#------------------------------------------------------------------------------
#$Date: 2011-09-10 04:16:28 +0100 (Sat, 10 Sep 2011) $
#$Revision: 25271 $
#$URL: svn://www.crystallography.net/cod/cif/2/2006622.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2006622
loop_
_publ_author_name
'White, J. M.'
'Tham, W.-Y.'
_publ_section_title
;
 9a-Trimethylsilyloctahydroquinolizinium Picrate
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1471
_journal_page_last               1472
_journal_volume                  53
_journal_year                    1997
_chemical_formula_iupac          'C12 H26 N1 Si1 1+, C6 H2 N3 O7 1-'
_chemical_formula_sum            'C18 H28 N4 O7 Si'
_chemical_formula_weight         440.52
_chemical_melting_point          422
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_method           SHELXL
_cell_angle_alpha                90.000(10)
_cell_angle_beta                 102.580(10)
_cell_angle_gamma                90.000(10)
_cell_formula_units_Z            1
_cell_length_a                   11.8710(10)
_cell_length_b                   21.586(2)
_cell_length_c                   8.4840(10)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      15
_cell_measurement_theta_min      12
_cell_volume                     2121.8(4)
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Enraf-Nonius CAD-4S diffractometer'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0247
_diffrn_reflns_av_sigmaI/netI    0.0231
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       1
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -1
_diffrn_reflns_number            4771
_diffrn_reflns_theta_max         24.96
_diffrn_reflns_theta_min         2.58
_diffrn_standards_decay_%        0.6
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.158
_exptl_absorpt_correction_T_max  0.97
_exptl_absorpt_correction_T_min  0.91
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   '(SHELX76; Sheldrick, 1976)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_density_method    'Not measured'
_exptl_crystal_description       'Thick plate'
_exptl_crystal_F_000             936
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.52
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.422
_refine_diff_density_min         -0.269
_refine_ls_extinction_coef       0.0034(13)
_refine_ls_extinction_method     'SHELXL93 (Sheldrick, 1993)'
_refine_ls_goodness_of_fit_all   1.034
_refine_ls_goodness_of_fit_obs   1.089
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     384
_refine_ls_number_reflns         3712
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.034
_refine_ls_restrained_S_obs      1.089
_refine_ls_R_factor_all          0.0587
_refine_ls_R_factor_obs          0.0500
_refine_ls_shift/esd_max         -0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme
'calc w = 1/[\s^2^(Fo^2^)+(0.0791P)^2^+0.8915P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_wR_factor_all         0.1392
_refine_ls_wR_factor_obs         0.1331
_reflns_number_observed          3121
_reflns_number_total             3712
