#------------------------------------------------------------------------------
#$Date: 2011-09-10 04:16:28 +0100 (Sat, 10 Sep 2011) $
#$Revision: 25271 $
#$URL: svn://www.crystallography.net/cod/cif/2/2008216.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2008216
loop_
_publ_author_name
'Foces-Foces, C.'
'Llamas-Saiz, A. L.'
'Alajar\'in, M.'
'L\'opez-L\'azaro, A.'
'Molina, P.'
_publ_section_title
;
 Two <i>C</i>~3~-symmetrical tris(<i>ortho</i>-substituted)
 tribenzylamines
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              373
_journal_page_last               377
_journal_volume                  55
_journal_year                    1999
_chemical_formula_moiety         'C21 H24 N4'
_chemical_formula_sum            'C21 H24 N4'
_chemical_formula_weight         332.447
_chemical_melting_point          .559E-305
_chemical_name_systematic        Tris(2-aminobenzyl)amine
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_audit_creation_method           from_xtal_archive_file_using_CIFIO
_cell_angle_alpha                90.00000
_cell_angle_beta                 90.00000
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
_cell_length_a                   8.4793(2)
_cell_length_b                   22.5318(10)
_cell_length_c                   9.7774(3)
_cell_measurement_reflns_used    83
_cell_measurement_temperature    293
_cell_measurement_theta_max      45
_cell_measurement_theta_min      2
_cell_volume                     1868.01(11)
_computing_cell_refinement       'LSUCRE (Appleman, 1971)'
_computing_data_collection       'Philips PW1100 (Hornstra & Vossers, 1973)'
_computing_data_reduction
'xtal (Hall et al., 1992) DIFDAT SORTRF ADDREF'
_computing_molecular_graphics    xtal_ORTEP
_computing_publication_material  xtal_BONDLA_CIFIO
_computing_structure_refinement  'xtal CRYLSQ'
_computing_structure_solution    'SIR92 (Altomare et al., 1994)'
_diffrn_ambient_temperature      293
_diffrn_measurement_device       'Philips PW1100 diffractometer'
_diffrn_measurement_method       '\w/2\q scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         xray_tube
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  .000
_diffrn_reflns_av_sigmaI/netI    .000
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            1792
_diffrn_reflns_reduction_process perpendicular_monochr_Lp
_diffrn_reflns_theta_max         67.46
_diffrn_reflns_theta_min         3.92
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  90
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    0.556
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.182
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'square prism'
_exptl_crystal_F_000             670
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.40
_refine_diff_density_max         .14
_refine_diff_density_min         -.12
_refine_ls_abs_structure_details 'not determined'
_refine_ls_extinction_coef       140(7)
