#------------------------------------------------------------------------------ #$Date: 2016-02-19 14:29:56 +0000 (Fri, 19 Feb 2016) $ #$Revision: 176759 $ #$URL: svn://www.crystallography.net/cod/cif/2/00/21/2002113.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2002113 loop_ _publ_author_name 'Lewinski, K.' 'Nitek, W.' 'Milart, P.' _publ_contact_author ; Dr Krzysztof Lewinski Department of Chemistry University of South Carolina Columbia, SC 29208 USA ; _publ_section_title ; Molecular complex of 2-[4-(dimethylamino)phenylimino]-3-oxo-N-phenylbutanamide and N,N-dimethyl-4-nitrosoaniline ; _journal_issue 1 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 188 _journal_page_last 190 _journal_paper_doi 10.1107/S0108270192010461 _journal_volume 49 _journal_year 1993 _chemical_formula_moiety 'C18 H19 N3 O2 , C8 H10 N2 O' _chemical_formula_sum 'C26 H29 N5 O3' _chemical_formula_weight 459.55 _chemical_name_systematic ; 2-[4-(Dimethylamino)phenyl]imino]-3-oxo-N-phenylbutanamide N,N-dimethyl-4-nitroso-benzenamine ; _space_group_IT_number 19 _symmetry_cell_setting orthorhombic _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _atom_type_scat_source 'International Tables vol IV Table 2.2B' _audit_creation_method manual _cell_angle_alpha 90.0 _cell_angle_beta 90.0 _cell_angle_gamma 90.0 _cell_formula_units_Z 4 _cell_length_a 19.361(4) _cell_length_b 13.942(3) _cell_length_c 9.054(3) _cell_measurement_reflns_used 25 _cell_measurement_temperature 293 _cell_measurement_theta_max 30 _cell_measurement_theta_min 9 _cell_volume 2444.0(11) _computing_cell_refinement 'KM-4 software' _computing_data_collection 'KM-4 software' _computing_data_reduction 'KM-4 software' _computing_molecular_graphics ; CHAIN (Sack, 1989) MOLDRAW (Ugliengo, Boranzi & Viterbo, 1988) ORTEP (Johnson, 1965) ; _computing_publication_material 'PARST88 (Nardelli, 1983)' _computing_structure_refinement 'SHELX76 (Sheldrick, 1976)' _computing_structure_solution 'SHELXS86 (Sheldrick, 1985)' _diffrn_measurement_device ; KM-4 four circle diffractometer (KUMA Diffraction) ; _diffrn_measurement_method '\w/2\q scan' _diffrn_radiation_monochromator graphite _diffrn_radiation_type CuK\a _diffrn_radiation_wavelength 1.54051 _diffrn_reflns_av_R_equivalents 0.011 _diffrn_reflns_limit_h_max 24 _diffrn_reflns_limit_h_min -24 _diffrn_reflns_limit_k_max 0 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_l_max 11 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_number 5918 _diffrn_reflns_theta_max 80.0 _diffrn_standards_decay_% .0 _diffrn_standards_interval_count 