_reflns_observed_criterion       >2sigma(I)
_[local]_cod_data_source_file    sx1022.cif
_[local]_cod_data_source_block   twy93
_[local]_cod_cif_authors_sg_H-M  'P 21/c '
_[local]_cod_chemical_formula_sum_orig 'C18 H28 N4 O7 Si1'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Gaussian'
changed to 'gaussian' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2006622
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Si 0.0397(3) 0.0416(3) 0.0522(4) 0.0026(2) 0.0168(3) 0.0063(3)
N1 0.0373(9) 0.0453(10) 0.0520(10) 0.0016(7) 0.0144(8) 0.0067(8)
C2 0.0573(15) 0.061(2) 0.072(2) -0.0043(12) 0.0310(14) 0.0135(13)
C3 0.066(2) 0.065(2) 0.093(2) -0.0213(14) 0.024(2) 0.013(2)
C4 0.085(2) 0.0432(14) 0.084(2) -0.0161(14) 0.018(2) 0.0004(14)
C5 0.075(2) 0.0454(13) 0.064(2) -0.0084(12) 0.0189(14) -0.0035(12)
C6 0.0421(11) 0.0360(10) 0.0506(12) 0.0012(8) 0.0173(9) 0.0012(9)
C7 0.0474(12) 0.0501(13) 0.0615(14) 0.0121(10) 0.0153(11) 0.0127(11)
C8 0.0499(14) 0.067(2) 0.070(2) 0.0005(12) -0.0014(13) 0.0106(14)
C9 0.081(2) 0.057(2) 0.0553(15) -0.0009(14) 0.0058(13) -0.0059(13)
C10 0.0621(15) 0.0450(12) 0.0609(14) 0.0056(11) 0.0260(12) -0.0033(11)
C11 0.057(2) 0.078(2) 0.064(2) 0.0074(14) 0.0120(13) 0.017(2)
C12 0.061(2) 0.070(2) 0.074(2) 0.0124(14) 0.035(2) 0.009(2)
C13 0.072(2) 0.0475(14) 0.084(2) -0.0084(13) 0.031(2) 0.0062(14)
C14 0.0380(11) 0.0527(13) 0.0460(12) 0.0027(9) 0.0068(9) -0.0022(9)
C15 0.0355(10) 0.0543(13) 0.0441(11) -0.0001(9) 0.0093(9) 0.0000(9)
C16 0.0411(12) 0.0502(14) 0.0549(13) 0.0040(10) 0.0053(10) 0.0003(11)
C17 0.0345(11) 0.0605(14) 0.0597(14) 0.0065(9) 0.0104(10) -0.0054(11)
C18 0.0350(11) 0.066(2) 0.0534(13) -0.0043(10) 0.0104(10) -0.0026(11)
C19 0.0391(11) 0.0508(12) 0.0485(12) -0.0011(9) 0.0058(9) 0.0011(10)
O1 0.0515(10) 0.0590(10) 0.0817(12) 0.0099(8) 0.0245(9) -0.0064(9)
O2 0.0565(12) 0.0823(14) 0.171(2) 0.0052(10) 0.0586(14) 0.0061(15)
O3 0.0619(11) 0.0778(13) 0.0776(13) -0.0093(9) 0.0149(9) 0.0222(10)
O4 0.096(2) 0.071(2) 0.227(4) 0.0243(13) 0.085(2) 0.001(2)
O5 0.0612(12) 0.104(2) 0.126(2) 0.0012(11) 0.0512(13) -0.0251(14)
O6 0.0746(15) 0.076(2) 0.224(3) -0.0067(12) 0.057(2) 0.033(2)
O7 0.113(2) 0.0593(13) 0.199(3) 0.0094(13) 0.085(2) 0.020(2)
N2 0.0437(11) 0.0646(13) 0.0569(12) -0.0037(9) 0.0149(9) -0.0005(10)
N3 0.0451(12) 0.077(2) 0.097(2) 0.0086(11) 0.0229(12) -0.0144(13)
N4 0.0494(12) 0.0570(12) 0.0771(14) -0.0044(10) 0.0140(10) 0.0059(10)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_type_symbol
Si 0.30577(5) 0.11822(3) 0.05271(7) 0.0434(2) Uani d 1 Si
N1 0.1806(2) 0.08988(9) 0.3024(2) 0.0442(4) Uani d 1 N
H1 0.120(2) 0.1034(12) 0.227(3) 0.056(7) Uiso d 1 H
C2 0.1257(2) 0.04243(13) 0.3933(4) 0.0610(7) Uani d 1 C
H2A 0.187(2) 0.0295(13) 0.487(4) 0.069(8) Uiso d 1 H
H2B 0.067(3) 0.0657(13) 0.434(3) 0.068(8) Uiso d 1 H
C3 0.0778(3) -0.01117(15) 0.2869(4) 0.0737(8) Uani d 1 C
H3A 0.013(3) 0.0048(15) 0.196(4) 0.085(9) Uiso d 1 H
H3B 0.042(3) -0.0379(18) 0.340(4) 0.099(11) Uiso d 1 H
C4 0.1709(3) -0.04264(13) 0.2211(4) 0.0708(8) Uani d 1 C
H4A 0.227(3) -0.0611(15) 0.307(4) 0.081(9) Uiso d 1 H
H4B 0.139(3) -0.0731(16) 0.156(4) 0.086(10) Uiso d 1 H
