#------------------------------------------------------------------------------
#$Date: 2011-09-28 15:24:46 +0100 (Wed, 28 Sep 2011) $
#$Revision: 26848 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/25/2002597.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2002597
_chemical_name_systematic          'Distrontium tribismuth trivanadium oxide'
_chemical_formula_structural       'Sr2 Bi3 V3 O14'
_chemical_formula_sum              'Bi3 O14 Sr2 V3'
_publ_section_title                'Zur Kenntnis von Sr2 Bi3 V3 O14'
loop_
_publ_author_name
  'Boje, J'
  'Mueller-Buschbaum, Hk'
_journal_name_full
;
Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_volume                    618
_journal_year                      1992
_journal_page_first                39
_journal_page_last                 42
_cell_length_a                     7.0838(29)
_cell_length_b                     7.1732(32)
_cell_length_c                     14.1067(54)
_cell_angle_alpha                  97.462(33)
_cell_angle_beta                   98.704(25)
_cell_angle_gamma                  110.989(20)
_cell_volume                       648.3
_cell_formula_units_Z              2
_symmetry_space_group_name_H-M     'P -1'
_symmetry_Int_Tables_number        2
_symmetry_cell_setting             triclinic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  Sr2+   2.000
  Bi3+   3.000
  V5+    5.000
  O2-   -2.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  Sr1   Sr2+   2 i 0.8303(6) 0.2727(6) 0.0568(3) 1.  0 d
  Bi1   Bi3+   2 i 0.1318(2) 0.2845(2) 0.3161(1) 1.  0 d
  Bi2   Bi3+   2 i 0.6160(2) 0.2231(2) 0.3019(1) 1.  0 d
  Sr2   Sr2+   2 i 0.3275(4) 0.2249(3) 0.8312(2) 0.5  0 d
  Bi3   Bi3+   2 i 0.3275(4) 0.2249(3) 0.8312(2) 0.5  0 d
  Sr3   Sr2+   2 i 0.9053(3) 0.2648(3) 0.5451(2) 0.5  0 d
  Bi4   Bi3+   2 i 0.9053(3) 0.2648(3) 0.5451(2) 0.5  0 d
  V1    V5+    2 i 0.3482(8) 0.2909(8) 0.0798(4) 1.  0 d
  V2    V5+    2 i 0.1621(7) 0.7645(7) 0.2034(3) 1.  0 d
  V3    V5+    2 i 0.3903(8) 0.2359(8) 0.5677(4) 1.  0 d
  O1    O2-    2 i 0.070(4) 0.616(4) 0.599(2) 1.  0 d
  O2    O2-    2 i 0.183(4) 0.169(4) 0.472(2) 1.  0 d
  O3    O2-    2 i 0.918(4) 0.088(4) 0.720(2) 1.  0 d
  O4    O2-    2 i 0.382(4) 0.004(4) 0.596(2) 1.  0 d
  O5    O2-    2 i 0.583(4) 0.103(4) 0.807(2) 1.  0 d
  O6    O2-    2 i 0.346(5) 0.369(5) 0.661(2) 1.  0 d
  O7    O2-    2 i 0.414(4) 0.645(4) 0.845(2) 1.  0 d
  O8    O2-    2 i 0.867(6) 0.442(6) 0.746(3) 1.  0 d
  O9    O2-    2 i 0.655(4) 0.486(4) 0.945(2) 1.  0 d
  O10   O2-    2 i 0.330(5) 0.115(4) 0.976(2) 1.  0 d
  O11   O2-    2 i 0.001(4) 0.322(4) 0.908(2) 1.  0 d
  O12   O2-    2 i 0.619(5) 0.366(5) 0.538(2) 1.  0 d
  O13   O2-    2 i 0.180(4) 0.868(3) 0.769(2) 1.  0 d
  O14   O2-    2 i 0.157(5) 0.190(5) 0.139(2) 1.  0 d
_refine_ls_R_factor_all            0.077
_cod_database_code 2002597