldiphenylsilanecarboxylato-O,O')bis(triphenylphosphine)
  dinickel
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_method           from_xtal_archive_file_using_CIFIO
_cell_angle_alpha                90.00000
_cell_angle_beta                 112.921(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   14.4610(10)
_cell_length_b                   23.4320(10)
_cell_length_c                   13.5420(10)
_cell_measurement_reflns_used    33
_cell_measurement_temperature    299
_cell_measurement_theta_max      15
_cell_measurement_theta_min      12
_cell_volume                     4226.4(5)
_diffrn_ambient_temperature      299.0(10)
_diffrn_measurement_device       'Rigaku AFC-5 four-circle diffractometer'
_diffrn_measurement_method       '\q--2\q scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Xray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  0.017
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8385
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.32
_diffrn_standards_decay_%        13.2
_diffrn_standards_interval_count 100
_diffrn_standards_number         5
_exptl_absorpt_coefficient_mu    0.592
_exptl_absorpt_correction_T_max  0.84
_exptl_absorpt_correction_T_min  0.76
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'Gauss numerical integration'
_exptl_crystal_colour            'dark green'
_exptl_crystal_density_diffrn    1.263
_exptl_crystal_density_meas      1.250(10)
_exptl_crystal_density_method    'flotation in n-butanol tetrachloromethane'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1680
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.35
_refine_diff_density_max         .420
_refine_diff_density_min         -.535
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   2.666
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           atomblock
_refine_ls_number_constraints    0
_refine_ls_number_parameters     652
_refine_ls_number_reflns         4341
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          .044
_refine_ls_shift/esd_max         0.222
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      'calc, w=1/\s'
_refine_ls_wR_factor_obs         .035
_reflns_number_observed          4341
_reflns_number_total             7989
_reflns_observed_criterion       |F~o~|>3\s(|F~o~|)
_[local]_cod_data_source_file    as1007.cif
_[local]_cod_data_source_block   VI
_[local]_cod_cif_authors_sg_Hall -P_2yn
_cod_original_cell_volume        4226.4(4)
_cod_database_code               2000570
loop_
_symmetry_equiv_pos_as_xyz
+x,+y,+z
1/2-x,1/2+y,1/2-z
-x,-y,-z
1/2+x,1/2-y,1/2+z
