data_2010201
_journal_name_full  'Acta Crystallographica'
_journal_year  1994
_journal_volume  C50
_journal_page_first  1753
_journal_page_last  1756
_publ_section_title
;
5-Acetyl-4-methyl-2-pyrimidinylhydrazine and 5-(1-Hydrazonoethyl)-4-methyl
-2-pyrimidinylhydrazine
;
loop_
_publ_author_name
  'Cousson, A.'
  'Nectoux, F.'
  'Bachet, B.'
  'Kokel, B.'
  'Hubert-Habart, M.'
_chemical_formula_sum  'C7 H12 N6'
_chemical_formula_weight  180.21
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_cell_length_a  7.944(5)
_cell_length_b  8.485(6)
_cell_length_c  6.829(3)
_cell_angle_alpha  87.11(2)
_cell_angle_beta  93.65(3)
_cell_angle_gamma  111.58(2)
_cell_volume  427.0(10)
_cell_formula_units_Z  2
_cell_measurement_temperature  293
_exptl_crystal_density_diffrn  1.402
_refine_ls_R_factor_obs  0.057
_refine_ls_wR_factor_obs  0.058
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
  C(1) .7559(4) .7053(4) 1.1558(5) .0295
  C(2) .7444(6) .6990(5) 1.3757(5) .0439
  C(3) .7203(4) .8379(4) 1.0322(4) .0271
  C(4) .7904(4) 1.0112(4) 1.0718(5) .0265
  C(5) .9074(5) 1.0835(4) 1.2512(5) .0378
  C(6) .6661(4) 1.0713(4) .7808(5) .0284
  C(7) .6186(4) .7965(4) .8553(5) .0318
  N(1) .8383(4) .4739(4) 1.1802(5) .0425
  N(2) .7933(4) .5946(3) 1.0657(4) .0342
  N(3) .7621(4) 1.1268(3) .9492(4) .0294
  N(4) .6444(4) 1.1863(4) .6489(4) .0394
  N(5) .7256(5) 1.3625(4) .6728(5) .0475
  N(6) .5883(4) .9079(4) .7296(4) .0329
  H(4) .5437 1.1325 .5295 .083(4)
  H(7) .5645 .6729 .8209 .083(4)
  H(11) .7883 .4432 1.3090 .083(4)
  H(12) .8162 .3746 1.0995 .083(4)
  H(21) .8796 .6979 1.4320 .083(4)
  H(22) .6367 .5714 1.4055 .083(4)
  H(23) .7029 .7896 1.4160 .083(4)
  H(51) .9692 .9982 1.3055 .083(4)
  H(52) 1.0029 1.2057 1.2095 .083(4)
  H(53) .8146 1.0893 1.3670 .083(4)
  H(501) .6708 1.3900 .7910 .083(4)
  H(502) .8621 1.4007 .7145 .083(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
  C(1) C(2) 1.508(5) yes
  C(1) C(3) 1.472(4) yes
  C(1) N(2) 1.279(4) yes
  C(3) C(4) 1.402(4) yes
  C(3) C(7) 1.394(4) yes
  C(4) C(5) 1.501(4) yes
  C(4) N(3) 1.330(4) yes
  C(6) N(3) 1.344(4) yes
  C(6) N(4) 1.345(4) yes
  C(6) N(6) 1.348(4) yes
  C(7) N(6) 1.323(4) yes
  N(1) N(2) 1.392(4) yes
  N(4) N(5) 1.407(4) yes
  C(2) H(21) 1.120(4) no
  C(2) H(22) 1.124(4) no
  C(2) H(23) 0.998(4) no
  C(5) H(51) 1.055(4) no
  C(5) H(52) 1.073(4) no
  C(5) H(53) 1.130(4) no
  C(7) H(7) 1.010(3) no
  N(1) H(11) 0.972(3) no
  N(1) H(12) 0.985(3) no
  N(4) H(4) 1.094(3) no
  N(5) H(501) 1.016(4) no
  N(5) H(502) 1.036(3) no