data_2005116
_journal_name_full  'Acta Crystallographica'
_journal_year      1996
_journal_volume    	C52
_journal_page_first    	1641
_journal_page_last    	1642
_publ_section_title    	
;
trans-Dichloro(2-n-propylsulfinylpyridine-N)(triethylphosphine-P)palladium(II)
;
_chemical_formula_iupac    	'[Pd Cl2 (C6 H15 P) (C8 H11 N1 O1 S1)]'
_chemical_formula_moiety    	'[PdCl2P(C2H5)3(NC5H4)SOC3H7]'
_chemical_formula_sum    	'C14 H26 Cl2 N O P Pd S'
_chemical_formula_weight    	464.69
_symmetry_cell_setting    	triclinic
loop_
_symmetry_equiv_pos_as_xyz
'x,y,z'
'-x,-y,-z'
_symmetry_space_group_name_H-M    	'P -1'
_cell_length_a    	8.0420(8)
_cell_length_b    	8.4045(8)
_cell_length_c    	15.174(1)
_cell_angle_alpha    	105.021(8)
_cell_angle_beta    	95.128(9)
_cell_angle_gamma    	95.326(8)
_cell_volume    	979.4(2)
_cell_formula_units_Z    	2
_exptl_crystal_density_diffrn    	1.576
_cell_measurement_temperature    	298
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_B_iso_or_equiv
Pd 0.37603(4) 0.32836(4) 0.21476(3) 3.66(1)
Cl1 0.2903(2) 0.4029(2) 0.0844(1) 6.05(4)
Cl2 0.4618(2) 0.2467(2) 0.3428(1) 5.71(4)
N 0.2816(4) 0.0786(5) 0.1438(3) 3.7(1)
C2 0.1192(5) 0.0160(5) 0.1283(3) 3.8(1)
C3 0.0578(6) -0.1369(6) 0.0700(3) 4.6(1)
C4 0.1728(8) -0.2358(7) 0.0281(4) 5.5(2)
C5 0.3417(7) -0.1743(6) 0.0442(4) 4.9(2)
C6 0.3916(6) -0.0180(6) 0.1026(3) 4.2(1)
S -0.0252(2) 0.1453(2) 0.1860(1) 5.71(4)
O -0.1970(4) 0.0624(7) 0.1461(3) 7.6(2)
C7 0.0144(7) 0.088(1) 0.2942(4) 6.8(2)
C8 -0.086(1) 0.162(1) 0.3692(8) 10.9(4)
C9 -0.042(2) 0.318(1) 0.407(1) 14.5(6)
P 0.4824(2) 0.5929(2) 0.2773(1) 4.47(4)
C10 0.6274(8) 0.6639(8) 0.2072(4) 6.1(2)
C11 0.7742(9) 0.5660(9) 0.1918(6) 7.9(3)
C12 0.3201(8) 0.7322(7) 0.2820(5) 6.5(2)
C13 0.205(1) 0.715(1) 0.3541(7) 9.7(3)
C14 0.5932(8) 0.6419(7) 0.3915(4) 6.1(2)
C15 0.667(1) 0.8209(9) 0.4326(5) 8.9(3)
H3 -0.0754 -0.1787 0.0577 6.00
H4 0.1311 -0.3580 -0.0170 6.00
H5 0.4339 -0.2479 0.0117 6.00
H6 0.5238 0.0283 0.1156 6.00
H7A 0.1455 0.127 0.3198 6.00
H7B -0.0098 -0.045 0.2786 6.00
H8A -0.067 0.099 0.4225 6.00
H8B -0.217 0.141 0.3416 6.00
H9A -0.125 0.361 0.459 6.00
H9B -0.059 0.380 0.354 6.00
H9C 0.087 0.346 0.439 6.00
H10A 0.6753 0.7918 0.2405 6.00
H10B 0.5594 0.6554 0.1411 6.00
H11A 0.8621 0.6023 0.1487 6.00
H11B 0.7240 0.4374 0.1627 6.00
H11C 0.8379 0.5820 0.2598 6.00
H12A 0.2458 0.7022 0.2157 6.00
H12B 0.3794 0.8587 0.2988 6.00
H13A 0.117 0.805 0.3606 6.00
H13B 0.271 0.724 0.4209 6.00
H13C 0.139 0.592 0.3258 6.00
H14A 0.6950 0.5662 0.3892 6.00
H14B 0.5063 0.6102 0.4363 6.00
H15A 0.722 0.8507 0.5033 6.00
H15B 0.564 0.8931 0.4273 6.00
H15C 0.761 0.8493 0.3905 6.00