_refine_ls_extinction_method     'Zachariasen (1967)'
_refine_ls_goodness_of_fit_all   .901
_refine_ls_goodness_of_fit_ref   .891
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     226
_refine_ls_number_reflns         1736
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .030
_refine_ls_R_factor_obs          .029
_refine_ls_shift/su_max          .0001
_refine_ls_shift/su_mean         .0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      'w = k/[(A+B Fo)^2^(C+D(sin\q)/\l]'
_refine_ls_wR_factor_all         .031
_refine_ls_wR_factor_obs         .030
_reflns_number_observed          1736
_reflns_number_total             1792
_reflns_observed_criterion       refl_observed_if_I____>2.000_sigma(I___)
_[local]_cod_data_source_file    bm1283.cif
_[local]_cod_data_source_block   I
_cod_database_code               2008216
loop_
_symmetry_equiv_pos_as_xyz
+x,+y,+z
-x,-y,1/2+z
1/2-x,1/2+y,1/2+z
1/2+x,1/2-y,+z
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
N1 .0489(7) .0379(6) .0403(6) .0010(5) .0011(6) -.0014(5)
C11 .0644(10) .0399(7) .0433(8) -.0018(7) -.0063(8) .0020(7)
C12 .0539(9) .0425(7) .0429(8) .0017(7) -.0030(7) .0022(6)
C13 .0502(8) .0491(8) .0461(8) -.0001(7) -.0013(8) .0031(7)
C14 .0653(11) .0580(10) .0633(11) -.0140(9) -.0012(10) .0018(9)
C15 .0923(15) .0583(10) .0617(12) -.0165(11) -.0064(12) -.0087(10)
C16 .0936(16) .0638(10) .0496(10) -.0081(11) .0041(11) -.0074(9)
C17 .0684(11) .0530(9) .0444(9) -.0069(8) .0033(9) .0021(8)
N18 .0694(11) .0814(11) .0564(9) -.0128(9) .0153(9) -.0055(9)
C21 .0506(8) .0465(8) .0462(8) .0024(7) .0103(8) .0012(7)
C22 .0428(7) .0428(7) .0496(9) .0058(6) .0079(7) -.0013(7)
C23 .0454(8) .0405(7) .0527(9) .0052(6) .0050(7) .0008(7)
C24 .0609(10) .0492(9) .0541(10) .0061(8) .0040(9) .0075(8)
C25 .0654(11) .0573(9) .0586(10) .0083(9) -.0044(10) .0020(9)
C26 .0561(10) .0591(10) .0710(12) .0009(8) -.0089(10) -.0069(9)
C27 .0489(8) .0478(8) .0662(11) -.0006(6) .0059(9) -.0005(8)
N28 .0554(8) .0501(7) .0658(10) -.0052(7) -.0016(8) .0064(7)
C31 .0520(8) .0408(7) .0512(9) -.0038(6) .0004(8) -.0041(7)
C32 .0487(8) .0421(7) .0488(8) -.0013(6) -.0035(7) -.0073(7)
C33 .0615(10) .0470(8) .0548(10) -.0050(7) .0033(8) -.0108(8)
C34 .0663(12) .0698(12) .0766(14) -.0162(10) .0194(11) -.0233(11)
C35 .0545(11) .0799(14) .108(2) .0108(10) .0026(13) -.0320(15)
C36 .0697(13) .0727(13) .0931(18) .0248(11) -.0159(14) -.0173(13)
C37 .0694(12) .0513(9) .0644(11) .0088(8) -.0124(10) -.0071(9)
N38 .1193(19) .0599(10) .0620(10) .0119(11) .0237(12) .0082(8)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
N1 .04781(17) .08843(5) .30000 .0424(6) Uani
C11 .1293(2) .07537(7) .4303(2) .0492(8) Uani
C12 .1929(2) .12953(7) .5016(2) .0464(8) Uani
C13 .3080(2) .16499(8) .4410(2) .0485(8) Uani
C14 .3732(3) .21205(9) .5153(3) .0622(11) Uani
C15 .3232(3) .22364(9) .6474(3) .0708(13) Uani
C16 .2082(3) .18910(10) .7075(3) .0690(12) Uani
C17 .1436(3) .14259(8) .6345(2) .0553(9) Uani
