data_2011992
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2001
_journal_volume  57
_journal_page_first  526
_journal_page_last  527
_publ_section_title
;
catena-Poly[[bis(thiocyanato-N)lead(II)]-\m-1,2-bis(4-pyridyl)ethane-N:N']
;
loop_
_publ_author_name
  'Niu, Yun-Yin'
  'Hou, Hong-Wei'
  'Zhang, Qian-Feng'
  'Xin, Xin-Quan'
  'Fun, Hoong-Kun'
  'Chantrapromma, Suchada'
  'Razak, Ibrahim Abdul'
_chemical_formula_moiety  'C14 H12 N4 Pb S2'
_chemical_formula_sum  'C14 H12 N4 Pb S2'
_chemical_formula_iupac  '[Pb(NCS)2 (C12 H12 N2 )]'
_chemical_formula_weight  507.59
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  Pc
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  'x, -y, z+1/2'
_cell_length_a  11.63350(10)
_cell_length_b  5.63090(10)
_cell_length_c  14.8578(2)
_cell_angle_alpha  90.00
_cell_angle_beta  121.0910(10)
_cell_angle_gamma  90.00
_cell_volume  833.48(2)
_cell_formula_units_Z  2
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  2.023
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Pb 1.00026(7)  .59744(4)  .25149(6)  .03240(12) Uani d . 1 . . Pb
  S1  .7742(4) 1.3377(9)  .2804(4)  .0528(10) Uani d . 1 . . S
  S2 1.2239(4) 1.3226(10)  .2282(4)  .0612(12) Uani d . 1 . . S
  N1  .8497(9)  .9230(16)  .2216(9)  .053(2) Uani d . 1 . . N
  N2 1.0960(12)  .8898(16)  .1902(10)  .055(2) Uani d . 1 . . N
  N3  .8194(7)  .5060(16)  .0599(5)  .0358(16) Uani d . 1 . . N
  N4  .1747(9)  -.1568(17)  -.5732(6)  .048(2) Uani d . 1 . . N
  C1  .8185(11) 1.0955(16)  .2469(9)  .033(2) Uani d . 1 . . C
  C2 1.1533(12) 1.070(2)  .2083(10)  .039(3) Uani d . 1 . . C
  C3  .8415(11)  .317(2)  .0169(7)  .049(2) Uani d . 1 . . C
  H3A  .9288  .2603  .0462  .07(4) Uiso d R 1 . . H
  C4  .7387(14)  .200(3)  -.0699(10)  .045(3) Uani d . 1 . . C
  H4B  .7566  .0631  -.0955  .10(6) Uiso d R 1 . . H
  C5  .6077(9)  .292(2)  -.1190(7)  .039(2) Uani d . 1 . . C
  C6  .5907(10)  .487(2)  -.0753(8)  .048(2) Uani d . 1 . . C
  H6A  .5054  .5527  -.1051  .12(7) Uiso d R 1 . . H
  C7  .6965(11)  .5943(19)  .0126(9)  .047(3) Uani d . 1 . . C
  H7A  .6805  .7321  .0389  .04(3) Uiso d R 1 . . H
  C8  .4961(14)  .170(3)  -.2150(10)  .053(4) Uani d . 1 . . C
  H8A  .4116  .2036  -.2194  .05(3) Uiso d R 1 . . H
  H8B  .5105  .0000  -.2071  .08(5) Uiso d R 1 . . H
  C9  .4861(13)  .246(2)  -.3148(8)  .049(3) Uani d . 1 . . C
  H9A  .4678  .4151  -.3245  .09(6) Uiso d R 1 . . H
  H9B  .5716  .2183  -.3097  .06(4) Uiso d R 1 . . H
  C10  .3775(10)  .115(2)  -.4089(7)  .044(2) Uani d . 1 . . C
  C11  .2417(16)  .174(3)  -.4558(12)  .052(4) Uani d . 1 . . C
