data_2005502
_journal_name_full  'Acta Crystallographica'
_journal_year       1996
_journal_volume    	C52
_journal_page_first    	2515
_journal_page_last    	2520
_publ_section_title    	
;
Monospiroaryloxyphosphazenes: p-Fluorophenoxy Derivatives Containing the
1,2-Phenylenedioxy and 2,3-Naphthalenedioxy Groups
;
_chemical_formula_sum    	'C34 H22 F4 N3 O6 P3'
_chemical_formula_weight    	737.46
_symmetry_cell_setting    	orthorhombic
loop_
_symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    '-x, y+1/2, -z+1/2'
    'x+1/2, -y+1/2, -z'
    '-x, -y, -z'
    'x-1/2, y, -z-1/2'
    'x, -y-1/2, z-1/2'
    '-x-1/2, y-1/2, z'
_symmetry_space_group_name_H-M    	'P b c a'
_cell_length_a    	8.13250(10)
_cell_length_b    	26.5942(3)
_cell_length_c    	29.8727(5)
_cell_angle_alpha    	90.00
_cell_angle_beta    	90.00
_cell_angle_gamma    	90.00
_cell_volume    	6460.8(2)
_cell_formula_units_Z    	8
_exptl_crystal_density_diffrn    	1.516
_cell_measurement_temperature    	203(2)
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
    P1 1 0.68951(11) 0.09392(3) 0.66268(3) 0.0355(2)
    P2 1 0.70453(10) 0.00391(3) 0.61651(3) 0.0348(2)
    P3 1 0.41897(10) 0.06074(3) 0.61425(3) 0.0340(2)
    F14 1 0.4853(4) -0.22961(8) 0.58888(9) 0.0975(9)
    F20 1 0.8657(2) 0.12434(8) 0.43545(6) 0.0624(6)
    F26 1 0.1733(3) -0.10325(8) 0.76060(7) 0.0746(7)
    F32 1 0.5403(3) 0.27617(7) 0.51783(8) 0.0829(8)
    O1 1 0.6931(3) 0.09828(7) 0.71649(6) 0.0374(5)
    O2 1 0.7954(3) 0.14391(8) 0.65252(7) 0.0414(6)
    O3 1 0.7214(3) -0.04681(8) 0.64346(7) 0.0396(6)
    O4 1 0.8192(2) -0.00898(7) 0.57479(7) 0.0370(5)
    O5 1 0.2466(2) 0.04397(8) 0.63386(7) 0.0378(5)
    O6 1 0.3454(3) 0.08869(8) 0.57181(7) 0.0412(6)
    N1 1 0.7859(3) 0.04614(9) 0.64668(8) 0.0378(7)
    N2 1 0.5224(3) 0.01311(9) 0.59959(8) 0.0336(6)
    N3 1 0.5071(3) 0.10015(9) 0.64569(8) 0.0358(7)
    C1 1 0.7975(4) 0.15804(12) 0.77200(11) 0.0363(8)
    H1 1 0.7582(32) 0.1399(9) 0.7964(8) 0.021(7)
    C2 1 0.7756(4) 0.14206(11) 0.72967(10) 0.0320(8)
    C3 1 0.8354(4) 0.16847(12) 0.69267(10) 0.0352(8)
    C4 1 0.9207(4) 0.21205(12) 0.69680(12) 0.0395(9)
    H4 1 0.9598(34) 0.2293(10) 0.6710(10) 0.034(9)
    C5 1 1.0356(5) 0.27588(13) 0.7486(2) 0.0503(10)
    H5 1 1.0739(40) 0.2923(12) 0.7230(11) 0.046(11)
    C6 1 1.0607(5) 0.2931(2) 0.7909(2) 0.0578(11)
    H6 1 1.1241(37) 0.3227(12) 0.7938(10) 0.041(9)
    C7 1 0.9981(5) 0.26717(15) 0.8276(2) 0.0569(11)
