data_2006918
_journal_name_full  'Acta Crystallographica'
_journal_year  1998
_journal_volume  C54
_journal_page_first  16
_journal_page_last  18
_publ_section_title
;
 Bis[\m-methylenebis(diphenylphosphine)]disilver(I) Diperchlorate
 Bis(dichloromethane) Solvate
;
loop_
_publ_author_name
  'Ahrens, Birte'
  'Jones*, Peter G.'
_chemical_formula_moiety  '[Ag2 (C25 H22 P2)2] 2Cl O4 , 2C H2 Cl2'
_chemical_formula_sum  'C52 H48 Ag2 Cl6 O8 P4'
_chemical_formula_weight  1353.22
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'P 21/n'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x-1/2, -y-1/2, z-1/2'
_cell_length_a  11.6819(14)
_cell_length_b  15.2304(16)
_cell_length_c  16.349(2)
_cell_angle_alpha  90.00
_cell_angle_beta  107.548(10)
_cell_angle_gamma  90.00
_cell_volume  2773.5(6)
_cell_formula_units_Z  2
_cell_measurement_temperature  173(2)
_exptl_crystal_density_diffrn  1.620
_diffrn_ambient_temperature  173(2)
_refine_ls_R_factor_obs  .0358
_refine_ls_wR_factor_obs  .0671
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_group
_atom_site_type_symbol
  Ag  .41326(3)  .50488(2)  .54946(2)  .03292(10) Uani d . 1 . Ag
  P1  .68954(10)  .37208(7)  .53216(7)  .0296(3) Uani d . 1 . P
  P2  .49057(9)  .36754(7)  .61627(7)  .0280(2) Uani d . 1 . P
  C1  .6526(3)  .3573(3)  .6330(2)  .0290(9) Uani d . 1 . C
  H1A  .6799  .2986  .6570  .035 Uiso calc R 1 . H
  H1B  .6957  .4019  .6751  .035 Uiso calc R 1 . H
  C11  .8515(4)  .3870(3)  .5642(3)  .0358(10) Uani d D 1 . C
  C12  .9195(5)  .3512(4)  .5186(4)  .0800(19) Uani d D 1 . C
  H12  .8822  .3140  .4715  .096 Uiso calc R 1 . H
  C13 1.0401(5)  .3671(4)  .5384(5)  .108(3) Uani d D 1 . C
  H13 1.0847  .3425  .5041  .129 Uiso calc R 1 . H
  C14 1.0952(5)  .4170(5)  .6058(4)  .089(2) Uani d D 1 . C
  H14 1.1796  .4254  .6213  .107 Uiso calc R 1 . H
  C15 1.0301(5)  .4560(5)  .6525(4)  .104(3) Uani d D 1 . C
  H15 1.0684  .4935  .6991  .125 Uiso calc R 1 . H
  C16  .9081(5)  .4404(4)  .6313(3)  .082(2) Uani d D 1 . C
  H16  .8629  .4673  .6640  .099 Uiso calc R 1 . H
  C21  .6622(4)  .2668(3)  .4775(3)  .0356(11) Uani d D 1 . C
  C22  .7246(4)  .1916(3)  .5139(3)  .0448(12) Uani d D 1 . C
  H22  .7827  .1940  .5688  .054 Uiso calc R 1 . H
  C23  .7011(5)  .1130(3)  .4691(4)  .0600(15) Uani d D 1 . C
  H23  .7431  .0613  .4938  .072 Uiso calc R 1 . H
  C24  .6187(6)  .1090(3)  .3901(4)  .0734(18) Uani d D 1 . C
  H24  .6059  .0551  .3595  .088 Uiso calc R 1 . H
  C25  .5540(5)  .1814(3)  .3540(3)  .0628(15) Uani d D 1 . C
  H25  .4947  .1776  .2996  .075 Uiso calc R 1 . H
  C26  .5763(4)  .2609(3)  .3983(3)  .0442(12) Uani d D 1 . C