  H11A  .2158  .3087  -.4343  .06(4) Uiso d R 1 . . H
  C12  .1449(11)  .028(3)  -.5359(9)  .054(3) Uani d . 1 . . C
  H12A  .0548  .0651  -.5638  .05(4) Uiso d R 1 . . H
  C13  .3028(12)  -.215(2)  -.5290(9)  .052(3) Uani d . 1 . . C
  H13A  .3254  -.3482  -.5536  .04(3) Uiso d R 1 . . H
  C14  .4048(12)  -.085(2)  -.4478(9)  .056(3) Uani d . 1 . . C
  H14A  .4934  -.1341  -.4189  .06(4) Uiso d R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Pb  .03174(15)  .02993(15)  .02920(16)  -.0068(2)  .01124(11)  -.0074(2)
  S1  .063(3)  .0359(17)  .079(3)  .0086(17)  .050(2)  -.0003(19)
  S2  .049(2)  .042(2)  .092(3)  -.0073(18)  .035(2)  -.008(2)
  N1  .039(5)  .046(5)  .064(6)  .006(3)  .019(5)  -.015(4)
  N2  .068(6)  .041(5)  .071(7)  -.005(4)  .047(6)  .002(4)
  N3  .033(4)  .044(4)  .022(3)  -.005(3)  .008(3)  -.009(3)
  N4  .048(5)  .052(5)  .029(4)  -.013(4)  .010(4)  -.017(4)
  C1  .036(5)  .033(5)  .031(6)  -.004(4)  .019(5)  -.002(4)
  C2  .039(6)  .046(6)  .032(6)  .007(4)  .017(5)  .001(4)
  C3  .042(5)  .062(6)  .029(4)  .003(5)  .008(4)  -.007(5)
  C4  .047(6)  .041(7)  .034(6)  .002(5)  .013(5)  -.004(5)
  C5  .037(5)  .045(5)  .030(4)  -.011(4)  .012(4)  .002(4)
  C6  .031(4)  .058(6)  .041(5)  -.006(5)  .008(4)  -.008(5)
  C7  .038(5)  .050(7)  .039(5)  .002(4)  .010(4)  -.011(4)
  C8  .055(7)  .059(7)  .038(6)  -.026(6)  .018(6)  -.010(5)
  C9  .049(7)  .061(8)  .026(5)  -.028(6)  .012(5)  -.014(5)
  C10  .036(5)  .062(7)  .023(4)  -.014(4)  .007(4)  -.008(4)
  C11  .051(7)  .056(7)  .040(7)  -.010(6)  .016(6)  -.023(6)
  C12  .034(5)  .070(7)  .041(5)  -.010(5)  .008(4)  -.007(6)
  C13  .054(6)  .041(6)  .050(6)  .001(5)  .018(5)  -.014(5)
  C14  .044(6)  .066(8)  .043(6)  .004(5)  .012(5)  -.013(5)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Pb N2 . 2.415(9) yes
  Pb N1 . 2.413(9) yes
  Pb N3 . 2.570(7) yes
  Pb N4 1_666 2.713(8) yes
  S1 C1 . 1.625(11) ?
  S2 C2 . 1.591(14) ?
  N1 C1 . 1.165(12) ?
  N2 C2 . 1.167(15) ?
  N3 C3 . 1.336(15) ?
  N3 C7 . 1.322(13) ?
  N4 C12 . 1.308(16) ?
  N4 C13 . 1.323(15) ?
  N4 Pb 1_444 2.713(8) ?
  C3 C4 . 1.389(17) ?
  C3 H3A .  .9300 ?
  C4 C5 . 1.404(17) ?
  C4 H4B .  .9300 ?
  C5 C6 . 1.343(17) ?
  C5 C8 . 1.508(14) ?
  C6 C7 . 1.387(14) ?
  C6 H6A .  .9300 ?
  C7 H7A .  .9300 ?
  C8 C9 . 1.488(16) ?
  C8 H8A .  .9700 ?
  C8 H8B .  .9701 ?
  C9 C10 . 1.508(13) ?
  C9 H9A .  .9701 ?
  C9 H9B .  .9699 ?
  C10 C14 . 1.375(16) ?
  C10 C11 . 1.40(2) ?
  C11 C12 . 1.406(17) ?
  C11 H11A .  .9300 ?
  C12 H12A .  .9300 ?
  C13 C14 . 1.386(15) ?
  C13 H13A .  .9300 ?
  C14 H14A .  .9301 ?