data_2008888
_journal_name_full  'Acta Crystallographica'
_journal_year  1999
_journal_volume  C55
_journal_page_first  1406
_journal_page_last  1408
_publ_section_title
;
cis-Bis(cyanomethyl)bis(triphenylphosphine)platinum(II)--dichloromethane
(1/0.6)
;
loop_
_publ_author_name
  'Henderson, William'
  'Oliver, Allen G.'
_chemical_formula_moiety  'C40 H34 N2 P2 Pt, 0.6C H2 Cl2'
_chemical_formula_sum  'C40.5 H35 Cl N2 P2 Pt'
_chemical_formula_iupac  '[Pt (C2 H2 N)2 (C18 H15 P)2] , 0.6C H2 Cl2'
_chemical_formula_weight  850.71
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
_cell_length_a  10.2264(2)
_cell_length_b  10.36060(10)
_cell_length_c  18.0965(3)
_cell_angle_alpha  87.3600(10)
_cell_angle_beta  81.6040(10)
_cell_angle_gamma  74.8390(10)
_cell_volume  1830.72(5)
_cell_formula_units_Z  2
_cell_measurement_temperature  203(2)
_exptl_crystal_density_diffrn  1.549
_diffrn_ambient_temperature  203(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Pt 0.87600(2) 0.91173(3) 0.721586(14) 0.03066(10) Uani d . 1 . . Pt
  P1 0.91172(17) 0.75145(19) 0.63215(9) 0.0313(4) Uani d . 1 . . P
  P2 0.98602(17) 0.77783(19) 0.81177(9) 0.0303(4) Uani d . 1 . . P
  N1 0.5204(8) 1.0782(13) 0.6661(5) 0.112(4) Uani d . 1 . . N
  C1 0.6338(9) 1.0731(10) 0.6597(5) 0.059(2) Uani d . 1 . . C
  C2 0.7764(7) 1.0591(7) 0.6502(4) 0.0375(16) Uani d . 1 . . C
  H2A 0.7936 1.1449 0.6602 0.045 Uiso calc R 1 . . H
  H2B 0.8145 1.0354 0.5983 0.045 Uiso calc R 1 . . H
  N2 0.5854(9) 1.1847(10) 0.8325(5) 0.086(3) Uani d . 1 . . N
  C3 0.7005(9) 1.1364(8) 0.8171(4) 0.0478(19) Uani d . 1 . . C
  C4 0.8430(7) 1.0718(7) 0.7982(4) 0.0371(16) Uani d . 1 . . C
  H4A 0.8815 1.0368 0.8438 0.044 Uiso calc R 1 . . H
  H4B 0.8911 1.1376 0.7759 0.044 Uiso calc R 1 . . H
  C11 1.0942(7) 0.6720(7) 0.6092(4) 0.0339(16) Uani d . 1 . . C
  C12 1.1549(8) 0.5363(9) 0.6058(4) 0.047(2) Uani d . 1 . . C
  H12A 1.1010 0.4748 0.6143 0.057 Uiso calc R 1 . . H
  C13 1.2970(9) 0.4910(10) 0.5894(4) 0.060(3) Uani d . 1 . . C
  H13A 1.3385 0.3987 0.5873 0.072 Uiso calc R 1 . . H
  C14 1.3773(9) 0.5801(14) 0.5764(5) 0.078(4) Uani d . 1 . . C
  H14A 1.4727 0.5480 0.5648 0.093 Uiso calc R 1 . . H
  C15 1.3197(8) 0.7133(12) 0.5800(5) 0.064(3) Uani d . 1 . . C
  H15A 1.3755 0.7730 0.5718 0.077 Uiso calc R 1 . . H
  C16 1.1782(7) 0.7628(10) 0.5960(4) 0.052(2) Uani d . 1 . . C
  H16A 1.1386 0.8555 0.5979 0.063 Uiso calc R 1 . . H
