data_2003616
_journal_name_full   'Acta Crystallographica'
_journal_year        1995
_journal_volume    	C51
_journal_page_first    	1260
_journal_page_last    	1263
_publ_section_title    	
;
Two Transition-Metal Antimony Ethoxides: M~2~Sb~4~(OEt)~16~; M = Ni or Mn
;
_chemical_formula_sum    	'C32 H80 Ni2 O16 Sb4'
_chemical_formula_weight    	1325.34
loop_
    _symmetry_equiv_pos_as_xyz
    'x,y,z'
    '-x,-y,-z'
_symmetry_space_group_name_H-M    	'P -1'
_cell_length_a    	9.093(7)
_cell_length_b    	12.108(9)
_cell_length_c    	12.599(8)
_cell_angle_alpha    	64.10(4)
_cell_angle_beta    	80.35(5)
_cell_angle_gamma    	87.61(6)
_cell_volume    	1229.4(15)
_cell_formula_units_Z    	1
_exptl_crystal_density_diffrn    	1.790(3)
_exptl_crystal_density_meas    	?
_diffrn_radiation_type    	'MoK\a'
_diffrn_radiation_wavelength    	0.71073
_cell_measurement_reflns_used    	23
_cell_measurement_theta_min    	12.5
_cell_measurement_theta_max    	15.0
_exptl_absorpt_coefficient_mu    	2.992
_cell_measurement_temperature    	178(1)
_exptl_crystal_description    	'prismatic'
_exptl_crystal_size_max    	0.5
_exptl_crystal_size_mid    	0.5
_exptl_crystal_size_min    	0.5
_exptl_crystal_size_rad    	?
_exptl_crystal_colour    	'green'
_chemical_compound_source    	?
_diffrn_measurement_device    	'Stoe four-circle'
_diffrn_measurement_method    	'\w-2\q'
_exptl_absorpt_correction_type    	'integration'
_exptl_absorpt_correction_T_min    	0.454
_exptl_absorpt_correction_T_max    	0.533
_diffrn_reflns_number    	4656
_reflns_number_total    	4355
_reflns_number_observed    	3241
_reflns_observed_criterion    	'|F~o~| > 3\s|F~o~|'
_diffrn_reflns_av_R_equivalents    	0.013
_diffrn_reflns_theta_max    	50.2
_diffrn_reflns_limit_h_min    	0
_diffrn_reflns_limit_h_max    	10
_diffrn_reflns_limit_k_min    	-14
_diffrn_reflns_limit_k_max    	14
_diffrn_reflns_limit_l_min    	-14
_diffrn_reflns_limit_l_max    	14
_diffrn_standards_number    	3
_diffrn_standards_interval_count    	?
_diffrn_standards_interval_time    	240
_diffrn_standards_decay_%    	6.5
_refine_ls_structure_factor_coef    	F
_refine_ls_R_factor_obs    	0.033
_refine_ls_wR_factor_obs    	0.038
_refine_ls_goodness_of_fit_obs    	?
_refine_ls_number_reflns    	3241
_refine_ls_number_parameters    	368
_refine_ls_hydrogen_treatment    	'refxyz'
_refine_ls_weighting_scheme    	'1/[\s^2^(F~o~)+(0.0002|F^2^|)]'
_refine_ls_shift/esd_max    	0.16
_refine_diff_density_max    	1.2
_refine_diff_density_min    	-1.4
_refine_ls_extinction_method    	none
_refine_ls_extinction_coef    	?
