#------------------------------------------------------------------------------
#$Date: 2008-01-13 22:15:36 +0000 (Sun, 13 Jan 2008) $
#$Revision: 14 $
#$URL: svn://www.crystallography.net/cod/cif/2/2008405.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2008405
_journal_name_full  'Acta Crystallographica'
_journal_year  1999
_journal_volume  C55
_publ_section_title
;
Redetermination of bis[(acetato-O,O')bis(triphenylphosphine-P)silver(I)]
monohydrate sesquiethanol solvate
;
loop_
_publ_author_name
  'Hanna, John V.'
  'Ng, Seik Weng'
_chemical_formula_moiety  '2C38 H33 Ag1 O2 P2, 1.5C2 H6 O, H2 O'
_chemical_formula_sum  'C79 H77 Ag2 O6.50 P4'
_chemical_formula_iupac  '2[Ag (C2 H3 O1) (C18 H15 P)2], 1.5C2 H6 O, H2 O'
_chemical_formula_weight  1470.03
_symmetry_cell_setting  Monoclinic
_symmetry_space_group_name_H-M  'C 2/c'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, y, -z+1/2'
  'x+1/2, y+1/2, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x, -y, z-1/2'
  '-x+1/2, -y+1/2, -z'
  'x+1/2, -y+1/2, z-1/2'
_cell_length_a  44.3229(4)
_cell_length_b  13.34130(10)
_cell_length_c  25.34330(10)
_cell_angle_alpha  90.00
_cell_angle_beta  105.8450(10)
_cell_angle_gamma  90.00
_cell_volume  14416.7(2)
_cell_formula_units_Z  8
_cell_measurement_temperature  298(2)
_exptl_crystal_density_diffrn  1.355
_diffrn_ambient_temperature  298(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ag1a 0.115148(5) 0.12692(2) 0.232270(10)
  0.05197(8) Uani d . 1 . . Ag
  P1a 0.07454(2) 0.02804(6) 0.16886(3) 0.04770(19) Uani d . 1 . . P
  P2a 0.17158(2) 0.12738(7) 0.24121(3) 0.05027(19) Uani d . 1 . . P
  O1a 0.09630(10)
  0.2733(2) 0.27140(10)
  0.0730(10)
  Uani d D 1 . . O
  O2a 0.10510(10)
  0.1398(2) 0.32250(10)
  0.0840(10)
  Uani d . 1 . . O
  O3a 0.10750(10)
  0.4818(3) 0.2855(2) 0.123(2) Uani d D 1 . . O
  C2 0.0159(2) 0.4214(6) 0.2482(6) 0.272(7) Uani d DU 1 . . C
  C1a 0.09700(10)
  0.2280(3) 0.31480(10)
  0.0580(10)
  Uani d . 1 . . C
  C2a 0.08780(10)
  0.2846(4) 0.3605(2) 0.0880(10)
  Uani d . 1 . . C
  O1 0.0385(2) 0.5067(7) 0.2497(4) 0.166(4) Uani d PDU 0.50 . . O
  C11a 0.03400(10)
  0.0395(2) 0.17190(10)
  0.0520(10)
  Uani d G 1 . . C
  C12a 0.01340(10)
  -0.04110(10)
  0.16090(10)
  0.0760(10)
  Uani d G 1 . . C
  C13a -0.01770(10)
  -0.0279(2) 0.16100(10)
  0.0840(10)
  Uani d G 1 . . C
  C14a -0.02820(10)
  0.0659(2) 0.17210(10)
  0.0800(10)
  Uani d G 1 . . C
  C15a -0.00750(10)
  0.1465(2) 0.18310(10)
  0.0830(10)
  Uani d G 1 . . C
  C16a 0.02360(10)
  0.13330(10)
  0.18310(10)
  0.0650(10)
  Uani d G 1 . . C
  C21a 0.07200(10)
  0.0490(2) 0.09600(10)
  0.0510(10)
  Uani d G 1 . . C