50 _diffrn_standards_number 2 _exptl_absorpt_coefficient_mu 6.410 _exptl_absorpt_correction_type none _exptl_crystal_colour 'Dark green' _exptl_crystal_density_diffrn 1.249 _exptl_crystal_description Prism _exptl_crystal_size_max 0.65 _exptl_crystal_size_mid 0.45 _exptl_crystal_size_min 0.25 _refine_diff_density_max 0.379 _refine_diff_density_min -0.242 _refine_ls_extinction_coef 0.0023(5) _refine_ls_extinction_method 'empirical (Sheldrick, 1976)' _refine_ls_goodness_of_fit_obs 0.967 _refine_ls_hydrogen_treatment refall _refine_ls_matrix_type userblock _refine_ls_number_parameters 484 _refine_ls_number_reflns 5022 _refine_ls_R_factor_obs 0.035 _refine_ls_shift/esd_max 0.028 _refine_ls_shift/esd_mean 0.002 _refine_ls_structure_factor_coef F _refine_ls_weighting_details 'w = 1/[\s^2^(F)+0.003F^2^]' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_obs 0.043 _reflns_number_observed 5022 _reflns_number_total 5267 _reflns_observed_criterion 'F > 3\s(F)' _cod_data_source_file ab1020.cif _cod_data_source_block default _cod_depositor_comments ; The following automatic conversions were performed: '_refine_ls_weighting_scheme' value '1/[\s^2^(F)+0.003F^2^]' was changed to 'calc'. New tag '_refine_ls_weighting_details' was created. The value of the new tag was set to 'w = 1/[\s^2^(F)+0.003F^2^]'. Automatic conversion script Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas ; _cod_original_cell_volume 2444.0(10) _cod_database_code 2002113 loop_ _symmetry_equiv_pos_as_xyz +x,+y,+z 1/2-x,-y,1/2+z -x,1/2+y,1/2-z 1/2+x,1/2-y,-z loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 C101 0.0384(4) 0.0545(5) 0.0421(4) 0.0019(3) 0.0011(3) 0.0016(4) C102 0.0461(4) 0.0474(4) 0.0435(4) 0.0017(3) 0.0039(3) -.0020(4) C103 0.0546(5) 0.0564(5) 0.0470(5) 0.0020(4) -.0001(4) -.0007(4) C104 0.0788(9) 0.0686(8) 0.0432(5) 0.0047(6) 0.0050(5) -.0033(5) N105 0.0466(4) 0.0461(4) 0.0451(4) 0.0027(3) 0.0036(3) -.0032(3) C106 0.0406(4) 0.0450(4) 0.0465(5) 0.0024(3) 0.0038(3) -.0034(4) C107 0.0443(5) 0.0597(5) 0.0510(5) 0.0026(4) 0.0103(4) 0.0001(4) C108 0.0413(5) 0.0665(6) 0.0576(6) -.0010(4) 0.0051(4) 0.0036(5) C109 0.0431(4) 0.0514(5) 0.0522(5) -.0015(4) 0.0003(4) 0.0006(4) C110 0.0448(5) 0.0643(6) 0.0451(5) 0.0002(4) 0.0048(4) 0.0013(4) C111 0.0404(4) 0.0613(6) 0.0476(5) -.0010(4) 0.0040(4) 0.0023(4) N112 0.0478(5) 0.1008(9) 0.0581(6) -.0072(5) -.0061(4) 0.0054(6) C113 0.0674(8) 0.0828(9) 0.0544(6) -.0083(7) -.0091(5) 0.0019(7) C114 0.0485(6) 0.1171(17) 0.0808(11) -.0114(8) -.0098(7) 0.0066(12) N115 0.0497(4) 0.0513(4) 