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ni .0269(3) .0253(3) .0328(3) .0008(3) .0049(2) .0034(3)
P .0304(6) .0272(6) .0335(8) .0010(5) .0033(6) .0041(6)
Si1 .0266(7) .0478(9) .0421(9) -.0014(6) .0118(7) -.0003(8)
Si2 .0411(8) .0353(8) .0347(9) .0014(6) .0040(7) -.0071(7)
O11 .034(2) .038(2) .059(2) .0010(10) .021(2) .008(2)
O12 .030(2) .051(2) .061(2) .000(2) .015(2) .011(2)
O21 .054(2) .035(2) .028(2) .004(2) .000(2) .003(2)
O22 .052(2) .033(2) .036(2) .000(2) .008(2) -.001(2)
C1 .028(2) .032(3) .031(3) -.003(2) .004(2) .002(2)
C2 .053(3) .032(3) .072(4) -.001(2) .026(3) -.008(3)
C3 .073(4) .061(4) .086(5) -.004(3) .052(4) -.007(3)
C4 .069(4) .045(3) .075(4) .006(3) .029(3) -.015(3)
C5 .074(4) .030(3) .074(4) -.001(3) .022(3) -.013(3)
C6 .052(3) .034(3) .050(4) -.002(2) .018(3) -.002(3)
C7 .039(3) .032(3) .027(3) .000(2) .005(2) .003(2)
C8 .064(3) .028(3) .056(4) .010(2) -.011(3) -.002(3)
C9 .066(4) .049(3) .056(4) .028(3) -.014(3) .004(3)
C10 .046(3) .056(3) .041(3) .005(3) -.009(3) .002(3)
C11 .069(4) .047(3) .049(4) -.008(3) -.005(3) -.013(3)
C12 .051(3) .040(3) .041(3) .008(2) -.002(3) .001(3)
C13 .043(3) .025(3) .046(3) .005(2) .015(3) .008(2)
C14 .046(3) .060(4) .065(4) -.012(3) .015(3) .014(3)
C15 .053(4) .090(5) .105(5) -.018(3) .024(4) .021(4)
C16 .082(5) .116(6) .124(6) -.024(4) .064(5) .009(5)
C17 .109(5) .162(7) .077(5) -.043(5) .059(4) .000(5)
C18 .078(4) .087(4) .065(4) -.025(3) .033(4) -.007(4)
C101 .031(2) .042(3) .035(3) -.007(2) .009(2) -.009(2)
C102 .053(3) .075(4) .058(4) -.001(3) .023(3) .008(3)
C103 .029(2) .053(3) .043(3) -.001(2) .011(2) -.002(3)
C104 .045(3) .055(3) .050(3) -.002(3) .016(3) -.012(3)
C105 .049(3) .101(5) .050(4) -.013(3) .002(3) -.018(4)
C106 .091(4) .071(4) .070(4) -.030(3) .023(4) -.027(4)
C107 .094(5) .066(4) .089(5) -.002(3) .023(4) -.025(4)
C108 .049(3) .061(4) .079(4) -.001(3) .000(3) -.007(3)
C109 .026(2) .048(3) .059(4) -.002(2) .017(3) -.002(3)
C110 .053(3) .070(4) .060(4) .009(3) .022(3) .011(3)
C111 .074(4) .070(4) .079(5) .008(3) .022(4) .020(4)
C112 .083(4) .064(4) .154(7) .020(3) .049(5) .024(4)
C113 .116(5) .071(4) .172(7) .022(4) .097(5) -.010(5)
C114 .076(4) .057(4) .089(5) .005(3) .052(4) -.001(3)
C201 .026(2) .034(3) .037(3) -.002(2) .008(2) .000(2)
C202 .103(5) .037(3) .060(4) -.013(3) -.013(4) .006(3)
C203 .046(3) .030(3) .032(3) -.005(2) .010(2) -.002(2)
C204 .059(3) .060(4) .044(3) -.006(3) .018(3) .001(3)
C205 .077(4) .065(4) .032(3) .000(3) .000(3) .005(3)
C206 .050(3) .041(3) .066(4) -.001(3) -.013(3) .005(3)
C207 .045(3) .047(3) .071(4) .000(3) .014(3) .001(3)
C208 .055(3) .045(3) .041(3) -.001(3) .010(3) .000(3)
