#------------------------------------------------------------------------------ #$Date: 2016-04-02 19:22:45 +0100 (Sat, 02 Apr 2016) $ #$Revision: 180780 $ #$URL: svn://www.crystallography.net/cod/hkl/2/01/11/2011160.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2011160_Fobs loop_ _publ_author_name 'Paredes-Garc\'ia, Ver\'onica' 'Venegas-Yazigi, Diego' 'Lough, Alan J.' 'Latorre, Ram\'on' _publ_section_title ; Potassium N-(6-oxocyclohexa-1,3-dien-5-ylidenemethyl)glycinate ; _journal_issue 7 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first e283 _journal_volume 56 _journal_year 2000 _space_group_IT_number 54 _symmetry_space_group_name_Hall '-P 2a 2ac' _symmetry_space_group_name_H-M 'P c c a' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 13.8864 _cell_length_b 18.4943 _cell_length_c 6.9664 _exptl_crystal_F_000 896.00 _reflns_d_resolution_high 0.7700 _cod_data_source_file qa0306Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' k99138a in Pcca' _shelx_refln_list_code 4 _shelx_f_calc_maximum 274.55 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z' '-x, y, -z+1/2' 'x+1/2, -y, -z+1/2' '-x, -y, -z' 'x-1/2, y, -z' 'x, -y, z-1/2' '-x-1/2, y, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 6642.89 5902.82 267.58 o 4 0 0 56778.13 53301.72 1914.99 o 6 0 0 365.35 371.16 17.26 o 8 0 0 1979.19 1748.53 62.89 o 10 0 0 2150.17 2188.74 88.78 o 12 0 0 21309.40 23269.72 974.14 o 14 0 0 132.39 106.05 30.83 o 16 0 0 9525.66 10847.53 547.49 o 18 0 0 2.04 -18.50 69.05 o 2 1 0 3.67 -3.70 3.70 o 4 1 0 24626.84 22688.93 654.77 o 6 1 0 246.13 261.42 9.86 o 8 1 0 4205.06 3905.21 115.91 o 10 1 0 276.34 255.25 13.56 o 12 1 0 807.50 805.21 29.59 o 14 1 0 10.02 -20.96 20.96 o 16 1 0 1630.96 1773.19 80.15 o 18 1 0 18.14 -17.26 57.96 o 2 2 0 5535.54 4848.53 145.51 o 4 2 0 3067.27 2670.88 67.82 o 6 2 0 569.91 578.32 17.26 o 8 2 0 248.89 261.42 12.33 o 10 2 0 0.31 8.63 12.33 o 12 2 0 111.83 133.17 16.03 o 14 2 0 506.16 503.10 23.43 o 16 2 0 577.26 607.92 34.53 o 0 3 0 5641.64 4961.97 318.14 o 2 3 0 4.45 35.76 4.93 o 4 3 0 3253.67 3270.17 88.78 o 6 3 0 41.93 32.06 8.63 o 8 3 0 2423.24 2659.78 71.52 o 10 3 0 7.72 -11.10 12.33 o 12 3 0 239.47 214.56 16.03 o 14 3 0 191.23 167.70 20.96 o 16 3 0 18.96 18.50 27.13 o 0 4 0 1823.92 1845.94 91.25 o 2 4 0 1100.93 1049.36 27.13 o 4 4 0 349.69 372.39 12.33 o 6 4 0 15.61 30.83 7.40 o 8 4 0 2175.55 2218.34 56.72 o 10 4 0 40.49 39.46 13.56 o 12 4 0 0.47 -4.93 14.80 o 14 4 0 93.29 115.91 19.73 o 16 4 0 237.57 261.42 30.83 o 0 5 0 7883.97 7692.04 466.11 o 2 5 0 278.92 287.31 9.86 o 4 5 0 1303.37 1097.45 32.06 o 6 5 0 75.51 71.52 8.63 o 8 5 0 59.97 65.35 9.86 o 10 5 0 80.79 64.12 12.33 o 12 5 0 323.51 319.37 18.50 o 14 5 0 295.16 251.55 23.43 o 16 5 0 278.02 328.00 34.53 o 0 6 0 53534.05 51349.73 3423.07 o 2 6 