0.0424(3) 0.0038(3) 0.0112(3) 0.0038(3) C116 0.0393(4) 0.0602(5) 0.0430(4) 0.0055(3) 0.0028(3) -.0023(4) C117 0.0655(6) 0.0697(7) 0.0481(5) 0.0072(5) 0.0138(5) 0.0036(5) C118 0.0803(8) 0.1033(11) 0.0540(7) 0.0065(8) 0.0228(6) -.0074(7) C119 0.0718(8) 0.1019(11) 0.0680(8) 0.0096(8) 0.0143(6) -.0295(8) C120 0.0717(8) 0.0677(8) 0.0874(10) 0.0030(6) 0.0113(8) -.0260(7) C121 0.0573(6) 0.0589(6) 0.0629(6) 0.0002(4) 0.0087(5) -.0064(5) O122 0.0516(4) 0.0614(4) 0.0583(4) -.0087(3) 0.0086(3) 0.0032(3) O123 0.0551(5) 0.1186(9) 0.0588(5) 0.0061(5) -.0072(4) 0.0014(6) C201 0.0520(5) 0.0444(4) 0.0481(4) -.0011(4) 0.0029(4) 0.0016(4) C202 0.0566(5) 0.0614(5) 0.0568(5) -.0047(5) 0.0103(4) 0.0008(5) C203 0.0798(8) 0.0629(6) 0.0512(5) -.0039(6) 0.0125(5) -.0010(5) C204 0.0829(8) 0.0512(5) 0.0532(6) -.0050(5) -.0072(5) -.0044(5) C205 0.0568(6) 0.0616(5) 0.0676(6) -.0085(5) -.0032(5) -.0059(5) C206 0.0520(5) 0.0663(6) 0.0548(5) -.0074(4) 0.0057(4) 0.0014(5) N207 0.1110(11) 0.0689(6) 0.0607(6) -.0005(7) -.0178(6) -.0100(5) N208 0.0598(5) 0.0621(5) 0.0514(4) 0.0004(4) -.0025(4) 0.0008(4) O209 0.1117(10) 0.0870(7) 0.0848(8) 0.0010(6) -.0379(7) -.0226(6) C210 0.0940(10) 0.0627(7) 0.0472(5) 0.0042(7) 0.0037(6) 0.0033(5) C211 0.0632(8) 0.1038(12) 0.0826(10) -.0022(8) -.0195(7) -.0008(10) loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_thermal_displace_type C101 0.91410(10) 0.33790(10) 0.08720(10) 0.0450(5) Uani C102 0.86860(10) 0.36270(10) 0.21890(10) 0.0457(5) Uani C103 0.90520(10) 0.36810(10) 0.36420(10) 0.0526(6) Uani C104 0.86270(10) 0.38410(10) 0.5007(2) 0.0636(8) Uani N105 0.80300(10) 0.37750(10) 0.21570(10) 0.0460(4) Uani C106 0.76210(10) 0.37490(10) 0.08900(10) 0.0440(5) Uani C107 0.69080(10) 0.36340(10) 0.11110(10) 0.0517(6) Uani C108 0.64470(10) 0.35890(10) -0.0047(2) 0.0551(6) Uani C109 0.66740(10) 0.36900(10) -0.15160(10) 0.0489(5) Uani C110 0.73870(10) 0.38440(10) -0.17350(10) 0.0514(5) Uani C111 0.78430(10) 0.38720(10) -0.05740(10) 0.0498(5) Uani N112 0.62360(10) 0.36550(10) -0.2690(2) 0.0689(7) Uani C113 0.64900(10) 0.37450(10) -0.4193(2) 0.0682(8) Uani C114 0.54960(10) 0.3673(2) -0.2515(3) 0.0821(12) Uani N115 0.91110(10) 0.24350(10) 0.05300(10) 0.0478(4) Uani C116 0.94180(10) 0.19610(10) -0.06740(10) 0.0475(5) Uani C117 0.97150(10) 0.24290(10) -0.18690(10) 0.0611(7) Uani C118 0.99850(10) 0.1886(2) -0.3027(2) 0.0792(9) Uani C119 0.99710(10) 0.0908(2) -0.2998(2) 0.0806(9) Uani C120 0.96800(10) 0.04390(10) -0.1811(2) 0.0756(9) Uani C121 0.94000(10) 0.09660(10) -0.0650(2) 0.0597(6) Uani O122 0.94740(10) 