#------------------------------------------------------------------------------ #$Date: 2016-02-19 14:29:56 +0000 (Fri, 19 Feb 2016) $ #$Revision: 176759 $ #$URL: svn://www.crystallography.net/cod/cif/2/00/85/2008510.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2008510 loop_ _publ_author_name 'Lo, Kong Mun' 'Kumar Das, V. G.' 'Ng, Seik Weng' 'Hook, James M.' _publ_section_title ;catena-Poly[triphenyltin-\m-(N,N-diethylthiocarbamoylthioacetato-O:O')], catena-poly[triphenyltin-\m-(N-methyl-N-phenylthiocarbamoylthioacetato-O:O')] and triphenyl(N,N-tetramethylenethiocarbamoylthioacetato-O)tin ; _journal_issue 5 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 744 _journal_page_last 748 _journal_paper_doi 10.1107/S0108270199002954 _journal_volume 55 _journal_year 1999 _chemical_formula_iupac '[Sn (C6 H5)3 (C7 H12 N O2 S2)]' _chemical_formula_moiety 'C25 H27 N O2 S2 Sn' _chemical_formula_sum 'C25 H27 N O2 S2 Sn' _chemical_formula_weight 556.29 _chemical_name_systematic ; catena-poly[triphenyltin-\m-(N,N-diethylthiocarbamoylthioacetato)-O:O'] ; _space_group_IT_number 14 _symmetry_cell_setting monoclinic _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _audit_creation_method SHELXL-97 _cell_angle_alpha 90.00 _cell_angle_beta 97.420(10) _cell_angle_gamma 90.00 _cell_formula_units_Z 8 _cell_length_a 12.900(2) _cell_length_b 18.135(2) _cell_length_c 21.822(4) _cell_measurement_reflns_used 25 _cell_measurement_temperature 298(2) _cell_measurement_theta_max 13.0 _cell_measurement_theta_min 12.0 _cell_volume 5062.3(13) _computing_cell_refinement 'CELDIM in CAD-4 VAX/PC Fortran System (Enraf-Nonius, 1988)' _computing_data_collection 'CAD-4/PC (Kretschmar, 1994)' _computing_data_reduction 'XCAD4 (Harms, 1997)' _computing_molecular_graphics 'ORTEPII (Johnson, 1976)' _computing_publication_material SHELXL97 _computing_structure_refinement 'SHELXL97 (Sheldrick, 1997a)' _computing_structure_solution 'SHELXS97 (Sheldrick, 1997b)' _diffrn_ambient_temperature 298(2) _diffrn_measured_fraction_theta_full 0.966 _diffrn_measured_fraction_theta_max 0.966 _diffrn_measurement_device_type 'Enraf-Nonius CAD-4' _diffrn_measurement_method \w _diffrn_radiation_monochromator graphite _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.029 _diffrn_reflns_av_sigmaI/netI 0.0515 _diffrn_reflns_limit_h_max 15 _diffrn_reflns_limit_h_min -15 _diffrn_reflns_limit_k_max 21 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_l_max 25 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_number 9167 _diffrn_reflns_theta_full 24.99 _diffrn_reflns_theta_max 25 _diffrn_reflns_theta_min 1.47 _diffrn_standards_decay_% 4 _diffrn_standards_interval_time 60 _diffrn_standards_number 3 _exptl_absorpt_coefficient_mu 1.195 _exptl_absorpt_correction_T_max 0.584 _exptl_absorpt_correction_T_min 0.493 _exptl_absorpt_correction_type '\y scan (North et al., 1968)' _exptl_crystal_colour Colorless _exptl_crystal_density_diffrn 1.460 _exptl_crystal_density_method 'not measured' _exptl_crystal_description Block _exptl_crystal_F_000 2256 _exptl_crystal_size_max 0.55 _exptl_crystal_size_mid 0.50 _exptl_crystal_size_min 0.45 _refine_diff_density_max 1.198 _refine_diff_density_min -0.598 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.009 _refine_ls_hydrogen_treatment 'constr, with U(H) = 1.5U~eq~(C)' _refine_ls_matrix_type full _refine_ls_number_parameters 487 _refine_ls_number_reflns 8911 _refine_ls_number_restraints 20 _refine_ls_restrained_S_all 1.015 _refine_ls_R_factor_all 0.100 _refine_ls_R_factor_gt 0.058 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w = 1/[\s^2^(Fo^2^)+(0.0818P)^2^+7.1495P] where P = (Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_ref 0.166 _reflns_number_gt 5739 _reflns_number_total 8911 _reflns_threshold_expression I>2\s(I) _cod_data_source_file sk1233.cif _cod_data_source_block I _cod_depositor_comments ; The following automatic conversions were performed: '_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic' according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29. Automatic conversion script Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius The following automatic conversions were performed: '_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic' according to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29. Automatic conversion script Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana The following automatic conversions were performed: '_refine_ls_weighting_scheme' value 'calc w = 1/[\s^2^(Fo^2^)+(0.0818P)^2^+7.1495P] where P = (Fo^2^+2Fc^2^)/3' was changed to 'calc'. New tag '_refine_ls_weighting_details' was created. The value of the new tag was set to 'w = 1/[\s^2^(Fo^2^)+(0.0818P)^2^+7.1495P] where P = (Fo^2^+2Fc^2^)/3'. Automatic conversion script Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas ; _cod_original_cell_volume 5062.0(10) _cod_original_sg_symbol_H-M 'P 21/c' _cod_database_code 2008510 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_refinement_flags _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group _atom_site_type_symbol Sn1a .33367(4) .49979(3) .26794(2) .0584(2) Uani d . 1 . . Sn S1a .2237(2) .3681(2) .45400(10) .0939(8) Uani d D 1 . . S S2a .1259(3) .2790(2) .3482(2) .1450(10) Uani d D 1 . . S N1a .0221(7) .3542(5) .4217(4) .121(3) Uani d D 1 . . N O1a .3059(4) .4281(3) .3447(2) .0670(10) Uani d . 1 . . O O2a .4346(4) .3488(3) .3400(2) .0650(10) Uani d . 