  C22a 0.09970(10)
  0.0656(2) 0.08180(10)
  0.0650(10)
  Uani d G 1 . . C
  C23a 0.09880(10)
  0.0899(2) 0.02810(10)
  0.0800(10)
  Uani d G 1 . . C
  C24a 0.07020(10)
  0.0976(2) -0.01150(10)
  0.0840(10)
  Uani d G 1 . . C
  C25a 0.04240(10)
  0.0809(2) 0.00270(10)
  0.0810(10)
  Uani d G 1 . . C
  C26a 0.04330(10)
  0.0566(2) 0.05650(10)
  0.0650(10)
  Uani d G 1 . . C
  C31a 0.08280(10)
  -0.10560(10)
  0.18120(10)
  0.0530(10)
  Uani d G 1 . . C
  C32a 0.08420(10)
  -0.1414(2) 0.23330(10)
  0.0850(10)
  Uani d G 1 . . C
  C33a 0.09130(10)
  -0.2415(2) 0.24610(10)
  0.100(2) Uani d G 1 . . C
  C34a 0.09700(10)
  -0.30590(10)
  0.20670(10)
  0.0950(10)
  Uani d G 1 . . C
  C35a 0.09560(10)
  -0.2701(2) 0.15460(10)
  0.100(2) Uani d G 1 . . C
  C36a 0.08850(10)
  -0.1700(2) 0.14180(10)
  0.0750(10)
  Uani d G 1 . . C
  C41a 0.19590(10)
  0.2165(2) 0.29010(10)
  0.0530(10)
  Uani d G 1 . . C
  C42a 0.22540(10)
  0.2463(2) 0.28680(10)
  0.0690(10)
  Uani d G 1 . . C
  C43a 0.24280(10)
  0.3142(2) 0.32460(10)
  0.0800(10)
  Uani d G 1 . . C
  C44a 0.23080(10)
  0.3524(2) 0.36570(10)
  0.0810(10)
  Uani d G 1 . . C
  C45a 0.20130(10)
  0.3226(2) 0.36900(10)
  0.0930(10)
  Uani d G 1 . . C
  C46a 0.18380(10)
  0.2547(2) 0.33120(10)
  0.0750(10)
  Uani d G 1 . . C
  C51a 0.18340(10)
  0.1510(2) 0.17800(10)
  0.0530(10)
  Uani d G 1 . . C
  C52a 0.16790(10)
  0.2274(2) 0.14400(10)
  0.0770(10)
  Uani d G 1 . . C
  C54a 0.19850(10)
  0.1931(2) 0.08090(10)
  0.0890(10)
  Uani d G 1 . . C
  C53a 0.17550(10)
  0.2485(2) 0.09540(10)
  0.0940(10)
  Uani d G 1 . . C
  C55a 0.21400(10)
  0.1167(2) 0.11490(10)
  0.0880(10)
  Uani d G 1 . . C
  C56a 0.20650(10)
  0.0956(2) 0.16350(10)
  0.0700(10)
  Uani d G 1 . . C
  C61a 0.18750(10)
  0.00190(10)
  0.26270(10)
  0.0530(10)
  Uani d G 1 . . C
  C62a 0.21390(10)
  -0.0133(2) 0.30640(10)
  0.0760(10)
  Uani d G 1 . . C
  C63a 0.22520(10)
  -0.1098(2) 0.32000(10)
  0.0960(10)
  Uani d G 1 . . C
  C64a 0.21000(10)
  -0.1911(2) 0.28990(10)
  0.0830(10)
  Uani d G 1 . . C
  C65a 0.18360(10)
  -0.1759(2) 0.24610(10)
  0.0790(10)
  Uani d G 1 . . C
  C66a 0.17230(10)
  -0.0794(2) 0.23260(10)
  0.0600(10)
  Uani d G 1 . . C
  Ag1b 0.129371(5) 0.52032(2) 0.483140(10)
  0.05130(10)
  Uani d . 1 . . Ag
  P1b 0.07478(2) 0.51937(6) 0.48114(3) 0.0453(2) Uani d . 1 . . P
  P2b 0.17300(2) 0.43322(6) 0.54776(3) 0.0466(2) Uani d . 1 . . P
  O1b 0.14440(9) 0.5161(2) 0.39710(10)
  0.0960(10)
  Uani d D 1 . . O
  O2b 0.15300(7) 0.6561(2) 0.44430(10)
  0.0770(10)
  Uani d . 1 . . O
  O3b 0.15290(10)
  0.8632(3) 0.4504(2) 0.161(2) Uani d DU 1 . . O