C5 0.2255(3) 0.00381(12) 0.1274(3) 0.0608(6) Uani d 1 C
H5A 0.296(3) -0.0175(14) 0.097(4) 0.076(8) Uiso d 1 H
H5B 0.169(3) 0.0148(13) 0.036(4) 0.069(8) Uiso d 1 H
C6 0.2738(2) 0.06331(9) 0.2197(3) 0.0418(5) Uani d 1 C
C7 0.3804(2) 0.04791(11) 0.3518(3) 0.0525(6) Uani d 1 C
H7A 0.438(2) 0.0327(13) 0.288(3) 0.063(7) Uiso d 1 H
H7B 0.363(2) 0.0125(12) 0.417(3) 0.053(6) Uiso d 1 H
C8 0.4246(2) 0.10089(14) 0.4641(4) 0.0645(7) Uani d 1 C
H8A 0.489(3) 0.0874(15) 0.550(4) 0.086(9) Uiso d 1 H
H8B 0.453(3) 0.1339(15) 0.409(4) 0.077(9) Uiso d 1 H
C9 0.3296(3) 0.12640(15) 0.5384(3) 0.0656(7) Uani d 1 C
H9A 0.307(2) 0.0943(15) 0.608(4) 0.074(8) Uiso d 1 H
H9B 0.355(3) 0.1594(16) 0.599(4) 0.083(10) Uiso d 1 H
C10 0.2243(2) 0.14369(11) 0.4117(3) 0.0541(6) Uani d 1 C
H10A 0.244(2) 0.1753(11) 0.343(3) 0.049(6) Uiso d 1 H
H10B 0.163(2) 0.1575(12) 0.461(3) 0.057(7) Uiso d 1 H
C11 0.1713(3) 0.1252(2) -0.1068(4) 0.0666(7) Uani d 1 C
H11A 0.182(3) 0.1570(16) -0.181(4) 0.082(9) Uiso d 1 H
H11B 0.110(3) 0.1367(16) -0.061(4) 0.094(11) Uiso d 1 H
H11C 0.154(3) 0.0877(19) -0.177(4) 0.102(12) Uiso d 1 H
C12 0.4220(3) 0.0794(2) -0.0254(4) 0.0652(7) Uani d 1 C
H12A 0.447(3) 0.1031(16) -0.102(4) 0.084(10) Uiso d 1 H
H12B 0.399(3) 0.0436(19) -0.073(5) 0.102(13) Uiso d 1 H
H12C 0.488(3) 0.0714(16) 0.061(4) 0.089(10) Uiso d 1 H
C13 0.3535(3) 0.19878(13) 0.1109(4) 0.0658(7) Uani d 1 C
H13A 0.414(4) 0.2013(18) 0.202(5) 0.106(13) Uiso d 1 H
H13B 0.291(3) 0.2242(16) 0.137(4) 0.084(9) Uiso d 1 H
H13C 0.368(3) 0.2157(18) 0.008(5) 0.111(12) Uiso d 1 H
C14 -0.1141(2) 0.16736(11) 0.1943(3) 0.0459(5) Uani d 1 C
C15 -0.1086(2) 0.23458(11) 0.1845(3) 0.0445(5) Uani d 1 C
C16 -0.1874(2) 0.27412(12) 0.2256(3) 0.0495(5) Uani d 1 C
H16 -0.180(3) 0.3136(15) 0.216(4) 0.075(9) Uiso d 1 H
C17 -0.2778(2) 0.25049(11) 0.2846(3) 0.0515(6) Uani d 1 C
C18 -0.2906(2) 0.18747(12) 0.3010(3) 0.0513(6) Uani d 1 C
H18 -0.347(2) 0.1721(11) 0.346(3) 0.051(6) Uiso d 1 H
C19 -0.2134(2) 0.14791(10) 0.2572(3) 0.0467(5) Uani d 1 C
O1 -0.04567(15) 0.13134(8) 0.1506(2) 0.0625(5) Uani d 1 O
O2 0.0752(2) 0.23551(11) 0.1374(4) 0.0980(8) Uani d 1 O
O3 -0.0279(2) 0.31645(10) 0.0742(2) 0.0725(5) Uani d 1 O
O4 -0.3513(2) 0.34723(12) 0.3078(5) 0.1236(11) Uani d 1 O
O5 -0.4332(2) 0.27024(12) 0.3970(3) 0.0923(7) Uani d 1 O
O6 -0.3225(2) 0.06574(11) 0.3130(4) 0.1210(11) Uani d 1 O
O7 -0.1590(2) 0.04502(11) 0.2780(4) 0.1160(10) Uani d 1 O
N2 -0.0148(2) 0.26372(10) 0.1268(2) 0.0545(5) Uani d 1 N
N3 -0.3598(2) 0.29223(12) 0.3319(3) 0.0721(7) Uani d 1 N
N4 -0.2331(2) 0.08248(10) 0.2818(3) 0.0611(5) Uani d 1 N
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C12 Si C11 111.3(2) ?
C12 Si C13 108.0(2) ?
C11 Si C13 106.3(2) ?
C12 Si C6 105.30(10) y
C11 Si C6 107.80(10) y
C13 Si C6 118.20(10) y
C10 N1 C2 109.7(2) y
C10 N1 C6 112.4(2) y
C2 N1 C6 114.3(2) y
C10 N1 H1 107.6(16) y
C2 N1 H1 102.7(16) y
C6 N1 H1 109.6(16) y
C3 C2 N1 111.3(2) y
C3 C2 H2A 112.5(17) ?
N1 C2 H2A 105.9(16) ?
C3 C2 H2B 113.6(16) ?
N1 C2 H2B 104.6(17) ?
H2A C2 H2B 108.(2) ?
C2 C3 C4 111.0(2) y
C2 C3 H3A 108.6(18) ?
C4 C3 H3A 111.4(18) ?