1 . . O C1a .3245(5) .4144(3) .2007(2) .072(2) Uani d G 1 . . C C2a .3767(4) .4211(3) .1491(3) .084(3) Uani d G 1 . . C C3a .3708(5) .3648(4) .1056(2) .107(4) Uani d G 1 . . C C4a .3127(6) .3018(3) .1137(3) .117(4) Uani d G 1 . . C C5a .2606(5) .2951(3) .1653(4) .109(4) Uani d G 1 . . C C6a .2665(5) .3514(4) .2088(3) .084(3) Uani d G 1 . . C C7a .4771(4) .5391(3) .3141(2) .059(2) Uani d G 1 . . C C8a .4816(5) .5628(3) .3750(2) .084(3) Uani d G 1 . . C C9a .5749(6) .5896(3) .4060(2) .115(4) Uani d G 1 . . C C10a .6636(5) .5929(3) .3760(4) .116(4) Uani d G 1 . . C C11a .6590(4) .5693(4) .3152(4) .104(3) Uani d G 1 . . C C12a .5658(4) .5424(3) .2842(2) .077(2) Uani d G 1 . . C C13a .1926(4) .5560(3) .2823(3) .066(2) Uani d G 1 . . C C14a .1885(5) .6326(3) .2814(3) .090(3) Uani d G 1 . . C C15a .0946(6) .6686(3) .2859(4) .122(4) Uani d G 1 . . C C16a .0048(5) .6279(5) .2912(4) .138(5) Uani d G 1 . . C C17a .0090(4) .5513(5) .2920(4) .159(6) Uani d G 1 . . C C18a .1028(5) .5154(3) .2876(4) .107(3) Uani d G 1 . . C C19a .3599(6) .3726(4) .3639(3) .054(2) Uani d . 1 . . C C20a .3286(6) .3348(5) .4199(3) .071(2) Uani d . 1 . . C C21a .1190(10) .3338(5) .4066(4) .112(4) Uani d D 1 . . C C22a .025(2) .4119(7) .4682(6) .35(2) Uani d D 1 . . C C23a .0190(10) .3753(9) .5312(7) .270(10) Uani d D 1 . . C C24a -.0720(10) .3225(8) .3903(7) .208(9) Uani d D 1 . . C C25a -.1080(10) .3700(10) .3336(9) .280(10) Uani d D 1 . . C Sn1b .56314(4) .25697(3) .35420(2) .0554(2) Uani d . 1 . . Sn S1b .9032(2) .11310(10) .41830(10) .0813(6) Uani d D 1 . . S S2b .7688(3) .0778(2) .5149(2) .1250(10) Uani d D 1 . . S O1b .6950(4) .1790(3) .3713(2) .0660(10) Uani d . 1 . . O O2b .6426(4) .0890(3) .3056(2) .0670(10) Uani d . 1 . . O N1b .9597(7) .1330(5) .5351(4) .114(3) Uani d D 1 . . N C1b .6354(4) .3157(2) .4331(2) .058(2) Uani d G 1 . . C C2b .6872(4) .2768(2) .4828(2) .069(2) Uani d G 1 . . C C3b .7365(4) .3145(3) .5339(2) .080(2) Uani d G 1 . . C C4b .7341(4) .3911(3) .5353(2) .081(3) Uani d G 1 . . C C5b .6823(5) .4300(2) .4856(3) .083(3) Uani d G 1 . . C C6b .6329(4) .3924(2) .4345(2) .072(2) Uani d G 1 . . C C7b .4514(4) .1747(3) .3663(3) .064(2) Uani d G 1 . . C C8b .3561(5) .1727(3) .3284(3) .081(2) Uani d G 1 . . C C9b .2830(4) .1186(4) .3371(3) .108(3) Uani d G 1 . . C C10b .3053(5) .0665(3) .3837(4) .120(4) Uani d G 1 . . C C11b .4005(6) .0685(3) .4216(3) .114(4) Uani d G 1 . . C C12b .4736(4) .1226(4) .4129(3) .091(3) Uani d G 1 . . C C13b .5926(4) .2886(3) .2648(2) .061(2) Uani d G 1 . . C C14b .6395(5) .3561(3) .2562(3) .092(3) Uani d G 1 . . C C15b .6625(5) .3761(3) .1980(3) .109(3) Uani d G 1 . . C C16b .6386(5) .3285(4) .1483(2) .099(3) Uani d G 1 . . C C17b .5917(5) .2609(3) .1568(2) .090(3) Uani d G 1 . . C C18b .5687(5) .2409(2) .2150(2) .076(2) Uani d G 1 . . C C19b .7049(6) .1158(4) .3491(3) .059(2) Uani d . 