  C3b 0.1268(2) 0.9018(6) 0.3956(3) 0.202(5) Uani d DU 1 . . C
  C4b 0.1485(2) 0.9352(7) 0.3671(4) 0.211(4) Uani d DU 1 . . C
  C1b 0.15540(10)
  0.6028(4) 0.4054(2) 0.0830(10)
  Uani d . 1 . . C
  C2b 0.1738(2) 0.6416(4) 0.3666(3) 0.152(3) Uani d . 1 . . C
  C11b 0.05810(10)
  0.39260(10)
  0.47230(10)
  0.0440(10)
  Uani d G 1 . . C
  C12b 0.02650(10)
  0.37500(10)
  0.44720(10)
  0.0600(10)
  Uani d G 1 . . C
  C13b 0.01480(10)
  0.2779(2) 0.44350(10)
  0.0770(10)
  Uani d G 1 . . C
  C14b 0.03460(10)
  0.19840(10)
  0.46500(10)
  0.0710(10)
  Uani d G 1 . . C
  C15b 0.06620(10)
  0.21600(10)
  0.49010(10)
  0.0630(10)
  Uani d G 1 . . C
  C16b 0.07790(10)
  0.3131(2) 0.49380(10)
  0.0530(10)
  Uani d G 1 . . C
  C21b 0.04780(10)
  0.5955(2) 0.42950(10)
  0.0550(10)
  Uani d G 1 . . C
  C22b 0.02150(10)
  0.6412(2) 0.43860(10)
  0.0680(10)
  Uani d G 1 . . C
  C23b 0.00060(10)
  0.6924(2) 0.39620(10)
  0.0880(10)
  Uani d G 1 . . C
  C24b 0.00600(10)
  0.6979(2) 0.34480(10)
  0.099(2) Uani d G 1 . . C
  C25b 0.03230(10)
  0.6522(2) 0.33570(10)
  0.112(2) Uani d G 1 . . C
  C26b 0.05320(10)
  0.6010(2) 0.37800(10)
  0.0850(10)
  Uani d G 1 . . C
  C31b 0.06910(10)
  0.5602(2) 0.54690(10)
  0.0460(10)
  Uani d G 1 . . C
  C32b 0.05500(10)
  0.49920(10)
  0.57770(10)
  0.0560(10)
  Uani d G 1 . . C
  C33b 0.05390(10)
  0.5296(2) 0.62960(10)
  0.0660(10)
  Uani d G 1 . . C
  C34b 0.06680(10)
  0.6209(2) 0.65060(10)
  0.0720(10)
  Uani d G 1 . . C
  C35b 0.08100(10)
  0.68190(10)
  0.61980(10)
  0.0760(10)
  Uani d G 1 . . C
  C36b 0.08210(10)
  0.65150(10)
  0.56790(10)
  0.0680(10)
  Uani d G 1 . . C
  C41b 0.21210(10)
  0.4550(2) 0.53840(10)
  0.0510(10)
  Uani d G 1 . . C
  C42b 0.23450(10)
  0.37990(10)
  0.54400(10)
  0.0740(10)
  Uani d G 1 . . C
  C43b 0.26370(10)
  0.4019(2) 0.53630(10)
  0.0910(10)
  Uani d G 1 . . C
  C44b 0.27050(10)
  0.4989(2) 0.52310(10)
  0.0900(10)
  Uani d G 1 . . C
  C45b 0.24810(10)
  0.5740(2) 0.51750(10)
  0.097(2) Uani d G 1 . . C
  C46b 0.21890(10)
  0.5520(2) 0.52520(10)
  0.0770(10)
  Uani d G 1 . . C
  C51b 0.17700(10)
  0.4566(2) 0.62050(10)
  0.0500(10)
  Uani d G 1 . . C
  C52b 0.15060(10)
  0.4891(2) 0.63510(10)
  0.0650(10)
  Uani d G 1 . . C
  C53b 0.15250(10)
  0.5111(2) 0.68950(10)
  0.0770(10)
  Uani d G 1 . . C
  C54b 0.18100(10)
  0.5006(2) 0.72940(10)
  0.0800(10)
  Uani d G 1 . . C
  C55b 0.20740(10)
  0.4680(3) 0.71490(10)
  0.099(2) Uani d G 1 . . C
  C56b 0.20540(10)
  0.4460(2) 0.66040(10)
  0.0850(10)
  Uani d G 1 . . C
  C61b 0.16770(10)
  0.29760(10)
  0.53920(10)
  0.0500(10)
  Uani d G 1 . . C
  C62b 0.15970(10)
  0.2631(2) 0.48540(10)
  0.0640(10)
