#------------------------------------------------------------------------------
#$Date: 2011-09-28 15:24:46 +0100 (Wed, 28 Sep 2011) $
#$Revision: 26848 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/47/2004783.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2004783
_journal_name_full               'Acta Crystallographica C'
_journal_volume                  52
_journal_year      1996
_journal_page_first     799
_journal_page_last     801
_publ_section_title
;
[Pt(PMe~3~)~2~(dppm)]Cl~2~.2H~2~O [dppm = Bis(diphenylphosphino)methane]
;
_chemical_formula_moiety     '[Pt(PMe~3~)~2~(dppm)]Cl~2~, 2H~2~O'
_chemical_formula_sum            'C31 H44 Cl2 O2 P4 Pt'
_[local]_cod_chemical_formula_sum_orig 'C31 H44 Cl2 O2 P4 Pt1'
_chemical_formula_weight     838.58
_symmetry_cell_setting    'monoclinic'
_symmetry_space_group_name_H-M   'C 1 c 1'
_[local]_cod_cif_authors_sg_H-M  'C c'
loop_
_symmetry_equiv_pos_as_xyz
'   +x,   +y,   +z'
'   +x,   +y,   +z'
'   +x,   -y,1/2+z'
'   +x,   -y,1/2+z'
_cell_length_a     12.670(10)
_cell_length_b     15.730(10)
_cell_length_c     17.471(9)
_cell_angle_alpha     90
_cell_angle_beta     102.76(5)
_cell_angle_gamma     90
_cell_volume     3397(4)
_cell_formula_units_Z     4
_exptl_crystal_density_diffrn     1.640
_cell_measurement_temperature     150
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Pt(1) -0.5030 -0.30321(3) -0.4997  .02430(10)
Cl(1) -0.2659(3) -0.2998(2) -0.5315(2)  .0398(10)
Cl(2) -0.3966(3) -0.1063(2) -0.9121(2)  .0407(10)
P(1) -0.5064(2) -0.3645(2) -0.3797(2)  .0250(8)
P(2) -0.5731(2) -0.4420(2) -0.5191(2)  .0262(7)
P(3) -0.5401(2) -0.2637(2) -0.6316(2)  .0292(8)
P(4) -0.4367(3) -0.1725(2) -0.4449(2)  .0289(7)
O(1) -0.5760(8) -0.2343(7) -0.8771(6)  .054(3)
O(2) -0.5888(8)  -.0595(7)  -.0562(6)  .048(3)
C(1) -0.3851(9) -0.4190(8) -0.3307(7)  .029(3)
C(2) -0.3843(9) -0.4695(8) -0.2610(7)  .026(3)
C(3) -0.2890(10)
               -0.5099(9) -0.2272(8)  .040(3)
C(4) -0.1979(10) -0.4995(8) -0.2568(7)  .032(3)
C(5) -0.1980(10)
               -0.4496(9) -0.3217(8)  .038(3)
C(6) -0.2916(9) -0.4082(8) -0.3581(7)  .031(3)
C(7) -0.5634(10) -0.3094(8) -0.3084(7)  .032(3)
C(8) -0.6710(10)
               -0.2782(9) -0.3316(8)  .042(3)
C(9) -0.7190(10)
               -0.2335(10) -0.2808(8)  .045(4)
C(10) -0.6640(10)
                -0.2219(10) -0.2047(9)  .046(4)
C(11) -0.5580(10)
                -0.2504(9) -0.1807(8)  .041(3)
C(12) -0.5090(10)
                -0.2917(9) -0.2309(8)  .040(3)
C(13) -0.6069(9) -0.4452(8) -0.4241(7)  .027(3)
C(14) -0.6923(9) -0.4649(8) -0.5945(6)  .024(3)
C(15) -0.7900(10)
