data_2005047
_journal_name_full  'Acta Crystallographica'
_journal_year       1996
_journal_volume    	C52
_journal_page_first    	1430
_journal_page_last    	1436
_publ_section_title    	
;
Les Compos\'es de la Metformine avec les Ions Co^II^, Cu^II^ et Ni^II^
;
_chemical_formula_sum    	'C4 H11 Cl2 Cu N5'
_chemical_formula_weight    	263.6
_symmetry_cell_setting    	monoclinic
loop_
_symmetry_equiv_pos_as_xyz
'x,y,z'
'-x,-y,-z'
'1/2+x,1/2-y,1/2+z'
'-1/2-x,-1/2+y,-1/2-z'
_symmetry_space_group_name_H-M    	'P 21/n'
_cell_length_a    	7.727(1)
_cell_length_b    	16.675(5)
_cell_length_c    	8.023(2)
_cell_angle_alpha    	90
_cell_angle_beta    	115.25(2)
_cell_angle_gamma    	90
_cell_volume    	935.0(4)
_cell_formula_units_Z    	4
_exptl_crystal_density_diffrn    	1.873
_exptl_crystal_density_meas    	1.85(2)
_cell_measurement_temperature    	293
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Cu 0.0363(1) 0.4340(1) 0.7057(1) 0.0270(1)
Cl(1) -0.0428(2) 0.3175(1) 0.5385(2) 0.0410(1)
Cl(2) -0.2387(2) 0.4986(1) 0.5053(2) 0.0340(1)
N(1) 0.2393(6) 0.3811(3) 0.9109(6) 0.0300(4)
N(2) 0.4847(8) 0.3653(3) 1.2040(7) 0.0440(5)
N(3) 0.3472(7) 0.4882(3) 1.1169(6) 0.0320(4)
N(4) 0.1053(7) 0.5324(3) 0.8446(6) 0.0340(4)
N(5) 0.2520(7) 0.6206(3) 1.0891(6) 0.3050(4)
C(1) 0.3535(7) 0.4093(3) 1.0697(7) 0.0280(4)
C(2) 0.2288(7) 0.5480(3) 1.0096(7) 0.0270(4)
C(51) 0.412(1) 0.6436(4) 1.2593(8) 0.0410(6)
C(52) 0.133(1) 0.6870(4) 0.9820(9) 0.0440(6)
H(1) 0.2610 0.3272 0.9037 0.0641
H(21) 0.4962 0.3160 1.1611 0.0641
H(22) 0.5788 0.3871 1.3001 0.0641
H(3) 0.4016 0.4980 1.2372 0.0641
H(4) 0.0471 0.5815 0.7894 0.0641
H(511) 0.3744 0.6846 1.3236 0.0641
H(512) 0.4370 0.6135 1.3564 0.0641
H(513) 0.4874 0.6789 1.2251 0.0641
H(521) 0.1625 0.7020 0.8839 0.0641
H(522) 0.1369 0.7312 1.0568 0.0641
H(523) 0.0029 0.6796 0.9488 0.0641