  H26  .5317  .3116  .3738  .053 Uiso calc R 1 . H
  C31  .4243(4)  .2705(2)  .5563(3)  .0299(9) Uani d D 1 . C
  C32  .4716(4)  .1881(3)  .5809(3)  .0446(12) Uani d D 1 . C
  H32  .5355  .1811  .6326  .053 Uiso calc R 1 . H
  C33  .4261(5)  .1162(3)  .5305(4)  .0582(14) Uani d D 1 . C
  H33  .4592  .0596  .5471  .070 Uiso calc R 1 . H
  C34  .3329(5)  .1263(3)  .4563(3)  .0593(15) Uani d D 1 . C
  H34  .3029  .0767  .4212  .071 Uiso calc R 1 . H
  C35  .2826(4)  .2077(3)  .4323(3)  .0520(13) Uani d D 1 . C
  H35  .2159  .2139  .3822  .062 Uiso calc R 1 . H
  C36  .3299(4)  .2802(3)  .4816(3)  .0389(11) Uani d D 1 . C
  H36  .2976  .3368  .4643  .047 Uiso calc R 1 . H
  C41  .4728(3)  .3563(2)  .7226(2)  .0286(9) Uani d D 1 . C
  C42  .3953(5)  .2979(4)  .7399(3)  .0725(18) Uani d D 1 . C
  H42  .3528  .2580  .6968  .087 Uiso calc R 1 . H
  C43  .3779(6)  .2962(4)  .8198(3)  .105(3) Uani d D 1 . C
  H43  .3227  .2555  .8308  .126 Uiso calc R 1 . H
  C44  .4381(4)  .3515(4)  .8822(3)  .0630(16) Uani d D 1 . C
  H44  .4274  .3485  .9375  .076 Uiso calc R 1 . H
  C45  .5137(5)  .4112(3)  .8658(3)  .0552(14) Uani d D 1 . C
  H45  .5546  .4516  .9089  .066 Uiso calc R 1 . H
  C46  .5315(4)  .4132(3)  .7859(3)  .0531(13) Uani d D 1 . C
  H46  .5856  .4549  .7749  .064 Uiso calc R 1 . H
  C99  .3987(5)  .6397(4)  .8067(3)  .0813(18) Uani d . 1 . C
  H99A  .4817  .6171  .8199  .098 Uiso calc R 1 . H
  H99B  .3997  .7028  .7922  .098 Uiso calc R 1 . H
  Cl1  .30542(14)  .58264(10)  .71737(9)  .0775(4) Uani d . 1 . Cl
  Cl2  .35070(18)  .62855(12)  .89587(10)  .1005(6) Uani d . 1 . Cl
  Cl0  .72453(11)  .60711(8)  .73986(8)  .0521(3) Uani d . 1 . Cl
  O1  .6467(3)  .5674(2)  .6635(2)  .0622(10) Uani d . 1 . O
  O2  .7745(4)  .5436(3)  .8017(3)  .122(2) Uani d . 1 . O
  O3  .8184(4)  .6520(3)  .7207(3)  .1036(16) Uani d . 1 . O
  O4  .6581(4)  .6706(4)  .7690(3)  .134(2) Uani d . 1 . O
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ag  .03802(17)  .02950(17)  .03497(16)  .00697(17)  .01664(13)  .00939(16)
  P1  .0333(6)  .0273(6)  .0314(6)  .0036(5)  .0147(5)  .0048(5)
  P2  .0298(6)  .0275(6)  .0284(6)  .0014(5)  .0112(5)  .0053(5)
  C1  .029(2)  .028(2)  .031(2)  .0034(18)  .0108(19)  .0084(18)
  C11  .032(2)  .038(3)  .039(3)  .003(2)  .014(2)  .012(2)
  C12  .048(3)  .087(4)  .119(5)  -.012(3)  .046(4)  -.042(4)
  C13  .045(4)  .086(5)  .209(9)  -.002(3)  .065(5)  -.045(5)
  C14  .032(3)  .115(6)  .115(6)  -.011(4)  .015(4)  .020(5)
  C15  .066(4)  .186(8)  .064(4)  -.063(5)  .028(4)  -.022(4)
  C16  .058(4)  .137(6)  .064(4)  -.035(4)  .036(3)  -.027(4)