N18 .3620(2) .15274(9) .3105(2) .0691(10) Uani
C21 -.1031(2) .11912(7) .3261(2) .0477(8) Uani
C22 -.1716(2) .14347(7) .1953(2) .0451(8) Uani
C23 -.0990(2) .19158(7) .1286(2) .0462(8) Uani
C24 -.1612(2) .21107(8) .0040(3) .0547(9) Uani
C25 -.2929(3) .18444(9) -.0524(3) .0604(10) Uani
C26 -.3666(3) .13796(9) .0137(3) .0621(11) Uani
C27 -.3050(2) .11804(8) .1378(3) .0543(9) Uani
N28 .0295(2) .22029(7) .1871(2) .0571(8) Uani
C31 .0200(2) .03188(7) .2263(2) .0480(8) Uani
C32 .1675(2) .00770(7) .1619(2) .0465(8) Uani
C33 .2310(2) .03459(8) .0451(2) .0544(9) Uani
C34 .3626(3) .00900(10) -.0175(3) .0709(13) Uani
C35 .4296(3) -.04212(12) .0362(4) .0808(15) Uani
C36 .3688(3) -.06828(11) .1517(4) .0785(14) Uani
C37 .2383(3) -.04358(8) .2133(3) .0617(10) Uani
N38 .1608(4) .08452(9) -.0097(2) .0804(13) Uani
H11a .21787 .04658 .40181 .03282 Uiso
H11b .05678 .05149 .49538 .03082 Uiso
H14 .46384 .23597 .47039 .05139 Uiso
H15 .36860 .25681 .69469 .05357 Uiso
H16 .17259 .19739 .80400 .04001 Uiso
H17 .06080 .11795 .67358 .04346 Uiso
H18a .44831 .17545 .27365 .06914 Uiso
H18b .30312 .12816 .25938 .06124 Uiso
H21a -.17753 .09206 .36951 .02498 Uiso
H21b -.08220 .15105 .39205 .03104 Uiso
H24 -.10438 .24589 -.04177 .03951 Uiso
H25 -.34165 .19908 -.14759 .05543 Uiso
H26 -.46001 .11922 -.02492 .04564 Uiso
H27 -.35556 .08331 .18393 .03501 Uiso
H28a .08456 .24492 .13087 .04898 Uiso
H28b .09211 .19830 .25185 .05205 Uiso
H31a -.06717 .04155 .15512 .03068 Uiso
H31b -.03100 .00197 .28842 .03489 Uiso
H34 .40211 .02736 -.10023 .07031 Uiso
H35 .51947 -.05882 -.00929 .06587 Uiso
H36 .42995 -.10478 .18040 .06411 Uiso
H37 .18410 -.06159 .30462 .04169 Uiso
H38a .21231 .10036 -.08708 .05417 Uiso
H38b .10096 .10421 .04307 .07428 Uiso
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C .017 .009 'International Tables for X-Ray Crystallography (1974)'
H 0 0 'International Tables for X-Ray Crystallography (1974)'
N .029 .018 'International Tables for X-Ray Crystallography (1974)'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
-2 2 2
2 -2 -2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C21 N1 C11 110.40(10) yes
C21 N1 C31 110.40(10) yes
C11 N1 C31 108.80(10) yes
H11a C11 H11b 105.77(15) ?
H11a C11 N1 103.47(16) ?
H11a C11 C12 111.96(17) ?
H11b C11 N1 110.82(17) ?
H11b C11 C12 110.43(18) ?
N1 C11 C12 113.90(10) ?
C13 C12 C17 119.0(2) yes
C13 C12 C11 121.23(19) ?
C17 C12 C11 119.65(17) ?
N18 C13 C12 120.7(2) yes
N18 C13 C14 120.0(2) yes
C12 C13 C14 119.4(2) yes
H14 C14 C15 121.6(2) ?
H14 C14 C13 117.9(2) ?
C15 C14 C13 120.4(2) ?
H15 C15 C16 121.2(3) ?
H15 C15 C14 118.3(2) ?
C16 C15 C14 120.5(2) ?
H16 C16 C15 120.4(2) ?
H16 C16 C17 120.4(2) ?
C15 C16 C17 119.2(2) ?
H17 C17 C16 121.0(2) ?
H17 C17 C12 117.5(2) ?
C16 C17 C12 121.5(2) ?
H18b N18 H18a 122.9(3) ?
H18b N18 C13 116.9(2) ?
H18a N18 C13 119.4(2) ?
H21a C21 H21b 106.8(2) ?
H21a C21 N1 110.09(14) ?
H21a C21 C22 110.29(17) ?
H21b C21 N1 107.51(15) ?
