#------------------------------------------------------------------------------
#$Date: 2013-12-28 13:58:47 +0000 (Sat, 28 Dec 2013) $
#$Revision: 91933 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/36/2003616.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2003616
loop_
_publ_author_name
'Bemm, U.'
'Norrestam, R.'
'Nygren, M.'
'Westin, G.'
_publ_section_title
;
 Two Transition-Metal Antimony Ethoxides: <i>M</i>~2~Sb~4~(OEt)~16~;
 <i>M</i> = Ni or Mn
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1260
_journal_page_last               1263
_journal_volume                  51
_journal_year                    1995
_chemical_formula_sum            'C32 H80 Ni2 O16 Sb4'
_chemical_formula_weight         1325.34
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                64.10(4)
_cell_angle_beta                 80.35(5)
_cell_angle_gamma                87.61(6)
_cell_formula_units_Z            1
_cell_length_a                   9.093(7)
_cell_length_b                   12.108(9)
_cell_length_c                   12.599(8)
_cell_measurement_reflns_used    23
_cell_measurement_temperature    178(1)
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      12.5
_cell_volume                     1229.4(16)
_diffrn_measurement_device       'Stoe four-circle'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.013
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            4656
_diffrn_reflns_theta_max         50.2
_diffrn_standards_decay_%        6.5
_diffrn_standards_interval_time  240
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.992
_exptl_absorpt_correction_T_max  0.533
_exptl_absorpt_correction_T_min  0.454
_exptl_absorpt_correction_type   integration
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.790(3)
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.5
_exptl_crystal_size_min          0.5
_refine_diff_density_max         1.2
_refine_diff_density_min         -1.4
_refine_ls_extinction_method     none
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_number_parameters     368
_refine_ls_number_reflns         3241
_refine_ls_R_factor_obs          0.033
_refine_ls_shift/esd_max         0.16
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      1/[\s^2^(F~o~)+(0.0002|F^2^|)]
_refine_ls_wR_factor_obs         0.038
_reflns_number_observed          3241
_reflns_number_total             4355
_reflns_observed_criterion       '|F~o~| > 3\s|F~o~|'
_[local]_cod_data_source_file    ab1151.cif
_[local]_cod_data_source_block   ab1151a
_cod_original_cell_volume        1229.4(15)
_cod_database_code               2003616
