#------------------------------------------------------------------------------
#$Date: 2012-02-03 17:16:24 +0000 (Fri, 03 Feb 2012) $
#$Revision: 32112 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/20/2002059.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2002059
loop_
_publ_author_name
'Viossat, B.'
'Dung, Nguyen-Huy'
'Robert, F.'
_publ_section_title
;
 Structure du <i>trans</i>-dichlorobis(pyridine)palladium(II)
;
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              84
_journal_page_last               85
_journal_volume                  49
_journal_year                    1993
_chemical_formula_sum            'C10 H10 Cl2 N2 Pd'
_chemical_formula_weight         335.51
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.560(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.7740(10)
_cell_length_b                   15.474(2)
_cell_length_c                   8.6350(10)
_cell_volume                     1172.3(2)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.7107
_exptl_absorpt_coefficient_mu    1.991
_exptl_crystal_density_diffrn    1.90
_exptl_crystal_density_meas      1.87(3)
_exptl_crystal_F_000             656
_[local]_cod_data_source_file    du1002.cif
_[local]_cod_data_source_block   du1002_structure_1_of_1
_[local]_cod_chemical_formula_sum_orig 'C10 H10 Cl2 N2 Pd1'
_cod_original_cell_volume        1172.3(3)
_cod_database_code               2002059
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Pd .0 .12684(4) .2500 .0383
Cl .26140(10) .1290(2) .2668(2) .0569
N(1) .0 -.0040(4) .2500 .0417
N(2) .0 .2575(4) .2500 .0455
C(1) .0942(6) -.0489(4) .1559(6) .0456
C(2) .0969(6) -.1379(4) .1547(6) .0501
C(3) .0 -.1813(5) .2500 .0485
C(4) .0565(7) .3011(4) .1299(6) .0492
C(5) .0570(7) .3908(4) .1278(7) .0570
C(6) .0 .4352(6) .2500 .0581
H(1) .165(6) -.011(4) .101(7) ?
H(2) .161(6) -.159(4) .065(7) ?
H(3) .0000 -.236(6) .2500 ?
H(4) .105(7) .268(4) .049(7) ?
H(5) .101(6) .414(4) .033(7) ?
H(6) .0000 .502(6) .2500 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C(1) H(1) 0.98(6)
C(3) H(3) 0.85(9)
C(5) H(5) 0.98(6)
Pd Cl 2.2970(10)
Pd N(2) 2.023(6)
N(2) C(4) 1.336(6)
C(2) C(3) 1.366(7)
C(5) C(6) 1.359(8)
C(2) H(2) 1.01(6)
C(4) H(4) 0.97(6)
C(6) H(6) 1.03(9)
Pd N(1) 2.024(6)
N(1) C(1) 1.356(6)
C(1) C(2) 1.377(8)
C(4) C(5) 1.388(8)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N(2) Pd(1) Cl 89.17(7)
C(3) C(2) C(1) 118.4(6)
C(5) C(4) N(2) 121.1(6)
N(1) Pd Cl 90.83(7)
C(1) N(1) Pd(1) 120.8(3)
C(4) N(2) Pd(1) 120.3(3)
C(2) C(1) N(1) 121.9(6)
C(6) C(5) C(4) 119.6(6)