C2 C3 H3B 111.(2) ?
C4 C3 H3B 112.(2) ?
H3A C3 H3B 103.(3) ?
C3 C4 C5 109.3(2) y
C3 C4 H4A 110.8(19) ?
C5 C4 H4A 111.5(19) ?
C3 C4 H4B 108.(2) ?
C5 C4 H4B 110.(2) ?
H4A C4 H4B 107.(3) ?
C4 C5 C6 116.0(2) y
C4 C5 H5A 107.4(17) ?
C6 C5 H5A 105.4(17) ?
C4 C5 H5B 107.0(18) ?
C6 C5 H5B 109.0(18) ?
H5A C5 H5B 112.(2) ?
C7 C6 N1 107.9(2) y
C7 C6 C5 110.2(2) y
N1 C6 C5 108.4(2) y
C7 C6 Si 113.77(15) y
N1 C6 Si 112.16(13) y
C5 C6 Si 104.27(15) y
C8 C7 C6 114.6(2) y
C8 C7 H7A 113.7(15) ?
C6 C7 H7A 103.0(15) ?
C8 C7 H7B 108.6(14) ?
C6 C7 H7B 109.5(14) ?
H7A C7 H7B 107.(2) ?
C7 C8 C9 110.6(2) y
C7 C8 H8A 110.5(19) ?
C9 C8 H8A 109.5(18) ?
C7 C8 H8B 111.5(19) ?
C9 C8 H8B 108.0(18) ?
H8A C8 H8B 107.(3) ?
C10 C9 C8 111.8(2) y
C10 C9 H9A 108.1(17) ?
C8 C9 H9A 108.7(17) ?
C10 C9 H9B 110.(2) ?
C8 C9 H9B 110.(2) ?
H9A C9 H9B 109.(3) ?
N1 C10 C9 111.7(2) y
N1 C10 H10A 105.8(14) ?
C9 C10 H10A 109.7(14) ?
N1 C10 H10B 108.5(15) ?
C9 C10 H10B 110.5(15) ?
H10A C10 H10B 111.(2) ?
Si C11 H11A 108.4(19) ?
Si C11 H11B 110.(2) ?
H11A C11 H11B 108.(3) ?
Si C11 H11C 114.(2) ?
H11A C11 H11C 103.(3) ?
H11B C11 H11C 113.(3) ?
Si C12 H12A 112.(2) ?
Si C12 H12B 112.(2) ?
H12A C12 H12B 106.(3) ?
Si C12 H12C 111.(2) ?
H12A C12 H12C 108.(3) ?
H12B C12 H12C 108.(3) ?
Si C13 H13A 114.(2) ?
Si C13 H13B 112.1(19) ?
H13A C13 H13B 105.(3) ?
Si C13 H13C 102.(2) ?
H13A C13 H13C 117.(3) ?
H13B C13 H13C 106.(3) ?
O1 C14 C15 124.7(2) ?
O1 C14 C19 124.3(2) ?
C15 C14 C19 110.9(2) ?
C16 C15 N2 115.6(2) ?
C16 C15 C14 124.5(2) ?
N2 C15 C14 119.8(2) ?
C15 C16 C17 119.5(2) ?
C15 C16 H16 120.(2) ?
C17 C16 H16 120.(2) ?
C16 C17 C18 120.9(2) ?
C16 C17 N3 119.7(2) ?
C18 C17 N3 119.4(2) ?
C19 C18 C17 119.7(2) ?
C19 C18 H18 119.2(16) ?
C17 C18 H18 121.0(16) ?
C18 C19 N4 115.5(2) ?
C18 C19 C14 124.4(2) ?
N4 C19 C14 120.1(2) ?
O2 N2 O3 122.3(2) ?
O2 N2 C15 118.9(2) ?
O3 N2 C15 118.8(2) ?
O4 N3 O5 123.3(2) ?
O4 N3 C17 118.5(2) ?
O5 N3 C17 118.1(3) ?
O7 N4 O6 119.3(2) ?
O7 N4 C19 120.6(2) ?
O6 N4 C19 120.0(2) ?
N1 H1 O1 153.0(16) n
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Si C12 1.856(3) y
Si C11 1.860(3) y
Si C13 1.862(3) y
Si C6 1.947(2) y
N1 C10 1.506(3) y
N1 C2 1.512(3) y
N1 C6 1.544(3) y
N1 H1 0.90(3) y
C2 C3 1.501(4) y
C2 H2A 1.00(3) ?
C2 H2B 0.98(3) ?
C3 C4 1.505(5) y
C3 H3A 1.02(3) ?
C3 H3B 0.90(4) ?