0.39890(10) 0.02250(10) 0.0571(4) Uani O123 0.96730(10) 0.35720(10) 0.36830(10) 0.0775(7) Uani H101A 0.8930(10) 0.375(2) 0.586(3) 0.036(6) Uiso H102A 0.854(2) 0.444(3) 0.511(5) 0.058(9) Uiso H103A 0.825(2) 0.331(3) 0.501(6) 0.076(11) Uiso H101B 0.873(5) 0.331(6) 0.534(11) 0.149(11) Uiso H102B 0.813(2) 0.425(3) 0.497(5) 0.071(10) Uiso H103B 0.894(2) 0.431(3) 0.582(5) 0.069(10) Uiso H104 0.6720(10) 0.359(2) 0.214(2) 0.073(6) Uiso H105 0.5970(10) 0.3520(10) 0.016(3) 0.069(5) Uiso H106 0.7560(10) 0.3950(10) -0.269(2) 0.061(5) Uiso H107 0.8310(10) 0.3970(10) -0.080(2) 0.048(3) Uiso H108A 0.688(2) 0.324(2) -0.423(4) 0.053(8) Uiso H109A 0.656(2) 0.447(3) -0.432(5) 0.057(9) Uiso H110A 0.610(2) 0.352(2) -0.482(3) 0.040(6) Uiso H108B 0.649(5) 0.312(5) -0.472(10) 0.146(11) Uiso H109B 0.620(2) 0.419(3) -0.483(5) 0.069(10) Uiso H110B 0.682(2) 0.423(3) -0.448(4) 0.047(8) Uiso H111A 0.549(2) 0.311(3) -0.243(5) 0.052(9) Uiso H112A 0.520(3) 0.373(4) -0.322(6) 0.076(11) Uiso H113A 0.540(2) 0.413(2) -0.184(4) 0.049(8) Uiso H111B 0.529(2) 0.438(4) -0.300(5) 0.086(11) Uiso H112B 0.526(2) 0.299(4) -0.336(6) 0.089(11) Uiso H113B 0.529(2) 0.341(2) -0.173(4) 0.045(7) Uiso H114 0.8880(10) 0.2080(10) 0.113(2) 0.055(4) Uiso H115 0.9760(10) 0.3150(10) -0.183(2) 0.074(5) Uiso H116 1.0200(10) 0.2280(10) -0.379(2) 0.081(6) Uiso H117 1.0170(10) 0.048(2) -0.375(3) 0.095(7) Uiso H118 0.9640(10) -0.030(2) -0.177(2) 0.086(6) Uiso H119 0.9190(10) 0.0660(10) 0.017(3) 0.079(5) Uiso C201 0.79640(10) -0.11730(10) 0.22680(10) 0.0482(5) Uani C202 0.83650(10) -0.11440(10) 0.09440(10) 0.0583(6) Uani C203 0.80530(10) -0.12140(10) -0.0397(2) 0.0646(7) Uani C204 0.73370(10) -0.13080(10) -0.0532(2) 0.0624(7) Uani C205 0.69330(10) -0.13420(10) 0.0771(2) 0.0620(6) Uani C206 0.72340(10) -0.12820(10) 0.2117(2) 0.0577(6) Uani N207 0.70820(10) -0.13640(10) -0.1938(2) 0.0802(8) Uani N208 0.82560(10) -0.11060(10) 0.35960(10) 0.0577(5) Uani O209 0.64450(10) -0.14320(10) -0.2052(2) 0.0945(9) Uani C210 0.78470(10) -0.11850(10) 0.4950(2) 0.0680(8) Uani C211 0.89900(10) -0.0962(2) 0.3801(2) 0.0832(10) Uani H201 0.8870(10) -0.1070(10) 0.100(2) 0.056(4) Uiso H202 0.8310(10) -0.1200(10) -0.134(2) 0.077(5) Uiso H203 0.6450(10) -0.1410(10) 0.060(2) 0.079(5) Uiso H204 0.6930(10) -0.1340(10) 0.294(2) 0.064(4) Uiso H205A 0.7400(10) -0.083(2) 0.501(3) 0.033(5) Uiso H206A 0.714(2) 0.184(3) 1.027(5) 0.066(10) Uiso H207A 0.700(2) 0.090(3) 1.085(5) 0.063(10) Uiso H205B 0.754(2) -0.176(2) 0.479(4) 0.045(7) Uiso H206B 0.775(3) -0.052(4) 0.496(9) 0.119(11) Uiso H207B 0.683(2) 0.125(3) 