#------------------------------------------------------------------------------
#$Date: 2011-09-28 15:24:46 +0100 (Wed, 28 Sep 2011) $
#$Revision: 26848 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/52/2005265.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2005265
_journal_name_full 'Acta Crystallographica Section C'
_journal_year       1996
_journal_volume 52
_journal_page_first             2063
_journal_page_last              2066
_publ_section_title
;
Two N-Aryl-Substituted Silyl Carbamates
;
_chemical_formula_iupac        'C10 H14 Br1 N1 O2 Si1'
_chemical_formula_sum          'C10 H14 Br N O2 Si'
_chemical_formula_weight        288.22
_symmetry_cell_setting          orthorhombic
loop_
_symmetry_equiv_pos_as_xyz
        'x, y, z'
        '-x+1/2, -y, z+1/2'
        'x+1/2, -y+1/2, -z'
        '-x, y+1/2, -z+1/2'
_symmetry_space_group_name_H-M  'P 21 21 21'
_cell_length_a                  10.303(2)
_cell_length_b                  23.585(3)
_cell_length_c                  5.335(3)
_cell_angle_alpha               90
_cell_angle_beta                90
_cell_angle_gamma               90
_cell_volume                    1296.3(9)
_cell_formula_units_Z           4
_exptl_crystal_density_diffrn   1.477
_cell_measurement_temperature   293(2)
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Br1     1       .40627(9)
                        .51255(4)
                                .1097(3)
                                        .0943(4)
Si1     1       1.2237(2)
                        .69320(8)
                                -0.2377(4)
                                        .0525(5)
O9      1       1.1113(4)
                        .6712(2)
                                -.0272(9)
                                        .056(1)
O13     1       .9607(5)
                        .6472(2)
                                -0.3141(9)
                                        .060(1)
N7      1       .9269(5)
                        .6322(2)
                                .109(1) .051(1)
H7      1       .9597(5)
                        .6382(2)
                                .254(1) .07(1)
C1      1       .8040(6)
                        .6051(2)
                                .097(1) .043(1)
C2      1       .7153(6)
                        .6152(3)
                                -.091(2)
                                        .057(2)
H2      1       .7341(6)
                        .6406(3)
                                -0.219(2)
                                        .07(1)
C3      1       .5975(6)
                        .5868(3)
                                -.086(2)
                                        .057(2)
H3      1       .5382(6)
                        .5921(3)
                                -0.215(2)
                                        .07(1)
C4      1       .5676(6)
                        .5513(3)
                                .107(2) .057(2)
C5      1       .6537(8)
                        .5422(3)
                                .297(2) .067(2)
H5      1       .6321(8)
                        .5179(3)
                                .427(2) .07(1)
C6      1       .7739(8)
                        .5691(3)
                                .295(2) .056(2)
H6      1       .8329(8)
                        .5631(3)
                                .424(2) .07(1)
C8      1       .9968(6)
                        .6493(3)
                                -.096(2)
                                        .052(2)
C10     1       1.3613(7)
                        .7142(4)
                                -.036(2)
                                        .077(3)
H10A    1       1.3360(7)
                        .7457(4)
                                .067(2) .10(1)
H10B    1       1.4337(7)
                        .7249(4)
                                -0.138(2)
                                        .10(1)
H10C    1       1.3855(7)
                        .6828(4)
                                .069(2) .10(1)
C11     1       1.2712(8)
                        .6326(3)
                                -0.436(2)
                                        .067(2)
H11A    1       1.3033(8)
                        .6025(3)
                                -0.332(2)
                                        .10(1)
H11B    1       1.3378(8)
                        .6443(3)
                                -0.551(2)
                                        .10(1)
H11C    1       1.1971(8)
                        .6195(3)
                                -0.529(2)
                                        .10(1)
C12     1       1.1593(8)
                        .7548(3)
                                -0.412(2)
                                        .074(2)
H12A    1       1.1368(8)
                        .7844(3)
                                -0.296(2)
                                        .10(1)
H12B    1       1.0834(8)
                        .7436(3)
                                -0.504(2)
                                        .10(1)
H12C    1       1.2241(8)
                        .7685(3)
                                -0.527(2)
                                        .10(1)
_cod_database_code 2005265