#------------------------------------------------------------------------------
#$Date: 2009-11-18 14:56:34 +0000 (Wed, 18 Nov 2009) $
#$Revision: 858 $
#$URL: svn://www.crystallography.net/cod/cif/2/2000751.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000751
loop_
_publ_author_name
'Ferguson, G.'
'Gallagher, J. F.'
'Murphy, D.'
'Spalding, T. R.'
'Glidewell, C.'
'Holden, H. D.'
_publ_section_title
;
 The structure of triphenylgermanium hydroxide
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1228
_journal_page_last               1231
_journal_volume                  48
_journal_year                    1992
_chemical_formula_sum            'C18 H16 Ge O'
_[local]_cod_chemical_formula_sum_orig 'C18 H16 Ge1 O1'
_chemical_formula_weight         320.9
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                107.78(4)
_cell_angle_beta                 103.54(4)
_cell_angle_gamma                101.51(3)
_cell_formula_units_Z            16
_cell_length_a                   15.408(6)
_cell_length_b                   19.974(7)
_cell_length_c                   23.264(11)
_cell_volume                     6338(5)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    1.91
_exptl_crystal_density_diffrn    1.34
_exptl_crystal_F_000             2624
_[local]_cod_data_source_file    mu0293.cif
_[local]_cod_data_source_block   mu0293a
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Ge(A) .28796(9) .55609(7) .37920(6)
Ge(B) .27623(8) .27744(7) .25176(6)
Ge(C) .04338(8) .35697(7) .08954(6)
Ge(D) -.06364(9) .37119(8) .29751(6)
Ge(E) .77599(8) .77987(7) .23371(6)
Ge(F) .77179(9) 1.04706(7) .37068(6)
Ge(G) .41413(8) .86165(7) .28845(6)
Ge(J) .52071(8) .85023(7) .08200(6)
OA .2117(6) .4663(4) .3271(4)
OB .2352(5) .3538(4) .2458(4)
OC .0818(5) .3529(4) .1667(3)
OD .0361(5) .3916(5) .2722(4)
OE .7131(5) .8435(4) .2241(3)
OF .7009(5) .9584(4) .3134(4)
OG .5192(5) .8884(5) .2697(4)
OJ .5484(5) .8444(4) .1592(3)
C(11A) .3204(7) .5559(5) .4639(3)
C(12A) .2506(5) .5288(5) .4868(4)
C(13A) .2738(7) .5283(5) .5483(5)
C(14A) .3668(8) .5550(5) .5870(3)
C(15A) .4366(5) .5821(5) .5641(4)
C(16A) .4134(6) .5826(5) .5026(5)
C(21A) .2199(5) .6250(4) .3701(4)
C(22A) .2014(6) .6697(5) .4221(3)
C(23A) .1508(6) .7187(5) .4145(4)
C(24A) .1186(6) .7231(4) .3549(5)
C(25A) .1370(6) .6784(5) .3029(4)
C(26A) .1877(6) .6294(5) .3104(3)