_atom_type_scat_source    	'IntTabIV'
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    Sb(1) .16692(5) .20025(4) -.20959(4) .0233(2)
    Sb(2) -.05941(5) .28055(4) .19646(4) .0284(2)
    Ni(1) -.02947(10) .08912(8) .06777(7) .0213(3)
    O(1) -.0477(5) .0859(4) -.0945(4) .023(2)
    O(2) .1642(5) .1839(4) -.0445(4) .026(3)
    O(3) -.2108(5) -.0262(4) .1725(4) .024(2)
    O(4) -.1236(5) .2471(4) .0535(4) .026(2)
    O(5) .0059(5) .1097(4) .2202(4) .026(2)
    O(6) .3855(5) .2393(4) -.2415(4) .031(2)
    O(7) -.0386(6) .2363(5) .3684(4) .037(2)
    O(8) -.2744(6) .2553(5) .2507(5) .052(3)
    C(1a) -.1718(8) .1399(7) -.1560(6) .030(3)
    C(1b) -.3207(9) .0847(7) -.0866(7) .036(3)
    C(2a) .2747(8) .2434(7) -.0144(7) .035(3)
    C(2b) .2661(10) .3812(8) -.0732(8) .050(4)
    C(3a) -.3515(8) .0105(7) .2234(6) .030(3)
    C(3b) -.3658(10) -.0368(8) .3587(7) .046(4)
    C(4a) -.1476(9) .3573(7) -.0465(7) .033(3)
    C(4b) -.3116(10) .3768(8) -.0524(8) .048(4)
    C(5a) .0321(8) .0153(7) .3330(6) .028(3)
    C(5b) .1924(10) .0139(8) .3487(7) .043(4)
    C(6a) .4426(12) .3406(10) -.3529(8) .064(5)
    C(6b) .5993(13) .3602(12) -.3718(11) .082(6)
    C(7a) .0785(10) .2958(9) .3858(8) .050(4)
    C(7b) .0192(15) .3855(11) .4346(11) .096(6)
    C(8a) -.3516(9) .2821(8) .3446(7) .041(4)
    C(8b) -.5085(10) .3092(9) .3235(8) .048(4)
    H(1a1) -0.166(8) 0.232(6) -0.179(6) 0.040(6)
    H(1a2) -0.151(8) 0.133(6) -0.231(6) 0.040(6)
    H(1b1) -0.400(8) 0.126(6) -0.133(6) 0.049(5)
    H(1b2) -0.338(9) 0.093(7) -0.011(6) 0.049(5)
    H(1b3) -0.324(9) 0.000(6) -0.080(7) 0.049(5)
    H(2a1) 0.259(8) 0.215(7) 0.073(5) 0.040(6)
    H(2a2) 0.375(7) 0.219(7) -0.035(6) 0.040(6)
    H(2b1) 0.335(8) 0.424(7) -0.048(6) 0.049(5)
    H(2b2) 0.165(7) 0.407(7) -0.044(6) 0.049(5)
    H(2b3) 0.282(9) 0.412(7) -.160(5) 0.049(5)
    H(3a1) -0.351(8) 0.102(5) 0.180(6) 0.040(6)
    H(3a2) -0.429(8) -0.026(6) 0.194(6) 0.040(6)
    H(3b1) -0.462(7) -0.011(7) 0.390(7) 0.049(5)
    H(3b2) -0.286(7) -0.004(6) 0.387(7) 0.049(5)
    H(3b3) -0.366(8) -0.128(5) 0.407(7) 0.049(5)
    H(4a1) -0.110(9) 0.427(6) -0.042(6) 0.040(6)
    H(4a2) -0.095(8) 0.354(6) -0.124(6) 0.040(6)
    H(4b1) -0.323(9) 0.456(5) -0.106(6) 0.049(5)
    H(4b2) -0.372(9) 0.373(7) 0.030(5) 0.049(5)
    H(4b3) -0.359(9) 0.315(6) -0.063(7) 0.049(5)
    H(5a1) -0.030(8) 0.026(6) 0.401(6) 0.040(6)
    H(5a2) 0.005(8) -0.063(6) 0.341(6) 0040(6)
    H(5b1) 0.205(9) -0.058(6) 0.422(6) 0.049(5)
    H(5b2) 0.218(9) 0.090(6) 0.356(6) 0.049(5)
    H(5b3) 0.261(8) 0.012(7) 0.282(6) 0.049(5)
    H(6a1) 0.393(8) 0.416(6) -0.355(6) 0.040(6)
    H(6a2) 0.416(9) 0.324(6) -0.419(6) 0.040(6)
    H(6b1) 0.632(9) 0.431(6) -0.451(5) 0.049(5)
    H(6b2) 0.650(9) 0.284(6) -0.372(7) 0.049(5)
    H(6b3) 0.627(9) 0.377(7) -0.307(6) 0.049(5)
    H(7a1) 0.136(8) 0.235(6) 0.446(6) 0.040(6)
    H(7a2) 0.151(8) 0.339(6) 0.307(5) 0.040(6)
    H(7b1) 0.101(7) 0.419(7) 0.455(7) 0.049(5)
    H(7b2) -0.050(8) 0.338(7) 0.511(6) 0.049(5)
    H(7b3) -0.028(8) 0.452(7) 0.372(6) 0.049(5)
    H(8a1) -0.342(9) 0.209(6) 0.408(6) 0.040(6)
    H(8a2) -0.306(8) 0.354(6) 0.342(7) 0.040(6)
    H(8b1) -0.563(9) 0.327(7) 0.384(6) 0.049(5)
    H(8b2) -0.558(9) 0.242(6) 0.318(7) 0.049(5)
    H(8b3) -0.501(9) 0.387(6) 0.256(6) 0.049(5)