#------------------------------------------------------------------------------ #$Date: 2012-02-03 17:16:24 +0000 (Fri, 03 Feb 2012) $ #$Revision: 32112 $ #$URL: svn://www.crystallography.net/cod/cif/2/00/49/2004961.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2004961 loop_ _publ_author_name 'Fernandez-Casta\~no, C.' 'Foces-Foces, C.' _publ_section_title ; p-Nitrophenyl \a-D-Mannopyranoside Hemihydrate ; _journal_issue 6 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 1586 _journal_page_last 1588 _journal_volume 52 _journal_year 1996 _chemical_formula_iupac '2C12 H15 N1 O8, H2 O1' _chemical_formula_moiety '2C12 H15 N1 O8, H2 O1' _chemical_formula_sum 'C24 H32 N2 O17' _chemical_formula_weight 620.52 _chemical_name_systematic 'p-nitrophenyl-\a-D-mannopyranoside hemihydrate' _space_group_IT_number 4 _symmetry_cell_setting monoclinic _symmetry_space_group_name_Hall 'P 2yb' _symmetry_space_group_name_H-M 'P 1 21 1' _cell_angle_alpha 90 _cell_angle_beta 98.440(10) _cell_angle_gamma 90 _cell_formula_units_Z 2 _cell_length_a 17.797(3) _cell_length_b 10.2594(6) _cell_length_c 7.4438(5) _cell_measurement_reflns_used 58 _cell_measurement_temperature 293 _cell_measurement_theta_max 45 _cell_measurement_theta_min 2 _cell_volume 1344.4(3) _computing_cell_refinement 'LSUCRE (Appleman, 1995)' _computing_data_collection 'Philips PW1100 software' _computing_data_reduction 'Xtal3.2 DIFDAT SORTRF ADDREF (Hall, Flack & Stewart, 1994)' _computing_molecular_graphics Xtal3.2 _computing_publication_material 'Xtal3.2 BONDLA CIFIO' _computing_structure_refinement 'Xtal3.2 CRYLSQ' _computing_structure_solution Xtal3.2 _diffrn_ambient_temperature 293 _diffrn_measurement_device 'Philips PW1100' _diffrn_measurement_method \w/2\q _diffrn_radiation_monochromator graphite _diffrn_radiation_source xray_tube _diffrn_radiation_type CuK\a _diffrn_radiation_wavelength 1.5418 _diffrn_reflns_av_R_equivalents .024 _diffrn_reflns_av_sigmaI/netI .034 _diffrn_reflns_limit_h_max 21 _diffrn_reflns_limit_h_min -21 _diffrn_reflns_limit_k_max 12 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_l_max 8 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_number 2720 _diffrn_reflns_reduction_process equatorial_monochr_Lp _diffrn_reflns_theta_max 67 _diffrn_reflns_theta_min 2 _diffrn_standards_decay_% 0 _diffrn_standards_interval_time 100 _diffrn_standards_number 2 _exptl_absorpt_coefficient_mu 1.14 _exptl_absorpt_correction_type none _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.533 _exptl_crystal_density_method 'not measured' _exptl_crystal_description plate _exptl_crystal_F_000 652 _exptl_crystal_size_max 0.33 _exptl_crystal_size_mid 0.20 _exptl_crystal_size_min 0.07 _refine_diff_density_max .253 _refine_diff_density_min -.211 _refine_ls_extinction_coef 132.E2(6) _refine_ls_extinction_method 'Zachariasen (1967)' _refine_ls_goodness_of_fit_all 1.017 _refine_ls_goodness_of_fit_obs 1.017 _refine_ls_hydrogen_treatment noref _refine_ls_matrix_type full _refine_ls_number_constraints 0 _refine_ls_number_parameters 387 _refine_ls_number_reflns 2451 _refine_ls_number_restraints 0 _refine_ls_R_factor_all .069 _refine_ls_R_factor_obs .069 _refine_ls_shift/esd_max .013 _refine_ls_shift/esd_mean .003 _refine_ls_structure_factor_coef F _refine_ls_weighting_scheme 'w = 0.5551/{[\c(|F~o~|)]^2^ x g(sin\q/\l)}' _refine_ls_wR_factor_all .069 _refine_ls_wR_factor_obs .069 _reflns_number_observed 2451 _reflns_number_total 2451 _reflns_observed_criterion 'F set to zero for negative F^2^' _[local]_cod_data_source_file cf1032.cif _[local]_cod_data_source_block cf1032 _[local]_cod_cif_authors_sg_H-M 'P 21' _[local]_cod_cif_authors_sg_Hall P_2y1 _cod_original_cell_volume 1344.4(2) _cod_database_code 2004961 loop_ _symmetry_equiv_pos_as_xyz +x,+y,+z -x,1/2+y,-z loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_thermal_displace_type _atom_site_calc_flag _atom_site_calc_attached_atom C101 .2858(3) .4807(6) .7622(7) .037(3) Uani yes yes C102 .3652(3) .4317(6) .8143(7) .037(3) Uani yes yes C103 .3778(3) .3869(6) 1.0137(7) .034(2) Uani yes yes C104 .3540(3) .4929(6) 1.1344(7) .031(2) Uani yes yes C105 .2722(3) .5319(6) 1.0697(6) .029(2) Uani yes yes C106 .2425(3) .6405(6) 1.1740(7) .038(3) Uani yes yes O101 .2381(2) .3675(5) .7592(5) .038(2) Uani yes yes O102 .4167(2) .5342(5) .7878(5) .040(2) Uani yes yes O103 .4553(2) .3557(5) 1.0700(6) .047(2) Uani yes yes O104 .3577(2) .4508(5) 1.3187(5) .041(2) Uani yes yes O105 .2654(2) .5752(5) .8818(4) .032(2) Uani yes yes O106 .2930(2) .7490(5) 1.1990(5) .039(2) Uani yes yes C107 .1620(3) .3794(6) .7094(6) .034(2) Uani yes yes C108 .1259(3) .4906(6) .6297(9) .046(3) Uani yes yes C109 .0490(3) .4893(7) .5768(8) .047(3) Uani yes yes C110 .0079(3) .3784(8) .6029(8) .047(3) Uani yes yes C111 .0432(3) .2698(7) .6870(8) .047(3) Uani yes yes C112 .1196(3) .2702(7) .7352(7) .041(3) Uani yes yes N113 -.0734(3) .3761(7) .5416(8) .057(3) Uani yes yes O114 -0.1021(3) .4732(7) .4587(8) .078(3) Uani yes yes O115 -0.1101(3) .2804(7) .5729(9) .079(3) Uani yes yes C201 .3348(3) .1376(6) .4528(7) .031(2) Uani yes yes C202 .4171(3) .0995(6) .4489(7) .032(2) Uani yes yes C203 .4217(3) -.0494(6) .4345(6) .026(2) Uani yes yes C204 .3855(3) -0.1142(6) .5869(6) .028(2) Uani yes yes C205 .3066(3) -.0616(6) .5963(7) .031(2) Uani yes yes C206 .2749(3) -0.1070(6) .7633(8) .037(3) Uani yes yes O201 .2945(2) .0951(5) .2848(4) .033(2) Uani yes yes O202 .4651(2) .1519(5) .6023(5) .035(2) Uani yes yes O203 .4987(2) -.0882(5) .4408(5) .033(2) Uani yes yes O204 .3793(2) -0.2504(5) .5398(5) .037(2) Uani yes yes O205 .3074(2) .08000 .6012(4) .032(2) Uani yes yes O206 .3280(2) -.0858(6) .9237(5) .050(2) Uani yes yes C207 .2187(3) .1198(6) .2464(7) .033(2) Uani yes yes C208 .1840(3) .2346(7) .2921(8) .044(3) Uani yes yes C209 .1076(3) .2513(8) .2411(8) .049(3) Uani yes yes C210 .0656(3) .1558(7) .1397(8) .045(3) Uani yes yes C211 .0992(3) .0425(7) .0915(8) .046(3) Uani yes yes C212 .1755(3) .0243(7) .1433(8) .043(3) Uani yes yes N213 -.0156(3) .1731(8) .0845(8) .058(3) Uani yes yes O214 -.0463(3) .2672(8) .1493(9) .087(4) Uani yes yes O215 -.0501(3) .0949(8) -.0171(8) .083(3) Uani yes yes O1 .4440(2) .0937(5) .9532(5) .042(2) Uani yes yes H101 .26800 .53590 .64230 .03131 Uiso ? ? H102 .37470 .35840 .73650 .02802 Uiso ? ? H103 .34900 .31120 1.04020 .02345 Uiso ? ? H104 .38550 .56840 1.12130 .02619 Uiso ? ? H105 .24280 .45440 1.07280 .02074 Uiso ? ? H1061 .23300 .61020 1.28610 .03341 Uiso ? ? H1062 .19510 .67060 1.10670 .03341 Uiso ? ? H108 .15430 .57000 .61460 .03699 Uiso ? ? H109 .02370 .56450 .52110 .04266 Uiso ? ? H111 .01550 .19180 .71210 .03898 Uiso ? ? H112 .14480 .19680 .79380 .03019 Uiso ? ? H1102 .46300 .50110 .73670 .02833 Uiso ? ? H1103 .46667 .28653 1.04240 .04488 Uiso ? ? H1104 .41250 .44690 1.35300 .02967 Uiso ? ? H1106 .33910 .73648 1.24806 .04849 Uiso ? ? H201 .33200 .22930 .46760 .02019 Uiso ? ? H202 .43270 .13660 .34160 .02523 Uiso ? ? H203 .39300 -0.07620 .31850 .02000 Uiso ? ? H204 .41660 -0.09260 .69960 .01990 Uiso ? ? H205 .27750 -0.09570 .45640 .02339 Uiso ? ? H208 .21340 .30330 .36640 .03430 Uiso ? ? H209 .08170 .33020 .27650 .03911 Uiso ? ? H211 .07020 -0.02280 .01980 .03886 Uiso ? ? H212 .19990 -0.05140 .10160 .03440 Uiso ? ? H2061 .22880 -0.05930 .77540 .02857 Uiso ? ? H2062 .26190 -0.19580 .75540 .02857 Uiso ? ? H2202 .44440 .11810 .74050 .03535 Uiso ? ? H2203 .51740 -0.18050 .44370 .03274 Uiso ? ? H2204 .41106 -0.30637 .64797 .03686 Uiso ? ? H2206 .30700 -0.11720 1.03400 .04779 Uiso ? ? H1 .48300 .03750 1.01930 .04105 Uiso ? ? H2 .39401 .03877 .95030 .04099 Uiso ? ? loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 C101 .043(3) .030(3) .037(3) -.010(2) .007(2) -.008(2) C102 .032(2) .034(3) .046(3) -.004(2) .013(2) -.013(2) C103 .027(2) .027(3) .047(3) -.003(2) .005(2) -.004(2) C104 .029(2) .030(3) .034(3) -.006(2) .008(2) .003(2) C105 .029(2) .028(2) .029(2) -.004(2) .004(2) -.001(2) C106 .035(3) .035(3) .045(3) -.005(2) .010(2) -.005(2) O101 .038(2) .028(2) .047(2) -.004(2) -.001(2) -.007(2) O102 .040(2) .038(2) .044(2) -.011(2) .013(2) -.010(2) O103 .031(2) .039(2) .070(3) .007(2) .000(2) -.013(2) O104 .042(2) .046(2) .034(2) .001(2) .0030(10) .010(2) O105 .035(2) .024(2) .035(2) .0000(10) .0020(10) -.0010(10) O106 .047(2) .028(2) .041(2) -.001(2) .007(2) -.004(2) C107 .037(3) .039(3) .026(2) -.004(2) .006(2) -.011(2) C108 .045(3) .031(3) .062(4) -.005(3) .006(3) -.002(3) C109 .041(3) .041(3) .057(4) .007(3) .002(3) -.003(3) C110 .037(3) .051(4) .053(3) -.002(3) .008(2) -.010(3) C111 .047(3) .046(3) .049(3) -.012(3) .012(3) -.004(3) C112 .042(3) .037(3) .043(3) -.005(2) .002(2) .001(3) N113 .041(3) .061(4) .069(4) -.004(3) .009(3) -.021(3) O114 .045(3) .081(4) .102(4) .009(3) -.014(3) -.009(4) O115 .040(2) .079(4) .118(4) -.014(3) .012(3) -.016(4) C201 .034(3) .022(2) .037(3) .000(2) .010(2) .002(2) C202 .030(2) .025(3) .040(3) -.006(2) .005(2) -.001(2) C203 .025(2) .025(2) .030(2) -.004(2) .009(2) .004(2) C204 .028(2) .023(2) .032(2) -.005(2) .003(2) .000(2) C205 .029(2) .026(3) .039(3) -.001(2) .011(2) .002(2) C206 .030(2) .038(3) .043(3) -.003(2) .010(2) .008(3) O201 .031(2) .038(2) .031(2) .006(2) .0040(10) -.004(2) O202 .033(2) .024(2) .048(2) -.0090(10) .005(2) -.001(2) O203 .0230(10) .028(2) .051(2) -.0010(10) .0130(10) .002(2) O204 .048(2) .019(2) .045(2) .000(2) .008(2) .000(2) O205 .034(2) .024(2) .040(2) .0020(10) .0100(10) .002(2) O206 .045(2) .069(3) .036(2) -.011(2) .007(2) .008(2) C207 .034(3) .034(3) .031(2) .003(2) .008(2) .002(2) C208 .041(3) .043(3) .048(3) .008(3) .007(2) -.004(3) C209 .048(3) .049(3) .051(3) .018(3) .012(3) .003(3) C210 .033(3) .059(4) .044(3) .004(3) .008(2) .016(3) C211 .048(3) .045(3) .045(3) -.001(3) .006(2) .000(3) C212 .043(3) .036(3) .051(3) .002(3) .007(2) -.005(3) N213 .037(3) .076(4) .061(3) .008(3) .009(3) .024(3) O214 .056(3) .091(4) .116(4) .035(3) .023(3) .023(4) O215 .040(2) .121(5) .084(4) -.002(3) -.006(2) .001(4) O1 .040(2) .035(2) .051(2) .006(2) .000(2) -.003(2) loop_ _atom_type_symbol _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C .017 .009 'International Tables' N .029 .018 'International Tables' O .047 .032 'International Tables' H 0 0 'International Tables' loop_ _diffrn_standard_refln_index_h _diffrn_standard_refln_index_k _diffrn_standard_refln_index_l 2 2 -1 3 1 1 loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_2 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C102 C101 O101 . . . 105.5(5) yes C102 C101 O105 . . . 113.0(4) yes C102 C101 H101 . . . 123.4(5) ? O101 C101 O105 . . . 111.2(4) yes O101 C101 H101 . . . 108.3(4) ? O105 C101 H101 . . . 95.2(5) ? C101 C102 C103 . . . 110.4(4) yes C101 C102 O102 . . . 108.5(5) yes C101 C102 H102 . . . 110.0(5) ? C102 C103 C104 . . . 110.2(5) yes C103 C102 O102 . . . 110.5(4) yes C103 C102 H102 . . . 109.2(5) ? O102 C102 H102 . . . 108.3(5) ? C103 C104 C105 . . . 109.9(4) yes C103 C104 O104 . . . 112.1(5) yes C104 C105 O105 . . . 109.1(4) yes C101 O105 C105 . . . 114.0(4) yes C202 C201 O201 . . . 105.6(4) yes C202 C201 O205 . . . 110.7(4) yes C202 C201 H201 . . . 108.9(5) ? O201 C201 O205 . . . 112.1(4) yes O201 C201 H201 . . . 112.3(5) ? O205 C201 H201 . . . 107.3(4) ? C201 C202 C203 . . . 108.6(4) yes C201 C202 O202 . . . 110.7(4) yes C201 C202 H202 . . . 108.1(5) ? C202 C203 C204 . . . 110.3(4) yes C202 C203 O203 . . . 109.7(4) yes C203 C204 C205 . . . 111.8(4) yes C203 C204 O204 . . . 105.4(4) yes C204 C205 O205 . . . 110.5(4) yes C201 O205 C205 . . . 113.9(4) yes H1103 O1 H2 . . . 