data_2011300
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2000
_journal_volume  56
_journal_page_first  1100
_journal_page_last  1103
_publ_section_title
;
Molecular building blocks for solid state chalcogenides:
solvothermal synthesis and crystal structures of [Mn(en)~3~]Te~4~
and [Fe(en)~3~]~2~Sb~2~Se~5~
;
loop_
_publ_author_name
  'Chen, Zhen'
  'Wang, Ru-Ji'
  'Xiao-Ying Huang'
  'Li, Jing'
_chemical_formula_moiety  'C6 H24 Mn N6 2- , Te4 2- '
_chemical_formula_sum  'C6 H24 Mn N6 Te4'
_chemical_formula_iupac  '[Mn(C2 H8 N2 )3 ]Te 4'
_chemical_formula_weight  745.65
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'P 21/n'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x-1/2, -y-1/2, z-1/2'
_cell_length_a  8.461(2)
_cell_length_b  15.653(3)
_cell_length_c  14.269(3)
_cell_angle_alpha  90.00
_cell_angle_beta  91.37(3)
_cell_angle_gamma  90.00
_cell_volume  1889.2(7)
_cell_formula_units_Z  4
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  2.622
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Te1  .35396(8) 1.16959(5)  .37880(5)  .0639(2) Uani d . 1 . . Te
  Te2  .37486(9)  .99798(5)  .40030(5)  .0708(2) Uani d . 1 . . Te
  Te3  .26166(7)  .91945(4)  .23989(5)  .0549(2) Uani d . 1 . . Te
  Te4  .47529(7)  .94980(4)  .10143(5)  .0544(2) Uani d . 1 . . Te
  Mn1  .36862(15)  .32343(8)  .68448(10)  .0451(3) Uani d . 1 . . Mn
  N1  .3190(9)  .1835(4)  .6486(5)  .057(2) Uani d . 1 . . N
  H1A  .3746  .1488  .6874  .100 Uiso d R 1 . . H
  H1B  .3463  .1722  .5893  .100 Uiso d R 1 . . H
  N2  .1023(8)  .3228(4)  .6625(5)  .054(2) Uani d . 1 . . N
  H2A  .0721  .3675  .6268  .100 Uiso d R 1 . . H
  H2B  .0547  .3269  .7181  .100 Uiso d R 1 . . H
  N3  .3973(11)  .2888(5)  .8385(6)  .079(3) Uani d . 1 . . N
  H3A  .4984  .2740  .8511  .100 Uiso d R 1 . . H
  H3B  .3356  .2437  .8511  .100 Uiso d R 1 . . H
  N4  .3508(10)  .4521(5)  .7598(6)  .066(2) Uani d . 1 . . N
  H4A  .2562  .4762  .7468  .100 Uiso d R 1 . . H
  H4B  .4266  .4876  .7398  .100 Uiso d R 1 . . H
  N5  .3894(8)  .3698(5)  .5331(5)  .059(2) Uani d . 1 . . N
  H5A  .3301  .4170  .5244  .100 Uiso d R 1 . . H
  H5B  .3529  .3292  .4935  .100 Uiso d R 1 . . H
  N6  .6308(8)  .3190(6)  .6567(5)  .066(2) Uani d . 1 . . N
  H6A  .6719  .2702  .6801  .100 Uiso d R 1 . . H
  H6B  .6793  .3631  .6859  .100 Uiso d R 1 . . H
  C1  .1487(12)  .1702(6)  .6595(8)  .072(3) Uani d . 1 . . C
  H1C  .1272  .1679  .7252  .100 Uiso d R 1 . . H
  H1D  .1160  .1170  .6317  .100 Uiso d R 1 . . H