0 373.16 376.09 13.56 o 4 6 0 11525.96 10800.67 328.00 o 6 6 0 15.15 22.20 8.63 o 8 6 0 536.43 468.58 16.03 o 10 6 0 507.13 489.54 19.73 o 12 6 0 2039.36 2115.99 71.52 o 14 6 0 16.85 -4.93 19.73 o 16 6 0 2754.23 2860.78 115.91 o 0 7 0 36452.63 36133.35 2546.34 o 2 7 0 5.97 1.23 6.17 o 4 7 0 14041.85 13617.06 424.18 o 6 7 0 170.54 172.63 9.86 o 8 7 0 369.27 236.75 13.56 o 10 7 0 393.68 378.56 17.26 o 12 7 0 1637.74 1593.16 46.86 o 14 7 0 29.18 9.86 20.96 o 16 7 0 2209.89 2371.24 112.21 o 0 8 0 58649.66 58946.82 2807.75 o 2 8 0 23.04 18.50 7.40 o 4 8 0 11044.72 11070.72 304.57 o 6 8 0 1306.11 1328.04 36.99 o 8 8 0 2415.85 2516.74 71.52 o 10 8 0 516.86 493.24 20.96 o 12 8 0 3213.05 3250.44 102.35 o 14 8 0 15.33 11.10 22.20 o 16 8 0 2196.04 2092.56 91.25 o 0 9 0 68.66 67.82 66.59 o 2 9 0 1204.82 1369.97 41.93 o 4 9 0 1231.27 1189.94 32.06 o 6 9 0 682.82 679.43 19.73 o 8 9 0 804.86 794.11 28.36 o 10 9 0 3.48 -2.47 14.80 o 12 9 0 40.82 65.35 18.50 o 14 9 0 102.92 110.98 25.89 o 16 9 0 143.37 131.94 33.29 o 0 10 0 4229.06 4779.47 214.56 o 2 10 0 509.51 569.69 18.50 o 4 10 0 363.80 340.33 13.56 o 6 10 0 154.71 167.70 11.10 o 8 10 0 745.22 733.69 23.43 o 10 10 0 0.63 1.23 14.80 o 12 10 0 112.20 80.15 17.26 o 14 10 0 62.59 60.42 25.89 o 16 10 0 0.31 -13.56 45.62 o 0 11 0 1776.00 2202.31 150.44 o 2 11 0 74.32 87.55 13.56 o 4 11 0 526.72 543.79 27.13 o 6 11 0 48.15 44.39 11.10 o 8 11 0 918.54 891.53 27.13 o 10 11 0 4.25 -14.80 14.80 o 12 11 0 351.47 355.13 20.96 o 14 11 0 122.85 104.81 28.36 o 16 11 0 7.38 24.66 51.79 o 0 12 0 1565.11 1604.26 67.82 o 2 12 0 17.79 19.73 12.33 o 4 12 0 372.89 372.39 16.03 o 6 12 0 8.57 13.56 11.10 o 8 12 0 4014.24 4203.62 130.71 o 10 12 0 185.62 184.96 18.50 o 12 12 0 32.84 39.46 18.50 o 14 12 0 90.67 71.52 28.36 o 0 13 0 6523.59 6767.22 228.12 o 2 13 0 181.77 197.30 14.80 o 4 13 0 250.94 231.82 14.80 o 6 13 0 6.98 17.26 13.56 o 8 13 0 315.68 291.01 17.26 o 10 13 0 187.78 186.20 19.73 o 12 13 0 347.20 332.94 23.43 o 14 13 0 58.48 32.06 29.59 o 0 14 0 7369.75 8148.28 365.00 o 2 14 0 87.48 104.81 14.80 o 4 14 0 4701.85 5065.55 147.97 o 6 14 0 63.96 78.92 17.26 o 8 14 0 2582.55 2818.85 90.02 o 10 14 0 215.51 213.33 19.73 o 12 14 0 638.66 696.70 35.76 o 14 14 0 34.10 -1.23 35.76 o 0 15 0 5283.41 5561.25 204.69 o 2 15 0 700.06 704.10 25.89 o 4 15 0 1874.93 1922.39 62.89 o 6 15 0 344.52 351.43 18.50 o 8 15 0 7.22 -9.86 18.50 o 10 15 0 16.66 0.00 19.73 o 12 15 0 610.24 633.81 44.39 o 14 15 0 94.95 155.37 40.69 o 0 16 0 246.44 309.51 22.20 o 2 16 0 649.90 697.93 22.20 o 4 16 0 2198.15 2278.76 66.59 o 6 16 0 744.44 812.61 30.83 o 8 16 0 2799.83 2939.70 85.08 o 10 16 0 14.31 -6.17 27.13 o 12 16 0 116.36 92.48 33.29 o 0 17 0 827.08 840.97 35.76 o 2 17 0 45.09 19.73 14.80 o 4 17 0 585.31 596.82 28.36 o 6 17 0 13.80 2.47 18.50 o 8 17 0 