129.2(3) ? H1103 O1 H2202 . . . 97.8(2) ? H2202 O1 H1 . . . 118.9(3) ? H2202 O1 O103 1_555 1_555 2_647 88.9(2) ? H2202 O1 O102 1_555 1_555 2_647 123.2(2) ? O206 O1 O102 1_555 1_555 2_647 117.3(2) ? O206 O1 O103 . . . 132.9(2) ? O103 O1 O202 . . . 94.1(2) ? O202 O1 O103 1_555 1_555 2_647 87.5(2) ? O202 O1 O102 1_555 1_555 2_647 116.2(2) ? O103 O1 O206 . . . 132.9(2) ? C102 C103 O103 . . . 110.5(4) no C102 C103 H103 . . . 115.5(5) ? C104 C103 O103 . . . 109.4(4) no C104 C103 H103 . . . 104.7(5) ? O103 C103 H103 . . . 106.2(5) ? C103 C104 H104 . . . 107.4(5) ? C105 C104 O104 . . . 106.9(4) no C105 C104 H104 . . . 107.4(5) ? O104 C104 H104 . . . 113.0(4) ? C104 C105 C106 . . . 115.3(4) no C104 C105 H105 . . . 106.1(5) ? C106 C105 O105 . . . 106.6(5) no C106 C105 H105 . . . 111.7(5) ? O105 C105 H105 . . . 108.0(4) ? C105 C106 O106 . . . 112.6(4) no C105 C106 H1061 . . . 110.0(6) ? C105 C106 H1062 . . . 108.5(5) ? O106 C106 H1061 . . . 109.8(5) ? O106 C106 H1062 . . . 107.6(6) ? H1061 C106 H1062 . . . 108.2(5) ? C101 O101 C107 . . . 119.7(5) no C102 O102 H1102 . . . 112.2(5) ? C103 O103 H1103 . . . 114.2(5) ? C104 O104 H1104 . . . 99.7(4) ? C106 O106 H1106 . . . 118.8(5) ? O101 C107 C108 . . . 124.6(6) no O101 C107 C112 . . . 115.7(5) no O101 C107 C1001 . . . 174.9(6) ? C108 C107 C112 . . . 119.7(5) ? C108 C107 C1001 . . . 60.0(3) ? C112 C107 C1001 . . . 59.7(3) ? C107 C108 C109 . . . 119.4(6) ? C107 C108 H108 . . . 121.2(5) ? C107 C108 C1001 . . . 59.2(4) ? C109 C108 H108 . . . 119.3(6) ? C109 C108 C1001 . . . 60.2(4) ? H108 C108 C1001 . . . 178.0(7) ? C108 C109 C110 . . . 119.8(6) ? C108 C109 H109 . . . 120.2(7) ? C108 C109 C1001 . . . 60.6(4) ? C110 C109 H109 . . . 120.0(6) ? C110 C109 C1001 . . . 59.2(4) ? H109 C109 C1001 . . . 179.2(6) ? C109 C110 C111 . . . 120.8(5) ? C109 C110 N113 . . . 119.6(6) no C109 C110 C1001 . . . 60.4(4) ? C111 C110 N113 . . . 119.7(6) no C111 C110 C1001 . . . 60.4(4) ? N113 C110 C1001 . . . 178.7(6) ? C110 C111 C112 . . . 119.3(6) ? C110 C111 H111 . . . 122.7(6) ? C110 C111 C1001 . . . 59.1(4) ? C112 C111 H111 . . . 118.0(6) ? C112 C111 C1001 . . . 60.2(4) ? H111 C111 C1001 . . . 177.9(6) ? C107 C112 C111 . . . 120.9(6) ? C107 C112 H112 . . . 118.5(5) ? C107 C112 C1001 . . . 60.0(4) ? C111 C112 H112 . . . 120.5(6) ? C111 C112 C1001 . . . 60.9(4) ? H112 C112 C1001 . . . 177.5(6) ? C110 N113 O114 . . . 117.4(6) no C110 N113 O115 . . . 119.4(6) no O114 N113 O115 . . . 123.2(5) no C203 C202 O202 . . . 113.5(4) no C203 C202 H202 . . . 108.1(5) ? O202 C202 H202 . . . 107.6(5) ? C202 C203 H203 . . . 108.4(4) ? C204 C203 O203 . . . 111.2(4) no C204 C203 H203 . . . 108.1(4) ? O203 C203 H203 . . . 109.1(4) ? C203 C204 H204 . . . 107.2(4) ? C205 C204 O204 . . . 108.6(4) no C205 C204 H204 . . . 107.2(5) ? O204 C204 H204 . . . 116.7(5) ? C204 C205 C206 . . . 112.8(4) no C204 C205 H205 . . . 