  Uani d G 1 . . C
  C63b 0.15490(10)
  0.1612(2) 0.47480(10)
  0.0830(10)
  Uani d G 1 . . C
  C64b 0.15880(10)
  0.09370(10)
  0.51790(10)
  0.0900(10)
  Uani d G 1 . . C
  C65b 0.16710(10)
  0.1282(2) 0.57170(10)
  0.0930(10)
  Uani d G 1 . . C
  C66b 0.17160(10)
  0.2302(2) 0.58240(10)
  0.0740(10)
  Uani d G 1 . . C
  H3aa 0.1030(10)
  0.424(3) 0.283(2) 0.13(2) Uiso d D 1 . . H
  H3aB 0.1180(10)
  0.493(4) 0.317(2) 0.13(2) Uiso d D 1 . . H
  H1a 0.0575 0.4811 0.2438 0.248 Uiso calc PR 0.50 . . H
  H2a 0.0150 0.3866 0.2142 0.409 Uiso calc R 1 . . H
  H2b 0.0269 0.3767 0.2773 0.409 Uiso calc R 1 . . H
  H2' 0.0307 0.4781 0.2486 0.050 Uiso d P 0.50 . . H
  H2a1 0.0821 0.3521 0.3488 0.132 Uiso calc R 1 . . H
  H2a2 0.1052 0.2855 0.3928 0.132 Uiso calc R 1 . . H
  H2a3 0.0703 0.2517 0.3685 0.132 Uiso calc R 1 . . H
  H12a 0.0204 -0.1039 0.1534 0.114 Uiso calc R 1 . . H
  H13a -0.0315 -0.0818 0.1535 0.126 Uiso calc R 1 . . H
  H14a -0.0490 0.0748 0.1721 0.120 Uiso calc R 1 . . H
  H15a -0.0145 0.2093 0.1906 0.125 Uiso calc R 1 . . H
  H16a 0.0374 0.1872 0.1905 0.097 Uiso calc R 1 . . H
  H22a 0.1189 0.0605 0.1083 0.097 Uiso calc R 1 . . H
  H23a 0.1174 0.1011 0.0186 0.119 Uiso calc R 1 . . H
  H24a 0.0696 0.1139 -0.0474 0.126 Uiso calc R 1 . . H
  H25a 0.0233 0.0861 -0.0237 0.122 Uiso calc R 1 . . H
  H26a 0.0248 0.0455 0.0660 0.097 Uiso calc R 1 . . H
  H32a 0.0804 -0.0983 0.2596 0.127 Uiso calc R 1 . . H
  H33a 0.0922 -0.2654 0.2809 0.150 Uiso calc R 1 . . H
  H34a 0.1017 -0.3729 0.2153 0.142 Uiso calc R 1 . . H
  H35a 0.0994 -0.3132 0.1283 0.150 Uiso calc R 1 . . H
  H36a 0.0876 -0.1460 0.1070 0.113 Uiso calc R 1 . . H
  H42a 0.2334 0.2207 0.2593 0.103 Uiso calc R 1 . . H
  H43a 0.2625 0.3341 0.3224 0.119 Uiso calc R 1 . . H
  H44a 0.2424 0.3978 0.3910 0.121 Uiso calc R 1 . . H
  H45a 0.1932 0.3481 0.3965 0.140 Uiso calc R 1 . . H
  H46a 0.1641 0.2347 0.3334 0.113 Uiso calc R 1 . . H
  H52a 0.1525 0.2644 0.1537 0.116 Uiso calc R 1 . . H
  H53a 0.1651 0.2996 0.0727 0.140 Uiso calc R 1 . . H
  H54a 0.2036 0.2072 0.0484 0.133 Uiso calc R 1 . . H
  H55a 0.2294 0.0796 0.1052 0.133 Uiso calc R 1 . . H
  H56a 0.2168 0.0445 0.1863 0.104 Uiso calc R 1 . . H
  H62a 0.2240 0.0412 0.3266 0.114 Uiso calc R 1 . . H
  H63a 0.2428 -0.1199 0.3492 0.144 Uiso calc R 1 . . H
  H64a 0.2175 -0.2557 0.2990 0.125 Uiso calc R 1 . . H
  H65a 0.1734 -0.2304 0.2260 0.119 Uiso calc R 1 . . H
  H66a 0.1546 -0.0693 0.2033 0.103 Uiso calc R 1 . . H
  H3b3 0.1658 0.8127 0.4405 0.241 Uiso calc R 1 . . H
  H3b4 0.1135 0.8478 0.3766 0.303 Uiso calc R 1 . . H
  H3b5 0.1139 0.9558 0.4032 0.303 Uiso calc R 1 . . H