C209 .044(3) .102(5) .042(4) .004(3) .003(3) -.022(3)
C210 .161(7) .203(9) .240(10) -.102(6) .158(7) -.126(8)
C211 .210(10) .76(3) .300(10) -.280(10) .230(10) -.30(2)
C212 .090(6) .60(2) .103(7) -.044(9) .058(5) -.030(10)
C213 .247(9) .300(10) .134(8) .222(9) .110(7) .038(8)
C214 .213(8) .182(8) .137(7) .140(7) .124(7) .050(6)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_calc_attached_atom
_atom_site_occupancy
Ni .47838(4) .54671(2) .43614(5) .0304(2) Uani ? ? 1.00000
P .42624(8) .63672(5) .35380(10) .0331(6) Uani ? ? 1.00000
Si1 .18655(9) .49288(6) .49030(10) .0393(7) Uani ? ? 1.00000
Si2 .60156(9) .61091(5) .79330(10) .0403(7) Uani ? ? 1.00000
O11 .3472(2) .53080(10) .4481(2) .043(2) Uani ? ? 1.00000
O12 .6198(2) .54430(10) .4426(2) .048(2) Uani ? ? 1.00000
O21 .5333(2) .58310(10) .5813(2) .044(2) Uani ? ? 1.00000
O22 .4373(2) .49280(10) .3107(2) .043(2) Uani ? ? 1.00000
C1 .3987(3) .6876(2) .4402(3) .033(2) Uani ? ? 1.00000
C2 .3470(3) .6686(2) .4993(4) .052(3) Uani ? ? 1.00000
C3 .3169(4) .7056(2) .5613(4) .067(3) Uani ? ? 1.00000
C4 .3394(4) .7628(2) .5638(4) .063(3) Uani ? ? 1.00000
C5 .3897(4) .7817(2) .5057(4) .061(3) Uani ? ? 1.00000
C6 .4186(3) .7460(2) .4430(4) .046(3) Uani ? ? 1.00000
C7 .3131(3) .6383(2) .2309(3) .035(2) Uani ? ? 1.00000
C8 .2580(3) .6877(2) .1959(4) .060(3) Uani ? ? 1.00000
C9 .1728(3) .6880(2) .1044(4) .069(3) Uani ? ? 1.00000
C10 .1394(3) .6399(2) .0459(4) .056(3) Uani ? ? 1.00000
C11 .1923(3) .5908(2) .0785(4) .063(3) Uani ? ? 1.00000
C12 .2797(3) .5895(2) .1723(4) .050(3) Uani ? ? 1.00000
C13 .5217(3) .6702(2) .3177(3) .039(2) Uani ? ? 1.00000
C14 .6103(3) .6883(2) .3980(4) .059(3) Uani ? ? 1.00000
C15 .6867(4) .7105(2) .3732(5) .084(4) Uani ? ? 1.00000
C16 .6774(4) .7156(3) .2700(5) .100(5) Uani ? ? 1.00000
C17 .5924(4) .6973(3) .1896(5) .110(5) Uani ? ? 1.00000
C18 .5143(4) .6753(2) .2141(4) .075(4) Uani ? ? 1.00000
C101 .3215(3) .4941(2) .4993(3) .037(2) Uani ? ? 1.00000
C102 .1891(3) .4721(2) .6219(4) .062(3) Uani ? ? 1.00000
C103 .1185(3) .4371(2) .3891(4) .043(3) Uani ? ? 1.00000
C104 .0248(3) .4447(2) .3085(4) .051(3) Uani ? ? 1.00000
C105 -.0295(3) .4016(2) .2439(4) .072(3) Uani ? ? 1.00000
C106 .0112(4) .3478(2) .2579(4) .080(4) Uani ? ? 1.00000
C107 .1050(4) .3374(2) .3336(5) .087(4) Uani ? ? 1.00000
C108 .1570(3) .3829(2) .3981(4) .071(3) Uani ? ? 1.00000
C109 .1256(3) .5644(2) .4432(4) .044(3) Uani ? ? 1.00000
C110 .1143(3) .5861(2) .3450(4) .061(3) Uani ? ? 1.00000
C111 .0654(4) .6371(2) .3077(4) .077(4) Uani ? ? 1.00000
C112 .0287(4) .6666(2) .3693(5) .099(4) Uani ? ? 1.00000