1.080(4) 0.057(9) Uiso H208A 0.910(2) -0.055(3) 0.483(5) 0.072(10) Uiso H209A 0.581(2) 0.056(3) 0.812(4) 0.048(8) Uiso H210A 0.566(2) 0.154(3) 0.899(6) 0.089(11) Uiso H208B 0.589(2) 0.118(2) 0.998(4) 0.045(6) Uiso H209B 0.903(2) -0.018(3) 0.330(5) 0.070(11) Uiso H210B 0.919(2) -0.142(2) 0.310(4) 0.045(6) Uiso loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_publ_flag N115 C101 O122 126.20(10) yes C102 C101 O122 121.70(10) yes C102 C101 N115 112.10(10) yes C101 C102 N105 126.20(10) yes C101 C102 C103 115.20(10) yes C103 C102 N105 118.70(10) yes C102 C103 O123 119.40(10) yes C102 C103 C104 118.10(10) yes C104 C103 O123 122.5(2) yes C103 C104 H103B 108.(2) no C103 C104 H102B 121.(2) no C103 C104 H101B 92.(6) no C103 C104 H103A 106.(3) no C103 C104 H102A 110.(3) no C103 C104 H101A 107.(2) no C102 N105 C106 125.00(10) yes N105 C106 C111 126.90(10) yes N105 C106 C107 116.30(10) yes C107 C106 C111 116.70(10) yes C106 C107 C108 122.20(10) yes C106 C107 H104 120.0(10) no H104 C107 C108 117.0(10) no C107 C108 C109 120.80(10) yes C107 C108 H105 119.0(10) no H105 C108 C109 119.0(10) no C108 C109 N112 122.70(10) yes C108 C109 C110 116.90(10) yes C110 C109 N112 120.40(10) yes C109 C110 C111 121.70(10) yes C109 C110 H106 120.0(10) no H106 C110 C111 118.0(10) no C106 C111 C110 121.60(10) yes C110 C111 H107 117.0(10) no C106 C111 H107 121.0(10) no C109 N112 C114 122.2(2) yes C109 N112 C113 121.20(10) yes C113 N112 C114 116.0(2) yes N112 C113 H108B 112.(5) no N112 C113 H109B 112.(2) no N112 C113 H110B 122.(2) no N112 C113 H108A 102.(2) no N112 C113 H109A 103.(2) no N112 C113 H110A 104.(2) no N112 C114 H113B 121.(2) no N112 C114 H112B 105.(2) no N112 C114 H111B 108.(2) no N112 C114 H113A 107.(2) no N112 C114 H112A 125.(3) no N112 C114 H111A 91.(3) no C101 N115 C116 128.10(10) yes C101 N115 H114 115.0(10) no H114 N115 C116 116.0(10) no N115 C116 C121 116.60(10) yes N115 C116 C117 123.90(10) yes C117 C116 C121 119.50(10) yes C116 C117 C118 119.1(2) yes C116 C117 H115 118.0(10) no H115 C117 C118 122.0(10) no C117 C118 C119 121.4(2) yes C117 C118 H116 112.0(10) no H116 C118 C119 126.0(10) no C118 C119 C120 119.8(2) yes C118 C119 H117 125.0(10) no H117 C119 C120 114.0(10) no C119 C120 C121 119.8(2) yes C119 C120 H118 122.0(10) no H118 C120 C121 118.0(10) no C116 C121 C120 120.4(2) yes C120 C121 H119 121.0(10) no C116 C121 H119 118.0(10) no C206 C201 N208 120.90(10) yes C202 C201 N208 121.80(10) yes C202 C201 C206 117.40(10) yes C201 C202 C203 120.50(10) yes C201 C202 H201 119.0(10) no H201 C202 C203 119.0(10) no C202 C203 C204 