#------------------------------------------------------------------------------
#$Date: 2008-01-13 22:15:36 +0000 (Sun, 13 Jan 2008) $
#$Revision: 14 $
#$URL: svn://www.crystallography.net/cod/cif/2/2005510.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2005510
_journal_name_full  'Acta Crystallographica'
_journal_year       1996
_journal_volume    	C52
_journal_page_first    	2399
_journal_page_last    	2402
_publ_section_title    	
;
(cis-1,2-Dichlorovinyl)bis(dimethylglyoximato-N,N')(pyridine-N)cobalt(III)
Chloroform Solvate,
[Co(dmgH)~2~(py)(CCl\\dbCHCl)].CHCl~3~
;
_chemical_formula_iupac   '[Co (C2 H Cl2) (C4 H7 N2 O2)2 (C5 H5 N)] , C H Cl3'
_chemical_formula_moiety    	'(C15 H20 Cl2 Co N5 O4) (C H Cl3)'
_chemical_formula_sum    	'C16 H21 Cl5 Co N5 O4'
_chemical_formula_weight    	583.56
_symmetry_cell_setting    	triclinic
loop_
_symmetry_equiv_pos_as_xyz
    'x, y, z'
_symmetry_space_group_name_H-M    	'P 1'
_cell_length_a    	8.1522(12)
_cell_length_b    	8.8910(8)
_cell_length_c    	8.9605(8)
_cell_angle_alpha    	82.552(8)
_cell_angle_beta    	89.561(4)
_cell_angle_gamma    	63.421(4)
_cell_volume    	575.00(11)
_cell_formula_units_Z    	1
_exptl_crystal_density_diffrn    	1.685
_cell_measurement_temperature    	173(2)
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
    Co 1 0.33595(4) 0.69406(4) 0.49950(3) 0.01353(8)
    C1 1 0.2917(4) 0.5815(3) 0.3414(3) 0.0157(6)
    Cl1 0.864(2) 0.3393(2) 0.36885(15) 0.38221(11) 0.0268(2)
    Cl2 0.864(2) 0.18816(13) 0.57030(12) 0.05584(9) 0.0285(2)
    C2 0.864(2) 0.2306(8) 0.6582(8) 0.2023(7) 0.0244(11)
    H2 0.864(2) 0.2078(8) 0.7736(8) 0.1810(7) 0.029
    Cl1' 0.136(2) 0.2069(15) 0.6933(12) 0.1712(10) 0.030(2)
    Cl2' 0.136(2) 0.2792(10) 0.3093(8) 0.2448(8) 0.038(2)
    C2' 0.136(2) 0.323(5) 0.424(3) 0.373(3) 0.029(9)
    H2' 0.136(2) 0.3724(50) 0.3672(27) 0.4707(29) 0.035
    C3 1 0.7068(4) 0.5019(4) 0.4844(3) 0.0225(6)
    C4 1 0.8985(5) 0.3635(5) 0.5154(5) 0.0332(8)
    H4A 1 0.9796(8) 0.4118(6) 0.5416(27) 0.040
    H4B 1 0.9405(13) 0.3077(20) 0.4254(9) 0.040
    H4C 1 0.9011(8) 0.2800(16) 0.5995(18) 0.040
    C5 1 0.6547(4) 0.6529(4) 0.3730(3) 0.0216(6)
    C6 1 0.7911(5) 0.6800(5) 0.2722(4) 0.0333(8)
    H6A 1 0.8185(25) 0.6080(23) 0.1923(16) 0.040
    H6B 1 0.9044(13) 0.6499(28) 0.3319(7) 0.040
    H6C 1 0.7389(13) 0.7995(8) 0.2270(21) 0.040
    C7 1 -0.0335(4) 0.8849(4) 0.5123(3) 0.0187(6)
    C8 1 -0.2258(5) 1.0222(4) 0.4804(4) 0.0285(7)
    H8A 1 -0.2664(12) 1.0826(19) 0.5680(10) 0.034
    H8B 1 -0.3070(7) 0.9720(5) 0.4598(25) 0.034
    H8C 1 -0.2300(7) 1.1021(16) 0.3925(16) 0.034
    C9 1 0.0131(4) 0.7332(4) 0.6234(3) 0.0185(6)
    C10 1 -0.1218(5) 0.7060(4) 0.7201(4) 0.0268(7)
    H10A 1 -0.1995(19) 0.6757(26) 0.6599(6) 0.032
    H10B 1 -0.1985(20) 0.8106(9) 0.7617(19) 0.032
    H10C 1 -0.0567(5) 0.6138(18) 0.8026(14) 0.032
    C11 1 0.3466(5) 0.9785(4) 0.6345(3) 0.0233(6)
    H11 1 0.3082(5) 1.0374(4) 0.5351(3) 0.028
    C12 1 0.3695(5) 1.0634(4) 0.7454(4) 0.0328(7)
    H12 1 0.3467(5) 1.1787(4) 0.7223(4) 0.039
    C13 1 0.4261(5) 0.9781(4) 0.8904(3) 0.0321(6)
    H13 1 0.4423(5) 1.0344(4) 0.9680(3) 0.038
    C14 1 0.4584(5) 0.8120(4) 0.9211(4) 0.0279(7)
    H14 1 0.4967(5) 0.7521(4) 1.0202(4) 0.034
    C15 1 0.4344(5) 0.7315(4) 0.8051(3) 0.0210(6)
    H15 1 0.4590(5) 0.6157(4) 0.8266(3) 0.025
    O1 1 0.5856(3) 0.3766(3) 0.6637(2) 0.0249(5)
    H01 1 0.4376(58) 0.4188(46) 0.6944(40) 0.030
    O2 1 0.4175(4) 0.9062(3) 0.2729(3) 0.0257(5)
    O3 1 0.0889(3) 1.0142(3) 0.3376(2) 0.0240(5)
    H03 1 0.3267(61) 0.9482(49) 0.2926(43) 0.029
    O4 1 0.2572(3) 0.4801(3) 0.7231(2) 0.0235(5)
    N1 1 0.5662(4) 0.5030(3) 0.5548(3) 0.0192(5)
    N2 1 0.4838(4) 0.7595(3) 0.3689(3) 0.0180(5)
    N3 1 0.1066(3) 0.8851(3) 0.4431(3) 0.0162(5)
    N4 1 0.1883(4) 0.6262(3) 0.6273(3) 0.0172(5)
    N5 1 0.3771(4) 0.8136(3) 0.6628(3) 0.0183(5)
    Cl3 1 0.9307(2) 0.02359(14) -0.0822(2) 0.0732(4)
    Cl4 1 0.6449(2) 0.2803(2) 0.0662(2) 0.0870(5)
    Cl5 1 0.9845(2) 0.2992(2) 0.0055(2) 0.0747(4)
    C99 0.50 0.8757(10) 0.1678(9) 0.0347(8) 0.0371(10)
    H99 0.50 0.9306(10) 0.0981(9) 0.1346(8) 0.044
    C99' 0.50 0.8311(10) 0.2351(9) -0.0448(9) 0.0371(10)
    H99' 0.50 0.7765(10) 0.3046(9) -0.1448(9) 0.044