data_2005485 _journal_name_full 'Acta Crystallographica' _journal_year 1996 _journal_volume C52 _journal_page_first 2463 _journal_page_last 2464 _publ_section_title ; cis-Dichloro(triethylphosphine-P)[tris(2,6-difluorophenyl)phosphite-P]- platinum(II) ; _chemical_formula_iupac '[Pt Cl2 (C18 H9 F6 O3 P) (C6 H15 P)]' _chemical_formula_sum 'C24 H24 Cl2 F6 O3 P2 Pt' _chemical_formula_structural 'Pt (Cl)2 (P (O C6 H3 F2)3) (P (C2 H5)3) ' _chemical_formula_weight 802.36 _symmetry_cell_setting monoclinic loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _symmetry_space_group_name_H-M 'P 21/c' _cell_length_a 9.709(2) _cell_length_b 15.482(2) _cell_length_c 18.267(3) _cell_angle_alpha 90. _cell_angle_beta 96.20(1) _cell_angle_gamma 90. _cell_volume 2729.7(8) _cell_formula_units_Z 4 _exptl_crystal_density_diffrn 1.952 _cell_measurement_temperature 293(2) loop_ _atom_site_label _atom_site_occupancy _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv Pt1 1 0.19555(2) 0.187793(13) 0.193358(11) 0.01968(8) P1 1 0.32510(14) 0.19229(9) 0.29829(7) 0.0192(3) P2 1 0.3516(2) 0.16848(10) 0.11047(8) 0.0260(4) Cl1 1 0.0306(2) 0.17799(10) 0.09153(8) 0.0356(4) Cl2 1 0.01502(14) 0.21799(10) 0.26642(8) 0.0271(3) F1 1 0.6713(4) 0.2919(2) 0.3088(2) 0.0467(10) F2 1 0.5037(4) 0.0431(2) 0.4150(2) 0.0408(9) F3 1 0.3367(4) -0.0017(2) 0.2775(2) 0.0400(9) F4 1 0.0615(4) 0.1232(2) 0.4424(2) 0.0395(9) F5 1 0.1241(4) 0.3503(3) 0.4053(2) 0.0560(11) F6 1 0.4432(4) 0.3698(3) 0.2331(2) 0.0516(11) O1 1 0.4834(4) 0.1630(2) 0.3003(2) 0.0236(9) O2 1 0.2738(4) 0.1374(2) 0.3641(2) 0.0212(9) O3 1 0.3414(4) 0.2817(2) 0.3425(2) 0.0266(9) C1 1 0.3313(7) 0.2513(4) 0.0382(3) 0.0317(15) H1A 1 0.2405(7) 0.2461(4) 0.0122(3) 0.048(14) H1B 1 0.3975(7) 0.2399(4) 0.0040(3) 0.048(14) C2 1 0.3529(8) 0.3436(4) 0.0657(4) 0.045(2) H2A 1 0.3412(8) 0.3831(4) 0.0250(4) 0.044(11) H2B 1 0.2857(8) 0.3560(4) 0.0991(4) 0.044(11) H2C 1 0.4444(8) 0.3497(4) 0.0908(4) 0.044(11) C3 1 0.5344(6) 0.1690(4) 0.1433(3) 0.036(2) H3A 1 0.5517(6) 0.1256(4) 0.1806(3) 0.067(17) H3B 1 0.5562(6) 0.2240(4) 0.1659(3) 0.067(17) C4 1 0.6332(8) 0.1555(6) 0.0849(4) 0.068(3) H4A 1 0.7275(8) 0.1573(6) 0.1069(4) 0.093(17) H4B 1 0.6143(8) 0.0999(6) 0.0627(4) 0.093(17) H4C 1 0.6189(8) 0.1995(6) 0.0479(4) 0.093(17) C5 1 0.3233(7) 0.0688(4) 0.0585(3) 0.037(2) H5A 1 0.3847(7) 0.0682(4) 0.0207(3) 0.032(11) H5B 1 0.2302(7) 0.0694(4) 0.0347(3) 0.032(11) C6 1 0.3440(10) -0.0132(4) 0.1023(4) 0.065(3) H6A 1 0.3266(10) -0.0621(4) 0.0704(4) 0.083(16) H6B 1 0.4377(10) -0.0155(4) 0.1253(4) 0.083(16) H6C 1 0.2813(10) -0.0142(4) 0.1395(4) 0.083(16) C11 1 0.5806(6) 0.1706(4) 0.3625(3) 0.0261(14) C12 1 0.6786(6) 0.2357(4) 0.3651(3) 0.0327(15) C13 1 0.7821(6) 0.2426(4) 0.4221(4) 0.040(2) H13A 1 0.8501(6) 0.2877(4) 0.4223(4) 0.048(11) C14 1 0.7860(7) 0.1843(5) 0.4785(4) 0.044(2) H14A 1 0.8544(7) 0.1905(5) 0.5202(4) 0.048(11) C15 1 0.6939(6) 0.1175(4) 0.4773(3) 0.035(2) H15A 1 0.6998(6) 0.0755(4) 0.5161(3) 0.048(11) C16 1 0.5929(6) 0.1102(4) 0.4182(3) 0.0272(14) C21 1 0.1971(6) 0.0624(4) 0.3585(3) 0.0225(13) C22 1 0.2280(6) -0.0080(4) 0.3164(3) 0.0286(14) C23 1 0.1500(7) -0.0827(4) 0.3146(3) 0.039(2) H23A 1 0.1718(7) -0.1307(4) 0.2846(3) 0.049(12) C24 1 0.0390(7) -0.0868(4) 0.3562(4) 0.042(2) H24A 1 -0.0166(7) -0.1382(4) 0.3554(4) 0.049(12) C25 1 0.0074(7) -0.0179(4) 0.3994(3) 0.035(2) H25A 1 -0.0690(7) -0.0209(4) 0.4286(3) 0.049(12) C26 1 0.0863(6) 0.0554(4) 0.3998(3) 0.0289(14) C31 1 0.2823(6) 0.3592(4) 0.3185(3) 0.0263(14) C32 1 0.1766(7) 0.3951(4) 0.3521(4) 0.039(2) C33 1 0.1255(8) 0.4758(5) 0.3325(5) 0.060(2) H33A 1 0.0508(8) 0.5007(5) 0.3558(5) 0.093(17) C34 1 0.1834(10) 0.5193(5) 0.2770(5) 0.070(3) H34A 1 0.1491(10) 0.5757(5) 0.2629(5) 0.093(17) C35 1 0.2897(9) 0.4854(5) 0.2420(5) 0.063(3) H35A 1 0.3291(9) 0.5161(5) 0.2037(5) 0.093(17) C36 1 0.3377(7) 0.4059(4) 0.2643(4) 0.039(2)