#------------------------------------------------------------------------------
#$Date: 2008-01-13 22:15:36 +0000 (Sun, 13 Jan 2008) $
#$Revision: 14 $
#$URL: svn://www.crystallography.net/cod/cif/2/2004937.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2004937
_journal_name_full  'Acta Crystallographica'
_journal_year       1996
_journal_volume    'C52'
_journal_page_first     1380
_journal_page_last     1384
_publ_section_title
;
(Z)-2,3-Bis(4'-[2.2.2]paracyclophanyl)but-2-ene and
\m-\h^6^:\h^6^-[(Z)-2,3-Bis(4'-[2.2.2]paracyclophanyl-but-2-ene]
-bis[hexafluoroantimonato-F)silver(I)] Toluene Dichloromethane (1/1/1)
;
_chemical_formula_iupac     '[Ag2 (Sb F6)2 (C52 H52) ] , C7 H8 , C H2 Cl2'
_chemical_formula_moiety     '[Ag2 (C52 H52) (Sb F6)2] , C7 H8 , C H2 Cl2'
_chemical_formula_sum     'C60 H62 Ag2 Cl2 F12 Sb2'
_chemical_formula_weight     1541.24
_symmetry_cell_setting    'monoclinic'
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
_symmetry_space_group_name_H-M     'C 2/c'
_cell_length_a     17.288(3)
_cell_length_b     12.159(2)
_cell_length_c     27.527(4)
_cell_angle_alpha     90.00
_cell_angle_beta     97.06(2)
_cell_angle_gamma     90.00
_cell_volume     5742.4(16)
_cell_formula_units_Z     4
_exptl_crystal_density_diffrn     1.783
_cell_measurement_temperature     163(2)
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Ag 1  .73437(2)  .48430(3)  .377709(14)  .03136(12)
C1 1  .7260(3)  .4828(5)  .2319(2)  .0321(11)
H1A 1  .7341(3)  .4024(5)  .2352(2)  .039
H1B 1  .7436(3)  .5060(5)  .2006(2)  .039
C2 1  .6380(3)  .5074(4)  .2301(2)  .0299(11)
H2A 1  .6285(3)  .5849(4)  .2201(2)  .036
H2B 1  .6090(3)  .4602(4)  .2048(2)  .036
C3 1  .6064(3)  .4888(4)  .2783(2)  .0277(10)
C4 1  .5552(3)  .5626(4)  .2965(2)  .0250(10)
C5 1  .5353(3)  .5462(4)  .3438(2)  .0283(10)
H5 1  .5013(3)  .5976(4)  .3563(2)  .034
C6 1  .5627(3)  .4587(4)  .3733(2)  .0282(10)
C7 1  .6103(3)  .3818(4)  .3537(2)  .0314(11)
H7 1  .6286(3)  .3191(4)  .3723(2)  .038
C8 1  .6311(3)  .3973(4)  .3067(2)  .0310(11)
H8 1  .6631(3)  .3440(4)  .2937(2)  .037
C9 1  .5457(3)  .4487(5)  .4258(2)  .0362(12)
H9A 1  .5764(3)  .3868(5)  .4415(2)  .043
H9B 1  .4899(3)  .4310(5)  .4258(2)  .043
C10 1  .5648(3)  .5535(5)  .4563(2)  .0354(12)
H10A 1  .5230(3)  .6081(5)  .4474(2)  .043
H10B 1  .5647(3)  .5352(5)  .4913(2)  .043
C11 1  .6418(3)  .6051(4)  .4496(2)  .0308(11)