  C2  .0569(11)  .2428(6)  .6161(7)  .060(3) Uani d . 1 . . C
  H2C  .0816  .2465  .5509  .100 Uiso d R 1 . . H
  H2D  -.0546  .2330  .6208  .100 Uiso d R 1 . . H
  C3  .3539(14)  .3555(7)  .8968(7)  .084(4) Uani d D 1 . . C
  H3C  .4149  .3520  .9542  .100 Uiso d R 1 . . H
  H3D  .2450  .3476  .9122  .100 Uiso d R 1 . . H
  C4  .3693(19)  .4414(7)  .8583(8)  .112(5) Uani d D 1 . . C
  H4C  .2940  .4772  .8887  .100 Uiso d R 1 . . H
  H4D  .4725  .4616  .8769  .100 Uiso d R 1 . . H
  C5  .5541(10)  .3891(7)  .5128(8)  .069(3) Uani d . 1 . . C
  H5C  .5811  .4440  .5385  .100 Uiso d R 1 . . H
  H5D  .5687  .3911  .4463  .100 Uiso d R 1 . . H
  C6  .6591(10)  .3234(7)  .5567(7)  .063(3) Uani d . 1 . . C
  H6C  .6351  .2689  .5291  .100 Uiso d R 1 . . H
  H6D  .7679  .3364  .5454  .100 Uiso d R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
_atom_site_aniso_type_symbol
  Te1  .0514(4)  .0720(5)  .0678(5)  -.0014(4)  -.0050(3)  -.0119(4) Te
  Te2  .0811(5)  .0779(5)  .0528(4)  .0252(4)  -.0100(4)  .0035(4) Te
  Te3  .0449(3)  .0515(4)  .0685(5)  -.0040(3)  .0019(3)  .0035(3) Te
  Te4  .0471(4)  .0478(4)  .0683(4)  -.0068(3)  .0023(3)  -.0129(3) Te
  Mn1  .0388(7)  .0389(8)  .0574(9)  .0036(6)  -.0021(6)  .0017(7) Mn
  N1  .058(5)  .041(5)  .073(6)  .012(4)  .003(4)  -.005(4) N
  N2  .038(4)  .045(5)  .079(6)  .005(4)  -.002(4)  .003(4) N
  N3  .119(8)  .056(6)  .062(6)  .017(6)  .008(5)  .006(5) N
  N4  .075(6)  .042(5)  .082(6)  -.001(4)  -.013(5)  -.009(5) N
  N5  .045(5)  .064(5)  .067(5)  .002(4)  -.007(4)  .019(4) N
  N6  .044(5)  .095(7)  .060(6)  .014(5)  -.004(4)  .010(5) N
  C1  .070(7)  .032(5)  .113(9)  -.001(5)  .006(6)  .007(6) C
  C2  .044(6)  .048(6)  .087(8)  -.006(5)  -.006(5)  -.008(5) C
  C3  .084(8)  .100(10)  .067(8)  .030(8)  -.008(6)  .001(7) C
  C4  .196(16)  .065(9)  .076(9)  -.021(9)  .048(10)  -.012(7) C
  C5  .046(6)  .071(7)  .089(8)  .006(5)  .007(6)  .026(6) C
  C6  .038(5)  .076(7)  .076(8)  -.005(5)  -.001(5)  .002(6) C
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Te1 Te2 . 2.7091(12) yes
  Te2 Te3 . 2.7500(12) yes
  Te3 Te4 . 2.7509(12) yes
  Mn1 N6 . 2.264(7) yes
  Mn1 N2 . 2.267(7) yes
  Mn1 N3 . 2.271(8) yes
  Mn1 N1 . 2.287(7) yes
  Mn1 N5 . 2.289(7) yes
  Mn1 N4 . 2.290(7) yes
  N1 C1 . 1.468(11) no
  N2 C2 . 1.464(11) no
  N3 C3 . 1.389(12) no
  N4 C4 . 1.420(13) no
  N5 C5 . 1.462(11) no
  N6 C6 . 1.454(11) no
  C1 C2 . 1.502(12) no
  C3 C4 . 1.460(8) no
  C5 C6 . 1.488(12) no