C(31A) .3945(5) .5733(5) .3501(4)
C(32A) .4501(6) .6456(4) .3704(4)
C(33A) .5264(6) .6612(4) .3491(4)
C(34A) .5470(5) .6043(6) .3074(4)
C(35A) .4914(7) .5320(5) .2870(4)
C(36A) .4151(6) .5164(4) .3084(4)
C(11B) .2987(5) .2809(5) .3386(3)
C(12B) .3147(6) .2201(4) .3519(4)
C(13B) .3337(6) .2220(5) .4141(5)
C(14B) .3366(6) .2847(7) .4630(3)
C(15B) .3206(7) .3454(5) .4496(4)
C(16B) .3016(6) .3435(4) .3874(4)
C(21B) .1815(5) .1886(3) .1897(3)
C(22B) .0888(6) .1782(4) .1886(4)
C(23B) .0203(4) .1141(5) .1452(4)
C(24B) .0444(5) .0605(4) .1027(4)
C(25B) .1371(6) .0709(4) .1037(3)
C(26B) .2056(4) .1350(4) .1472(4)
C(31B) .3884(4) .2873(4) .2289(4)
C(32B) .4601(6) .2630(4) .2567(4)
C(33B) .5407(5) .2690(5) .2389(4)
C(34B) .5498(5) .2992(5) .1931(4)
C(35B) .4781(7) .3235(5) .1653(4)
C(36B) .3974(6) .3176(5) .1831(4)
C(11C) -.0117(5) .4368(3) .0976(4)
C(12C) -.0144(5) .4796(4) .1567(3)
C(13C) -.0548(6) .5369(4) .1618(3)
C(14C) -.0924(5) .5514(3) .1078(4)
C(15C) -.0897(5) .5086(4) .0487(3)
C(16C) -.0494(5) .4513(4) .0436(3)
C(21C) .1547(5) .3737(4) .0653(4)
C(22C) .2384(6) .4223(4) .1101(3)
C(23C) .3183(5) .4363(4) .0920(4)
C(24C) .3145(5) .4016(5) .0292(5)
C(25C) .2307(7) .3530(5) -.0156(3)
C(26C) .1509(5) .3390(4) .0024(3)
C(31C) -.0469(5) .2634(3) .0326(3)
C(32C) -.1367(6) .2582(4) -.0020(4)
C(33C) -.1999(4) .1894(5) -.0406(3)
C(34C) -.1732(6) .1258(3) -.0446(4)
C(35C) -.0834(6) .1310(4) -.0100(4)
C(36C) -.0202(4) .1998(5) .0286(4)
C(11D) -.1445(5) .2776(4) .2374(4)
C(12D) -.1506(6) .2564(5) .1733(4)
C(13D) -.2105(7) .1883(5) .1298(3)
C(14D) -.2645(6) .1415(4) .1504(4)
C(15D) -.2584(7) .1627(5) .2145(5)
C(16D) -.1984(7) .2307(5) .2580(3)
C(21D) -.0186(6) .3677(5) .3810(3)
C(22D) .0523(7) .3356(6) .3948(4)
C(23D) .0833(6) .3323(6) .4549(5)
C(24D) .0434(7) .3611(6) .5013(3)
C(25D) -.0275(7) .3932(6) .4876(4)
C(26D) -.0584(6) .3965(5) .4274(4)
C(31D) -.1217(6) .4492(4) .2996(4)
C(32D) -.2184(6) .4338(4) .2854(4)
C(33D) -.2597(5) .4905(6) .2903(4)
C(34D) -.2043(8) .5628(5) .3094(4)
C(35D) -.1076(7) .5782(4) .3237(4)
C(36D) -.0664(4) .5214(5) .3188(4)
C(11E) .6942(5) .6822(3) .1805(3)
C(12E) .6049(6) .6721(4) .1415(4)
C(13E) .5471(5) .6012(5) .1032(4)
C(14E) .5785(6) .5405(4) .1039(4)
C(15E) .6677(7) .5507(4) .1429(4)
C(16E) .7255(5) .6215(5) .1812(4)
C(21E) .8088(7) .7908(5) .3216(3)
C(22E) .7389(5) .7838(6) .3500(5)