98.4(4) ? C206 C205 O205 . . . 107.0(4) no C206 C205 H205 . . . 118.6(4) ? O205 C205 H205 . . . 109.2(4) ? C205 C206 O206 . . . 111.1(4) no C205 C206 H2061 . . . 110.1(5) ? C205 C206 H2062 . . . 111.4(5) ? O206 C206 H2061 . . . 108.1(5) ? O206 C206 H2062 . . . 109.1(5) ? H2061 C206 H2062 . . . 107.0(5) ? C201 O201 C207 . . . 119.1(4) no C202 O202 H2202 . . . 110.8(4) ? C203 O203 H2203 . . . 125.5(4) ? C204 O204 H2204 . . . 108.8(3) ? C206 O206 H2206 . . . 110.8(4) ? O201 C207 C208 . . . 124.5(5) no O201 C207 C212 . . . 115.6(5) no O201 C207 C1002 . . . 174.5(5) ? C208 C207 C212 . . . 119.8(5) ? C208 C207 C1002 . . . 60.1(3) ? C212 C207 C1002 . . . 59.7(3) ? C207 C208 C209 . . . 119.7(6) ? C207 C208 H208 . . . 121.2(5) ? C207 C208 C1002 . . . 59.5(4) ? C209 C208 H208 . . . 119.0(7) ? C209 C208 C1002 . . . 60.2(4) ? H208 C208 C1002 . . . 178.3(6) ? C208 C209 C210 . . . 119.8(7) ? C208 C209 H209 . . . 120.9(7) ? C208 C209 C1002 . . . 60.7(4) ? C210 C209 H209 . . . 119.3(6) ? C210 C209 C1002 . . . 59.1(4) ? H209 C209 C1002 . . . 178.0(7) ? C209 C210 C211 . . . 121.1(5) ? C209 C210 N213 . . . 120.1(6) no C209 C210 C1002 . . . 60.3(4) ? C211 C210 N213 . . . 118.8(6) no C211 C210 C1002 . . . 60.8(4) ? N213 C210 C1002 . . . 179.3(7) ? C210 C211 C212 . . . 119.5(6) ? C210 C211 H211 . . . 120.9(6) ? C210 C211 C1002 . . . 59.2(4) ? C212 C211 H211 . . . 119.6(7) ? C212 C211 C1002 . . . 60.3(4) ? H211 C211 C1002 . . . 178.9(6) ? C207 C212 C211 . . . 120.1(6) ? C207 C212 H212 . . . 120.1(5) ? C207 C212 C1002 . . . 59.4(4) ? C211 C212 H212 . . . 119.7(6) ? C211 C212 C1002 . . . 60.6(4) ? H212 C212 C1002 . . . 175.8(6) ? C210 N213 O214 . . . 117.4(6) no C210 N213 O215 . . . 119.3(7) no O214 N213 O215 . . . 123.3(6) no H1 O1 H2 . . . 103.4(4) ? C107 C1001 C108 . . . 60.8(4) ? C107 C1001 C109 . . . 120.0(4) ? C107 C1001 C110 . . . 179.2(5) ? C107 C1001 C111 . . . 119.1(4) ? C107 C1001 C112 . . . 60.3(4) ? C108 C1001 C109 . . . 59.2(4) ? C108 C1001 C110 . . . 119.6(4) ? C108 C1001 C111 . . . 178.8(4) ? C108 C1001 C112 . . . 121.1(4) ? C109 C1001 C110 . . . 60.4(4) ? C109 C1001 C111 . . . 120.8(4) ? C109 C1001 C112 . . . 179.6(5) ? C110 C1001 C111 . . . 60.5(4) ? C110 C1001 C112 . . . 119.3(4) ? C111 C1001 C112 . . . 58.8(4) ? C207 C1002 C208 . . . 60.4(4) ? C207 C1002 C209 . . . 119.5(4) ? C207 C1002 C210 . . . 179.7(4) ? C207 C1002 C211 . . . 120.0(4) ? C207 C1002 C212 . . . 60.9(4) ? C208 C1002 C209 . . . 59.1(4) ? C208 C1002 C210 . . . 119.6(5) ? C208 C1002 C211 . . . 179.5(5) ? C208 C1002 C212 . . . 121.3(4) ? C209 C1002 C210 . . . 60.5(4) ? C209 C1002 C211 . . . 120.6(4) ? C209 C1002 C212 . . . 179.6(4) ? C210 C1002 C211 . . . 60.0(4) ? C210 C1002 C212 . . . 119.1(4) ? C211 C1002 C212 . . . 