                -0.4266(9) -0.5922(7)  .034(3)
C(16) -0.8830(10)
                -0.4411(9) -0.6563(7)  .036(3)
C(17) -0.8688(10) -0.4953(8) -0.7164(7)  .031(3)
C(18) -0.7700(10)
                -0.5352(9) -0.7160(8)  .040(3)
C(19) -0.6850(10)
                -0.5251(9) -0.6530(8)  .040(3)
C(20) -0.4790(9) -0.5216(7) -0.5174(6)  .025(3)
C(21) -0.495(2) -0.6047(7) -0.4980(10)
                                      .038(3)
C(22) -0.4210(10)
                -0.6681(9) -0.4907(8)  .038(3)
C(23) -0.3250(10)
                -0.6535(10) -0.5162(8)  .044(4)
C(24) -0.3040(10)
                -0.5747(10) -0.5412(8)  .044(3)
C(25) -0.3780(10)
                -0.5081(9) -0.5429(7)  .036(3)
C(26) -0.4720(10)
                -0.1750(10)
                          -0.6691(9)  .052(4)
C(27) -0.6770(10)
                -0.2371(10) -0.6683(8)  .043(3)
C(28) -0.5160(10)
                -0.3515(9) -0.6948(8)  .041(3)
C(29) -0.3330(10)
                -0.1859(9) -0.3564(8)  .036(3)
C(30) -0.5390(10)
                -0.1093(10) -0.4148(9)  .049(4)
C(31) -0.3700(10)
                 -.0971(9) -0.4993(8)  .044(3)
H(1) -0.4577 -0.4770 -0.2448  .0262
H(2) -0.2982 -0.5470 -0.1831  .0425
H(3) -0.1407 -0.5309 -0.2312  .0417
H(4) -0.1426 -0.4447 -0.3410  .0420
H(5) -0.3021 -0.3746 -0.4027  .0321
H(6) -0.7176 -0.2909 -0.3846  .0500
H(7) -0.8013 -0.2187 -0.2967  .0595
H(8) -0.7060 -0.1938 -0.1675  .0522
H(9) -0.5269 -0.2412 -0.1264  .0413
H(10) -0.4432 -0.3134 -0.2143  .0453
H(11) -0.6885 -0.4301 -0.4245  .0331
H(12) -0.6029 -0.5009 -0.3986  .0331
H(13) -0.8050 -0.3885 -0.5534  .0331
H(14) -0.9544 -0.4132 -0.6570  .0385
H(15) -0.9390 -0.5068 -0.7585  .0353
H(16) -0.7742 -0.5756 -0.7563  .0488
H(17) -0.6248 -0.5509 -0.6527  .0465
H(18) -0.5712 -0.6162 -0.4798  .0484
H(19) -0.4459 -0.7262 -0.4781  .0399
H(20) -0.2837 -0.6997 -0.5176  .0494
H(21) -0.2470 -0.5632 -0.5589  .0484
H(22) -0.3723 -0.4531 -0.5606  .0451
H(23) -0.4032 -0.1813 -0.6545  .0652
H(24) -0.4997 -0.1224 -0.6496  .0652
H(25) -0.5005 -0.1735 -0.7257  .0652
H(26) -0.7016 -0.1848 -0.6466  .0460
H(27) -0.7031 -0.2367 -0.7224  .0460
H(28) -0.7299 -0.2809 -0.6496  .0460
H(29) -0.5414 -0.3357 -0.7478  .0460
H(30) -0.5721 -0.3990 -0.6882  .0460
H(31) -0.4525 -0.3715 -0.6798  .0460
H(32) -0.2822 -0.2184 -0.3632  .0484
H(33) -0.3717 -0.2138 -0.3154  .0484
H(34) -0.3147 -0.1314 -0.3336  .0484
H(35) -0.5770 -0.1385 -0.3775  .0699
H(36) -0.5203 -0.0559 -0.3957  .0699
H(37) -0.6068 -0.0990 -0.4609  .0699
H(38) -0.3600 -0.0449 -0.4791  .0779
H(39) -0.4246 -0.0869 -0.5555  .0779
H(40) -0.3121 -0.1224 -0.5146  .0779
_cod_database_code 2004783