#------------------------------------------------------------------------------
#$Date: 2009-11-18 14:56:34 +0000 (Wed, 18 Nov 2009) $
#$Revision: 858 $
#$URL: svn://www.crystallography.net/cod/cif/2/2000811.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000811
loop_
_publ_author_name
'Chiang, H.-C.'
'Lin, S.-M.'
'Ueng, C.-H.'
_publ_section_title
;
 Synthesis and structure of
 dihydroxo(\h^3^-2,2'-iminodiethoxo)germanium(IV)
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              991
_journal_page_last               993
_journal_volume                  48
_journal_year                    1992
_chemical_formula_sum            'C4 H11 Ge N O4'
_[local]_cod_chemical_formula_sum_orig 'C4 H11 Ge1 N1 O4'
_chemical_formula_weight         209.6
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 94.87(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.161(2)
_cell_length_b                   12.251(4)
_cell_length_c                   11.266(3)
_cell_volume                     709.8(3)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.7093
_exptl_absorpt_coefficient_mu    4.21
_exptl_crystal_density_diffrn    1.96
_exptl_crystal_F_000             424
_[local]_cod_data_source_file    as0538.cif
_[local]_cod_data_source_block   as0538a
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Ge .00293(9) .14709(4) .15760(5)
N -.2573(8) .2551(3) .2346(4)
O1 .1873(7) .2690(3) .1369(3)
O2 .0305(7) .0852(3) .3021(3)
O3 .2311(6) .0566(3) .0972(3)
O4 -.2650(7) .1140(3) .0566(3)
C1 -.0885(13) .1377(5) .3943(5)
C2 -.3217(12) .1995(5) .3463(5)
C3 -.1161(12) .3585(4) .2543(6)
C4 .0595(13) .3696(4) .1561(6)
HN -.428 .258 .192
HO3 .418 .087 .105
HO4 -.204 .073 .013
H1A -.139 .085 .456
H1B .038 .193 .436
H2A -.469 .147 .329
H2B -.374 .255 .405
H3A -.246 .422 .256
H3B -.014 .357 .334
H4A .186 .431 .173
H4B -.052 .391 .078
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ge N 2.123(4)
Ge O1 1.797(3)
Ge O2 1.791(4)
Ge O3 1.793(3)
Ge O4 1.762(4)
N C2 1.493(7)
N C3 1.469(7)
N HN 0.964(4)
O1 C4 1.423(7)
O2 C1 1.406(7)
O3 HO3 1.028(3)
O4 HO4 0.790(3)
C1 C2 1.484(9)
C1 H1A 0.999(6)
C1 H1B 1.025(7)
C2 H2A 1.005(7)
C2 H2B 1.003(6)
C3 C4 1.495(9)
C3 H3A 1.027(6)
C3 H3B 1.004(7)
C4 H4A 1.004(6)
C4 H4B 1.042(7)