121.7(2) yes C202 C203 H202 123.0(10) no H202 C203 C204 115.0(10) no C203 C204 N207 116.4(2) yes C203 C204 C205 118.5(2) yes C205 C204 N207 125.1(2) yes C204 C205 C206 120.70(10) yes C204 C205 H203 114.0(10) no H203 C205 C206 125.0(10) no C201 C206 C205 121.30(10) yes C205 C206 H204 115.0(10) no C201 C206 H204 123.0(10) no C204 N207 O209 116.1(2) yes C201 N208 C211 122.8(2) yes C201 N208 C210 121.50(10) yes C210 N208 C211 115.7(2) yes N208 C210 H207B 108.(2) no N208 C210 H206B 92.(4) no N208 C210 H205B 105.(2) no N208 C210 H205A 118.(2) no N208 C210 H206A 108.(2) no N208 C210 H207A 121.(2) no N208 C211 H210B 102.(2) no N208 C211 H209B 98.(2) no N208 C211 H208B 106.(2) no N208 C211 H210A 122.(2) no N208 C211 H209A 114.(2) no N208 C211 H208A 111.(2) no loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_publ_flag C101 C102 1.522(2) yes C101 N115 1.353(2) yes C101 O122 1.218(2) yes C102 C103 1.497(2) yes C102 N105 1.287(2) yes C103 C104 1.501(2) yes C103 O123 1.212(2) yes C104 H101A 0.98(3) no C104 H102A 0.86(4) no C104 H103A 1.04(4) no C104 H101B 0.82(9) no C104 H102B 1.11(4) no C104 H103B 1.15(4) no N105 C106 1.395(2) yes C106 C107 1.404(2) yes C106 C111 1.404(2) yes C107 H104 1.01(2) no C107 C108 1.378(2) yes C108 H105 0.95(2) no C108 C109 1.408(2) yes C109 C110 1.411(2) yes C109 N112 1.361(2) yes C110 H106 0.94(2) no C110 C111 1.372(2) yes C111 H107 0.930(10) no N112 C113 1.453(2) yes N112 C114 1.441(2) yes C113 H108A 1.03(4) no C113 H109A 1.02(4) no C113 H110A 1.00(3) no C113 H108B 0.99(8) no C113 H109B 1.02(4) no C113 H110B 0.96(4) no C114 H111A 0.78(4) no C114 H112A 0.87(5) no C114 H113A 0.90(4) no C114 H111B 1.15(5) no C114 H112B 1.31(5) no C114 H113B 0.89(3) no N115 H114 0.86(2) no N115 C116 1.406(2) yes C116 C117 1.388(2) yes C116 C121 1.389(2) yes C117 H115 1.00(2) no C117 C118 1.395(2) yes C118 H116 0.98(2) no C118 C119 1.364(3) yes C119 H117 0.98(2) no C119 C120 1.379(3) yes C120 H118 1.04(2) no C120 C121 1.391(2) yes C121 H119 0.95(2) no C201 C202 1.428(2) yes C201 C206 1.428(2) yes C201 N208 1.331(2) yes C202 H201 0.98(2) no C202 C203 1.359(2) yes C203 H202 0.99(3) no C203 C204 1.399(2) yes C204 C205 1.416(2) yes C204 N207 1.367(2) yes C205 H203 0.95(2) no C205 C206 1.354(2) yes C206 H204 0.95(2) no N207 O209 1.243(3) yes N208 C210 1.462(2) yes N208 C211 1.449(2) yes C210 H205A 0.99(3) no C210 H206A 0.95(3) no C210 H207A 0.96(3) no C210 H205B 1.01(3) no C210 H206B 0.94(6) no C210 H207B 1.00(5) no C211 H208A 1.12(5) no C211 H209A 0.92(5) no C211 H210A 1.07(5) no C211 H208B 1.13(4) no C211 H209B 1.18(4) no C211 H210B 0.98(3) no loop_ _geom_contact_atom_site_label_1 _geom_contact_atom_site_label_2 _geom_contact_distance _geom_contact_site_symmetry_1 _geom_contact_site_symmetry_2 _geom_contact_publ_flag C101 O209 3.491(2) . 