915.15 930.99 35.76 o 10 17 0 58.75 22.20 34.53 o 12 17 0 569.63 614.08 57.96 o 0 18 0 1635.75 1437.79 78.92 o 2 18 0 2.88 0.00 16.03 o 4 18 0 1244.90 1217.06 38.23 o 6 18 0 4.20 -14.80 22.20 o 8 18 0 952.74 1049.36 65.35 o 10 18 0 48.40 55.49 41.93 o 0 19 0 1414.40 1307.08 53.02 o 2 19 0 52.82 43.16 18.50 o 4 19 0 0.07 -16.03 18.50 o 6 19 0 32.53 73.99 29.59 o 8 19 0 232.40 170.17 32.06 o 10 19 0 198.75 199.76 45.62 o 0 20 0 845.45 847.14 44.39 o 2 20 0 0.00 8.63 18.50 o 4 20 0 216.15 182.50 23.43 o 6 20 0 3.61 -30.83 30.83 o 8 20 0 33.50 44.39 30.83 o 0 21 0 969.75 1138.15 64.12 o 2 21 0 63.33 54.26 25.89 o 4 21 0 644.80 653.54 34.53 o 6 21 0 22.54 -24.66 24.66 o 8 21 0 93.15 59.19 33.29 o 0 22 0 706.39 651.07 53.02 o 2 22 0 73.32 91.25 25.89 o 4 22 0 1059.44 1205.97 70.29 o 6 22 0 186.73 181.26 28.36 o 0 23 0 1413.96 1691.80 130.71 o 2 23 0 40.66 35.76 27.13 o 4 23 0 983.37 1006.20 59.19 o 0 24 0 535.18 584.49 60.42 o 1 1 1 1728.40 1527.80 34.53 o 2 1 1 1395.76 1478.48 27.13 o 3 1 1 4493.78 4351.59 78.92 o 4 1 1 1246.83 1093.75 20.96 o 5 1 1 413.85 387.19 9.86 o 6 1 1 6634.69 6471.28 117.14 o 7 1 1 6.90 -4.93 6.17 o 8 1 1 638.01 664.64 13.56 o 9 1 1 1810.61 1707.84 33.29 o 10 1 1 717.29 626.41 14.80 o 11 1 1 59.54 62.89 9.86 o 12 1 1 47.67 40.69 11.10 o 13 1 1 665.20 653.54 17.26 o 14 1 1 320.14 305.81 14.80 o 15 1 1 486.44 494.47 17.26 o 16 1 1 0.13 -9.86 20.96 o 17 1 1 25.38 16.03 25.89 o 1 2 1 2108.43 1954.45 41.93 o 2 2 1 5876.92 5693.20 114.68 o 3 2 1 7487.93 7386.23 139.34 o 4 2 1 4776.83 4757.28 87.55 o 5 2 1 6421.86 6383.73 119.61 o 6 2 1 7263.11 7149.48 135.64 o 7 2 1 1438.72 1324.34 27.13 o 8 2 1 145.80 165.23 7.40 o 9 2 1 659.42 644.91 14.80 o 10 2 1 1374.69 1309.55 27.13 o 11 2 1 856.48 834.80 19.73 o 12 2 1 487.18 459.94 13.56 o 13 2 1 252.62 242.92 13.56 o 14 2 1 349.42 323.07 14.80 o 15 2 1 20.11 35.76 16.03 o 16 2 1 236.81 226.89 22.20 o 17 2 1 0.06 -27.13 27.13 o 1 3 1 1180.14 1123.35 24.66 o 2 3 1 4672.57 4267.74 85.08 o 3 3 1 12.93 -4.93 4.93 o 4 3 1 110.79 80.15 4.93 o 5 3 1 435.65 414.32 8.63 o 6 3 1 125.20 92.48 6.17 o 7 3 1 284.73 229.36 7.40 o 8 3 1 1655.60 1659.74 30.83 o 9 3 1 267.65 228.12 9.86 o 10 3 1 2227.90 2111.06 45.62 o 11 3 1 2257.19 2176.41 48.09 o 12 3 1 300.29 287.31 12.33 o 13 3 1 24.51 55.49 12.33 o 14 3 1 782.56 789.18 20.96 o 15 3 1 1087.27 1048.13 24.66 o 16 3 1 118.54 118.38 20.96 o 17 3 1 156.50 159.07 25.89 o 1 4 1 729.65 668.34 14.80 o 2 4 1 1308.21 1177.60 23.43 o 3 4 1 372.36 278.68 6.17 o 4 4 1 1810.10 1744.83 34.53 o 5 4 1 2428.76 2283.69 43.16 o 6 4 1 5879.77 5576.05 109.75 o 7 4 1 1300.38 1247.89 24.66 o 8 4 1 56.68 59.19 7.40 o 9 4 1 1054.49 1053.06 22.20 o 10 4 1 2282.90 2215.87 46.86 o 11 4 1 2030.99 1963.09 41.93 o 12 4 1 73.05 71.52 11.10 o 13 4 1 80.01 73.99 12.33 o 14 4 1 792.94 