1 . . C C20b .7928(7) .0688(5) .3775(4) .086(3) Uani d . 1 . . C C21b .8782(6) .1098(3) .4956(4) .078(2) Uani d D 1 . . C C22b 1.0530(9) .1686(7) .5153(6) .163(6) Uani d D 1 . . C C23b 1.1280(10) .1080(10) .5023(8) .250(10) Uani d D 1 . . C C24b .9470(10) .1471(8) .6009(5) .185(7) Uani d D 1 . . C C25b .976(2) .0790(10) .6384(7) .250(10) Uani d D 1 . . C H2a .4155 .4633 .1437 .125 Uiso calc R 1 . . H H3a .4057 .3693 .0711 .160 Uiso calc R 1 . . H H4a .3088 .2641 .0846 .176 Uiso calc R 1 . . H H5a .2218 .2529 .1707 .164 Uiso calc R 1 . . H H6a .2316 .3469 .2434 .127 Uiso calc R 1 . . H H8a .4223 .5606 .3950 .126 Uiso calc R 1 . . H H9a .5779 .6054 .4467 .172 Uiso calc R 1 . . H H10a .7260 .6109 .3968 .174 Uiso calc R 1 . . H H11a .7184 .5714 .2951 .157 Uiso calc R 1 . . H H12a .5627 .5266 .2434 .115 Uiso calc R 1 . . H H14a .2486 .6598 .2779 .135 Uiso calc R 1 . . H H15a .0918 .7198 .2853 .182 Uiso calc R 1 . . H H16a -.0580 .6520 .2942 .208 Uiso calc R 1 . . H H17a -.0511 .5242 .2956 .239 Uiso calc R 1 . . H H18a .1056 .4641 .2881 .160 Uiso calc R 1 . . H H20a .3892 .3347 .4513 .107 Uiso calc R 1 . . H H20b .3137 .2837 .4088 .107 Uiso calc R 1 . . H H22a -.0328 .4455 .4581 .529 Uiso calc R 1 . . H H22b .0899 .4396 .4695 .529 Uiso calc R 1 . . H H23a .0259 .4123 .5630 .399 Uiso calc R 1 . . H H23b .0740 .3398 .5395 .399 Uiso calc R 1 . . H H23c -.0475 .3511 .5304 .399 Uiso calc R 1 . . H H24a -.1253 .3212 .4176 .312 Uiso calc R 1 . . H H24b -.0583 .2724 .3778 .312 Uiso calc R 1 . . H H25a -.1695 .3478 .3112 .416 Uiso calc R 1 . . H H25b -.0537 .3718 .3075 .416 Uiso calc R 1 . . H H25c -.1240 .4184 .3465 .416 Uiso calc R 1 . . H H2b .6888 .2256 .4818 .103 Uiso calc R 1 . . H H3b .7712 .2885 .5671 .119 Uiso calc R 1 . . H H4b .7671 .4163 .5695 .121 Uiso calc R 1 . . H H5b .6806 .4813 .4866 .125 Uiso calc R 1 . . H H6b .5982 .4184 .4013 .107 Uiso calc R 1 . . H H8b .3412 .2075 .2972 .121 Uiso calc R 1 . . H H9b .2193 .1173 .3118 .162 Uiso calc R 1 . . H H10b .2564 .0303 .3896 .180 Uiso calc R 1 . . H H11b .4154 .0337 .4527 .170 Uiso calc R 1 . . H H12b .5373 .1239 .4382 .137 Uiso calc R 1 . . H H14b .6555 .3880 .2895 .138 Uiso calc R 1 . . H H15b .6939 .4213 .1923 .163 Uiso calc R 1 . . H H16b .6540 .3419 .1093 .149 Uiso calc R 1 . . H H17b .5757 .2291 .1235 .135 Uiso calc R 1 . . H H18b .5373 .1957 .2207 .114 Uiso calc R 1 . . H H20c .8167 .0396 .3448 .130 Uiso calc R 1 . . H H20d .7653 .0348 .4056 .130 Uiso calc R 1 . . H H22c 1.0856 .2010 .5475 .244 Uiso calc R 1 . . H H22d 1.0333 .1977 .4783 .244 Uiso calc R 1 . . H H23d 1.1899 .1299 .4894 .370 Uiso calc R 1 . . H H23e 1.0955 .0767 .4702 .370 Uiso calc R 1 . . H H23f 1.1475 .0799 .5392 .370 Uiso calc R 1 . . H H24c .8745 .1600 .6040 .278 Uiso calc R 1 . . H H24d .9906 .1880 .6166 .278 Uiso calc R 1 . . H H25d .9683 .0882 .6808 .367 Uiso calc R 1 . . H H25e 1.0476 .0666 .6352 .367 Uiso calc R 1 . . H H25f .9315 .0390 .6231 .367 Uiso calc R 1 . . H loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Sn1a .0574(3) .0589(3) .0574(3) .0051(2) .0013(2) .0046(2) S1a .093(2) .108(2) .085(2) -.013(2) .0270(10) -.0180(10) S2a .133(3) .153(3) .151(3) -.011(2) .020(2) -.052(3) N1a .064(5) .118(7) .180(10) -.010(5) .032(6) .005(7) O1a .061(3) .069(3) .070(3) .010(3) .012(3) .013(3) O2a .060(3) .069(3) .068(3) .007(3) .014(3) .014(3) C1a .078(6) .067(5) .066(5) .014(4) -.011(4) .004(4) C2a .097(7) .077(6) .076(6) .022(5) .007(5) -.008(5) C3a .124(9) .106(8) .086(7) .040(7) -.004(6) -.025(6) C4a .160(10) .087(8) .093(8) .039(8) -.042(7) -.035(7) C5a .140(10) .066(6) .109(8) -.007(6) -.047(7) -.004(6) C6a .089(6) .077(6) .080(6) -.006(5) -.018(5) .008(5) C7a .064(5) .050(4) .061(5) .005(4) -.003(4) .005(4) C8a .092(7) .078(6) .076(6) .018(5) -.007(5) -.007(5) C9a .150(10) .082(7) .095(8) .000(7) -.046(8) -.010(6) C10a .130(10) .071(7) .130(10) -.020(7) -.060(8) .024(7) C11a .086(7) .104(8) .117(9) -.018(6) -.010(6) .027(7) C12a .069(5) .080(6) .077(6) .000(5) -.005(4) .008(5) C13a .062(5) .075(6) .059(5) .012(4) -.002(4) .013(4) C14a .089(7) .080(7) .100(7) .018(5) .005(5) -.004(5) C15a .120(9) .097(8) .150(10) .050(8) .029(8) -.002(7) C16a .076(8) .152(13) .190(10) .045(8) .023(8) .000(10) C17a .063(7) .115(10) .30(2) .017(7) .043(9) -.010(10) C18a .075(6) .089(7) .160(10) .008(6) .028(6) .018(7) C19a .050(4) .062(5) .050(4) -.002(4) .000(3) .003(4) C20a .064(5) .092(6) .057(5) .003(4) .006(4) .008(4) C21a .130(10) .091(8) .106(8) -.048(7) -.008(7) .000(6) C22a .83(7) .130(10) .14(2) .10(2) .22(3) -.010(10) C23a .120(10) .27(2) .42(3) -.010(10) .07(2) -.22(3) C24a .120(10) .21(2) .29(2) -.020(10) -.020(10) .12(2) C25a .20(2) .27(3) .32(3) -.10(2) -.11(2) .16(2) Sn1b .0621(3) .0500(3) .0541(3) -.0020(2) .0077(2) .0003(2) S1b .0730(10) .099(2) .0710(10) .0040(10) .0040(10) -.0080(10) S2b .125(2) .140(3) .112(2) -.014(2) .030(2) .029(2) O1b .078(4) .054(3) .064(3) .015(3) .000(3) -.007(3) O2b .077(3) .067(3) .054(3) .006(3) -.007(3) -.009(3) N1b .117(7) .148(9) .068(5) -.023(6) -.025(5) -.012(5) C1b .061(5) .060(5) .055(4) -.002(4) .016(4) -.006(4) C2b .087(6) .067(5) .053(5) -.006(4) .008(4) .003(4) C3b .089(6) .093(7) .055(5) -.002(5) .003(4) .004(5) C4b .085(6) .089(7) .068(5) -.014(5) .006(5) -.020(5) C5b .101(7) .063(5) .083(6) -.003(5) .005(5) -.013(5) C6b .085(6) .054(5) .071(5) .004(4) -.007(4) -.010(4) C7b .066(5) .060(5) .067(5) -.010(4) .016(4) -.003(4) C8b .086(6) .067(6) .088(6) -.015(5) .001(5) -.011(5) C9b .089(7) .105(8) .131(9) -.034(6) .018(7) -.029(7) C10b .140(10) .093(8) .140(10) -.044(8) .052(9) -.003(7) C11b .140(10) .105(9) .098(8) -.040(8) .023(7) .006(7) C12b .091(7) .093(7) .093(7) -.015(6) .026(5) .022(6) C13b .060(4) .057(5) .066(5) .002(4) .010(4) .001(4) C14b .114(8) .078(6) .092(7) -.023(6) .042(6) -.003(5) C15b .119(9) .097(8) .117(9) -.022(7) .038(7) .018(7) C16b .107(8) .116(9) .080(7) .015(7) .030(6) .021(6) C17b .116(8) .089(7) .068(6) .012(6) .023(5) .012(5) C18b .103(6) .064(5) .061(5) .006(5) .009(4) .005(4) C19b .071(5) .049(4) .055(4) .006(4) .003(4) .001(4) C20b .107(7) .068(5) .073(5) .025(5) -.033(5) -.017(4) C21b .083(6) .073(6) .073(5) -.011(5) -.009(5) .001(4) C22b .090(9) .21(2) .180(10) .010(10) -.040(9) -.050(10) C23b .21(2) .26(2) .24(2) .02(2) -.10(2) -.10(2) C24b .23(2) .18(2) .130(10) -.010(10) -.050(10) .010(10) C25b .21(2) .33(3) .17(2) .06(2) -.070(10) .01(2) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C1a Sn1a C7a . 122.8(2) yes C1a Sn1a C13a . 118.3(2) yes C1a Sn1a O1a . 95.4(2) yes C1a Sn1a O2b 2_655 91.8(2) yes C7a Sn1a C13a . 118.5(2) yes C7a Sn1a O1a . 93.2(2) yes C7a Sn1a O2b 2_655 84.8(2) yes C13a Sn1a O1a . 86.9(2) yes C13a Sn1a O2b 2_655 87.7(2) yes O1a Sn1a O2b 2_655 172.4(2) yes C19a O1a Sn1a . 126.2(5) yes C19a O2a Sn1b . 140.6(5) yes C21a S1a C20a . 102.4(6) no C21a N1a C24a . 121.0(10) no C21a N1a C22a . 115.0(10) no C24a N1a C22a . 125.0(10) no C2a C1a C6a . 120.0 nos C2a C1a Sn1a . 120.4(4) nos C6a C1a Sn1a . 119.6(4) no C1a C2a C3a . 120.0 no C2a C3a C4a . 120.0 no C3a C4a C5a . 120.0 no C6a C5a C4a . 120.0 no C5a C6a C1a . 120.0 no C8a C7a C12a . 120.0 no C8a C7a Sn1a . 119.1(3) no C12a C7a Sn1a . 120.9(3) no C7a C8a C9a . 120.0 no C10a C9a C8a . 120.0 no C11a C10a C9a . 120.0 no C12a C11a C10a . 120.0 no C11a C12a C7a . 120.0 no C14a C13a C18a . 120.0 no C14a C13a Sn1a . 120.3(3) no C18a C13a Sn1a . 119.5(3) no C13a C14a C15a . 120.0 no C16a C15a C14a . 120.0 no C15a C16a C17a . 120.0 no C18a C17a C16a . 120.0 no C17a C18a C13a . 120.0 no O1a C19a O2a . 124.5(7) no O1a C19a C20a . 116.1(7) no O2a C19a C20a . 119.5(7) no C19a C20a S1a . 119.8(6) no N1a C21a S2a . 119.8(8) no N1a C21a S1a . 115.2(9) no S2a C21a S1a . 124.9(9) no N1a C22a C23a . 108.0(10) no N1a C24a C25a . 109.0(10) no C1b Sn1b C7b . 119.0(2) yes C1b Sn1b C13b . 119.9(2) yes C1b Sn1b O1b . 86.4(2) yes C1b Sn1b O2a . 88.8(2) yes C7b Sn1b C13b . 120.8(2) yes C7b Sn1b O1b . 92.9(2) yes C7b Sn1b O2a . 