C12 1  .7125(3)  .5495(4)  .4614(2)  .0318(11)
H12 1  .7124(3)  .4768(4)  .4740(2)  .038
C13 1  .7827(3)  .5996(5)  .4547(2)  .0348(12)
H13 1  .8301(3)  .5604(5)  .4629(2)  .042
C14 1  .7848(3)  .7071(4)  .4362(2)  .0343(11)
C15 1  .7150(3)  .7614(4)  .4253(2)  .0384(12)
H15 1  .7150(3)  .8348(4)  .4135(2)  .046
C16 1  .6446(3)  .7112(4)  .4311(2)  .0356(12)
H16 1  .5974(3)  .7502(4)  .4223(2)  .043
C17 1  .8601(3)  .7620(5)  .4285(2)  .0426(13)
H17A 1  .8903(3)  .7761(5)  .4609(2)  .051
H17B 1  .8483(3)  .8340(5)  .4126(2)  .051
C18 1  .9107(3)  .6961(5)  .3976(2)  .0398(13)
H18A 1  .9504(3)  .7456(5)  .3864(2)  .048
H18B 1  .9385(3)  .6385(5)  .4183(2)  .048
C19 1  .8661(3)  .6426(5)  .3537(2)  .0321(11)
C20 1  .8651(3)  .5291(5)  .3486(2)  .0339(11)
H20 1  .8954(3)  .4854(5)  .3724(2)  .041
C21 1  .8209(3)  .4778(5)  .3094(2)  .0326(11)
H21 1  .8212(3)  .3998(5)  .3071(2)  .039
C22 1  .7758(3)  .5395(4)  .2734(2)  .0311(11)
C23 1  .7774(3)  .6532(4)  .2784(2)  .0372(12)
H23 1  .7477(3)  .6974(4)  .2545(2)  .045
C24 1  .8220(3)  .7032(5)  .3178(2)  .0380(13)
H24 1  .8221(3)  .7811(5)  .3201(2)  .046
C25 1  .5256(3)  .6648(4)  .2702(2)  .0274(10)
C26 1  .5561(4)  .7696(4)  .2950(2)  .0425(14)
H26A 1  .6020(14)  .7529(6)  .3185(10)  .051
H26B 1  .5156(8)  .8026(17)  .3123(12)  .051
H26C 1  .571(2)    .8213(13)  .2704(3)  .051
Sb 1  .81721(2)  .17527(3)  .405021(13)  .03546(12)
F1 1  .8458(3)  .0363(3)  .38503(15)  .0710(13)
F2 1  .8713(3)  .1511(3)  .46660(14)  .0728(13)
F3 1  .9068(3)  .2333(4)  .3842(2)  .0739(12)
F4 1  .7642(3)  .2044(4)  .3436(2)  .084(2)
F5 1  .7291(3)  .1191(6)  .4257(3)  .129(2)
F6 1  .7918(3)  .3167(3)  .42440(14)  .0642(12)
C99 1  .5000  .1917(12)  .2500  .096(5)
H99A  .50  .4631  .2390(12)  .2652  .115
H99B  .50  .5369  .2390(12)  .2348  .115
Cl 1  .4462(2)  .0957(3)  .2031(2)  .1346(13)
C91  .50  .9726(6)  .4899(8)  .0284(3)  .062(4)
C92  .50  .9627(5)  .5743(7)  -.0059(4)  .060(4)
H92  .50  .9262(7)  .6313(9)  -.0025(5)  .072
C93  .50 1.0063(6)  .5751(7)  -.0451(3)  .067(4)
H93  .50  .9995(9)  .6327(9)  -.0685(4)  .080
C94  .50 1.0597(5)  .4916(9)  -.0500(3)  .060(4)
H94  .50 1.0895(8)  .4922(13)  -.0768(4)  .072
C95  .50 1.0696(5)  .4073(7)  -.0157(3)  .056(3)
H95  .50 1.1061(6)  .3502(9)  -.0191(5)  .067
C96  .50 1.0260(5)  .4065(7)  .0235(3)  .043(3)
H96  .50 1.0328(8)  .3488(8)  .0470(4)  .051
C97  .50  .9287(13)  .4965(18)  .0710(8)  .091(6)