2_655 no C102 N207 3.577(2) . 2_655 no C102 O209 3.147(2) . 2_655 no C103 O209 3.340(2) . 2_655 no C104 C108 3.586(2) . 2_665 no N105 C110 3.561(2) . 2_665 no N105 N207 3.467(2) . 2_655 no N105 O209 3.496(2) . 2_655 no C114 N115 3.579(3) . 4_555 no N115 N207 3.582(2) . 2_655 no N115 O209 2.813(2) . 2_655 no C119 O122 3.519(2) . 3_744 no O122 C211 3.101(2) . 3_755 no O123 C211 3.489(2) . 3_755 no C204 C210 3.521(2) . 2_654 no N207 N208 3.538(2) . 2_654 no N207 C210 3.193(2) . 1_554 no O209 C211 3.527(3) . 2_654 no loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_publ_flag C102 C101 N115 C116 174.80(10) yes N115 C101 C102 N105 -81.3(2) yes N115 C101 C102 C103 97.60(10) no O122 C101 C102 N105 97.6(2) no O122 C101 C102 C103 -83.5(2) yes O122 C101 N115 C116 -4.1(2) no C101 C102 N105 C106 -1.2(2) yes C101 C102 C103 C104 -175.10(10) no C101 C102 C103 O123 3.3(2) no C103 C102 N105 C106 179.90(10) no N105 C102 C103 O123 -177.80(10) yes N105 C102 C103 C104 3.9(2) no C102 N105 C106 C107 161.00(10) yes C102 N105 C106 C111 -22.2(2) no N105 C106 C111 C110 -179.10(10) no N105 C106 C107 C108 -179.40(10) no C107 C106 C111 C110 -2.4(2) no C111 C106 C107 C108 3.5(2) no C106 C107 C108 C109 -2.1(2) no C107 C108 C109 C110 -0.4(2) no C107 C108 C109 N112 -179.7(2) no C108 C109 N112 C113 -178.9(2) no C108 C109 N112 C114 10.7(3) yes C108 C109 C110 C111 1.5(2) no C110 C109 N112 C113 1.9(2) yes C110 C109 N112 C114 -168.6(2) no N112 C109 C110 C111 -179.20(10) no C109 C110 C111 C106 0.0(2) no C101 N115 C116 C117 -11.4(2) no C101 N115 C116 C121 170.20(10) yes N115 C116 C121 C120 178.7(2) no N115 C116 C117 C118 -177.9(2) no C117 C116 C121 C120 0.3(2) no C121 C116 C117 C118 0.5(2) no C116 C117 C118 C119 -0.9(3) no C117 C118 C119 C120 0.7(3) no C118 C119 C120 C121 0.1(3) no C119 C120 C121 C116 -0.5(3) no C206 C201 N208 C210 2.9(2) yes C202 C201 N208 C210 -176.90(10) no C206 C201 N208 C211 -177.8(2) no C202 C201 N208 C211 2.4(2) yes N208 C201 C206 C205 179.4(2) no C202 C201 C206 C205 -0.9(2) no C206 C201 C202 C203 0.2(2) no N208 C201 C202 C203 -180.00(10) no C201 C202 C203 C204 0.7(2) no C202 C203 C204 C205 -0.9(2) no C202 C203 C204 N207 179.4(2) no C203 C204 N207 O209 -178.9(2) no C203 C204 C205 C206 0.2(2) no C205 C204 N207 O209 1.4(3) yes N207 C204 C205 C206 179.9(2) no C204 C205 C206 C201 0.6(2) no