data_2005279
_journal_name_full  'Acta Crystallographica'
_journal_year       1996
_journal_volume                 C52
_journal_page_first             1954
_journal_page_last              1957
_publ_section_title
;
Bis(N,N'-dimethylthiourea-S)silver(I) Perchlorate and
Tris(N,N'-dimethylthiourea-S)silver(I) Perchlorate
;
_chemical_formula_iupac        '[Ag (C3 H8 N2 S)3] Cl O4'
_chemical_formula_sum          'C9 H24 Ag Cl N6 O4 S3'
_chemical_formula_weight        519.84
_symmetry_cell_setting          triclinic
loop_
_symmetry_equiv_pos_as_xyz
        'x, y, z'
        '-x, -y, -z'
_symmetry_space_group_name_H-M  'P -1'
_cell_length_a                  9.887(1)
_cell_length_b                  10.096(1)
_cell_length_c                  10.687(1)
_cell_angle_alpha               90.96(1)
_cell_angle_beta                105.68(1)
_cell_angle_gamma               95.15(1)
_cell_volume                    1022.0(2)
_cell_formula_units_Z           2
_exptl_crystal_density_diffrn   1.689
_cell_measurement_temperature   293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Ag              .46926(2)       .84828(2)       .54823(2)       .0508(1)
S1              .44087(7)       .92984(6)       .30671(6)       .0419(2)
N1              .1917(3)        1.0264(2)       .2396(3)        .0514(5)
N2              .1836(3)        .8001(2)        .2269(2)        .0463(5)
C1              .2584(3)        .9176(2)        .2543(2)        .0389(5)
C2              .0395(4)        1.0291(4)       .2001(4)        .0655(8)
C3              .2405(4)        .6722(3)        .2382(4)        .0584(7)
S2              .65186(7)       .67750(6)       .58405(6)       .0448(2)
N3              .7419(3)        .7384(2)        .3749(3)        .0501(5)
N4              .5808(3)        .5571(2)        .3512(2)        .0473(5)
C4              .6582(3)        .6576(2)        .4248(2)        .0400(5)
C5              .8251(5)        .8573(4)        .4402(5)        .0686(9)
C6              .5738(4)        .5299(4)        .2160(3)        .0581(7)
S3              .22652(7)       .76191(8)       .56388(7)       .0532(2)
N5              .3371(4)        .8245(4)        .8138(3)        .0756(9)
N6              .1413(3)        .6748(3)        .7639(3)        .0630(7)
C7              .2362(3)        .7529(3)        .7246(3)        .0464(6)
C8              .359(1)         .820(1)         .9532(5)        .118(2)
C9              .0328(5)        .5846(5)        .6817(6)        .088(1)
Cl              .18118(9)       .32315(8)       .98868(7)       .0595(2)
O1              .1402(3)        .2751(3)        .8558(3)        .0909(9)
O2              .2245(4)        .4613(3)        .9906(3)        .098(1)
O3              .0607(4)        .2981(4)        1.0363(3)       .110(1)
O4              .2924(4)        .2597(5)        1.0663(5)       .138(2)
H1N             .240(4)         1.097(4)        .257(4)         .06(1)
H3N             .736(4)         .726(3)         .301(3)         .051(9)
H5N             .387(4)         .872(4)         .789(4)         .06(1)
H2N             .101(4)         .800(4)         .197(4)         .07(1)
H4N             .532(3)         .511(3)         .387(3)         .038(7)
H6N             .157(4)         .674(4)         .845(4)         .07(1)
H2A             .001(5)         .987(5)         .109(5)         .10(2)
H2B             -.002(5)        .978(5)         .254(5)         .10(2)
H2C             .019(5)         1.124(6)        .204(5)         .11(2)
H3A             .190(5)         .613(5)         .181(5)         .10(2)
H3B             .324(6)         .679(5)         .228(5)         .10(2)
H3C             .250(5)         .645(4)         .320(5)         .08(1)
H5A             .827(7)         .927(7)         .376(7)         .15(2)
H5B             .777(7)         .917(6)         .472(6)         .13(2)
H5C             .908(8)         .851(7)         .483(7)         .15(3)
H6A             .508(5)         .462(4)         .183(4)         .08(1)
H6B             .538(4)         .603(4)         .165(4)         .07(1)
H6C             .665(5)         .517(4)         .201(4)         .08(1)
H8A             .455(8)         .872(8)         .998(8)         .16(3)
H8B             .300(7)         .875(7)         .959(6)         .12(3)
H8C             .363(8)         .747(8)         .981(7)         .14(3)
H9A             .06(1)          .514(9)         .674(9)         .19(4)
H9B             -.023(7)        .628(7)         .620(7)         .14(2)
H9C             -.05(1)         .56(1)          .72(1)          .26(5)