  C21 0.8579(7) 0.8059(7) 0.5405(4) 0.0344(16) Uani d . 1 . . C
  C22 0.7179(8) 0.8342(9) 0.5339(4) 0.050(2) Uani d . 1 . . C
  H22A 0.6546 0.8278 0.5762 0.060 Uiso calc R 1 . . H
  C23 0.6724(8) 0.8711(9) 0.4663(4) 0.053(2) Uani d . 1 . . C
  H23A 0.5784 0.8891 0.4629 0.063 Uiso calc R 1 . . H
  C24 0.7639(8) 0.8822(9) 0.4029(4) 0.051(2) Uani d . 1 . . C
  H24A 0.7326 0.9065 0.3566 0.061 Uiso calc R 1 . . H
  C25 0.9013(9) 0.8569(10) 0.4090(4) 0.057(2) Uani d . 1 . . C
  H25A 0.9639 0.8650 0.3666 0.068 Uiso calc R 1 . . H
  C26 0.9480(8) 0.8198(9) 0.4770(4) 0.048(2) Uani d . 1 . . C
  H26A 1.0418 0.8038 0.4802 0.058 Uiso calc R 1 . . H
  C31 0.8172(7) 0.6247(7) 0.6543(4) 0.0340(16) Uani d . 1 . . C
  C32 0.7192(7) 0.6404(8) 0.7186(4) 0.0415(18) Uani d . 1 . . C
  H32A 0.7066 0.7121 0.7511 0.050 Uiso calc R 1 . . H
  C33 0.6403(8) 0.5470(9) 0.7333(4) 0.053(2) Uani d . 1 . . C
  H33A 0.5755 0.5561 0.7766 0.063 Uiso calc R 1 . . H
  C34 0.6560(8) 0.4447(9) 0.6865(5) 0.056(2) Uani d . 1 . . C
  H34A 0.6041 0.3820 0.6984 0.067 Uiso calc R 1 . . H
  C35 0.7488(8) 0.4311(8) 0.6205(5) 0.049(2) Uani d . 1 . . C
  H35A 0.7566 0.3621 0.5869 0.059 Uiso calc R 1 . . H
  C36 0.8288(8) 0.5206(8) 0.6056(4) 0.0427(18) Uani d . 1 . . C
  H36A 0.8922 0.5111 0.5617 0.051 Uiso calc R 1 . . H
  C41 1.0823(7) 0.6031(7) 0.7975(3) 0.0323(15) Uani d . 1 . . C
  C42 1.0103(8) 0.5072(8) 0.7945(4) 0.0409(17) Uani d . 1 . . C
  H42A 0.9142 0.5331 0.7996 0.049 Uiso calc R 1 . . H
  C43 1.0799(10) 0.3720(8) 0.7840(5) 0.055(2) Uani d . 1 . . C
  H43A 1.0310 0.3073 0.7822 0.066 Uiso calc R 1 . . H
  C44 1.2219(10) 0.3346(10) 0.7763(4) 0.060(2) Uani d . 1 . . C
  H44A 1.2695 0.2444 0.7688 0.072 Uiso calc R 1 . . H
  C45 1.2916(9) 0.4283(9) 0.7795(4) 0.056(2) Uani d . 1 . . C
  H45A 1.3876 0.4021 0.7746 0.067 Uiso calc R 1 . . H
  C46 1.2249(7) 0.5602(8) 0.7897(4) 0.0442(18) Uani d . 1 . . C
  H46A 1.2759 0.6232 0.7914 0.053 Uiso calc R 1 . . H
  C51 1.1122(7) 0.8575(8) 0.8389(4) 0.0357(16) Uani d . 1 . . C
  C52 1.2107(8) 0.8842(9) 0.7816(4) 0.049(2) Uani d . 1 . . C
  H52A 1.2096 0.8620 0.7320 0.059 Uiso calc R 1 . . H
  C53 1.3102(8) 0.9436(9) 0.7987(5) 0.054(2) Uani d . 1 . . C
  H53A 1.3778 0.9587 0.7607 0.065 Uiso calc R 1 . . H
  C54 1.3101(8) 0.9801(9) 0.8702(5) 0.057(2) Uani d . 1 . . C
  H54A 1.3773 1.0206 0.8810 0.069 Uiso calc R 1 . . H
  C55 1.2125(9) 0.9582(10) 0.9268(5) 0.060(2) Uani d . 1 . . C
  H55A 1.2116 0.9862 0.9756 0.072 Uiso calc R 1 . . H