746.02 19.73 o 15 4 1 1037.71 1069.09 28.36 o 16 4 1 80.79 130.71 22.20 o 17 4 1 1.24 13.56 30.83 o 1 5 1 2906.35 2689.38 62.89 o 2 5 1 7399.34 7012.61 160.30 o 3 5 1 1780.53 1630.15 32.06 o 4 5 1 2793.17 3000.12 59.19 o 5 5 1 10880.88 11291.44 225.66 o 6 5 1 21055.83 22232.68 457.48 o 7 5 1 4636.92 4613.00 90.02 o 8 5 1 177.87 180.03 8.63 o 9 5 1 3294.84 3370.05 66.59 o 10 5 1 4616.77 4657.40 96.18 o 11 5 1 2624.26 2674.58 64.12 o 12 5 1 21.20 19.73 11.10 o 13 5 1 129.99 156.60 13.56 o 14 5 1 543.67 559.82 17.26 o 15 5 1 680.59 729.99 22.20 o 16 5 1 378.07 368.70 24.66 o 17 5 1 104.52 110.98 30.83 o 1 6 1 521.10 493.24 13.56 o 2 6 1 1456.11 1441.49 34.53 o 3 6 1 18.02 9.86 4.93 o 4 6 1 101.68 112.21 4.93 o 5 6 1 801.29 739.86 16.03 o 6 6 1 1132.05 1016.07 19.73 o 7 6 1 127.85 106.05 7.40 o 8 6 1 2.37 -2.47 7.40 o 9 6 1 903.42 864.40 19.73 o 10 6 1 1135.80 1181.30 24.66 o 11 6 1 190.51 187.43 11.10 o 12 6 1 108.65 82.62 12.33 o 13 6 1 241.68 241.69 13.56 o 14 6 1 132.36 155.37 14.80 o 15 6 1 77.76 69.05 19.73 o 16 6 1 0.11 7.40 22.20 o 17 6 1 6.21 14.80 29.59 o 1 7 1 316.68 319.37 8.63 o 2 7 1 1838.07 1891.57 48.09 o 3 7 1 233.50 239.22 6.17 o 4 7 1 659.94 779.32 16.03 o 5 7 1 115.22 83.85 6.17 o 6 7 1 27.87 30.83 6.17 o 7 7 1 77.55 69.05 7.40 o 8 7 1 24.75 29.59 7.40 o 9 7 1 43.10 45.62 8.63 o 10 7 1 136.34 131.94 11.10 o 11 7 1 24.28 7.40 11.10 o 12 7 1 39.22 49.32 12.33 o 13 7 1 143.16 146.74 14.80 o 14 7 1 459.38 448.85 17.26 o 15 7 1 17.29 32.06 22.20 o 16 7 1 115.93 136.87 32.06 o 17 7 1 106.11 101.11 29.59 o 1 8 1 28.01 30.83 6.17 o 2 8 1 830.97 873.03 19.73 o 3 8 1 277.54 299.64 7.40 o 4 8 1 1450.45 1499.44 30.83 o 5 8 1 453.79 436.52 9.86 o 6 8 1 1488.18 1429.16 28.36 o 7 8 1 143.89 152.90 8.63 o 8 8 1 1.38 -2.47 8.63 o 9 8 1 142.02 154.14 9.86 o 10 8 1 666.40 681.90 16.03 o 11 8 1 70.85 75.22 11.10 o 12 8 1 435.48 422.95 14.80 o 13 8 1 4.36 -1.23 12.33 o 14 8 1 271.69 242.92 17.26 o 15 8 1 2.70 3.70 19.73 o 16 8 1 46.38 48.09 24.66 o 1 9 1 217.23 244.15 7.40 o 2 9 1 312.97 382.26 9.86 o 3 9 1 96.25 108.51 8.63 o 4 9 1 170.04 152.90 7.40 o 5 9 1 520.21 543.79 12.33 o 6 9 1 1672.23 1717.70 33.29 o 7 9 1 6.57 11.10 8.63 o 8 9 1 58.58 55.49 8.63 o 9 9 1 624.60 639.98 17.26 o 10 9 1 468.97 472.27 13.56 o 11 9 1 275.43 281.15 12.33 o 12 9 1 0.31 13.56 12.33 o 13 9 1 158.39 138.11 13.56 o 14 9 1 308.22 288.54 18.50 o 15 9 1 341.29 319.37 24.66 o 16 9 1 0.67 7.40 25.89 o 1 10 1 7.14 -4.93 6.17 o 2 10 1 99.30 59.19 7.40 o 3 10 1 423.97 494.47 13.56 o 4 10 1 429.41 426.65 11.10 o 5 10 1 2501.52 2510.58 50.56 o 6 10 1 2809.34 2900.24 57.96 o 7 10 1 676.46 676.97 14.80 o 8 10 1 12.88 9.86 8.63 o 9 10 1 657.23 641.21 17.26 o 10 10 1 1118.54 1180.07 27.13 o 11 10 1 1213.51 1226.93 28.36 o 12 10 1 8.52 7.40 12.33 o 13 10 1 10.31 -4.93 13.56 o 14 