data_2008910
_journal_name_full  'Acta Crystallographica'
_journal_year  1999
_journal_volume  C55
_journal_page_first  1443
_journal_page_last  1447
_publ_section_title
;
N,N,N',N'-Tetramethylguanidinum tetrachloroantimonate(III) at 295 and 92 K
;
loop_
_publ_author_name
  'Bujak, Maciej'
  'Osadczuk, Przemys\/law'
  'Zaleski, Jacek'
_chemical_formula_sum  'C5 H14 Cl4 N3 Sb'
_chemical_formula_iupac  '(C5 H14 N3) [Sb Cl4]'
_chemical_formula_weight  379.74
_symmetry_cell_setting  'triclinic'
_symmetry_space_group_name_H-M  'P -1'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
_cell_length_a  7.873(2)
_cell_length_b  8.985(2)
_cell_length_c  10.412(2)
_cell_angle_alpha  101.55(3)
_cell_angle_beta  104.51(3)
_cell_angle_gamma  103.52(3)
_cell_volume  666.6(3)
_cell_formula_units_Z  2
_cell_measurement_temperature  295(2)
_exptl_crystal_density_diffrn  1.892
_exptl_crystal_density_meas  1.880(10)
_diffrn_ambient_temperature  295(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Sb1 0.68848(5) 0.90246(4) 0.93457(4) 0.0331(2) Uani d . 1 . . Sb
  Cl1 0.9545(2) 0.8129(2) 1.04422(18) 0.0523(4) Uani d . 1 . . Cl
  Cl2 0.3588(3) 0.9483(2) 0.79950(18) 0.0603(5) Uani d . 1 . . Cl
  Cl3 0.6990(3) 0.7738(2) 0.70787(17) 0.0570(5) Uani d . 1 . . Cl
  Cl4 0.4971(2) 0.6668(2) 0.95169(18) 0.0524(4) Uani d . 1 . . Cl
  N1 0.9633(8) 0.4255(8) 1.2267(7) 0.068(2) Uani d . 1 . . N
  H1A 0.8566 0.3619 1.2269 0.14(3) Uiso d R 1 . . H
  H1B 1.0312 0.3856 1.1791 0.14(3) Uiso d R 1 . . H
  N2 1.1781(8) 0.6720(6) 1.3008(6) 0.0487(13) Uani d . 1 . . N
  N3 0.9126(9) 0.6334(7) 1.3665(6) 0.0545(14) Uani d . 1 . . N
  C1 1.0198(9) 0.5797(8) 1.2974(6) 0.0443(14) Uani d . 1 . . C
  C2 1.2673(11) 0.6276(10) 1.1969(9) 0.065(2) Uani d . 1 . . C
  H2A 1.1848 0.5359 1.1249 0.125(13) Uiso d R 1 . . H
  H2B 1.2989 0.7149 1.1584 0.125(13) Uiso d R 1 . . H
  H2C 1.3768 0.6035 1.2397 0.125(13) Uiso d R 1 . . H
  C3 1.2922(16) 0.8100(11) 1.4162(9) 0.091(3) Uani d . 1 . . C
  H3A 1.2240 0.8304 1.4789 0.125(13) Uiso d R 1 . . H
  H3B 1.4021 0.7896 1.4635 0.125(13) Uiso d R 1 . . H
  H3C 1.3243 0.9010 1.3823 0.125(13) Uiso d R 1 . . H
  C4 0.7753(12) 0.5223(11) 1.4023(8) 0.071(2) Uani d . 1 . . C
  H4A 0.7830 0.4164 1.3733 0.125(13) Uiso d R 1 . . H
  H4B 0.7985 0.5523 1.5003 0.125(13) Uiso d R 1 . . H
  H4C 0.6547 0.5256 1.3566 0.125(13) Uiso d R 1 . . H
  C5 0.894(2) 0.7910(13) 1.3799(13) 0.107(4) Uani d . 1 . . C
  H5A 0.9880 0.8567 1.3550 0.125(13) Uiso d R 1 . . H
  H5B 0.7754 0.7800 1.3181 0.125(13) Uiso d R 1 . . H
  H5C 0.8999 0.8393 1.4727 0.125(13) Uiso d R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Sb1 0.0353(3) 0.0343(3) 0.0341(3) 0.01545(16) 0.01433(16) 0.00847(15)
  Cl1 0.0472(9) 0.0574(10) 0.0568(9) 0.0243(7) 0.0107(7) 0.0223(8)
  Cl2 0.0709(11) 0.0650(11) 0.0406(8) 0.0290(9) 0.0068(8) 0.0083(7)
  Cl3 0.0718(11) 0.0710(11) 0.0394(8) 0.0370(9) 0.0261(8) 0.0097(7)
  Cl4 0.0540(9) 0.0456(9) 0.0595(10) 0.0093(7) 0.0214(8) 0.0208(7)
  N1 0.040(3) 0.058(4) 0.085(5) 0.010(3) 0.021(3) -0.023(3)
  N2 0.054(3) 0.041(3) 0.044(3) 0.015(2) 0.005(2) 0.009(2)
  N3 0.072(4) 0.057(3) 0.041(3) 0.036(3) 0.022(3) 0.005(3)
  C1 0.051(4) 0.049(3) 0.031(3) 0.029(3) 0.003(3) 0.001(2)
  C2 0.059(4) 0.069(5) 0.076(5) 0.027(4) 0.026(4) 0.020(4)
  C3 0.127(9) 0.057(5) 0.052(5) -0.011(5) 0.011(5) 0.003(4)
  C4 0.063(5) 0.087(6) 0.054(4) 0.020(4) 0.025(4) -0.005(4)
  C5 0.189(13) 0.091(7) 0.115(8) 0.100(8) 0.103(9) 0.046(6)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Sb1 Cl1 . 2.509(2) y
  Sb1 Cl1 2_777 3.255(2) y
  Sb1 Cl2 . 2.790(2) y
  Sb1 Cl2 2_677 2.978(2) y
  Sb1 Cl3 . 2.442(2) y
  Sb1 Cl4 . 2.362(2) y
  N1 C1 . 1.342(9) ?
  N2 C1 . 1.314(9) ?
  N2 C2 . 1.470(10) ?
  N2 C3 . 1.459(9) ?
  N3 C1 . 1.347(8) ?
  N3 C4 . 1.466(11) ?
  N3 C5 . 1.442(10) ?
  N1 H1A . 0.9000 ?
  N1 H1B . 0.9001 ?
  C2 H2A . 0.9600 ?
  C2 H2B . 0.9600 ?
  C2 H2C . 0.9600 ?
  C3 H3A . 0.9600 ?
  C3 H3B . 0.9600 ?
  C3 H3C . 0.9600 ?
  C4 H4A . 0.9600 ?
  C4 H4B . 0.9601 ?
  C4 H4C . 0.9599 ?
  C5 H5A . 0.9600 ?
  C5 H5B . 0.9600 ?
  C5 H5C . 0.9600 ?