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Sb(1) .16692(5) .20025(4) -.20959(4) .0233(2)
Sb(2) -.05941(5) .28055(4) .19646(4) .0284(2)
Ni(1) -.02947(10) .08912(8) .06777(7) .0213(3)
O(1) -.0477(5) .0859(4) -.0945(4) .023(2)
O(2) .1642(5) .1839(4) -.0445(4) .026(3)
O(3) -.2108(5) -.0262(4) .1725(4) .024(2)
O(4) -.1236(5) .2471(4) .0535(4) .026(2)
O(5) .0059(5) .1097(4) .2202(4) .026(2)
O(6) .3855(5) .2393(4) -.2415(4) .031(2)
O(7) -.0386(6) .2363(5) .3684(4) .037(2)
O(8) -.2744(6) .2553(5) .2507(5) .052(3)
C(1a) -.1718(8) .1399(7) -.1560(6) .030(3)
C(1b) -.3207(9) .0847(7) -.0866(7) .036(3)
C(2a) .2747(8) .2434(7) -.0144(7) .035(3)
C(2b) .2661(10) .3812(8) -.0732(8) .050(4)
C(3a) -.3515(8) .0105(7) .2234(6) .030(3)
C(3b) -.3658(10) -.0368(8) .3587(7) .046(4)
C(4a) -.1476(9) .3573(7) -.0465(7) .033(3)
C(4b) -.3116(10) .3768(8) -.0524(8) .048(4)
C(5a) .0321(8) .0153(7) .3330(6) .028(3)
C(5b) .1924(10) .0139(8) .3487(7) .043(4)
C(6a) .4426(12) .3406(10) -.3529(8) .064(5)
C(6b) .5993(13) .3602(12) -.3718(11) .082(6)
C(7a) .0785(10) .2958(9) .3858(8) .050(4)
C(7b) .0192(15) .3855(11) .4346(11) .096(6)
C(8a) -.3516(9) .2821(8) .3446(7) .041(4)
C(8b) -.5085(10) .3092(9) .3235(8) .048(4)
H(1a1) -0.166(8) 0.232(6) -0.179(6) 0.040(6)
H(1a2) -0.151(8) 0.133(6) -0.231(6) 0.040(6)
H(1b1) -0.400(8) 0.126(6) -0.133(6) 0.049(5)
H(1b2) -0.338(9) 0.093(7) -0.011(6) 0.049(5)
H(1b3) -0.324(9) 0.000(6) -0.080(7) 0.049(5)
H(2a1) 0.259(8) 0.215(7) 0.073(5) 0.040(6)
H(2a2) 0.375(7) 0.219(7) -0.035(6) 0.040(6)
H(2b1) 0.335(8) 0.424(7) -0.048(6) 0.049(5)
H(2b2) 0.165(7) 0.407(7) -0.044(6) 0.049(5)
H(2b3) 0.282(9) 0.412(7) -.160(5) 0.049(5)
H(3a1) -0.351(8) 0.102(5) 0.180(6) 0.040(6)
H(3a2) -0.429(8) -0.026(6) 0.194(6) 0.040(6)
H(3b1) -0.462(7) -0.011(7) 0.390(7) 0.049(5)
H(3b2) -0.286(7) -0.004(6) 0.387(7) 0.049(5)
H(3b3) -0.366(8) -0.128(5) 0.407(7) 0.049(5)
H(4a1) -0.110(9) 0.427(6) -0.042(6) 0.040(6)
H(4a2) -0.095(8) 0.354(6) -0.124(6) 0.040(6)
H(4b1) -0.323(9) 0.456(5) -0.106(6) 0.049(5)
H(4b2) -0.372(9) 0.373(7) 0.030(5) 0.049(5)
H(4b3) -0.359(9) 0.315(6) -0.063(7) 0.049(5)
H(5a1) -0.030(8) 0.026(6) 0.401(6) 0.040(6)
H(5a2) 0.005(8) -0.063(6) 0.341(6) 0040(6)
H(5b1) 0.205(9) -0.058(6) 0.422(6) 0.049(5)
H(5b2) 0.218(9) 0.090(6) 0.356(6) 0.049(5)
H(5b3) 0.261(8) 0.012(7) 0.282(6) 0.049(5)
H(6a1) 0.393(8) 0.416(6) -0.355(6) 0.040(6)
H(6a2) 0.416(9) 0.324(6) -0.419(6) 0.040(6)
H(6b1) 0.632(9) 0.431(6) -0.451(5) 0.049(5)
H(6b2) 0.650(9) 0.284(6) -0.372(7) 0.049(5)
H(6b3) 0.627(9) 0.377(7) -0.307(6) 0.049(5)
H(7a1) 0.136(8) 0.235(6) 0.446(6) 0.040(6)
H(7a2) 0.151(8) 0.339(6) 0.307(5) 0.040(6)
H(7b1) 0.101(7) 0.419(7) 0.455(7) 0.049(5)