C113 .0392(4) .6477(2) .4678(6) .107(5) Uani ? ? 1.00000
C114 .0880(4) .5958(2) .5045(4) .068(4) Uani ? ? 1.00000
C201 .5618(3) .5605(2) .6727(3) .033(2) Uani ? ? 1.00000
C202 .6254(4) .6829(2) .7465(4) .080(3) Uani ? ? 1.00000
C203 .7215(3) .5847(2) .8996(3) .037(2) Uani ? ? 1.00000
C204 .7374(3) .5818(2) 1.0065(4) .055(3) Uani ? ? 1.00000
C205 .8309(4) .5670(2) 1.0851(4) .065(3) Uani ? ? 1.00000
C206 .9075(3) .5556(2) 1.0550(4) .063(3) Uani ? ? 1.00000
C207 .8949(3) .5568(2) .9505(4) .057(3) Uani ? ? 1.00000
C208 .8027(3) .5712(2) .8732(4) .050(3) Uani ? ? 1.00000
C209 .4993(3) .6127(2) .8421(4) .067(3) Uani ? ? 1.00000
C210 .4525(5) .5669(3) .8525(7) .176(7) Uani ? ? 1.00000
C211 .3758(7) .5700(7) .8869(9) .39(2) Uani ? ? 1.00000
C212 .3457(5) .6076(5) .9173(6) .260(10) Uani ? ? 1.00000
C213 .3869(6) .6629(4) .9059(6) .217(8) Uani ? ? 1.00000
C214 .4664(6) .6626(3) .8706(6) .160(7) Uani ? ? 1.00000
H2 .335(2) .6370(10) .501(3) .040(10) Uiso ? ? 1.00000
H3 .281(2) .6890(10) .599(3) .060(10) Uiso ? ? 1.00000
H4 .316(2) .7840(10) .612(3) .060(10) Uiso calc C4 1.00000
H5 .404(3) .815(2) .508(3) .070(10) Uiso ? ? 1.00000
H6 .454(2) .7560(10) .403(2) .030(10) Uiso ? ? 1.00000
H8 .273(2) .7160(10) .233(3) .050(10) Uiso ? ? 1.00000
H9 .138(2) .7150(10) .087(3) .030(10) Uiso ? ? 1.00000
H10 .082(3) .6410(10) -.017(3) .060(10) Uiso ? ? 1.00000
H11 .170(2) .5650(10) .040(3) .060(10) Uiso ? ? 1.00000
H12 .318(2) .5510(10) .195(2) .030(10) Uiso ? ? 1.00000
H14 .613(3) .685(2) .472(3) .070(10) Uiso calc C14 1.00000
H15 .736(3) .724(2) .423(3) .09(2) Uiso ? ? 1.00000
H16 .734(3) .732(2) .250(4) .12(2) Uiso ? ? 1.00000
H17 .586(3) .700(2) .121(3) .09(2) Uiso ? ? 1.00000
H18 .458(2) .6650(10) .163(3) .070(10) Uiso ? ? 1.00000
H1021 .225(3) .498(2) .678(3) .070(10) Uiso ? ? 1.00000
H1022 .125(3) .462(2) .628(3) .080(10) Uiso ? ? 1.00000
H1023 .225(3) .439(2) .645(3) .070(10) Uiso ? ? 1.00000
H104 .001(2) .4800(10) .305(2) .020(9) Uiso ? ? 1.00000
H105 -.091(3) .407(2) .189(3) .080(10) Uiso ? ? 1.00000
H106 -.024(3) .324(2) .206(3) .09(2) Uiso ? ? 1.00000
H107 .140(3) .300(2) .335(3) .11(2) Uiso ? ? 1.00000
H108 .214(2) .3760(10) .443(3) .050(10) Uiso ? ? 1.00000
H110 .140(2) .5690(10) .295(3) .050(10) Uiso ? ? 1.00000
H111 .070(3) .645(2) .242(3) .070(10) Uiso ? ? 1.00000
H112 -.012(3) .698(2) .347(3) .080(10) Uiso ? ? 1.00000
H113 .009(3) .664(2) .505(4) .13(2) Uiso ? ? 1.00000
H114 .100(2) .5860(10) .583(3) .040(10) Uiso ? ? 1.00000
H2021 .646(2) .7030(10) .803(3) .060(10) Uiso ? ? 1.00000
H2022 .573(3) .696(2) .691(3) .09(2) Uiso ? ? 1.00000
H2023 .665(4) .687(3) .703(5) .26(3) Uiso ? ? 1.00000