59.0(4) ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_publ_flag C101 C102 1.496(7) yes C101 O101 1.437(8) yes C101 O105 1.400(7) yes C101 H101 1.065(6) ? C102 C103 1.538(8) yes C102 O102 1.427(7) yes C102 H102 .979(6) ? C103 C104 1.510(8) yes C103 O103 1.418(6) yes C103 H103 .966(6) ? C104 C105 1.518(6) yes C104 O104 1.430(6) yes C104 H104 .970(6) ? C105 C106 1.498(8) no C105 O105 1.455(6) yes C105 H105 .954(6) ? C106 O106 1.426(8) no C106 H1061 .929(6) ? C106 H1062 .967(5) ? O101 C107 1.356(6) no O102 H1102 1.016(4) ? O103 H1103 .774(5) ? O104 H1104 .971(4) ? O106 H1106 .8610(4) ? C107 C108 1.398(9) ? C107 C112 1.380(9) ? C107 C1001 1.376(5) ? C108 C109 1.368(8) ? C108 H108 .974(6) ? C108 C1001 1.386(7) ? C109 C110 1.380(10) ? C109 H109 .957(7) ? C109 C1001 1.381(7) ? C110 C111 1.380(10) ? C110 N113 1.452(7) no C110 C1001 1.365(6) ? C111 C112 1.353(8) ? C111 H111 .973(7) ? C111 C1001 1.382(7) ? C112 H112 .950(6) ? C112 C1001 1.372(7) ? N113 O114 1.240(10) no N113 O115 1.220(10) no C201 C202 1.520(7) yes C201 O201 1.416(6) yes C201 O205 1.401(6) yes C201 H201 .949(6) ? C202 C203 1.534(8) yes C202 O202 1.428(6) yes C202 H202 .962(5) ? C203 C204 1.536(7) yes C203 O203 1.421(6) yes C203 H203 .976(5) ? C204 C205 1.516(7) yes C204 O204 1.440(7) yes C204 H204 .961(4) ? C205 C206 1.512(8) no C205 O205 1.453(6) yes C205 H205 1.147(5) ? C206 O206 1.427(6) no C206 H2061 .970(5) ? C206 H2062 .939(7) ? O201 C207 1.361(6) no O202 H2202 1.194(4) ? O203 H2203 1.003(5) ? O204 H2204 1.079(4) ? O206 H2206 1.004(4) ? C207 C208 1.394(9) ? C207 C212 1.403(8) ? C207 C1002 1.382(5) ? C208 C209 1.368(8) ? C208 H208 .996(6) ? C208 C1002 1.391(7) ? C209 C210 1.387(9) ? C209 H209 .986(7) ? C209 C1002 1.384(8) ? C210 C211 1.380(10) ? C210 N213 1.454(7) no C210 C1002 1.367(6) ? C211 C212 1.367(8) ? C211 H211 .959(6) ? C211 C1002 1.390(7) ? C212 H212 .964(7) ? C212 C1002 1.385(7) ? N213 O214 1.240(10) no N213 O215 1.210(10) no O1 H1 .978(4) ? O1 H2 1.050(4) ? loop_ _geom_contact_publ_flag yes yes yes yes yes yes yes yes yes yes yes yes yes yes yes loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_publ_flag O101 C101 O105 C105 61.0(5) yes C102 C101 O105 C105 -57.3(6) yes O102 C102 C101 O105 -68.9(6) yes C103 C102 C101 O105 52.2(7) yes O103 C103 C102 C101 -172.8(5) yes C104 C103 C102 C101 -51.8(6) yes O104 C104 C103 C102 174.3(4) yes C105 C104 C103 C102 55.6(6) yes C106 C105 C104 C103 -177.7(5) yes O105 C105 C104 C103 -57.9(6) yes O201 C201 O205 C205 55.1(5) yes C202 C201 O205 C205 -62.5(5) yes O202 C202 C201 O205 -65.7(6) yes C203 C202 C201 O205 59.6(5) yes O203 C203 C202 C201 -176.8(4) yes C204 C203 C202 C201 -54.0(5) yes O204 C204 C203 C202 168.9(3) yes C205 C204 C203 C202 51.2(5) yes C206 C205 C204 C203 -170.6(4) yes O205 C205 C204 C203 -50.8(5) yes O106 C106 C105 C104 48.3(6) no C101 O101 C107 C108 11.4(8) no C102 C101 O101 C107 -177.6(4) no O105 C101 O101 C107 59.6(6) no O206 C206 C205 C204 50.1(7) no C201 O201 C207 C208 38.3(8) no C202 C201 O201 C207 -177.9(5) no O205 C201 O201 C207 61.4(6) no