H21b C21 C22 111.08(15) ?
N1 C21 C22 110.9(2) ?
C27 C22 C23 119.2(2) yes
C27 C22 C21 120.49(17) ?
C23 C22 C21 120.31(16) ?
N28 C23 C24 120.5(2) yes
N28 C23 C22 120.7(2) yes
C24 C23 C22 118.8(2) yes
H24 C24 C25 122.6(2) ?
H24 C24 C23 116.38(19) ?
C25 C24 C23 121.04(19) ?
H25 C25 C26 117.8(2) ?
H25 C25 C24 121.7(2) ?
C26 C25 C24 120.6(2) ?
H26 C26 C25 121.0(3) ?
H26 C26 C27 120.2(2) ?
C25 C26 C27 118.8(2) ?
H27 C27 C22 119.4(2) ?
H27 C27 C26 118.9(2) ?
C22 C27 C26 121.64(19) ?
H28a N28 H28b 115.30(18) ?
H28a N28 C23 115.9(2) ?
H28b N28 C23 117.59(15) ?
H31b C31 H31a 103.82(16) ?
H31b C31 N1 110.54(17) ?
H31b C31 C32 111.63(14) ?
H31a C31 N1 104.98(13) ?
H31a C31 C32 112.83(18) ?
N1 C31 C32 112.50(10) ?
C37 C32 C33 119.1(2) yes
C37 C32 C31 120.48(19) ?
C33 C32 C31 120.32(16) ?
N38 C33 C34 120.7(2) yes
N38 C33 C32 120.2(2) yes
C34 C33 C32 119.1(2) yes
H34 C34 C35 122.0(3) ?
H34 C34 C33 117.8(2) ?
C35 C34 C33 120.2(2) ?
H35 C35 C36 120.7(3) ?
H35 C35 C34 118.4(3) ?
C36 C35 C34 120.9(3) ?
H36 C36 C35 112.6(3) ?
H36 C36 C37 128.2(3) ?
C35 C36 C37 119.2(2) ?
H37 C37 C36 123.4(2) ?
H37 C37 C32 115.1(2) ?
C36 C37 C32 121.5(2) ?
H38b N38 H38a 124.5(2) ?
H38b N38 C33 116.6(2) ?
H38a N38 C33 114.8(3) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
N1 C21 1.476(2) yes
N1 C11 1.479(2) yes
N1 C31 1.483(2) yes
C11 H11a 1.031(2) ?
C11 H11b 1.036(2) ?
C11 C12 1.506(3) ?
C12 C13 1.394(3) ?
C12 C17 1.396(3) ?
C13 N18 1.384(3) yes
C13 C14 1.399(3) ?
C14 H14 1.036(2) ?
C14 C15 1.385(4) ?
C15 H15 .959(2) ?
C15 C16 1.379(4) ?
C16 H16 1.008(3) ?
C16 C17 1.381(3) ?
C17 H17 .974(2) ?
N18 H18b .898(2) ?
N18 H18a .962(2) ?
C21 H21a .9750(18) ?
C21 H21b .982(2) ?
C21 C22 1.509(3) ?
C22 C27 1.386(3) ?
C22 C23 1.407(2) ?
C23 N28 1.390(2) yes
C23 C24 1.398(3) ?
C24 H24 1.023(2) ?
C24 C25 1.382(3) ?
C25 H25 1.071(2) ?
C25 C26 1.380(3) ?
C26 H26 .974(2) ?
C26 C27 1.395(4) ?
C27 H27 1.000(2) ?
N28 H28a .9102(18) ?
N28 H28b .9637(18) ?
C31 H31b 1.0052(18) ?
C31 H31a 1.039(2) ?
C31 C32 1.503(3) ?
C32 C37 1.396(3) ?
C32 C33 1.401(3) ?
C33 N38 1.381(3) yes
C33 C34 1.397(3) ?
C34 H34 .968(3) ?