  H4b1 0.1372 0.9622 0.3321 0.317 Uiso calc R 1 . . H
  H4b2 0.1611 0.8798 0.3617 0.317 Uiso calc R 1 . . H
  H4b3 0.1617 0.9862 0.3882 0.317 Uiso calc R 1 . . H
  H2b1 0.1743 0.5910 0.3400 0.227 Uiso calc R 1 . . H
  H2b2 0.1948 0.6578 0.3872 0.227 Uiso calc R 1 . . H
  H2b3 0.1637 0.7006 0.3482 0.227 Uiso calc R 1 . . H
  H12b 0.0133 0.4282 0.4329 0.090 Uiso calc R 1 . . H
  H13b -0.0063 0.2661 0.4267 0.115 Uiso calc R 1 . . H
  H14b 0.0268 0.1334 0.4625 0.107 Uiso calc R 1 . . H
  H15b 0.0795 0.1628 0.5044 0.094 Uiso calc R 1 . . H
  H16b 0.0991 0.3249 0.5106 0.079 Uiso calc R 1 . . H
  H22b 0.0179 0.6376 0.4730 0.102 Uiso calc R 1 . . H
  H23b -0.0170 0.7230 0.4023 0.132 Uiso calc R 1 . . H
  H24b -0.0080 0.7322 0.3165 0.149 Uiso calc R 1 . . H
  H25b 0.0360 0.6558 0.3013 0.168 Uiso calc R 1 . . H
  H26b 0.0708 0.5704 0.3719 0.128 Uiso calc R 1 . . H
  H32b 0.0463 0.4381 0.5636 0.083 Uiso calc R 1 . . H
  H33b 0.0444 0.4888 0.6502 0.099 Uiso calc R 1 . . H
  H34b 0.0661 0.6412 0.6853 0.108 Uiso calc R 1 . . H
  H35b 0.0896 0.7430 0.6338 0.115 Uiso calc R 1 . . H
  H36b 0.0915 0.6923 0.5472 0.101 Uiso calc R 1 . . H
  H42b 0.2300 0.3150 0.5528 0.111 Uiso calc R 1 . . H
  H43b 0.2787 0.3517 0.5400 0.136 Uiso calc R 1 . . H
  H44b 0.2900 0.5136 0.5179 0.136 Uiso calc R 1 . . H
  H45b 0.2526 0.6389 0.5087 0.146 Uiso calc R 1 . . H
  H46b 0.2039 0.6022 0.5215 0.116 Uiso calc R 1 . . H
  H52b 0.1315 0.4961 0.6084 0.098 Uiso calc R 1 . . H
  H53b 0.1349 0.5328 0.6993 0.116 Uiso calc R 1 . . H
  H54b 0.1823 0.5153 0.7659 0.119 Uiso calc R 1 . . H
  H55b 0.2264 0.4610 0.7416 0.149 Uiso calc R 1 . . H
  H56b 0.2231 0.4243 0.6507 0.128 Uiso calc R 1 . . H
  H62b 0.1568 0.3082 0.4565 0.097 Uiso calc R 1 . . H
  H63b 0.1493 0.1381 0.4388 0.124 Uiso calc R 1 . . H
  H64b 0.1558 0.0255 0.5108 0.134 Uiso calc R 1 . . H
  H65b 0.1697 0.0831 0.6006 0.139 Uiso calc R 1 . . H
  H66b 0.1772 0.2532 0.6183 0.112 Uiso calc R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ag1a 0.04540(10)
  0.0545(2) 0.05450(10)
  -0.00200(10)
  0.01130(10)
  -0.00860(10)
  P1a 0.0431(4) 0.0447(4) 0.0538(5) -0.0007(3) 0.0107(3) -0.0085(4)
  P2a 0.0402(4) 0.0562(5) 0.0536(5) -0.0027(4) 0.0113(3) -0.0048(4)
  O1a 0.105(2) 0.066(2) 0.0520(10)
  0.0080(10)
  0.0260(10)
  -0.0040(10)
  O2a 0.103(2) 0.085(2) 0.073(2) 0.011(2) 0.041(2) 0.016(2)
  O3a 0.191(5) 0.089(3) 0.083(2) -0.018(3) 0.028(3) 0.012(2)
  O1 0.190(10)
  0.152(8) 0.173(9) 0.007(7) 0.086(8) -0.003(7)
  C2 0.37(2) 0.122(6) 0.43(2) -0.057(8) 0.28(2) -0.014(9)
  C1a 0.051(2) 0.074(2) 0.049(2) -0.009(2) 0.0150(10)
  -0.008(2)
  C2a 0.095(3) 0.118(4) 0.062(2) -0.009(3) 0.039(2) -0.021(2)