10 1 116.58 129.47 20.96 o 15 10 1 131.49 106.05 25.89 o 16 10 1 38.90 19.73 28.36 o 1 11 1 894.23 895.23 19.73 o 2 11 1 3427.73 3460.06 77.68 o 3 11 1 191.70 187.43 8.63 o 4 11 1 0.01 -1.23 7.40 o 5 11 1 1510.46 1532.74 32.06 o 6 11 1 1621.99 1630.15 34.53 o 7 11 1 1276.22 1308.31 28.36 o 8 11 1 634.60 625.18 16.03 o 9 11 1 551.83 565.99 16.03 o 10 11 1 3023.26 3208.51 66.59 o 11 11 1 1817.10 1823.75 43.16 o 12 11 1 29.06 34.53 12.33 o 13 11 1 107.75 108.51 16.03 o 14 11 1 781.61 765.75 29.59 o 15 11 1 639.55 614.08 29.59 o 1 12 1 1431.18 1483.41 25.89 o 2 12 1 3793.49 3961.93 82.62 o 3 12 1 1937.45 2098.73 44.39 o 4 12 1 86.19 86.32 8.63 o 5 12 1 865.38 840.97 18.50 o 6 12 1 3593.89 3767.10 81.38 o 7 12 1 602.17 642.44 16.03 o 8 12 1 11.48 13.56 9.86 o 9 12 1 1379.15 1366.27 29.59 o 10 12 1 1547.90 1572.19 33.29 o 11 12 1 755.86 766.98 19.73 o 12 12 1 41.66 16.03 13.56 o 13 12 1 522.56 474.74 22.20 o 14 12 1 1027.24 988.94 36.99 o 15 12 1 1005.33 940.85 36.99 o 1 13 1 866.75 928.52 20.96 o 2 13 1 3050.29 3240.57 67.82 o 3 13 1 658.81 685.60 18.50 o 4 13 1 351.44 363.76 13.56 o 5 13 1 4868.85 5214.75 103.58 o 6 13 1 8569.94 9223.54 191.13 o 7 13 1 2741.84 2938.46 61.65 o 8 13 1 255.86 270.05 12.33 o 9 13 1 1620.99 1670.84 34.53 o 10 13 1 1860.28 1890.33 41.93 o 11 13 1 1239.78 1260.22 29.59 o 12 13 1 0.04 -13.56 16.03 o 13 13 1 55.54 36.99 20.96 o 14 13 1 470.57 468.58 27.13 o 15 13 1 155.75 147.97 32.06 o 1 14 1 152.36 165.23 11.10 o 2 14 1 1157.87 1235.56 23.43 o 3 14 1 14.47 6.17 11.10 o 4 14 1 2175.18 2271.36 55.49 o 5 14 1 176.13 160.30 12.33 o 6 14 1 1727.96 1806.48 38.23 o 7 14 1 122.42 115.91 11.10 o 8 14 1 328.06 344.03 13.56 o 9 14 1 15.65 13.56 11.10 o 10 14 1 0.58 -1.23 12.33 o 11 14 1 2.74 9.86 13.56 o 12 14 1 181.12 183.73 19.73 o 13 14 1 166.09 141.81 23.43 o 14 14 1 515.28 526.53 29.59 o 1 15 1 81.59 75.22 9.86 o 2 15 1 32.62 29.59 9.86 o 3 15 1 19.24 19.73 11.10 o 4 15 1 337.52 335.40 14.80 o 5 15 1 789.78 813.84 19.73 o 6 15 1 1523.57 1568.50 30.83 o 7 15 1 211.32 217.02 13.56 o 8 15 1 130.04 130.71 13.56 o 9 15 1 347.17 360.06 16.03 o 10 15 1 285.76 265.12 16.03 o 11 15 1 133.26 118.38 17.26 o 12 15 1 98.05 77.68 23.43 o 13 15 1 9.97 -23.43 23.43 o 1 16 1 281.70 267.58 12.33 o 2 16 1 559.79 559.82 14.80 o 3 16 1 24.01 28.36 9.86 o 4 16 1 134.79 152.90 13.56 o 5 16 1 29.74 32.06 12.33 o 6 16 1 1.76 8.63 12.33 o 7 16 1 0.06 -13.56 13.56 o 8 16 1 216.54 177.57 13.56 o 9 16 1 162.45 168.93 16.03 o 10 16 1 708.45 722.59 29.59 o 11 16 1 210.85 234.29 23.43 o 12 16 1 7.37 -9.86 23.43 o 13 16 1 203.02 194.83 27.13 o 1 17 1 33.17 32.06 11.10 o 2 17 1 0.58 -4.93 11.10 o 3 17 1 229.66 209.63 12.33 o 4 17 1 62.09 43.16 12.33 o 5 17 1 435.96 445.15 17.26 o 6 17 1 407.23 427.88 17.26 o 7 17 1 154.85 157.84 14.80 o 8 17 1 0.87 -14.80 14.80 