data_2010298
_journal_name_full  'Acta Crystallographica'
_journal_year  1994
_journal_volume  C50
_journal_page_first  1909
_journal_page_last  1911
_publ_section_title
;
Guanidinium Pentafluoroantimonate
;
loop_
_publ_author_name
  "Ma\/luszy\'nska, Hanna"
_chemical_formula_sum  'C2 H12 F5 N6 Sb'
_chemical_formula_structural  '(C(NH~2~)~3~)~2~. SbF~5~'
_chemical_formula_weight  336.9
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'C 2/m'
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '1/2+x,1/2+y, z'
  '-x, -y, -z'
  '1/2-x,1/2-y,-z'
  '-x, y, -z'
  '1/2-x,1/2+y,-z'
  'x, -y, z'
  '1/2+x,1/2-y, z'
_cell_length_a  15.900(4)
_cell_length_b  8.456(2)
_cell_length_c  9.725(3)
_cell_angle_alpha  90.00
_cell_angle_beta  121.19(2)
_cell_angle_gamma  90.00
_cell_volume  1118.5(5)
_cell_formula_units_z  4.00
_cell_measurement_temperature  295
_exptl_crystal_density_diffrn  2.001
_refine_ls_R_factor_obs  0.0231
_refine_ls_wR_factor_obs  0.0314
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_calc_flag
  Sb 0.153980(10)
  0.5 0.13674(2) 0.03240(10)
  0.5
  F(1) 0.2573(2) 0.5 0.3593(3) 0.0488(8) 0.5
  F(2) 0.10220(10)
  0.6688(2) 0.2308(2) 0.0560(8) 1
  F(3) 0.24900(10)
  0.3327(2) 0.1334(2) 0.0522(8) 1
  C(1) 0.4853(2) 0.5 0.1990(4) 0.0410(10)
  0.5
  C(2) 0.1861(2) 0.5 0.6457(4) 0.0400(10)
  0.5
  N(1) 0.5750(2) 0.5 0.2209(5) 0.055(2) 0.5
  N(2) 0.4407(2) 0.3637(3) 0.1866(4) 0.0580(10)
  1
  N(3) 0.2161(3) 0.5 0.8033(4) 0.0510(10)
  0.5
  N(4) 0.1712(2) 0.3637(3) 0.5699(3) 0.0530(10)
  1
  H(1) 0.6093 0.6034 0.2299 0.098(16) 1
  H(2) 0.3726 0.3617 0.1704 0.056(9) 1
  H(21) 0.4751 0.2603 0.1937 0.077(13) 1
  H(3) 0.2287 0.6034 0.8624 0.056(9) 1
  H(4) 0.1480 0.3625 0.4515 0.15(3)  1
  H(41) 0.1819 0.2611 0.6297 0.082(13) 1
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Sb 0.03200(10)
  0.02870(10)
  0.04040(10)
  0 0.02160(10)
  0
  F(1) 0.0456(10) 0.0540(11) 0.0437(10) 0 0.0209(8) 0
  F(2) 0.0602(9) 0.0419(8) 0.0781(11) 0.0134(7) 0.0445(9) 0.0018(7)
  F(3) 0.0601(8) 0.0380(7) 0.0771(10) 0.0029(6) 0.0486(8) -0.0054(7)
  C(1) 0.0340(12) 0.0371(13) 0.0529(16) 0 0.0228(12) 0
  C(2) 0.0375(13) 0.0395(14) 0.0456(15) 0 0.0237(12) 0
  N(1) 0.0358(13) 0.0378(13) 0.093(3)  0 0.0352(16) 0
  N(2) 0.0463(10) 0.0382(10) 0.0943(18) -0.0058(8) 0.0407(12) -0.0024(10)
  N(3) 0.0639(19) 0.0455(15) 0.0454(14) 0 0.0293(14) 0
  N(4) 0.0680(13) 0.0399(9) 0.0527(11) -0.0051(9) 0.0331(10) -0.0039(8)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
  Sb F(1) 1.924(2) yes
  Sb F(2) 2.081(2) yes
  Sb F(2)' 2.081(2) yes
  Sb F(3) 2.082(2) yes
  Sb F(3)' 2.082(2) yes
  C(1) N(1) 1.328(6) yes
  C(1) N(2) 1.326(3) yes
  C(1) N(2)' 1.326(3) yes
  C(2) N(3) 1.349(5) yes
  C(2) N(4) 1.322(3) yes
  C(2) N(4)' 1.322(3) yes
  N(1) H(1) 1.01 no
  N(1) H(1)' 1.01 no
  N(2) H(2) 1.01 no
  N(2) H(21) 1.01 no
  N(3) H(3) 1.01 no
  N(3) H(3)' 1.01 no
  N(4) H(4) 1.01 no
  N(4) H(41) 1.01 no