  C11a 0.047(2) 0.055(2) 0.054(2) 0.000(2) 0.0120(10)
  -0.006(2)
  C12a 0.056(2) 0.063(2) 0.111(3) -0.006(2) 0.027(2) -0.017(2)
  C13a 0.053(2) 0.087(3) 0.112(3) -0.011(2) 0.022(2) -0.008(3)
  C14a 0.056(2) 0.105(3) 0.084(3) 0.011(2) 0.027(2) -0.001(2)
  C15a 0.067(2) 0.083(3) 0.104(3) 0.020(2) 0.031(2) -0.012(2)
  C16a 0.063(2) 0.057(2) 0.076(2) 0.004(2) 0.023(2) -0.008(2)
  C21a 0.0540(10)
  0.044(2) 0.055(2) 0.0040(10)
  0.014(2) -0.0050(10)
  C22a 0.055(2) 0.071(2) 0.071(2) 0.011(2) 0.022(2) 0.002(2)
  C23a 0.089(3) 0.084(3) 0.077(3) 0.015(2) 0.042(2) 0.005(2)
  C24a 0.104(3) 0.088(3) 0.060(2) 0.013(3) 0.023(2) 0.004(2)
  C25a 0.082(3) 0.091(3) 0.062(2) -0.001(2) 0.004(2) 0.002(2)
  C26a 0.056(2) 0.071(2) 0.061(2) -0.003(2) 0.006(2) -0.002(2)
  C31a 0.048(2) 0.042(2) 0.065(2) -0.0010(10)
  0.010(2) -0.006(2)
  C32a 0.109(3) 0.070(3) 0.079(3) 0.014(2) 0.033(2) 0.013(2)
  C33a 0.112(4) 0.086(3) 0.105(4) 0.016(3) 0.032(3) 0.037(3)
  C34a 0.092(3) 0.054(2) 0.129(4) 0.005(2) 0.014(3) 0.013(3)
  C35a 0.134(4) 0.052(2) 0.105(4) 0.016(3) 0.017(3) -0.012(2)
  C36a 0.099(3) 0.050(2) 0.072(2) 0.008(2) 0.015(2) -0.009(2)
  C41a 0.046(2) 0.055(2) 0.055(2) -0.0010(10)
  0.0070(10)
  -0.003(2)
  C42a 0.053(2) 0.072(2) 0.083(3) -0.008(2) 0.020(2) -0.012(2)
  C43a 0.062(2) 0.080(3) 0.090(3) -0.018(2) 0.008(2) -0.006(2)
  C44a 0.089(3) 0.071(3) 0.070(3) -0.020(2) 0.000(2) -0.010(2)
  C45a 0.097(3) 0.111(4) 0.075(3) -0.026(3) 0.030(2) -0.032(3)
  C46a 0.067(2) 0.095(3) 0.066(2) -0.020(2) 0.024(2) -0.020(2)
  C51a 0.049(2) 0.055(2) 0.054(2) -0.005(2) 0.0140(10)
  -0.003(2)
  C52a 0.075(2) 0.072(3) 0.090(3) 0.017(2) 0.030(2) 0.021(2)
  C53a 0.105(3) 0.086(3) 0.095(3) 0.010(3) 0.036(3) 0.032(3)
  C54a 0.124(4) 0.078(3) 0.077(3) -0.009(3) 0.048(3) 0.008(2)
  C55a 0.118(4) 0.076(3) 0.093(3) 0.012(3) 0.064(3) -0.003(2)
  C56a 0.075(2) 0.067(2) 0.072(2) 0.013(2) 0.030(2) 0.002(2)
  C61a 0.045(2) 0.059(2) 0.058(2) -0.0020(10)
  0.018(2) 0.003(2)
  C62a 0.063(2) 0.074(3) 0.082(3) -0.003(2) 0.004(2) 0.012(2)
  C63a 0.084(3) 0.087(3) 0.104(3) 0.004(3) 0.005(3) 0.031(3)
  C64a 0.091(3) 0.068(3) 0.103(3) 0.015(2) 0.045(3) 0.030(2)
  C65a 0.088(3) 0.062(2) 0.094(3) -0.002(2) 0.038(2) 0.000(2)
  C66a 0.066(2) 0.066(2) 0.071(2) 0.001(2) 0.014(2) -0.003(2)
  Ag1b 0.04120(10)
  0.0573(2) 0.0573(2) 0.00050(10)
  0.01650(10)
  0.00810(10)
  P1b 0.0373(4) 0.0463(4) 0.0523(4) 0.0018(3) 0.0120(3) 0.0044(4)
  P2b 0.0355(4) 0.0518(5) 0.0524(4) -0.0001(3) 0.0117(3) 0.0033(4)
  O1b 0.147(3) 0.082(2) 0.076(2) -0.022(2) 0.058(2) -0.007(2)
  O2b 0.101(2) 0.059(2) 0.083(2) -0.0050(10)
  0.046(2) 0.0050(10)
  O3b 0.280(6) 0.098(3) 0.090(3) 0.001(3) 0.026(3) -0.008(2)
