#------------------------------------------------------------------------------
#$Date: 2008-01-13 22:15:36 +0000 (Sun, 13 Jan 2008) $
#$Revision: 14 $
#$URL: svn://www.crystallography.net/cod/cif/2/2005224.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2005224
_journal_name_full  'Acta Crystallographica'
_journal_year       1996
_journal_volume                 C52
_journal_page_first             1942
_journal_page_last              1943
_publ_section_title
;
trans-Di-\m-chloro-bis[chloro(trimethylphosphine-P)platinum(II)]
;
_chemical_formula_iupac        '[Pt2 Cl4 (C3 H9 P1)2]'
_chemical_formula_moiety        'C3 H9 Cl2 P Pt'
_chemical_formula_sum          'C3 H9 Cl2 P Pt'
_chemical_formula_structural    'Pt P (CH3)3 Cl2'
_chemical_formula_analytical    'C10.53 H2.63 Cl20.76 P9.06 Pt57.02'
_chemical_formula_weight        684.12
_symmetry_cell_setting          monoclinic
loop_
_symmetry_equiv_pos_as_xyz
        'x, y, z'
        '-x+1/2, y+1/2, -z+1/2'
        '-x, -y, -z'
        'x-1/2, -y-1/2, z-1/2'
_symmetry_space_group_name_H-M  'P 21/n'
_cell_length_a                  6.594(1)
_cell_length_b                  10.763(2)
_cell_length_c                  11.649(2)
_cell_angle_alpha               90
_cell_angle_beta                105.36(1)
_cell_angle_gamma               90
_cell_volume                    797.2(2)
_cell_formula_units_Z           2
_exptl_crystal_density_diffrn   2.85
_cell_measurement_temperature   293(2)
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Pt1     1       .11762(6)
                        .10541(4)
                                .11383(3)
                                        .0335(2)
Cl1     1       -0.1500(5)
                        -.0395(4)
                                .0794(3)
                                        .0600(9)
Cl2     1       .3836(5)
                        .2455(4)
                                .1314(3)
                                        .0578(8)
P1      1       .0863(4)
                        .1609(3)
                                .2905(2)
                                        .0359(6)
C1      1       .040(2) .324(1) .301(1) .064(4)
H1A     1       .15(1)  .370(1) .279(9) .096
H1B     1       .04(2)  .345(2) .381(2) .096
H1C     1       -.094(8)
                        .345(2) .248(7) .096
C2      1       -0.119(2)
                        .085(1) .337(1) .057(3)
H2A     1       -.095(9)
                        -.004(2)
                                .341(9) .086
H2B     1       -0.252(3)
                        .102(8) .282(5) .086
H2C     1       -0.12(1)
                        .114(7) .415(4) .086
C3      1       .318(2) .127(2) .409(1) .067(4)
H3A     1       .427(6) .185(7) .407(6) .101
H3B     1       .37(1)  .044(4) .400(6) .101
H3C     1       .285(5) .13(1)  .485(1) .101