  C21  .043(3)  .033(2)  .039(3)  .000(2)  .026(2)  .003(2)
  C22  .056(3)  .036(3)  .053(3)  .006(2)  .032(3)  .008(2)
  C23  .086(4)  .029(3)  .084(4)  .010(3)  .053(4)  .010(3)
  C24  .130(6)  .039(3)  .070(4)  -.016(4)  .058(4)  -.015(3)
  C25  .092(4)  .051(3)  .047(3)  -.017(3)  .023(3)  -.009(3)
  C26  .053(3)  .045(3)  .039(3)  -.002(2)  .021(2)  .002(2)
  C31  .036(2)  .025(2)  .034(2)  -.004(2)  .018(2)  .001(2)
  C32  .042(3)  .036(3)  .056(3)  -.004(2)  .016(2)  .003(2)
  C33  .072(4)  .030(3)  .082(4)  -.002(3)  .038(3)  .000(3)
  C34  .084(4)  .041(3)  .066(4)  -.019(3)  .042(3)  -.017(3)
  C35  .064(3)  .055(3)  .036(3)  -.023(3)  .013(2)  -.004(2)
  C36  .045(3)  .040(3)  .033(3)  -.008(2)  .014(2)  .003(2)
  C41  .028(2)  .033(2)  .027(2)  .0044(18)  .0117(19)  .0096(18)
  C42  .084(4)  .095(4)  .041(3)  -.056(3)  .024(3)  -.011(3)
  C43  .120(6)  .154(7)  .052(4)  -.093(5)  .044(4)  -.012(4)
  C44  .051(3)  .107(5)  .036(3)  -.011(3)  .022(3)  .010(3)
  C45  .074(4)  .063(3)  .035(3)  .001(3)  .026(3)  -.001(2)
  C46  .071(4)  .053(3)  .045(3)  -.012(3)  .031(3)  -.001(2)
  C99  .085(5)  .089(5)  .072(4)  -.021(4)  .027(4)  -.009(3)
  Cl1  .0777(10)  .0889(11)  .0627(9)  -.0049(9)  .0166(8)  -.0013(8)
  Cl2  .1387(16)  .1092(14)  .0631(10)  .0262(12)  .0447(11)  .0084(10)
  Cl0  .0541(8)  .0480(7)  .0461(7)  -.0150(6)  .0028(6)  .0006(6)
  O1  .069(2)  .0403(19)  .057(2)  -.0117(17)  -.0122(19)  -.0050(17)
  O2  .141(4)  .085(3)  .085(3)  -.056(3)  -.049(3)  .048(3)
  O3  .078(3)  .128(4)  .087(3)  -.053(3)  -.001(2)  .027(3)
  O4  .095(4)  .204(6)  .086(3)  .041(4)  .003(3)  -.076(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ag P1 3_666 2.4017(11) y
  Ag P2 . 2.4060(11) y
  Ag Ag 3_666 2.9532(7) y
  Ag O1 . 2.959(3) y
  P1 C21 . 1.816(4) ?
  P1 C11 . 1.819(4) ?
  P1 C1 . 1.839(4) y
  P2 C31 . 1.813(4) ?
  P2 C41 . 1.819(4) ?
  P2 C1 . 1.835(4) y
  C11 C12 . 1.357(6) ?
  C11 C16 . 1.365(6) ?
  C12 C13 . 1.368(7) ?
  C13 C14 . 1.333(7) ?
  C14 C15 . 1.365(8) ?
  C15 C16 . 1.383(7) ?
  C21 C26 . 1.382(5) ?
  C21 C22 . 1.391(5) ?
  C22 C23 . 1.387(6) ?
  C23 C24 . 1.360(7) ?
  C24 C25 . 1.366(7) ?
  C25 C26 . 1.395(6) ?
  C31 C32 . 1.381(5) ?
  C31 C36 . 1.384(5) ?
  C32 C33 . 1.378(6) ?
  C33 C34 . 1.372(6) ?
  C34 C35 . 1.377(6) ?
  C35 C36 . 1.381(6) ?
  C41 C42 . 1.359(5) ?
  C41 C46 . 1.366(5) ?
  C42 C43 . 1.381(6) ?
  C43 C44 . 1.346(6) ?
  C44 C45 . 1.350(6) ?
  C45 C46 . 1.384(6) ?
  C99 Cl2 . 1.721(5) ?
  C99 Cl1 . 1.765(5) ?
  Cl0 O2 . 1.395(4) ?
  Cl0 O3 . 1.405(4) ?
  Cl0 O4 . 1.410(4) ?
  Cl0 O1 . 1.438(3) ?