  C3b 0.38(2) 0.141(6) 0.124(6) -0.037(8) 0.128(8) -0.012(5)
  C4b 0.210(10)
  0.240(10)
  0.201(9) 0.007(8) 0.089(8) -0.035(8)
  C1b 0.109(3) 0.074(3) 0.082(3) -0.007(3) 0.053(3) 0.010(2)
  C2b 0.237(8) 0.124(5) 0.149(5) -0.040(5) 0.145(6) -0.001(4)
  C11b 0.040(2) 0.048(2) 0.046(2) 0.0030(10)
  0.0160(10)
  -0.0020(10)
  C12b 0.046(2) 0.056(2) 0.074(2) 0.002(2) 0.008(2) -0.007(2)
  C13b 0.058(2) 0.071(3) 0.092(3) -0.012(2) 0.005(2) -0.009(2)
  C14b 0.079(3) 0.054(2) 0.080(3) -0.015(2) 0.020(2) -0.009(2)
  C15b 0.074(2) 0.052(2) 0.060(2) 0.005(2) 0.016(2) 0.007(2)
  C16b 0.050(2) 0.055(2) 0.052(2) 0.005(2) 0.0110(10)
  0.003(2)
  C21b 0.048(2) 0.048(2) 0.063(2) -0.0010(10)
  0.007(2) 0.010(2)
  C22b 0.053(2) 0.055(2) 0.093(3) 0.005(2) 0.016(2) 0.017(2)
  C23b 0.060(2) 0.062(3) 0.127(4) 0.018(2) 0.002(2) 0.025(3)
  C24b 0.100(4) 0.075(3) 0.096(4) 0.008(3) -0.017(3) 0.025(3)
  C25b 0.141(5) 0.111(4) 0.071(3) 0.031(4) 0.008(3) 0.032(3)
  C26b 0.100(3) 0.088(3) 0.068(3) 0.017(3) 0.023(2) 0.016(2)
  C31b 0.037(2) 0.043(2) 0.055(2) 0.0040(10)
  0.0070(10)
  -0.0020(10)
  C32b 0.061(2) 0.052(2) 0.055(2) -0.008(2) 0.016(2) -0.009(2)
  C33b 0.081(3) 0.068(2) 0.051(2) 0.001(2) 0.020(2) -0.005(2)
  C34b 0.076(3) 0.069(2) 0.061(2) 0.021(2) 0.003(2) -0.023(2)
  C35b 0.075(3) 0.055(2) 0.091(3) -0.001(2) 0.008(2) -0.027(2)
  C36b 0.069(2) 0.046(2) 0.087(3) -0.007(2) 0.021(2) -0.009(2)
  C41b 0.039(2) 0.062(2) 0.053(2) -0.0030(10)
  0.0130(10)
  -0.001(2)
  C42b 0.048(2) 0.075(3) 0.103(3) 0.007(2) 0.028(2) 0.010(2)
  C43b 0.047(2) 0.112(4) 0.119(4) 0.011(2) 0.034(2) 0.008(3)
  C44b 0.050(2) 0.131(4) 0.099(3) -0.012(2) 0.035(2) 0.005(3)
  C45b 0.069(3) 0.091(3) 0.145(4) -0.016(2) 0.052(3) 0.013(3)
  C46b 0.058(2) 0.068(2) 0.114(3) -0.002(2) 0.039(2) 0.007(2)
  C51b 0.043(2) 0.053(2) 0.053(2) -0.0040(10)
  0.0120(10)
  0.0020(10)
  C52b 0.050(2) 0.083(3) 0.063(2) 0.001(2) 0.018(2) 0.001(2)
  C53b 0.076(3) 0.095(3) 0.068(2) 0.000(2) 0.031(2) -0.002(2)
  C54b 0.095(3) 0.089(3) 0.056(2) -0.012(2) 0.021(2) -0.004(2)
  C55b 0.074(3) 0.153(5) 0.060(3) 0.001(3) 0.001(2) -0.016(3)
  C56b 0.049(2) 0.134(4) 0.065(2) 0.009(2) 0.003(2) -0.014(2)
  C61b 0.036(2) 0.051(2) 0.062(2) 0.0020(10)
  0.0140(10)
  0.002(2)
  C62b 0.058(2) 0.068(2) 0.068(2) 0.000(2) 0.019(2) -0.007(2)
  C63b 0.073(3) 0.078(3) 0.102(3) -0.010(2) 0.033(2) -0.030(3)
  C64b 0.079(3) 0.058(2) 0.142(4) -0.013(2) 0.047(3) -0.021(3)
  C65b 0.113(4) 0.056(2) 0.113(4) -0.008(2) 0.037(3) 0.015(2)
  C66b 0.085(3) 0.064(2) 0.072(2) -0.007(2) 0.018(2) 0.004(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ag1a P1a . 2.4461(8) ?
