data_2010246
_journal_name_full  'Acta Crystallographica'
_journal_year  1994
_journal_volume  C50
_journal_page_first  1998
_journal_page_last  2000
_publ_section_title
;
Structures of Pyrazolo[1,5-a]pyridine Derivatives
;
loop_
_publ_author_name
  'Kakehi, A.'
  'Kitajima, K.'
  'Ito, S.'
  'Takusagawa, N.'
_chemical_formula_sum  'C15 H11 Cl1 N2 O1 S2'
_chemical_formula_weight  334.84
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  'x,1/2-y,1/2+z'
  '-x,-y,-z'
  '-x,1/2+y,1/2-z'
_cell_length_a  16.940(2)
_cell_length_b  5.6800(10)
_cell_length_c  17.3880(10)
_cell_angle_alpha  90
_cell_angle_beta  115.880(6)
_cell_angle_gamma  90
_cell_volume  1505.4(4)
_cell_formula_units_Z  4
_cell_measurement_temperature  293
_exptl_crystal_density_diffrn  1.477
_refine_ls_R_factor_obs  0.043
_refine_ls_wR_factor_obs  0.046
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
  Cl(1) -.04162(9) -.3077(3) .62410(10)
  S(1) .23187(8) .5973(3) .39629(9)
  S(2) .29709(8) .1626(2) .54622(8)
  O(1) .2612(2) .4724(6) .6397(2)
  N(1) .4683(2) .6488(6) .5680(2)
  N(2) .4006(2) .7302(6) .4943(2)
  C(1) .3360(3) .5759(8) .4817(3)
  C(2) .3601(3) .4000(8) .5431(3)
  C(3) .4475(3) .4481(8) .6002(3)
  C(4) .5119(3) .3497(9) .6751(3)
  C(5) .5920(3) .4529(10) .7136(3)
  C(6) .6108(3) .6585(10) .6790(3)
  C(7) .5494(3) .7520(9) .6063(3)
  C(8) .2426(5) .8474(13) .3387(4)
  C(9) .2423(3) .2828(8) .6046(3)
  C(10) .1730(3) .1306(8) .6093(3)
  C(11) .1333(3) .1967(11) .6602(3)
  C(12) .0676(3) .0614(11) .6652(3)
  C(13) .0421(3) -.1398(10) .6187(3)
  C(14) .0808(3) -.2140(10) .5681(4)
  C(15) .1457(3) -.0780(9) .5634(3)
  H(1) .498(2) .215(7) .696(2)
  H(2) .636(3) .386(8) .761(3)
  H(3) .669(3) .730(8) .708(3)
  H(4) .555(2) .897(7) .580(2)
  H(5) .258(4) .980(10)
  .371(4)
  H(6) .191(4) .850(10)
  .291(4)
  H(7) .288(4) .830(10)
  .324(4)
  H(8) .144(3) .343(8) .683(3)
  H(9) .037(3) .129(9) .694(3)
  H(10) .064(3) -.340(8) .537(3)
  H(11) .171(2) -.125(7) .529(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  N(1) N(2) . . 1.375(5) yes
  N(1) C(3) . . 1.382(5) yes
  N(1) C(7) . . 1.369(5) yes
  C(1) C(2) . . 1.388(6) yes
  C(2) C(3) . . 1.403(6) yes
  C(3) C(4) . . 1.400(6) yes
  C(4) C(5) . . 1.357(6) yes
  C(5) C(6) . . 1.412(7) yes
  C(6) C(7) . . 1.347(7) yes
  S(1) C(1) . . 1.745(4) yes
  S(2) C(2) . . 1.735(4) yes
  Cl(1) C(13) . . 1.745(5) no
  S(1) C(8) . . 1.792(6) no
  S(2) C(9) . . 1.782(5) no
  O(1) C(9) . . 1.210(5) no
  N(2) C(1) . . 1.343(5) no
  C(4) H(1) . . 0.92(4) no
  C(5) H(2) . . 0.92(4) no
  C(6) H(3) . . 0.98(4) no
  C(7) H(4) . . 0.97(4) no
  C(8) H(5) . . 0.92(6) no
  C(8) H(6) . . 0.90(6) no
  C(8) H(7) . . 0.91(6) no
  C(9) C(10) . . 1.490(6) no
  C(10) C(11) . . 1.376(6) no
  C(10) C(15) . . 1.390(6) no
  C(11) C(12) . . 1.386(7) no
  C(11) H(8) . . 0.90(4) no
  C(12) C(13) . . 1.357(7) no
  C(12) H(9) . . 0.95(5) no
  C(13) C(14) . . 1.372(7) no
  C(14) C(15) . . 1.376(7) no
  C(14) H(10) . . 0.86(4) no
  C(15) H(11) . . 0.91(4) no