C(23E) .7610(8) .7870(7) .4126(5)
C(24E) .8531(9) .7972(6) .4469(3)
C(25E) .9231(7) .8042(6) .4185(5)
C(26E) .9009(6) .8010(6) .3558(5)
C(31E) .8849(5) .7994(6) .2053(5)
C(32E) .9488(7) .7591(6) .2095(6)
C(33E) 1.0253(7) .7734(7) .1880(6)
C(34E) 1.0378(6) .8279(7) .1623(5)
C(35E) .9738(8) .8682(6) .1582(6)
C(36E) .8974(7) .8539(6) .1796(6)
C(11F) .8048(6) 1.0408(5) .4538(3)
C(12F) .8608(7) .9962(5) .4648(4)
C(13F) .8890(7) .9921(5) .5248(5)
C(14F) .8612(7) 1.0326(6) .5739(4)
C(15F) .8051(8) 1.0771(6) .5630(4)
C(16F) .7769(6) 1.0812(5) .5029(5)
C(21F) .8794(5) 1.0693(5) .3442(4)
C(22F) .8728(6) 1.0342(6) .2808(4)
C(23F) .9499(9) 1.0497(8) .2603(4)
C(24F) 1.0337(6) 1.1004(7) .3032(6)
C(25F) 1.0404(5) 1.1356(6) .3666(5)
C(26F) .9632(7) 1.1200(6) .3871(3)
C(31F) .7004(5) 1.1159(4) .3709(3)
C(32F) .7456(4) 1.1913(5) .3977(4)
C(33F) .6935(7) 1.2413(3) .4020(4)
C(34F) .5961(7) 1.2158(5) .3795(4)
C(35F) .5510(4) 1.1404(5) .3527(4)
C(36F) .6031(6) 1.0905(3) .3484(3)
C(11G) .3475(6) .9310(4) .2786(5)
C(12G) .3013(8) .9570(6) .3217(4)
C(13G) .2489(8) 1.0046(6) .3127(5)
C(14G) .2426(7) 1.0261(5) .2605(6)
C(15G) .2888(7) 1.0000(5) .2174(4)
C(16G) .3412(6) .9525(5) .2264(4)
C(21G) .3425(6) .7627(4) .2290(3)
C(22G) .2525(6) .7483(4) .1890(4)
C(23G) .2015(5) .6765(5) .1482(4)
C(24G) .2406(7) .6190(4) .1474(4)
C(25G) .3306(7) .6334(4) .1874(5)
C(26G) .3815(5) .7052(5) .2283(4)
C(31G) .4549(6) .8661(5) .3744(3)
C(32G) .3933(5) .8293(4) .3978(4)
C(33G) .4205(6) .8367(5) .4616(4)
C(34G) .5095(7) .8808(6) .5019(3)
C(35G) .5711(5) .9176(6) .4785(4)
C(36G) .5439(6) .9102(6) .4148(4)
C(11J) .6343(4) .8611(5) .0587(4)
C(12J) .6458(5) .8052(4) .0104(4)
C(13J) .7277(6) .8160(5) -.0058(4)
C(14J) .7983(5) .8826(6) .0264(4)
C(15J) .7869(5) .9384(4) .0748(4)
C(16J) .7049(6) .9277(4) .0909(3)
C(21J) .4811(5) .9378(4) .0930(4)
C(22J) .5103(5) .9956(5) .1518(3)
C(23J) .4848(6) 1.0598(4) .1567(4)
C(24J) .4302(6) 1.0663(4) .1028(5)
C(25J) .4010(6) 1.0085(6) .0440(4)
C(26J) .4265(6) .9443(4) .0391(3)
C(31J) .4251(4) .7601(3) .0242(3)
C(32J) .3897(5) .7453(4) -.0408(4)
C(33J) .3211(5) .6794(5) -.0804(3)
C(34J) .2880(5) .6283(4) -.0551(4)
C(35J) .3234(5) .6432(4) .0098(4)
C(36J) .3920(5) .7090(5) .0495(3)
H(12A) .1872 .5106 .4605
H(13A) .2262 .5098 .5639
H(14A) .3826 .5547 .6289
H(15A) .5000 .6003 .5904
H(16A) .4610 .6011 .4870
H(22A) .2233 .6667 .4627