H204 .689(3) .582(2) 1.029(3) .070(10) Uiso ? ? 1.00000
H205 .834(2) .5690(10) 1.153(3) .040(10) Uiso ? ? 1.00000
H206 .965(2) .550(2) 1.100(3) .070(10) Uiso ? ? 1.00000
H207 .946(2) .5510(10) .926(3) .050(10) Uiso ? ? 1.00000
H208 .791(2) .5730(10) .791(3) .050(10) Uiso ? ? 1.00000
H210 .479(3) .526(2) .849(3) .080(10) Uiso calc C210 1.00000
H211 .359(5) .542(3) .895(6) .31(4) Uiso calc C211 1.00000
H212 .303(5) .610(3) .942(5) .26(3) Uiso calc C212 1.00000
H213 .384(3) .699(2) .921(3) .09(2) Uiso calc C213 1.00000
H214 .506(4) .692(2) .860(5) .19(3) Uiso calc C214 1.00000
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P Ni O11 . 93.78(8) yes
P Ni O12 . 100.23(9) yes
P Ni O21 . 90.86(8) yes
P Ni O22 . 103.07(8) yes
P Ni Ni 3_666 166.66(5) yes
O11 Ni O12 . 166.00(10) yes
O11 Ni O21 . 91.50(10) yes
O11 Ni O22 . 88.50(10) yes
O11 Ni Ni 3_666 77.78(8) yes
O12 Ni O21 . 87.80(10) yes
O12 Ni O22 . 88.80(10) yes
O12 Ni Ni 3_666 88.35(9) yes
O21 Ni O22 . 166.00(10) yes
O21 Ni Ni 3_666 79.19(8) yes
O22 Ni Ni 3_666 87.17(8) yes
Ni P C1 . 113.00(10) no
Ni P C7 . 117.10(10) no
Ni P C13 . 112.10(10) no
C1 P C7 . 103.3(2) no
C1 P C13 . 105.7(2) no
C7 P C13 . 104.6(2) no
C101 Si1 C102 . 108.0(2) no
C101 Si1 C103 . 106.8(2) no
C101 Si1 C109 . 109.9(2) no
C102 Si1 C103 . 109.4(2) no
C102 Si1 C109 . 113.3(2) no
C103 Si1 C109 . 109.3(2) no
C201 Si2 C202 . 107.4(2) no
C201 Si2 C203 . 109.5(2) no
C201 Si2 C209 . 107.7(2) no
C202 Si2 C203 . 108.5(2) no
C202 Si2 C209 . 112.3(3) no
C203 Si2 C209 . 111.3(2) no
Ni O11 C101 . 132.0(2) yes
Ni O12 C101 3_666 117.9(3) yes
Ni O21 C201 . 129.7(2) yes
Ni O22 C201 3_666 119.2(3) yes
P C1 C2 . 118.0(3) no
P C1 C6 . 124.4(4) no
C2 C1 C6 . 117.3(4) no
C1 C2 C3 . 121.6(4) no
C1 C2 H2 . 121(3) no
C3 C2 H2 . 117(3) no
C2 C3 C4 . 119.6(6) no
C2 C3 H3 . 116(2) no
C4 C3 H3 . 125(2) no
C3 C4 C5 . 119.1(5) no
C3 C4 H4 . 112(2) no
C5 C4 H4 . 129(2) no
C4 C5 C6 . 122.0(4) no
C4 C5 H5 . 119(3) no
C6 C5 H5 . 119(3) no
C1 C6 C5 . 120.4(5) no
C1 C6 H6 . 114(2) no
C5 C6 H6 . 126(2) no
P C7 C8 . 121.5(3) no
P C7 C12 . 120.1(3) no
C8 C7 C12 . 118.4(3) no
C7 C8 C9 . 120.8(4) no
C7 C8 H8 . 120(2) no
C9 C8 H8 . 119(2) no
C8 C9 C10 . 121.1(4) no
C8 C9 H9 . 121(2) no
C10 C9 H9 . 117(2) no
C9 C10 C11 . 119.2(4) no
C9 C10 H10 . 120(2) no
C11 C10 H10 . 121(2) no
C10 C11 C12 . 120.6(4) no
C10 C11 H11 . 114(2) no
C12 C11 H11 . 125(2) no
C7 C12 C11 . 119.8(4) no
C7 C12 H12 . 122.0(10) no
C11 C12 H12 . 119.0(10) no
P C13 C14 . 119.3(4) no
P C13 C18 . 123.4(3) no
C14 C13 C18 . 117.1(5) no
C13 C14 C15 . 120.6(5) no
C13 C14 H14 . 115(2) no