92.1(2) yes C13b Sn1b O1b . 95.9(2) yes C13b Sn1b O2a . 83.9(2) yes O1b Sn1b O2a . 174.4(2) yes C19b O1b Sn1b . 129.3(5) yes C19b O2b Sn1a 2_645 131.3(5) yes C21b S1b C20b . 103.4(4) no C21b N1b C22b . 123.3(8) no C21b N1b C24b . 120.0(10) no C22b N1b C24b . 113.9(9) no C2b C1b C6b . 120.0 no C2b C1b Sn1b . 119.4(3) no C6b C1b Sn1b . 120.6(3) no C1b C2b C3b . 120.0 no C4b C3b C2b . 120.0 no C5b C4b C3b . 120.0 no C6b C5b C4b . 120.0 no C5b C6b C1b . 120.0 no C8b C7b C12b . 120.0 no C8b C7b Sn1b . 120.6(3) no C12b C7b Sn1b . 119.4(3) no C7b C8b C9b . 120.0 no C8b C9b C10b . 120.0 no C11b C10b C9b . 120.0 no C12b C11b C10b . 120.0 no C11b C12b C7b . 120.0 no C14b C13b C18b . 120.0 no C14b C13b Sn1b . 119.7(3) no C18b C13b Sn1b . 120.3(3) no C15b C14b C13b . 120.0 no C14b C15b C16b . 120.0 no C17b C16b C15b . 120.0 no C16b C17b C18b . 120.0 no C17b C18b C13b . 120.0 no O1b C19b O2b . 123.7(7) no O1b C19b C20b . 118.2(7) no O2b C19b C20b . 118.1(7) no C19b C20b S1b . 118.0(6) no N1b C21b S2b . 125.4(7) no N1b C21b S1b . 112.4(7) no S2b C21b S1b . 122.1(5) no N1b C22b C23b . 108.0(10) no N1b C24b C25b . 109.0(10) no loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Sn1a C1a . 2.125(4) yes Sn1a C7a . 2.113(4) yes Sn1a C13a . 2.144(4) yes Sn1a O1a . 2.186(5) yes Sn1a O2b 2_655 2.326(5) yes S1a C21a . 1.710(10) no S1a C20a . 1.736(8) no S2a C21a . 1.630(10) no N1a C21a . 1.380(10) no N1a C24a . 1.430(8) no N1a C22a . 1.453(9) no O1a C19a . 1.264(8) no O2a C19a . 1.231(8) no C1a C2a . 1.3900 no C1a C6a . 1.3900 no C2a C3a . 1.3900 no C3a C4a . 1.3900 no C4a C5a . 1.3900 no C5a C6a . 1.3900 no C7a C8a . 1.3900 no C7a C12a . 1.3900 no C8a C9a . 1.3900 no C9a C10a . 1.3900 no C10a C11a . 1.3900 no C11a C12a . 1.3900 no C13a C14a . 1.3900 no C13a C18a . 1.3900 no C14a C15a . 1.3900 no C15a C16a . 1.3900 no C16a C17a . 1.3900 no C17a C18a . 1.3900 no C19a C20a . 1.500(10) no C22a C23a . 1.540(9) no C24a C25a . 1.525(9) no Sn1b C1b . 2.134(3) yes Sn1b C7b . 2.115(4) yes Sn1b C13b . 2.115(4) yes Sn1b O1b . 2.206(5) yes Sn1b O2a . 2.343(5) yes S1b C21b . 1.758(9) no S1b C20b . 1.772(9) no S2b C21b . 1.631(9) no O1b C19b . 1.258(8) no O2b C19b . 1.260(8) no N1b C21b . 1.340(10) no N1b C22b . 1.480(8) no N1b C24b . 1.488(8) no C1b C2b . 1.3900 no C1b C6b . 1.3900 no C2b C3b . 1.3900 no C3b C4b . 1.3900 no C4b C5b . 1.3900 no C5b C6b . 1.3900 no C7b C8b . 1.3900 no C7b C12b . 1.3900 no C8b C9b . 1.3900 no C9b C10b . 1.3900 no C10b C11b . 1.3900 no C11b C12b . 1.3900 no C13b C14b . 1.3900 no C13b C18b . 1.3900 no C14b C15b . 1.3900 no C15b C16b . 1.3900 no C16b C17b . 1.3900 no C17b C18b . 1.3900 no C19b C20b . 1.490(10) no C22b C23b . 1.514(9) no C24b C25b . 1.501(9) no