o 9 17 1 50.75 51.79 22.20 o 10 17 1 176.28 164.00 30.83 o 11 17 1 299.12 297.18 27.13 o 12 17 1 1.79 20.96 34.53 o 1 18 1 85.81 106.05 11.10 o 2 18 1 501.97 604.22 17.26 o 3 18 1 108.30 127.01 12.33 o 4 18 1 35.35 35.76 12.33 o 5 18 1 430.92 472.27 19.73 o 6 18 1 1019.63 1117.18 29.59 o 7 18 1 185.88 165.23 14.80 o 8 18 1 49.45 35.76 20.96 o 9 18 1 421.12 434.05 27.13 o 10 18 1 260.90 300.87 27.13 o 11 18 1 329.30 267.58 35.76 o 1 19 1 605.58 635.04 16.03 o 2 19 1 1759.99 1937.19 43.16 o 3 19 1 535.92 548.73 17.26 o 4 19 1 0.80 -13.56 13.56 o 5 19 1 641.44 647.37 20.96 o 6 19 1 1307.74 1361.34 46.86 o 7 19 1 656.33 680.67 27.13 o 8 19 1 66.07 70.29 25.89 o 9 19 1 529.17 522.83 32.06 o 10 19 1 1314.18 1372.43 67.82 o 1 20 1 170.82 194.83 13.56 o 2 20 1 823.67 908.79 25.89 o 3 20 1 85.75 106.05 13.56 o 4 20 1 134.63 127.01 16.03 o 5 20 1 163.84 136.87 17.26 o 6 20 1 69.20 83.85 20.96 o 7 20 1 157.12 186.20 24.66 o 8 20 1 46.67 61.65 25.89 o 9 20 1 66.49 65.35 28.36 o 1 21 1 56.69 45.62 16.03 o 2 21 1 392.17 381.03 19.73 o 3 21 1 107.03 87.55 17.26 o 4 21 1 18.00 27.13 17.26 o 5 21 1 56.70 76.45 17.26 o 6 21 1 118.38 127.01 18.50 o 7 21 1 79.54 61.65 23.43 o 8 21 1 0.97 -9.86 28.36 o 1 22 1 4.64 -4.93 17.26 o 2 22 1 0.06 29.59 19.73 o 3 22 1 1.72 -14.80 18.50 o 4 22 1 92.94 108.51 19.73 o 5 22 1 62.63 72.75 19.73 o 6 22 1 217.80 241.69 22.20 o 1 23 1 2.14 -1.23 19.73 o 2 23 1 0.13 -6.17 19.73 o 3 23 1 34.12 55.49 20.96 o 4 23 1 7.63 9.86 20.96 o 0 0 2 9477.87 9190.25 601.75 o 1 0 2 75377.88 72353.02 2469.89 o 2 0 2 49659.37 48652.95 1450.12 o 3 0 2 49961.97 46894.56 1234.33 o 4 0 2 331.40 332.94 9.86 o 5 0 2 18067.41 17535.83 432.82 o 6 0 2 5124.37 5313.40 123.31 o 7 0 2 4795.68 4375.02 112.21 o 8 0 2 53.05 57.96 8.63 o 9 0 2 9420.80 9459.06 254.02 o 10 0 2 6674.85 6768.45 178.80 o 11 0 2 5955.93 6245.62 173.87 o 12 0 2 1448.11 1429.16 39.46 o 13 0 2 5681.24 6100.12 166.47 o 14 0 2 76.97 80.15 20.96 o 15 0 2 3743.75 3917.54 110.98 o 16 0 2 12.87 35.76 34.53 o 17 0 2 1904.07 2042.00 108.51 o 0 1 2 240.01 219.49 8.63 o 1 1 2 6138.42 5726.49 118.38 o 2 1 2 272.83 210.86 4.93 o 3 1 2 3544.60 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199.76 6.17 o 2 4 4 3.65 -2.47 4.93 o 3 4 4 45.53 54.26 4.93 o 4 4 4 44.13 44.39 3.70 o 5 4 4 67.10 66.59 4.93 o 6 4 4 22.07 9.86 6.17 o 7 4 4 479.04 489.54 12.33 o 8 4 4 293.23 318.14 9.86 o 9 4 4 52.05 54.26 9.86 o 10 4 4 19.28 18.50 8.63 o 11 4 4 19.30 24.66 9.86 o 12 4 4 36.74 34.53 11.10 o 13 4 4 1.45 22.20 12.33 o 14 4 4 0.41 4.93 13.56 o 15 4 4 2.74 3.70 18.50 o 0 5 4 29.94 36.99 6.17 o 1 5 4 3.31 1.23 3.70 o 2 5 4 22.14 22.20 4.93 o 3 5 4 68.27 64.12 4.93 o 4 5 4 559.96 602.98 12.33 o 5 5 4 0.23 1.23 4.93 o 6 5 4 14.07 24.66 6.17 o 7 5 4 127.58 119.61 7.40 o 8 5 4 1119.80 1130.75 27.13 o 9 5 4 289.76 