    H7 1 1.0156(41) 0.2805(12) 0.8569(12) 0.056(11)
    C8 1 0.9133(5) 0.22351(14) 0.82169(13) 0.0473(10)
    H8 1 0.8676(40) 0.2056(12) 0.8449(11) 0.048(11)
    C9 1 0.8853(4) 0.20403(12) 0.77840(11) 0.0376(8)
    C10 1 0.9470(4) 0.23048(11) 0.74083(11) 0.0378(8)
    C11 1 0.6575(4) -0.09300(12) 0.62758(10) 0.0361(8)
    C12 1 0.5105(5) -0.10931(14) 0.64404(13) 0.0469(10)
    H12 1 0.4534(40) -0.0882(12) 0.6645(11) 0.051(10)
    C13 1 0.4514(5) -0.1557(2) 0.63052(15) 0.0581(11)
    H13 1 0.3531(47) -0.1676(13) 0.6424(12) 0.064(12)
    C14 1 0.5429(6) -0.18336(14) 0.60122(14) 0.0611(12)
    C15 1 0.6886(7) -0.1677(2) 0.5851(2) 0.0724(13)
    H15 1 0.7547(55) -0.1881(16) 0.5653(14) 0.100(16)
    C16 1 0.7466(6) -0.12135(15) 0.59832(14) 0.0611(11)
    H16 1 0.8506(46) -0.1074(13) 0.5886(12) 0.068(12)
    C17 1 0.8314(4) 0.02547(12) 0.53918(10) 0.0345(8)
    C18 1 0.9433(4) 0.06434(13) 0.54166(12) 0.0407(9)
    H18 1 1.0094(36) 0.0678(10) 0.5663(10) 0.036(9)
    C19 1 0.9559(4) 0.09729(14) 0.50609(12) 0.0429(9)
    H19 1 1.0251(37) 0.1236(11) 0.5071(10) 0.036(9)
    C20 1 0.8559(4) 0.09081(13) 0.46992(11) 0.0434(9)
    C21 1 0.7458(4) 0.05201(14) 0.46676(12) 0.0453(9)
    H21 1 0.6814(41) 0.0491(12) 0.4403(11) 0.057(11)
    C22 1 0.7333(4) 0.01881(14) 0.50197(11) 0.0409(9)
    H22 1 0.6631(38) -0.0087(11) 0.5011(10) 0.043(10)
    C23 1 0.2335(4) 0.00610(12) 0.66690(10) 0.0349(8)
    C24 1 0.3034(4) 0.01212(13) 0.70839(11) 0.0403(9)
    H24 1 0.3551(34) 0.0398(11) 0.7148(9) 0.026(9)
    C25 1 0.2836(5) -0.02502(14) 0.74041(12) 0.0471(9)
    H25 1 0.3246(38) -0.0214(11) 0.7699(11) 0.048(10)
    C26 1 0.1928(4) -0.06645(13) 0.72928(12) 0.0472(9)
    C27 1 0.1204(5) -0.07262(15) 0.68845(13) 0.0492(10)
    H27 1 0.0566(42) -0.1004(12) 0.6833(11) 0.055(11)
    C28 1 0.1410(4) -0.03563(13) 0.65648(12) 0.0411(9)
    H28 1 0.0934(39) -0.0381(11) 0.6269(11) 0.051(10)
    C29 1 0.3986(4) 0.13696(12) 0.55889(10) 0.0352(8)
    C30 1 0.2937(5) 0.17652(14) 0.56415(12) 0.0478(10)
    H30 1 0.1893(40) 0.1708(11) 0.5774(10) 0.041(9)
    C31 1 0.3438(6) 0.22389(15) 0.55030(13) 0.0546(11)
    H31 1 0.2753(43) 0.2535(13) 0.5530(11) 0.065(11)
    C32 1 0.4944(5) 0.22904(13) 0.53198(13) 0.0534(10)
    C33 1 0.6012(6) 0.1905(2) 0.5271(2) 0.0683(13)
    H33 1 0.7108(50) 0.1957(14) 0.5170(13) 0.082(14)
    C34 1 0.5506(5) 0.1434(2) 0.54093(14) 0.0566(11)
    H34 1 0.6114(41) 0.1184(13) 0.5382(11) 0.050(11)