C15 C14 H14 . 124(2) no
C14 C15 C16 . 121.2(5) no
C14 C15 H15 . 118(4) no
C16 C15 H15 . 121(4) no
C15 C16 C17 . 119.6(6) no
C15 C16 H16 . 122(2) no
C17 C16 H16 . 118(3) no
C16 C17 C18 . 119.4(6) no
C16 C17 H17 . 121(3) no
C18 C17 H17 . 120(3) no
C13 C18 C17 . 121.9(4) no
C13 C18 H18 . 118(3) no
C17 C18 H18 . 120(3) no
Si1 C101 O11 . 119.5(3) yes
Si1 C101 O12 3_666 116.6(3) yes
O11 C101 O12 3_666 123.9(4) yes
Si1 C102 H1021 . 113(3) no
Si1 C102 H1022 . 119(2) no
Si1 C102 H1023 . 111(3) no
H1021 C102 H1022 . 109(4) no
H1021 C102 H1023 . 102(3) no
H1022 C102 H1023 . 100(3) no
Si1 C103 C104 . 124.2(3) no
Si1 C103 C108 . 120.1(3) no
C104 C103 C108 . 115.5(4) no
C103 C104 C105 . 123.5(4) no
C103 C104 H104 . 114(2) no
C105 C104 H104 . 123(2) no
C104 C105 C106 . 118.8(4) no
C104 C105 H105 . 123(2) no
C106 C105 H105 . 118(2) no
C105 C106 C107 . 121.0(5) no
C105 C106 H106 . 112(2) no
C107 C106 H106 . 126(2) no
C106 C107 C108 . 117.8(5) no
C106 C107 H107 . 121(2) no
C108 C107 H107 . 121(2) no
C103 C108 C107 . 123.3(4) no
C103 C108 H108 . 121(2) no
C107 C108 H108 . 116(2) no
Si1 C109 C110 . 121.4(4) no
Si1 C109 C114 . 121.1(4) no
C110 C109 C114 . 117.4(4) no
C109 C110 C111 . 121.8(5) no
C109 C110 H110 . 126(2) no
C111 C110 H110 . 113(2) no
C110 C111 C112 . 119.3(6) no
C110 C111 H111 . 107(2) no
C112 C111 H111 . 133(2) no
C111 C112 C113 . 121.6(5) no
C111 C112 H112 . 125(3) no
C113 C112 H112 . 113(3) no
C112 C113 C114 . 118.8(7) no
C112 C113 H113 . 123(3) no
C114 C113 H113 . 118(3) no
C109 C114 C113 . 121.2(6) no
C109 C114 H114 . 124(2) no
C113 C114 H114 . 115(2) no
Si2 C201 O21 . 116.9(3) yes
Si2 C201 O22 3_666 118.5(3) yes
O21 C201 O22 3_666 124.5(4) yes
Si2 C202 H2021 . 104(3) no
Si2 C202 H2022 . 113(3) no
Si2 C202 H2023 . 121(4) no
H2021 C202 H2022 . 117(4) no
H2021 C202 H2023 . 114(5) no
H2022 C202 H2023 . 88(5) no
Si2 C203 C204 . 123.4(4) no
Si2 C203 C208 . 119.9(3) no
C204 C203 C208 . 116.6(4) no
C203 C204 C205 . 121.9(5) no
C203 C204 H204 . 123(2) no
C205 C204 H204 . 114(2) no
C204 C205 C206 . 118.9(5) no
C204 C205 H205 . 114(2) no
C206 C205 H205 . 127(2) no
C205 C206 C207 . 121.3(4) no
C205 C206 H206 . 121(3) no
C207 C206 H206 . 118(3) no
C206 C207 C208 . 119.7(5) no
C206 C207 H207 . 124(2) no
C208 C207 H207 . 116(2) no
C203 C208 C207 . 121.6(5) no
C203 C208 H208 . 117(2) no
C207 C208 H208 . 121(2) no
Si2 C209 C210 . 122.8(5) no
Si2 C209 C214 . 122.3(5) no
C210 C209 C214 . 114.9(7) no
C209 C210 C211 . 121.2(9) no
C209 C210 H210 . 122(3) no
C211 C210 H210 . 116(3) no
C210 C211 C212 . 130.0(10) no
C210 C211 H211 . 112(7) no
C212 C211 H211 . 117(8) no