278.68 12.33 o 10 5 4 31.20 32.06 8.63 o 11 5 4 414.41 410.62 13.56 o 12 5 4 418.76 437.75 13.56 o 13 5 4 3.19 -3.70 12.33 o 14 5 4 23.48 16.03 16.03 o 15 5 4 3.67 -11.10 18.50 o 0 6 4 703.47 681.90 19.73 o 1 6 4 1.66 -1.23 6.17 o 2 6 4 200.86 199.76 6.17 o 3 6 4 373.26 389.66 9.86 o 4 6 4 3760.50 3728.88 77.68 o 5 6 4 0.73 0.00 6.17 o 6 6 4 91.95 101.11 7.40 o 7 6 4 365.95 367.46 9.86 o 8 6 4 5871.71 6149.44 120.84 o 9 6 4 234.35 229.36 12.33 o 10 6 4 127.50 129.47 12.33 o 11 6 4 18.36 19.73 11.10 o 12 6 4 1716.49 1773.19 39.46 o 13 6 4 286.76 260.18 14.80 o 14 6 4 0.93 -2.47 16.03 o 15 6 4 12.63 1.23 25.89 o 0 7 4 918.03 797.81 25.89 o 1 7 4 1.35 4.93 6.17 o 2 7 4 52.94 49.32 6.17 o 3 7 4 230.19 262.65 8.63 o 4 7 4 3057.83 2942.16 64.12 o 5 7 4 24.50 29.59 7.40 o 6 7 4 4.10 6.17 7.40 o 7 7 4 254.84 240.45 9.86 o 8 7 4 4911.16 5244.35 109.75 o 9 7 4 131.99 118.38 9.86 o 10 7 4 10.71 14.80 9.86 o 11 7 4 4.53 9.86 12.33 o 12 7 4 1236.40 1265.15 29.59 o 13 7 4 450.48 411.85 16.03 o 14 7 4 64.45 67.82 17.26 o 15 7 4 4.44 17.26 22.20 o 0 8 4 1793.75 1808.95 54.26 o 1 8 4 12.32 20.96 6.17 o 2 8 4 23.90 20.96 7.40 o 3 8 4 365.06 363.76 9.86 o 4 8 4 5826.37 6072.99 145.51 o 5 8 4 6.20 8.63 7.40 o 6 8 4 3.33 3.70 8.63 o 7 8 4 187.43 182.50 8.63 o 8 8 4 5893.56 5979.27 124.54 o 9 8 4 687.66 622.71 16.03 o 10 8 4 98.00 114.68 12.33 o 11 8 4 60.60 59.19 12.33 o 12 8 4 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4 520.81 492.00 14.80 o 4 11 4 6.17 6.17 9.86 o 5 11 4 504.87 508.03 14.80 o 6 11 4 44.71 34.53 9.86 o 7 11 4 114.89 94.95 9.86 o 8 11 4 27.13 33.29 9.86 o 9 11 4 115.04 98.65 11.10 o 10 11 4 14.65 12.33 12.33 o 11 11 4 169.26 164.00 16.03 o 12 11 4 287.09 277.45 19.73 o 13 11 4 62.51 76.45 19.73 o 0 12 4 2803.76 3002.58 76.45 o 1 12 4 129.39 115.91 8.63 o 2 12 4 40.72 39.46 8.63 o 3 12 4 107.99 97.41 9.86 o 4 12 4 145.83 157.84 9.86 o 5 12 4 11.98 4.93 9.86 o 6 12 4 65.50 77.68 11.10 o 7 12 4 222.43 210.86 12.33 o 8 12 4 349.37 305.81 13.56 o 9 12 4 62.42 60.42 13.56 o 10 12 4 0.03 4.93 13.56 o 11 12 4 77.74 72.75 16.03 o 12 12 4 154.00 152.90 19.73 o 13 12 4 108.45 76.45 28.36 o 0 13 4 149.99 141.81 13.56 o 1 13 4 7.27 7.40 8.63 o 2 13 4 27.78 25.89 9.86 o 3 13 4 207.14 225.66 9.86 o 4 13 4 245.70 261.42 12.33 o 5 13 4 131.85 146.74 11.10 o 6 13 4 0.23 4.93 11.10 o 7 13 4 0.47 6.17 12.33 o 8 13 4 951.13 959.35 23.43 o 9 13 4 230.81 224.42 14.80 o 10 13 4 34.48 7.40 14.80 o 11 13 4 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16 4 33.22 20.96 22.20 o 10 16 4 446.27 425.42 33.29 o 0 17 4 880.67 948.25 32.06 o 1 17 4 74.13 85.08 11.10 o 2 17 4 3.35 -13.56 13.56 o 3 17 4 134.22 119.61 12.33 o 4 17 4 539.08 549.96 17.26 o 5 17 4 24.17 11.10 13.56 o 6 17 4 0.24 -1.23 14.80 o 7 17 4 11.52 -1.23 19.73 o 8 17 4 224.60 209.63 23.43 o 9 