data_2010355
_journal_name_full  'Acta Crystallographica'
_journal_year  1995
_journal_volume  C51
_journal_page_first  32
_journal_page_last  34
_publ_section_title
;
Disodium \m-(ethylenediaminetetraacetato)-di-\m -oxo-bis[oxomolybdate
(V)](Mo-Mo) Tetrahydrate
;
loop_
_publ_author_name
  'Mukherjee, K.'
  'Roychowdhury, P.'
  'Roy, K.'
  'Mukherjee, D.'
  'Kusunoki, M.'
_chemical_formula_sum  'C10 H20 Mo2 N2 Na2 O16'
_chemical_formula_weight  662.13
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'P a'
_symmetry_space_group_name_Hall  'P -2ya'
_cell_length_a  7.540(3)
_cell_length_b  16.761(6)
_cell_length_c  8.650(3)
_cell_angle_alpha  90.
_cell_angle_beta  99.56(2)
_cell_angle_gamma  90.
_cell_volume  1078.0(7)
_cell_formula_units_Z  2
_cell_measurement_temperature  293
_exptl_crystal_density_diffrn  2.0399
_exptl_crystal_density_meas  2.01
_refine_ls_R_factor_obs  0.043
_refine_ls_wR_factor_obs  0.051
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
  Mo(1) -.99280 -.18079(3) -.92590 .02340(10)
  Mo(2) -.96286(8) -.33120(3) -.96167(7) .01880(10)
  O(1) -.9047(6) -.2420(2) -1.0857(5) .0260(10)
  O(2) -.9443(6) -.2667(2) -.7743(5) .0260(10)
  O(3) -1.2176(7) -.1682(3) -.9755(8) .040(2)
  O(4) -1.1806(6) -.3575(3) -1.0220(6) .0320(10)
  O(5) -.9423(6) -.0793(3) -1.0569(7) .0380(10)
  O(6) -.9722(7) -.1089(3) -.7247(7) .039(2)
  O(7) -.9195(6) -.4288(2) -.8054(5) .0270(10)
  O(8) -.8765(6) -.3985(3) -1.1398(5) .0310(10)
  O(9) -.7735(7) -.0245(3) -1.2091(7) .043(2)
  O(10) -.8216(8) -.0248(3) -.5544(7) .044(2)
  O(11) -.6715(8) -.4644(4) -1.2364(6) .044(2)
  O(12) -.7586(7) -.4846(3) -.5934(6) .0360(10)
  N(1) -.6792(6) -.1434(3) -.8631(6) .0210(10)
  N(2) -.6460(6) -.3494(2) -.8789(5) .0190(10)
  C(1) -.7914(9) -.0680(4) -1.1021(8) .032(2)
  C(2) -.6323(8) -.1141(3) -1.0136(7) .0260(10)
  C(3) -.6705(9) -.0758(4) -.7531(8) .030(2)
  C(4) -.8304(9) -.0694(4) -.6715(8) .031(2)
  C(5) -.5502(7) -.2050(3) -.7901(7) .0230(10)
  C(6) -.5220(7) -.2799(3) -.8867(7) .0240(10)
  C(7) -.6237(8) -.3797(3) -.7157(6) .0230(10)
  C(8) -.7758(9) -.4366(3) -.6999(7) .0260(10)
  C(9) -.5885(8) -.4137(3) -.9782(7) .0240(10)
  C(10) -.7176(8) -.4266(3) -1.1329(7) .0250(10)
  Na(1) -.4750(4) -.5115(2) -1.4014(3) .0376(9)
  Na(2) -1.0541(4) -.0066(2) -1.3683(4) .0440(10)
  O(1W) -.3542(11) -.3696(4) -1.3551(8) .058(2)
  O(2W) -.5370(2) -.6567(6) -1.49270(10)
  .094(5)
  O(3W) -1.10510(10)
  -.1491(5) -1.4268(2) .097(5)
  O(4W) -.94600(10)
  .1317(5) -1.36360(10)
  .101(5)
  H(3A) -.5603 -.0820 -.6720 ?
  H(3B) -.6607 -.0253 -.8127 ?
  H(2A) -.6301 -.1710 -1.0486 ?
  H(2B) -.5154 -.0884 -1.0583 ?
  H(5A) -.5922 -.2235 -.6924 ?
  H(5B) -.4305 -.1785 -.7612 ?
  H(6A) -.3964 -.2991 -.8505 ?
  H(6B) -.5345 -.2633 -.9990 ?
  H(7A) -.6253 -.3340 -.6417 ?
  H(7B) -.5060 -.4082 -.6895 ?
  H(9A) -.4706 -.4114 -1.0165 ?
  H(9B) -.5792 -.4647 -.9174 ?
  H(1WO) -.2700 -.3672 -1.3782 ?
  H(1W') -.2692 -.3417 -1.3094 ?
  H(2WO) -.5926 -.6341 -1.5246 ?
  H(2W') -.4950 -.6874 -1.4756 ?
  H(3WO) -1.0027 -.1332 -1.4200 ?
  H(3W') -1.0094 -.1894 -1.3831 ?
  H(4WO) -.9920 .1825 -1.3866 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
  Mo(1) Mo(2) 2.5540(10)
  yes
  Mo(1) O(1) 1.926(4) yes
  Mo(1) O(2) 1.941(4) yes
  Mo(1) O(3) 1.691(5) yes
  Mo(1) O(5) 2.113(5) yes
  Mo(1) O(6) 2.101(6) yes
  Mo(1) N(1) 2.419(5) yes
  Mo(2) O(1) 1.932(4) yes
  Mo(2) O(2) 1.934(4) yes
  Mo(2) O(4) 1.696(4) yes
  Mo(2) O(7) 2.113(4) yes
  Mo(2) O(8) 2.098(5) yes
  Mo(2) N(2) 2.397(4) yes
  O(5) C(1) 1.277(9) yes
  O(6) C(4) 1.277(8) yes
  O(7) C(8) 1.302(7) yes
  O(8) C(10) 1.279(7) yes
  O(9) C(1) 1.203(9) yes
  O(9) Na(2) 2.344(9) yes
  O(10) C(4) 1.252(9) yes
  O(11) C(10) 1.195(8) yes
  O(11) Na(1) 2.357(7) yes
  O(12) C(8) 1.218(8) yes
  N(1) C(2) 1.488(8) yes
  N(1) C(3) 1.474(8) yes
  N(1) C(5) 1.485(7) yes
  N(2) C(6) 1.502(6) yes
  N(2) C(7) 1.483(7) yes
  N(2) C(9) 1.487(7) yes
  C(1) C(2) 1.522(8) yes
  C(3) C(4) 1.500(10)
  yes
  C(5) C(6) 1.542(8) yes
  C(7) C(8) 1.515(8) yes
  C(9) C(10) 1.534(8) yes
  Na(1) O(1W) 2.554(8) yes
  Na(1) O(2W) 2.580(10)
  yes
  Na(2) O(3W) 2.458(9) yes
  Na(2) O(4W) 2.455(9) yes
  C(3) H(3A) 1.00(7) no
  C(3) H(3B) 1.00(7) no
  C(5) H(5A) 1.00(7) no
  C(5) H(5B) 1.00(6) no
  C(6) H(6A) 1.00(6) no
  C(6) H(6B) 1.00(7) no
  C(7) H(7A) 1.00(6) no
  C(7) H(7B) 1.00(6) no
  C(9) H(9A) 1.00(7) no
  C(9) H(9B) 1.00(6) no