C4 C5 1.511(4) y
C4 H4A 0.96(3) ?
C4 H4B 0.89(3) ?
C5 C6 1.548(3) y
C5 H5A 1.03(3) ?
C5 H5B 0.94(3) ?
C6 C7 1.534(3) y
C7 C8 1.508(4) y
C7 H7A 1.01(3) ?
C7 H7B 0.99(3) ?
C8 C9 1.511(4) y
C8 H8A 0.98(4) ?
C8 H8B 0.95(3) ?
C9 C10 1.507(4) y
C9 H9A 0.99(3) ?
C9 H9B 0.89(4) ?
C10 H10A 0.96(3) ?
C10 H10B 0.96(3) ?
C11 H11A 0.96(4) ?
C11 H11B 0.92(4) ?
C11 H11C 1.00(4) ?
C12 H12A 0.92(4) ?
C12 H12B 0.89(4) ?
C12 H12C 0.97(4) ?
C13 H13A 0.94(4) ?
C13 H13B 0.99(3) ?
C13 H13C 1.00(4) ?
C14 O1 1.238(3) ?
C14 C15 1.455(3) ?
C14 C19 1.458(3) ?
C15 C16 1.366(3) ?
C15 N2 1.454(3) ?
C16 C17 1.377(3) ?
C16 H16 0.86(3) ?
C17 C18 1.379(4) ?
C17 N3 1.446(3) ?
C18 C19 1.363(3) ?
C18 H18 0.90(3) ?
C19 N4 1.454(3) ?
O2 N2 1.216(3) ?
O3 N2 1.220(3) ?
O4 N3 1.213(3) ?
O5 N3 1.224(3) ?
O6 N4 1.204(3) ?
O7 N4 1.200(3) ?
O1 H1 2.025(3) n
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C10 N1 C2 C3 178.3(2)
C6 N1 C2 C3 -54.4(3)
N1 C2 C3 C4 59.1(3)
C2 C3 C4 C5 -58.3(4)
C3 C4 C5 C6 55.1(4)
C10 N1 C6 C7 53.8(2)
C2 N1 C6 C7 -72.0(2)
C10 N1 C6 C5 173.2(2)
C2 N1 C6 C5 47.3(3)
C10 N1 C6 Si -72.3(2)
C2 N1 C6 Si 161.9(2)
C4 C5 C6 C7 69.2(3)
C4 C5 C6 N1 -48.7(3)
C4 C5 C6 Si -168.3(2)
C12 Si C6 C7 55.3(2)
C11 Si C6 C7 174.2(2)
C13 Si C6 C7 -65.4(2)
C12 Si C6 N1 178.1(2)
C11 Si C6 N1 -62.9(2)
C13 Si C6 N1 57.5(2)
C12 Si C6 C5 -64.8(2)
C11 Si C6 C5 54.1(2)
C13 Si C6 C5 174.5(2)
N1 C6 C7 C8 -53.8(3)
C5 C6 C7 C8 -171.9(2)
Si C6 C7 C8 71.4(2)
C6 C7 C8 C9 54.7(3)
C7 C8 C9 C10 -53.8(3)
C2 N1 C10 C9 71.8(3)
C6 N1 C10 C9 -56.5(3)
C8 C9 C10 N1 55.7(3)
O1 C14 C15 C16 176.8(2)
C19 C14 C15 C16 -1.3(3)
O1 C14 C15 N2 -2.8(3)
C19 C14 C15 N2 179.1(2)
N2 C15 C16 C17 -178.7(2)
C14 C15 C16 C17 1.7(3)
C15 C16 C17 C18 -0.8(4)
C15 C16 C17 N3 178.5(2)
C16 C17 C18 C19 -0.5(4)
N3 C17 C18 C19 -179.7(2)
C17 C18 C19 N4 178.9(2)
C17 C18 C19 C14 0.8(4)
O1 C14 C19 C18 -178.0(2)
C15 C14 C19 C18 0.0(3)
O1 C14 C19 N4 3.9(3)
C15 C14 C19 N4 -178.0(2)
C16 C15 N2 O2 156.6(3)
C14 C15 N2 O2 -23.8(3)
C16 C15 N2 O3 -21.1(3)
C14 C15 N2 O3 158.5(2)
C16 C17 N3 O4 5.1(4)
C18 C17 N3 O4 -175.7(3)
C16 C17 N3 O5 -173.7(2)
C18 C17 N3 O5 5.6(4)
C18 C19 N4 O7 -165.1(3)
C14 C19 N4 O7 13.1(4)
C18 C19 N4 O6 11.7(4)
C14 C19 N4 O6 -170.1(3)