H(23A) .1382 .7491 .4500
H(24A) .0841 .7565 .3498
H(25A) .1151 .6814 .2623
H(26A) .2003 .5990 .2750
H(32A) .4361 .6843 .3988
H(33A) .5643 .7104 .3629
H(34A) .5990 .6149 .2929
H(35A) .5054 .4933 .2587
H(36A) .3772 .4672 .2945
H(12B) .3127 .1774 .3187
H(13B) .3446 .1806 .4232
H(14B) .3496 .2860 .5054
H(15B) .3226 .3881 .4829
H(16B) .2907 .3849 .3783
H(22B) .0724 .2147 .2175
H(23B) -.0429 .1070 .1445
H(24B) -.0023 .0169 .0731
H(25B) .1535 .0344 .0748
H(26B) .2688 .1421 .1479
H(32B) .4539 .2424 .2879
H(33B) .5896 .2524 .2578
H(34B) .6047 .3033 .1810
H(35B) .4843 .3442 .1341
H(36B) .3486 .3341 .1642
H(12C) .0112 .4697 .1934
H(13C) -.0566 .5661 .2020
H(14C) -.1199 .5904 .1112
H(15C) -.1153 .5185 .0119
H(16C) -.0475 .4221 .0033
H(22C) .2410 .4459 .1529
H(23C) .3753 .4694 .1225
H(24C) .3689 .4111 .0169
H(25C) .2281 .3294 -.0584
H(26C) .0938 .3059 -.0281
H(32C) -.1549 .3015 .0007
H(33C) -.2611 .1859 -.0642
H(34C) -.2162 .0789 -.0710
H(35C) -.0652 .0876 -.0128
H(36C) .0410 .2033 .0522
H(12D) -.1138 .2883 .1592
H(13D) -.2147 .1739 .0861
H(14D) -.3053 .0952 .1208
H(15D) -.2951 .1308 .2286
H(16D) -.1943 .2452 .3017
H(22D) .0795 .3160 .3632
H(23D) .1316 .3105 .4643
H(24D) .0645 .3588 .5423
H(25D) -.0546 .4127 .5192
H(26D) -.1067 .4183 .4181
H(32D) -.2561 .3846 .2723
H(33D) -.3255 .4800 .2806
H(34D) -.2324 .6014 .3128
H(35D) -.0699 .6274 .3367
H36D -.0005 .5319 .3284
H12E .5836 .7134 .1411
H13E .4864 .5943 .0767
H14E .5391 .4922 .0778
H15E .6891 .5093 .1434
H16E .7863 .6284 .2078
H22E .6761 .7768 .3267
H23E .7134 .7823 .4320
H24E .8682 .7994 .4896
H25E .9858 .8112 .4418
H26E .9485 .8057 .3365
H32E .9403 .7220 .2269
H33E 1.0688 .7460 .1909
H34E 1.0898 .8376 .1477
H35E .9823 .9053 .1407
H36E .8538 .8813 .1768
H12F .8798 .9686 .4314
H13F .9272 .9618 .5323
H14F .8804 1.0298 .6148
H15F .7861 1.047 .5964
H16F .7387 1.1116 .4955
H22F .8157 .9997 .2516
H23F .9454 1.0258 .2172
H24F 1.0863 1.1110 .2892
H25F 1.0975 1.1701 .3958
H26F .9678 1.1439 .4330
H32F .8118 1.2087 .4130
H33F .7242 1.2926 .4203
H34F .5607 1.2498 .3825
H35F .4847 1.1231 .3374
H36F .5723 1.0392 .3301
H12G .3056 .9424 .3572
H13G .2175 1.0223 .3421
H14G .2069 1.0584 .2544
H15G .2845 1.0147 .1819
H16G .3726 .9348 .1971
H22G .2260 .7874 .1895
H23G .1403 .6667 .1209
H24G .2058 .5701 .1196
H25G .3571 .5943 .1869
H26G .4428 .7150 .2555
H32G .3327 .7993 .3704
