#------------------------------------------------------------------------------
#$Date: 2009-11-18 14:56:34 +0000 (Wed, 18 Nov 2009) $
#$Revision: 858 $
#$URL: svn://www.crystallography.net/cod/cif/2/2010415.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2010415
_journal_name_full 'Acta Crystallographica Section C'
_journal_year  1995
_journal_volume 51
_journal_page_first  70
_journal_page_last  72
_publ_section_title
;
T {\bf Chlorobis(N,N-diethyldithiocarbamato)(vinyl)tin(IV)}
;
loop_
_publ_author_name
  'Vrabel, V.'
  'Kello, E.'
  'Holecek, J.'
  'Sivy, J.'
  'Lokaj, J.'
_chemical_formula_moiety  'C12 H23 Cl1 N2 S4 Sn1'
_chemical_formula_sum            'C12 H23 Cl N2 S4 Sn'
_[local]_cod_chemical_formula_sum_orig 'C12 H23 Cl1 N2 S4 Sn1'
_chemical_formula_weight  477.71
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
_symmetry_space_group_name_Hall  '-P 1'
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,-y,-z'
_cell_length_a  7.082(10)
_cell_length_b  10.065(8)
_cell_length_c  14.559(10)
_cell_angle_alpha  96.03(6)
_cell_angle_beta  94.13(9)
_cell_angle_gamma  107.59(9)
_cell_volume  978(2)
_cell_formula_units_Z  2
_cell_measurement_temperature  293
_exptl_crystal_density_diffrn  1.62
_exptl_crystal_density_meas  1.64(3)
_refine_ls_R_factor_obs  0.038
_refine_ls_wR_factor_obs  0.046
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
  Sn(1) .07713(3) .26090(2) .240370(10)
  Cl(1) .11691(12) .09551(7) .34379(5)
  S(1) .20396(11) .13253(7) .11334(5)
  S(2) .10054(13) .38878(8) .09266(5)
  S(3) .42934(10) .41847(7) .29727(5)
  S(4) .06994(11) .46720(7) .35851(5)
  N(1) .2443(4) .2558(3) -.0376(2)
  N(2) .4349(3) .6246(2) .42740(10)
  C(1) .1882(4) .2594(3) .0455(2)
  C(2) .2354(5) .3637(4) -.0979(2)
  C(3) .0592(7) .3144(5) -.1606(3)
  C(4) .3212(5) .1463(3) -.0783(2)
  C(5) .5402(6) .1871(5) -.0631(3)
  C(6) .3217(4) .5170(3) .3673(2)
  C(7) .3438(5) .7094(3) .4875(2)
  C(8) .2973(5) .8211(4) .4424(3)
  C(9) .6529(5) .6672(3) .4348(2)
  C(10) .7381(6) .7788(5) .3803(4)
  C(11) -.2392(4) .1839(3) .2193(2)
  C(12) -.3502(5) .1086(4) .2718(3)
  H(21) .2406 .4507 -.0617
  H(22) .3495 .3837 -.1346
  H(31) .0497 .3839 -.2005
  H(32) -.0582 .2954 -.1259
  H(33) .0507 .2284 -.1989
  H(41) .2675 .0612 -.0517
  H(42) .2805 .1270 -.1449
  H(51) .5916 .1166 -.0910
  H(52) .5821 .2066 .0017
  H(53) .5950 .2724 -.0915
  H(71) .2216 .6475 .5051
  H(72) .4334 .7509 .5433
  H(81) .2366 .8771 .4815
  H(82) .2063 .7803 .3871
  H(83) .4180 .8838 .4254
  H(91) .7046 .709 .5004
  H(92) .6944 .5863 .4168
  H(101) .8827 .8073 .3841
  H(102) .6996 .8603 .3981
  H(103) .6894 .7457 .3145
  H(111) -.3049 .2067 .1652
  H(121) -.4949 .0720 .2622
  H(122) -.2876 .0835 .3254
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Sn(1) Cl(1) . . 2.422(2) yes
  Sn(1) S(1) . . 2.517(2) yes
  Sn(1) S(2) . . 2.610(2) yes
  Sn(1) S(3) . . 2.541(4) yes
  Sn(1) S(4) . . 2.569(2) yes
  Sn(1) C(11) . . 2.125(4) yes
  N(1) C(1) . . 1.302(4) yes
  N(1) C(2) . . 1.479(5) yes
  N(1) C(4) . . 1.461(5) yes
  N(2) C(6) . . 1.326(3) yes
  N(2) C(7) . . 1.472(5) yes
  N(2) C(9) . . 1.465(5) yes
  C(11) C(12) . . 1.274(5) yes