#------------------------------------------------------------------------------
#$Date: 2008-11-20 19:58:43 +0000 (Thu, 20 Nov 2008) $
#$Revision: 481 $
#$URL: svn://www.crystallography.net/cod/cif/2/2000846.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2000846
_journal_name_full 'Acta Crystallographica Section C'
_journal_year  1992
_journal_volume 48
_journal_page_first  1111
_journal_page_last  1112
loop_
_publ_author_name
 'Uekusa, H.'
 'Ohba, S.'
 'Simonsen, K.P.'
 'Kojima, M.'
 'Fujita, J.'
_chemical_formula_moiety  'C8 H24 Cl2 Ir1 N2 P2,F6 P1'
_chemical_formula_sum  'C8 H24 Cl2 F6 Ir1 N2 P3'
_chemical_formula_weight  618.3
_symmetry_cell_setting  orthorhombic
_symmetry_space_group_name_H-M  'F dd2'
_symmetry_space_group_name_Hall  ?
_cell_length_a  23.659(8)
_cell_length_b  32.794(10)
_cell_length_c  10.042(5)
_cell_angle_alpha  90.
_cell_angle_beta  90.
_cell_angle_gamma  90.
_cell_volume  7791(5)
_cell_formula_units_Z  16
_exptl_crystal_density_diffrn  2.13
_exptl_crystal_density_meas  2.11
_exptl_crystal_F_000  4736
_exptl_absorpt_coefficient_mu  7.44
_diffrn_radiation_type  Mo
_diffrn_radiation_wavelength  0.71073
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
 Ir .07259(2) .085200(10)
         0
 Cl(1) -.01850(10)
     .05650(10)
        -.0190(4)
 Cl(2) .16300(10)
       .11470(10)
       .0202(5)
 P(1) .0949(2) .06220(10)
         -.2126(3)
 P(2) .04800(10)
      .10800(10)
         .2115(4)
 N(1) .1028(5) .0278(3) .0558(12)
 N(2) .0402(5) .1418(3) -.0610(12)
 C(1) .1168(7) .0102(4) -.1816(16)
 C(2) .1537(9) .0862(5) -.2971(19)
 C(3) 0.0396(8) .0574(7) -.3368(17)
 C(4) .0104(7) .1563(4) .1664(19)
 C(5) -.0007(7) .0774(6) .3115(18)
 C(6) .1048(7) .1207(5) .3264(16)
 C(7) .1422(6) .0091(4) -.0408(17)
 C(8) .0391(7) .1725(4) .0502(19)
 P(3) .1659(2) -.02480(10)
       .3895(5)
 F(1) .2141(8) -.0162(9) .300(2)
 F(2) .1306(6) -.0405(4) .2704(18)
 F(3) .1187(9) -.0305(9) .482(2)
 F(4) .2012(8) -.0110(6) .512(2)
 F(5) .1462(11) .0177(5) .372(3)
 F(6) .1858(12) -.0681(6) .412(2)
 H(C11) .085(5) -.009(4) -.193(14)
 H(C12) .147(6) .005(4) -.24(2)
 H(C21) .159(8) .117(6) -.32(2)
 H(C22) .164(6) .068(5) -.390(18)
 H(C23) .193(6) .083(4) -.24(2)
 H(C31) .023(6) .086(4) -.367(17)
 H(C32) .057(6) .041(4) -.421(16)
 H(C33) .007(6) .037(4) -.310(16)
 H(C41) -.032(6) .147(4) .129(16)
 H(C42) .002(6) .175(4) .24(2)
 H(C51) -.015(6) .093(4) .398(17)
 H(C52) -.034(6) .072(4) .25(2)
 H(C53) .018(5) .054(4) .354(15)
 H(C61) .129(6) .101(4) .339(17)
 H(C62) .088(6) .134(4) .410(16)
 H(C63) .133(5) .141(3) .279(17)
 H(C71) .180(6) .026(4) -.049(17)
 H(C72) .149(5) -.016(3) -.032(13)
 H(C81) .079(5) .179(4) .072(16)
 H(C82) .023(6) .191(4) .01(2)
 H(N11) .073(6) .003(4) .076(16)
 H(N12) .123(6) .032(4) .131(19)
 H(N21) -.004(6) .127(4) -.109(16)
 H(N22) .075(7) .155(5) -.14(2)