C34 C35 1.388(4) ?
C35 H35 .960(3) ?
C35 C36 1.374(5) ?
C36 H36 1.012(3) ?
C36 C37 1.377(4) ?
C37 H37 1.083(2) ?
N38 H38b .849(3) ?
N38 H38a .944(2) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N18 H18b N1 . 0.90 2.38 3.035(3) 130 yes
N18 H18b N38 . 0.90 3.06 3.882(3) 154 ?
N28 H28b N1 . 0.96 2.55 3.173(2) 123 yes
N28 H28b N18 . 0.96 2.57 3.424(3) 147 ?
N38 H38b N1 . 0.85 2.58 3.177(3) 135 yes
N38 H38b N28 . 0.85 3.03 3.782(3) 149 ?
N18 H18a N28 4_555 0.96 2.59 3.414(2) 144 yes
C14 H14 N28 4_555 1.04 2.99 3.791(3) 135 yes
C31 H31b N38 2_555 1.00 2.98 3.987(3) 175 yes
C35 H35 N18 2_654 0.96 2.93 3.769(4) 146 yes
N28 H28a C22-27 4_555 0.91 2.63 3.478(2) 156 yes
C21 H21a C32-37 2_555 0.97 2.99 3.892(2) 155 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
C21 N1 C11 C12 -70.2(2) yes
C21 N1 C11 H11a 168.04(13) ?
C21 N1 C11 H11b 55.09(18) ?
C31 N1 C11 C12 168.5(2) yes
C31 N1 C11 H11a 46.71(18) ?
C31 N1 C11 H11b -66.25(18) ?
C11 N1 C21 C22 168.70(10) yes
C11 N1 C21 H21a -68.9(2) ?
C11 N1 C21 H21b 47.1(2) ?
C31 N1 C21 C22 -71.0(2) yes
C31 N1 C21 H21a 51.4(2) ?
C31 N1 C21 H21b 167.42(14) ?
C11 N1 C31 C32 -75.2(2) yes
C11 N1 C31 H31a 161.72(15) ?
C11 N1 C31 H31b 50.4(2) ?
C21 N1 C31 C32 163.5(2) yes
C21 N1 C31 H31a 40.39(18) ?
C21 N1 C31 H31b -70.97(18) ?
N1 C11 C12 C13 -62.3(2) yes
N1 C11 C12 C17 121.9(2) ?
H11a C11 C12 C13 54.7(3) ?
H11a C11 C12 C17 -121.2(2) ?
H11b C11 C12 C13 172.26(17) ?
H11b C11 C12 C17 -3.6(3) ?
C11 C12 C13 C14 -174.81(18) ?
C11 C12 C13 N18 2.9(3) ?
C17 C12 C13 C14 1.1(3) ?
C17 C12 C13 N18 178.76(19) ?
C11 C12 C17 C16 174.9(2) ?
C11 C12 C17 H17 -5.9(3) ?
C13 C12 C17 C16 -1.1(3) ?
C13 C12 C17 H17 178.13(18) ?
C12 C13 C14 C15 -.5(3) ?
C12 C13 C14 H14 175.94(19) ?
N18 C13 C14 C15 -178.2(2) ?
N18 C13 C14 H14 -1.8(3) ?
C12 C13 N18 H18a -174.3(2) ?
C12 C13 N18 H18b 16.1(3) ?
C14 C13 N18 H18a 3.4(3) ?
C14 C13 N18 H18b -166.2(2) ?
C13 C14 C15 C16 -.2(4) ?
C13 C14 C15 H15 -178.6(2) ?
H14 C14 C15 C16 -176.5(2) ?
H14 C14 C15 H15 5.1(4) ?
C14 C15 C16 C17 .2(4) ?
C14 C15 C16 H16 179.5(2) ?
H15 C15 C16 C17 178.6(2) ?
H15 C15 C16 H16 -2.2(4) ?
