#------------------------------------------------------------------------------
#$Date: 2009-11-18 14:56:34 +0000 (Wed, 18 Nov 2009) $
#$Revision: 858 $
#$URL: svn://www.crystallography.net/cod/cif/2/2005191.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2005191
_journal_name_full 'Acta Crystallographica Section C'
_journal_year       1996
_journal_volume 52
_journal_page_first             1881
_journal_page_last              1884
_publ_section_title
;
{4-Methyl-2-[(2-oxidobenzylidene)amino]phenolato(2-)-N,O,O'}(piperidine-N)
nickel(II)
;
_chemical_formula_iupac        '[Ni (C14 H11 N1 O2) (C5 H11 N1)]'
_chemical_formula_moiety        'Ni(C14 H11 O2 N)(C5 H11 N)'
_chemical_formula_sum            'C19 H22 N2 Ni O2'
_[local]_cod_chemical_formula_sum_orig 'C19 H22 N2 O2 Ni'
_chemical_formula_weight        369.11
_symmetry_cell_setting          monoclinic
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_[local]_cod_cif_authors_sg_H-M  'P 21/c'
loop_
_symmetry_equiv_pos_as_xyz
        x,y,z
        '-x,-y,-z'
        '-x,1/2+y,1/2-z'
        x,1/2-y,1/2+z
_cell_length_a                  10.664(3)
_cell_length_b                  14.088(5)
_cell_length_c                  12.494(2)
_cell_angle_alpha               90
_cell_angle_beta                110.6(1)
_cell_angle_gamma               90
_cell_volume                    1757(1)
_cell_formula_units_Z           4
_exptl_crystal_density_diffrn   1.395
_exptl_crystal_density_meas     1.358
_cell_measurement_temperature   296
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_B_iso_or_equiv
Ni              .0576(1)        .17291(8)       .33844(8)       3.87(2)
O1              .1839(5)        .0919(4)        .4260(4)        5.2(1)
O2              -.0669(4)       .2536(4)        .2431(4)        4.0(1)
N1              -.0330(5)       .1859(4)        .4406(4)        3.6(1)
N2              .1360(5)        .1671(5)        .2207(5)        4.3(2)
C1              .1963(7)        .0592(6)        .5274(6)        4.4(2)
C2              .3017(8)        -.0034(6)       .5816(7)        5.8(3)
C3              .3188(8)        -.0417(7)       .6854(8)        6.5(3)
C4              .2318(9)        -.0201(7)       .7438(7)        6.6(3)
C5              .1287(9)        .0424(6)        .6944(7)        5.3(2)
C6              .1077(7)        .0821(6)        .5865(6)        4.2(2)
C7              -.0042(7)       .1422(5)        .5372(6)        3.9(2)
C8              -0.1465(6)      .2469(5)        .3967(5)        3.0(2)
C9              -0.2370(7)      .2736(6)        .4474(6)        3.6(2)
C10             -0.3445(6)      .3293(6)        .3916(6)        4.0(2)
C11             -0.3630(7)      .3581(6)        .2807(6)        4.7(2)
C12             -0.2711(7)      .3353(6)        .2300(6)        4.5(2)
C13             -0.1611(7)      .2784(6)        .2866(5)        3.6(2)
C14             -0.4447(7)      .3569(7)        .4466(7)        6.0(3)
C15             .2724(7)        .1982(6)        .2512(7)        5.6(3)
C16             .3249(8)        .1986(7)        .1508(7)        6.8(3)
C17             .3031(8)        .1054(7)        .0920(8)        7.0(3)
C18             .1611(7)        .0739(7)        .0602(6)        5.7(2)
C19             .1132(7)        .0753(7)        .1619(6)        5.8(2)
H2              .363            -0.019          .545            7.7
H3              .391            -0.084          .72             8.9
H4              .243            -0.049          .815            8.4
H5              .07             .06             .733            7.4
H7              -0.064          .15             .578            4.8
H9              -0.224          .252            .523            4.6
H11             -0.44           .394            .24             6.4
H12             -0.281          .359            .156            5.5
H141            -0.512          .395            .394            8.2
H142            -0.485          .302            .465            8.2
H143            -0.401          .392            .514            8.2
H151            .326            .155            .307            7.5
H152            .281            .26             .283            7.5
H161            .417            .215            .177            8.8
H162            .275            .245            .097            8.8
H171            .359            .06             .144            8.9
H172            .327            .109            .026            8.9
H181            .151            .011            .03             8
H182            .107            .116            .004            8
H191            .02             .061            .137            7.7
H192            .162            .029            .215            7.7
H2'             .082            .213            .169            5.7