C211 C212 C213 . 115.0(10) no
C211 C212 H212 . 133(5) no
C213 C212 H212 . 112(5) no
C212 C213 C214 . 117.0(8) no
C212 C213 H213 . 141(3) no
C214 C213 H213 . 101(3) no
C209 C214 C213 . 121.2(7) no
C209 C214 H214 . 107(4) no
C213 C214 H214 . 132(4) no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ni P . 2.3680(10) yes
Ni O11 . 2.001(3) yes
Ni O12 . 2.013(3) yes
Ni O21 . 2.002(3) yes
Ni O22 . 2.013(3) yes
Ni Ni 3_666 2.7079(8) yes
P C1 . 1.821(5) no
P C7 . 1.824(4) no
P C13 . 1.812(5) no
Si1 C101 . 1.908(5) yes
Si1 C102 . 1.833(6) no
Si1 C103 . 1.873(4) no
Si1 C109 . 1.884(4) no
Si2 C201 . 1.914(4) yes
Si2 C202 . 1.881(5) no
Si2 C203 . 1.874(4) no
Si2 C209 . 1.841(6) no
O11 C101 . 1.249(6) yes
O12 C101 3_666 1.275(5) yes
O21 C201 . 1.259(5) yes
O22 C201 3_666 1.268(5) yes
C1 C2 . 1.365(8) no
C1 C6 . 1.395(6) no
C2 C3 . 1.390(8) no
C2 H2 . .76(3) no
C3 C4 . 1.377(7) no
C3 H3 . .94(4) no
C4 C5 . 1.336(9) no
C4 H4 . .99(4) no
C5 C6 . 1.368(8) no
C5 H5 . .81(4) no
C6 H6 . .90(4) no
C7 C8 . 1.380(6) no
C7 C12 . 1.369(6) no
C8 C9 . 1.365(6) no
C8 H8 . .82(3) no
C9 C10 . 1.354(6) no
C9 H9 . .79(3) no
C10 C11 . 1.358(6) no
C10 H10 . .93(3) no
C11 C12 . 1.401(5) no
C11 H11 . .79(3) no
C12 H12 . 1.03(3) no
C13 C14 . 1.386(5) no
C13 C18 . 1.370(8) no
C14 C15 . 1.376(8) no
C14 H14 . 1.00(4) no
C15 C16 . 1.360(10) no
C15 H15 . .83(3) no
C16 C17 . 1.357(7) no
C16 H16 . 1.03(5) no
C17 C18 . 1.390(10) no
C17 H17 . .90(5) no
C18 H18 . .87(3) no
C102 H1021 . .95(3) no
C102 H1022 . 1.00(4) no
C102 H1023 . .92(3) no
C103 C104 . 1.381(5) no
C103 C108 . 1.372(6) no
C104 C105 . 1.367(6) no
C104 H104 . .90(3) no
C105 C106 . 1.372(7) no
C105 H105 . .92(3) no
C106 C107 . 1.367(7) no
C106 H106 . .88(4) no
C107 C108 . 1.398(7) no
C107 H107 . 1.01(4) no
C108 H108 . .83(3) no
C109 C110 . 1.373(7) no
C109 C114 . 1.371(8) no
C110 C111 . 1.381(7) no
C110 H110 . .98(4) no
C111 C112 . 1.340(10) no
C111 H111 . .93(4) no
C112 C113 . 1.360(10) no
C112 H112 . .92(4) no
C113 C114 . 1.397(7) no
C113 H113 . .86(6) no
C114 H114 . 1.04(4) no
C202 H2021 . .85(4) no
C202 H2022 . .89(3) no
C202 H2023 . .98(8) no
C203 C204 . 1.376(7) no
C203 C208 . 1.391(7) no
C204 C205 . 1.400(6) no
C204 H204 . .87(4) no
C205 C206 . 1.347(8) no
C205 H205 . .91(4) no
C206 C207 . 1.354(8) no
C206 H206 . .83(3) no
C207 C208 . 1.378(5) no
C207 H207 . .93(4) no
C208 H208 . 1.06(4) no
C209 C210 . 1.310(10) no
C209 C214 . 1.370(10) no
C210 C211 . 1.36(2) no
C210 H210 . 1.03(4) no
C211 C212 . 1.13(2) no
C211 H211 . .72(8) no
C212 C213 . 1.46(2) no
C212 H212 . .82(8) no
C213 C214 . 1.410(10) no
C213 H213 . .88(4) no
C214 H214 . .94(6) no