C15 C16 C17 C12 .4(4) ?
C15 C16 C17 H17 -178.8(2) ?
H16 C16 C17 C12 -178.8(2) ?
H16 C16 C17 H17 2.0(4) ?
N1 C21 C22 C23 -69.8(2) yes
N1 C21 C22 C27 108.96(19) ?
H21a C21 C22 C23 167.98(16) ?
H21a C21 C22 C27 -13.3(3) ?
H21b C21 C22 C23 49.7(2) ?
H21b C21 C22 C27 -131.52(19) ?
C21 C22 C23 C24 176.83(17) ?
C21 C22 C23 N28 -4.9(3) ?
C27 C22 C23 C24 -1.9(3) ?
C27 C22 C23 N28 176.34(18) ?
C21 C22 C27 C26 -177.04(19) ?
C21 C22 C27 H27 .0(3) ?
C23 C22 C27 C26 1.7(3) ?
C23 C22 C27 H27 178.74(18) ?
C22 C23 C24 C25 1.0(3) ?
C22 C23 C24 H24 -179.41(17) ?
N28 C23 C24 C25 -177.3(2) ?
N28 C23 C24 H24 2.3(3) ?
C22 C23 N28 H28a 166.24(17) ?
C22 C23 N28 H28b 24.0(3) ?
C24 C23 N28 H28a -15.5(3) ?
C24 C23 N28 H28b -157.75(19) ?
C23 C24 C25 C26 .2(3) ?
C23 C24 C25 H25 179.8(2) ?
H24 C24 C25 C26 -179.3(2) ?
H24 C24 C25 H25 .2(4) ?
C24 C25 C26 C27 -.5(3) ?
C24 C25 C26 H26 179.4(2) ?
H25 C25 C26 C27 179.9(2) ?
H25 C25 C26 H26 -.2(4) ?
C25 C26 C27 C22 -.5(3) ?
C25 C26 C27 H27 -177.5(2) ?
H26 C26 C27 C22 179.6(2) ?
H26 C26 C27 H27 2.6(3) ?
N1 C31 C32 C33 -73.3(2) yes
N1 C31 C32 C37 110.12(19) ?
H31a C31 C32 C33 45.3(2) ?
H31a C31 C32 C37 -131.3(2) ?
H31b C31 C32 C33 161.78(18) ?
H31b C31 C32 C37 -14.8(3) ?
C31 C32 C33 C34 -176.1(2) ?
C31 C32 C33 N38 1.8(3) ?
C37 C32 C33 C34 .6(3) ?
C37 C32 C33 N38 178.4(2) ?
C31 C32 C37 C36 176.6(2) ?
C31 C32 C37 H37 -4.2(3) ?
C33 C32 C37 C36 -.1(3) ?
C33 C32 C37 H37 179.15(19) ?
C32 C33 C34 C35 -.4(4) ?
C32 C33 C34 H34 177.6(2) ?
N38 C33 C34 C35 -178.2(2) ?
N38 C33 C34 H34 -.2(4) ?
C32 C33 N38 H38a 178.6(2) ?
C32 C33 N38 H38b 20.3(4) ?
C34 C33 N38 H38a -3.6(4) ?
C34 C33 N38 H38b -161.9(3) ?
C33 C34 C35 C36 -.3(4) ?
C33 C34 C35 H35 179.6(2) ?
H34 C34 C35 C36 -178.2(3) ?
H34 C34 C35 H35 1.7(5) ?
C34 C35 C36 C37 .8(4) ?
C34 C35 C36 H36 -179.1(3) ?
H35 C35 C36 C37 -179.1(3) ?
H35 C35 C36 H36 1.0(4) ?
C35 C36 C37 C32 -.7(4) ?
C35 C36 C37 H37 -179.8(2) ?
H36 C36 C37 C32 179.3(3) ?
H36 C36 C37 H37 .1(5) ?