17 4 65.06 60.42 24.66 o 0 18 4 1062.75 1099.92 36.99 o 1 18 4 24.56 17.26 12.33 o 2 18 4 30.15 27.13 12.33 o 3 18 4 128.65 102.35 13.56 o 4 18 4 986.07 884.13 27.13 o 5 18 4 0.50 -6.17 14.80 o 6 18 4 35.13 39.46 16.03 o 7 18 4 0.00 2.47 19.73 o 8 18 4 549.20 574.62 34.53 o 0 19 4 166.61 157.84 20.96 o 1 19 4 13.03 30.83 13.56 o 2 19 4 40.96 40.69 14.80 o 3 19 4 57.36 25.89 16.03 o 4 19 4 47.74 51.79 16.03 o 5 19 4 68.01 71.52 19.73 o 6 19 4 22.14 23.43 20.96 o 7 19 4 5.98 0.00 22.20 o 0 20 4 0.53 -8.63 28.36 o 1 20 4 4.28 4.93 18.50 o 2 20 4 0.09 -7.40 18.50 o 3 20 4 14.20 12.33 19.73 o 4 20 4 69.64 71.52 20.96 o 5 20 4 17.42 36.99 22.20 o 6 20 4 1.59 -6.17 25.89 o 0 21 4 128.60 82.62 25.89 o 1 21 4 2.55 -11.10 19.73 o 2 21 4 9.57 2.47 19.73 o 3 21 4 18.00 35.76 20.96 o 1 1 5 1047.57 1128.28 32.06 o 2 1 5 889.19 871.80 25.89 o 3 1 5 3.63 -2.47 6.17 o 4 1 5 126.36 131.94 6.17 o 5 1 5 380.61 409.39 9.86 o 6 1 5 1012.61 1048.13 20.96 o 7 1 5 341.02 367.46 9.86 o 8 1 5 10.47 12.33 9.86 o 9 1 5 71.68 71.52 9.86 o 10 1 5 256.82 270.05 12.33 o 11 1 5 195.68 188.66 13.56 o 12 1 5 9.73 25.89 14.80 o 13 1 5 193.06 188.66 9.86 o 14 1 5 38.51 83.85 23.43 o 15 1 5 93.12 101.11 34.53 o 1 2 5 671.97 738.62 22.20 o 2 2 5 3574.98 3741.21 76.45 o 3 2 5 349.32 332.94 11.10 o 4 2 5 0.41 7.40 6.17 o 5 2 5 81.23 91.25 6.17 o 6 2 5 627.80 667.10 13.56 o 7 2 5 292.86 318.14 9.86 o 8 2 5 63.03 76.45 8.63 o 9 2 5 158.15 149.20 11.10 o 10 2 5 34.90 34.53 11.10 o 11 2 5 2.71 -8.63 12.33 o 12 2 5 20.51 24.66 9.86 o 13 2 5 181.70 192.36 13.56 o 14 2 5 948.14 1044.43 36.99 o 1 3 5 521.17 554.89 14.80 o 2 3 5 2633.34 2685.68 50.56 o 3 3 5 793.95 802.74 17.26 o 4 3 5 79.98 86.32 4.93 o 5 3 5 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639.17 716.43 23.43 o 14 5 5 1851.37 2103.66 67.82 o 1 6 5 49.87 45.62 4.93 o 2 6 5 960.50 967.98 19.73 o 3 6 5 235.06 220.72 7.40 o 4 6 5 0.23 3.70 6.17 o 5 6 5 173.78 172.63 7.40 o 6 6 5 630.17 632.58 13.56 o 7 6 5 0.52 -1.23 8.63 o 8 6 5 2.90 0.00 8.63 o 9 6 5 4.13 2.47 8.63 o 10 6 5 237.03 242.92 11.10 o 11 6 5 0.16 4.93 12.33 o 12 6 5 7.46 17.26 11.10 o 13 6 5 11.72 0.00 13.56 o 14 6 5 206.82 213.33 25.89 o 1 7 5 5.31 11.10 4.93 o 2 7 5 148.89 160.30 6.17 o 3 7 5 11.47 12.33 7.40 o 4 7 5 49.28 50.56 6.17 o 5 7 5 25.36 18.50 7.40 o 6 7 5 527.18 505.57 12.33 o 7 7 5 43.68 34.53 7.40 o 8 7 5 37.23 33.29 8.63 o 9 7 5 86.10 77.68 11.10 o 10 7 5 284.67 281.15 11.10 o 11 7 5 0.50 7.40 12.33 o 12 7 5 22.52 18.50 12.33 o 13 7 5 3.21 6.17 14.80 o 14 7 5 56.46 36.99 27.13 o 1 8 5 66.32 67.82 7.40 o 2 8 5 545.83 536.40 12.33 o 3 8 5 73.44 71.52 7.40 o 4 8 5 56.92 49.32 8.63 o 5 8 5 18.85 20.96 8.63 o 6 8 5 198.56 173.87 8.63 o 7 8 5 45.68 43.16 8.63 o 8 8 5 15.50 22.20 8.63 o 9 8 5 30.46 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