  Ag1a P2a . 2.4490(8) ?
  Ag1a O1a . 2.438(2) ?
  Ag1a O2a . 2.451(3) ?
  P1a C11a . 1.825(2) ?
  P1a C21a . 1.840(2) ?
  P1a C31a . 1.830(2) ?
  P2a C41a . 1.839(2) ?
  P2a C61a . 1.840(2) ?
  P2a C51a . 1.842(2) ?
  O1a C1a . 1.249(4) ?
  O2a C1a . 1.231(4) ?
  O1 C2 . 1.508(7) ?
  C2 C2 2 1.438(9) ?
  C1a C2a . 1.527(5) ?
  C11a C12a . 1.3900 ?
  C11a C16a . 1.3900 ?
  C12a C13a . 1.3900 ?
  C13a C14a . 1.3900 ?
  C14a C15a . 1.3900 ?
  C15a C16a . 1.3900 ?
  C21a C22a . 1.3900 ?
  C21a C26a . 1.3900 ?
  C22a C23a . 1.3900 ?
  C23a C24a . 1.3900 ?
  C24a C25a . 1.3900 ?
  C25a C26a . 1.3900 ?
  C31a C32a . 1.3900 ?
  C31a C36a . 1.3900 ?
  C32a C33a . 1.3900 ?
  C33a C34a . 1.3900 ?
  C34a C35a . 1.3900 ?
  C35a C36a . 1.3900 ?
  C41a C42a . 1.3900 ?
  C41a C46a . 1.3900 ?
  C42a C43a . 1.3900 ?
  C43a C44a . 1.3900 ?
  C44a C45a . 1.3900 ?
  C45a C46a . 1.3900 ?
  C51a C52a . 1.3900 ?
  C51a C56a . 1.3900 ?
  C52a C53a . 1.3900 ?
  C53a C54a . 1.3900 ?
  C54a C55a . 1.3900 ?
  C55a C56a . 1.3900 ?
  C61a C62a . 1.3900 ?
  C61a C66a . 1.3900 ?
  C62a C63a . 1.3900 ?
  C63a C64a . 1.3900 ?
  C64a C65a . 1.3900 ?
  C65a C66a . 1.3900 ?
  Ag1b P1b . 2.4063(8) ?
  Ag1b P2b . 2.4582(8) ?
  Ag1b O1b . 2.449(3) ?
  Ag1b O2b . 2.431(2) ?
  P1b C21b . 1.823(2) ?
  P1b C31b . 1.833(2) ?
  P1b C11b . 1.834(2) ?
  P2b C51b . 1.831(2) ?
  P2b C61b . 1.830(2) ?
  P2b C41b . 1.836(2) ?
  O1b C1b . 1.251(5) ?
  O2b C1b . 1.243(5) ?
  O3b C3b . 1.631(7) ?
  C3b C4b . 1.424(7) ?
  C1b C2b . 1.529(6) ?
  C11b C12b . 1.3900 ?
  C11b C16b . 1.3900 ?
  C12b C13b . 1.3900 ?
  C13b C14b . 1.3900 ?
  C14b C15b . 1.3900 ?
  C15b C16b . 1.3900 ?
  C21b C22b . 1.3900 ?
  C21b C26b . 1.3900 ?
  C22b C23b . 1.3900 ?
  C23b C24b . 1.3900 ?
  C24b C25b . 1.3900 ?
  C25b C26b . 1.3900 ?
  C31b C32b . 1.3900 ?
  C31b C36b . 1.3900 ?
  C32b C33b . 1.3900 ?
  C33b C34b . 1.3900 ?
  C34b C35b . 1.3900 ?
  C35b C36b . 1.3900 ?
  C41b C42b . 1.3900 ?
  C41b C46b . 1.3900 ?
  C42b C43b . 1.3900 ?
  C43b C44b . 1.3900 ?
  C44b C45b . 1.3900 ?
  C45b C46b . 1.3900 ?
  C51b C52b . 1.3900 ?
  C51b C56b . 1.3900 ?
  C52b C53b . 1.3900 ?
  C53b C54b . 1.3900 ?
  C54b C55b . 1.3900 ?
  C55b C56b . 1.3900 ?
  C61b C62b . 1.3900 ?
  C61b C66b . 1.3900 ?
  C62b C63b . 1.3900 ?
  C63b C64b . 1.3900 ?
  C64b C65b . 1.3900 ?
  C65b C66b . 1.3900 ?