H33G .3785 .8117 .4775
H34G .5280 .8859 .5453
H35G .6317 .9477 .5060
H36G .5859 .9353 .3988
H12J .5977 .7599 -.0115
H13J .735 .7779 -.0387
H14J .8541 .8899 .0154
H15J .8349 .9838 .0967
H16J .6971 .9658 .1238
H22J .5475 .9912 .1885
H23J .5047 1.0992 .1967
H24J .4128 1.1100 .1061
H25J .3638 1.0129 .0073
H26J .4066 .9049 -.0009
H32J .4123 .7800 -.0580
H33J .2970 .6693 -.1247
H34J .2413 .5835 -.0822
H35J .3008 .6084 .0271
H36J .4161 .7191 .0938
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ge(A) OA 1.798(8)
Ge(A) C(31A) 1.925(9)
Ge(B) C(21B) 1.944(5)
Ge(C) C(11C) 1.932(8)
Ge(D) OD 1.788(7)
Ge(D) C(31D) 1.940(10)
Ge(E) C(21E) 1.919(7)
Ge(F) C(11F) 1.931(9)
Ge(G) OG 1.796(7)
Ge(G) C(31G) 1.920(7)
Ge(J) C(21J) 1.930(8)
Ge(A) C(11A) 1.918(8)
Ge(B) OB 1.794(7)
Ge(B) C(31B) 1.915(8)
Ge(C) C(21C) 1.926(8)
Ge(D) C(11D) 1.914(6)
Ge(E) OE 1.780(7)
Ge(E) C(31E) 1.955(10)
Ge(F) C(21F) 1.918(9)
Ge(G) C(11G) 1.918(10)
Ge(J) OJ 1.792(7)
Ge(J) C(31J) 1.938(5)
Ge(A) C(21A) 1.921(9)
Ge(B) C(11B) 1.945(8)
Ge(C) OC 1.787(7)
Ge(C) C(31C) 1.942(6)
Ge(D) C(21D) 1.932(8)
Ge(E) C(11E) 1.934(6)
Ge(F) OF 1.791(7)
Ge(F) C(31F) 1.925(9)
Ge(G) C(21G) 1.945(6)
Ge(J) C(11J) 1.942(8)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
OA Ge(A) C(11A) 107.4(4)
OA Ge(A) C(31A) 107.1(4)
C(11A) Ge(A) C(31A) 112.9(4)
OB Ge(B) C(11B) 108.7(4)
OB Ge(B) C(31B) 106.7(4)
C(11B) Ge(B) C(31B) 111.8(4)
OC Ge(C) C(11C) 107.5(4)
OC Ge(C) C(31C) 108.3(3)
C(11C) Ge(C) C(31C) 111.5(3)
OD Ge(D) C(11D) 107.2(4)
OD Ge(D) C(31D) 107.5(4)
C(11D) Ge(D) C(31D) 112.1(3)
OE Ge(E) C(11E) 107.6(3)
OE Ge(E) C(31E) 108.7(4)
C(11E) Ge(E) C(13E) 109.5(4)
OF Ge(F) C(11F) 108.7(4)
Of Ge(F) C(31F) 108.7(3)
C(11F) Ge(F) C(31F) 108.9(4)
OG Ge(G) C(11G) 106.2(4)
OG Ge(G) C(31G) 105.3(4)
C(11G) Ge(G) C(31G) 113.4(4)
OA Ge(A) C(21A) 106.7(3)
C(11A) Ge(A) C(21A) 112.4(4)
C(21A) Ge(A) C(31A) 109.9(4)
OB Ge(B) C(21B) 107.1(3)
C(11B) Ge(B) C(21B) 112.9(3)
C(21B) Ge(B) C(31B) 109.3(3)
OC Ge(C) C(21C) 104.7(4)
C(11C) Ge(C) C(21C) 112.9(4)
C(21C) Ge(C) C(31C) 111.5(3)
OD Ge(D) C(21D) 106.8(4)
C(11D) Ge(D) C(21D) 111.2(4)
C(21D) Ge(D) C(31D) 111.7(4)
OE Ge(E) C(21E) 107.8(4)
C(11E) Ge(E) C(21E) 110.3(4)
C(21E) Ge(E) C(31E) 112.8(4)
OF Ge(F) C(21F) 105.0(4)
C(11F) Ge(F) C(21F) 111.7(4)
C(21F) Ge(F) C(31F) 113.6(4)
OG Ge(G) C(21G) 108.5(4)
C(11G) Ge(G) C(21G) 111.0(3)
C(21G) Ge(G) C(31G) 112.0(4)