  C56 1.1149(8) 0.8945(9) 0.9118(4) 0.051(2) Uani d . 1 . . C
  H56A 1.0507 0.8764 0.9509 0.062 Uiso calc R 1 . . H
  C61 0.8704(7) 0.7631(7) 0.8967(4) 0.0355(16) Uani d . 1 . . C
  C62 0.7294(7) 0.8263(7) 0.9021(4) 0.0375(16) Uani d . 1 . . C
  H62A 0.6942 0.8781 0.8621 0.045 Uiso calc R 1 . . H
  C63 0.6423(8) 0.8117(8) 0.9671(4) 0.0432(18) Uani d . 1 . . C
  H63A 0.5485 0.8549 0.9710 0.052 Uiso calc R 1 . . H
  C64 0.6931(8) 0.7345(8) 1.0254(4) 0.0464(19) Uani d . 1 . . C
  H64A 0.6337 0.7246 1.0689 0.056 Uiso calc R 1 . . H
  C65 0.8294(9) 0.6718(9) 1.0207(4) 0.051(2) Uani d . 1 . . C
  H65A 0.8630 0.6196 1.0611 0.061 Uiso calc R 1 . . H
  C66 0.9193(7) 0.6846(8) 0.9564(4) 0.0416(18) Uani d . 1 . . C
  H66A 1.0127 0.6404 0.9535 0.050 Uiso calc R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Pt 0.02451(14) 0.03889(17) 0.02553(14) -0.00522(10) 0.00174(9) -0.00287(10)
  P1 0.0285(9) 0.0403(11) 0.0231(8) -0.0070(7) -0.0006(7) -0.0014(8)
  P2 0.0273(8) 0.0384(11) 0.0237(8) -0.0068(7) -0.0005(7) -0.0050(7)
  N1 0.039(5) 0.212(13) 0.078(6) -0.018(6) -0.014(5) 0.014(7)
  C1 0.045(5) 0.080(7) 0.041(5) 0.003(4) -0.009(4) 0.001(4)
  C2 0.034(4) 0.032(4) 0.042(4) -0.004(3) 0.001(3) 0.001(3)
  N2 0.058(5) 0.093(7) 0.086(6) 0.008(5) 0.014(5) -0.021(5)
  C3 0.053(5) 0.041(5) 0.043(5) -0.003(4) -0.001(4) -0.012(4)
  C4 0.033(4) 0.034(4) 0.042(4) -0.007(3) -0.004(3) -0.003(3)
  C11 0.028(3) 0.047(5) 0.021(3) -0.002(3) 0.001(3) -0.005(3)
  C12 0.045(4) 0.063(6) 0.028(4) -0.002(4) -0.005(3) -0.006(4)
  C13 0.050(5) 0.078(7) 0.032(4) 0.021(5) -0.007(4) -0.017(4)
  C14 0.035(5) 0.144(11) 0.036(5) 0.009(6) 0.002(4) -0.023(6)
  C15 0.027(4) 0.114(9) 0.048(5) -0.016(5) 0.005(4) -0.015(5)
  C16 0.032(4) 0.086(7) 0.038(4) -0.016(4) 0.003(3) -0.014(4)
  C21 0.032(4) 0.049(5) 0.023(3) -0.012(3) 0.000(3) -0.003(3)
  C22 0.038(4) 0.082(7) 0.030(4) -0.013(4) -0.007(3) 0.007(4)
  C23 0.040(4) 0.075(6) 0.043(5) -0.010(4) -0.012(4) 0.003(4)
  C24 0.060(5) 0.063(6) 0.031(4) -0.013(4) -0.013(4) -0.002(4)
  C25 0.055(5) 0.088(7) 0.025(4) -0.024(5) 0.007(4) 0.008(4)
  C26 0.037(4) 0.076(6) 0.033(4) -0.018(4) -0.003(3) 0.010(4)
  C31 0.032(4) 0.045(4) 0.027(3) -0.013(3) -0.004(3) 0.000(3)
  C32 0.038(4) 0.052(5) 0.034(4) -0.013(4) 0.000(3) -0.004(3)
  C33 0.044(5) 0.075(7) 0.040(5) -0.025(4) 0.008(4) 0.001(4)
  C34 0.047(5) 0.060(6) 0.065(6) -0.025(4) -0.002(4) 0.004(5)