H(7b2) -0.050(8) 0.338(7) 0.511(6) 0.049(5)
H(7b3) -0.028(8) 0.452(7) 0.372(6) 0.049(5)
H(8a1) -0.342(9) 0.209(6) 0.408(6) 0.040(6)
H(8a2) -0.306(8) 0.354(6) 0.342(7) 0.040(6)
H(8b1) -0.563(9) 0.327(7) 0.384(6) 0.049(5)
H(8b2) -0.558(9) 0.242(6) 0.318(7) 0.049(5)
H(8b3) -0.501(9) 0.387(6) 0.256(6) 0.049(5)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O(1) Sb(1) O(2) 73.9(2) yes
O(1) Sb(1) O(3') 73.7(2) yes
O(1) Sb(1) O(6) 153.1(2) yes
O(2) Sb(1) O(3') 96.3(2) yes
O(2) Sb(1) O(6) 87.7(2) yes
O(3') Sb(1) O(6) 89.4(2) yes
O(4) Sb(2) O(5) 72.2(2) yes
O(4) Sb(2) O(7) 154.9(2) yes
O(4) Sb(2) O(8) 80.3(2) yes
O(5) Sb(2) O(7) 89.5(2) yes
O(5) Sb(2) O(8) 102.4(2) yes
O(7) Sb(2) O(8) 87.4(2) yes
O(1) Ni O(1') 77.9(2) yes
O(1) Ni O(2) 77.0(2) yes
O(1') Ni O(2) 95.0(2) yes
O(1) Ni O(3) 98.0(2) yes
O(1') Ni O(3) 76.9(2) yes
O(1) Ni O(4) 103.5(2) yes
O(1') Ni O(4) 173.9(2) yes
O(1) Ni O(5) 173.5(2) yes
O(1') Ni O(5) 105.2(2) yes
O(2) Ni O(3) 171.3(2) yes
O(2) Ni O(4) 91.1(2) yes
O(2) Ni O(5) 97.0(2) yes
O(3) Ni O(4) 97.0(2) yes
O(3) Ni O(5) 88.3(2) yes
O(4) Ni O(5) 74.0(2) yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Sb(1) O(1) 2.313(4) yes
Sb(1) O(2) 1.996(4) yes
Sb(1) O(3') 1.987(4) yes
Sb(1) O(6) 1.995(5) yes
Sb(2) O(4) 2.182(5) yes
Sb(2) O(5) 2.034(4) yes
Sb(2) O(7) 2.033(5) yes
Sb(2) O(8) 1.950(5) yes
Ni(1) O(1) 2.097(4) yes
Ni(1) O(2) 2.082(5) yes
Ni(1) O(3) 2.066(4) yes
Ni(1) O(4) 2.010(4) yes
Ni(1) O(5) 2.117(4) yes
O(1) C(1a) 1.446(8) yes
O(2) C(2a) 1.449(8) yes
O(3) C(3a) 1.474(8) yes
O(4) C(4a) 1.420(8) yes
O(5) C(5a) 1.434(8) yes
O(6) C(6a) 1.431(10) yes
O(7) C(7a) 1.407(10) yes
O(8) C(8a) 1.427(9) yes
C(1a) H(1a1) 1.03(8) no
C(1a) H(1a2) 0.98(8) no
C(1b) H(1b1) 1.00(8) no
C(1b) H(1b2) 0.97(8) no
C(1b) H(1b3) 1.00(8) no
C(2a) H(2a1) 0.99(8) no
C(2a) H(2a2) 0.98(8) no
C(2b) H(2b1) 0.99(8) no
C(2b) H(2b2) 1.02(8) no
C(2b) H(2b3) 0.98(8) no
C(3a) H(3a1) 1.00(8) no
C(3a) H(3a2) 1.06(8) no
C(3b) H(3b1) 0.99(8) no
C(3b) H(3b2) 1.01(8) no
C(3b) H(3b3) 1.01(8) no
C(4a) H(4a1) 0.94(8) no
C(4a) H(4a2) 1.04(8) no
C(4b) H(4b1) 0.92(8) no
C(4b) H(4b2) 1.07(8) no
C(4b) H(4b3) 0.96(8) no
C(5a) H(5a1) 1.00(8) no
C(5a) H(5a2) 0.97(8) no
C(5b) H(5b1) 0.98(8) no
C(5b) H(5b2) 1.00(8) no
C(5b) H(5b3) 0.97(8) no
C(6a) H(6a1) 1.00(8) no
C(6a) H(6a2) 1.00(8) no
C(6b) H(6b1) 1.00(8) no
C(6b) H(6b2) 1.01(8) no
C(6b) H(6b3) 0.99(8) no
C(7a) H(7a1) 1.00(8) no
C(7a) H(7a2) 1.03(8) no
C(7b) H(7b1) 0.98(8) no
C(7b) H(7b2) 1.00(8) no
C(7b) H(7b3) 1.00(8) no
C(8a) H(8a1) 0.91(8) no
C(8a) H(8a2) 0.96(8) no
C(8b) H(8b1) 0.94(8) no
C(8b) H(8b2) 0.98(8) no
C(8b) H(8b3) 0.95(8) no
_journal_paper_doi 10.1107/S0108270195000783