  C35 0.059(5) 0.045(5) 0.048(5) -0.019(4) -0.009(4) -0.008(4)
  C36 0.044(4) 0.048(5) 0.033(4) -0.011(4) 0.002(3) -0.002(3)
  C41 0.035(4) 0.040(4) 0.017(3) -0.003(3) -0.001(3) 0.000(3)
  C42 0.047(4) 0.046(5) 0.030(4) -0.010(4) -0.010(3) 0.001(3)
  C43 0.090(7) 0.036(5) 0.044(5) -0.019(5) -0.016(5) -0.003(4)
  C44 0.075(6) 0.054(6) 0.031(4) 0.013(5) 0.003(4) -0.003(4)
  C45 0.056(5) 0.053(6) 0.038(5) 0.010(4) 0.013(4) 0.007(4)
  C46 0.040(4) 0.052(5) 0.035(4) -0.005(4) -0.002(3) 0.003(4)
  C51 0.030(4) 0.048(5) 0.029(4) -0.009(3) -0.005(3) -0.001(3)
  C52 0.044(4) 0.065(6) 0.040(4) -0.018(4) -0.010(4) 0.006(4)
  C53 0.051(5) 0.059(6) 0.056(5) -0.025(4) -0.007(4) 0.013(4)
  C54 0.046(5) 0.056(6) 0.077(6) -0.021(4) -0.015(5) -0.007(5)
  C55 0.055(5) 0.077(7) 0.054(5) -0.021(5) -0.012(4) -0.021(5)
  C56 0.046(5) 0.069(6) 0.042(5) -0.022(4) -0.001(4) -0.012(4)
  C61 0.035(4) 0.046(5) 0.027(3) -0.015(3) 0.001(3) -0.010(3)
  C62 0.036(4) 0.045(5) 0.031(4) -0.009(3) -0.004(3) -0.002(3)
  C63 0.037(4) 0.048(5) 0.042(4) -0.011(3) 0.005(3) -0.005(4)
  C64 0.051(5) 0.057(5) 0.030(4) -0.020(4) 0.011(3) -0.009(4)
  C65 0.064(5) 0.059(6) 0.027(4) -0.012(4) 0.000(4) -0.006(4)
  C66 0.038(4) 0.052(5) 0.032(4) -0.007(3) -0.004(3) 0.003(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Pt C2 . 2.104(7) Y
  Pt C4 . 2.138(7) Y
  Pt P1 . 2.2953(18) Y
  Pt P2 . 2.3161(18) Y
  P1 C31 . 1.822(7) ?
  P1 C11 . 1.826(7) ?
  P1 C21 . 1.840(7) ?
  P2 C61 . 1.824(7) ?
  P2 C41 . 1.830(7) ?
  P2 C51 . 1.836(7) ?
  N1 C1 . 1.136(10) Y
  C1 C2 . 1.413(10) Y
  N2 C3 . 1.150(10) Y
  C3 C4 . 1.433(10) Y
  C11 C12 . 1.381(11) ?
  C11 C16 . 1.422(10) ?
  C12 C13 . 1.396(11) ?
  C13 C14 . 1.379(14) ?
  C14 C15 . 1.351(15) ?
  C15 C16 . 1.394(11) ?
  C21 C26 . 1.391(9) ?
  C21 C22 . 1.407(9) ?
  C22 C23 . 1.374(10) ?
  C23 C24 . 1.392(11) ?
  C24 C25 . 1.380(11) ?
  C25 C26 . 1.386(10) ?
  C31 C36 . 1.395(10) ?
  C31 C32 . 1.405(9) ?
  C32 C33 . 1.407(10) ?
  C33 C34 . 1.349(12) ?
  C34 C35 . 1.401(11) ?
  C35 C36 . 1.382(10) ?
  C41 C42 . 1.390(10) ?
  C41 C46 . 1.397(10) ?
  C42 C43 . 1.403(11) ?
  C43 C44 . 1.389(12) ?
  C44 C45 . 1.354(13) ?
  C45 C46 . 1.365(11) ?
  C51 C56 . 1.396(10) ?
  C51 C52 . 1.407(10) ?
  C52 C53 . 1.396(10) ?
  C53 C54 . 1.364(12) ?
  C54 C55 . 1.376(12) ?
  C55 C56 . 1.395(11) ?
  C61 C66 . 1.395(10) ?
  C61 C62 . 1.410(9) ?
  C62 C63 . 1.395(9) ?
  C63 C64 . 1.375(11) ?
  C64 C65 . 1.367(11) ?
  C65 C66 . 1.397(10) ?