data_2012089
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2001
_journal_volume  57
_journal_page_first  851
_journal_page_last  853
_publ_section_title
;
1,6-Interactions between dimethylamino and aldehyde groups in two
biphenyl derivatives
;
loop_
_publ_author_name
  "O'Leary, Jane"
  'Wallis, John D.'
  'Wood, Michael L.'
_chemical_formula_moiety  'C15 H15 N O'
_chemical_formula_sum  'C15 H15 N O'
_chemical_formula_weight  225.28
_chemical_melting_point  .348E-305
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'P 21/n'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x-1/2, -y-1/2, z-1/2'
_cell_length_a  8.169(2)
_cell_length_b  11.042(3)
_cell_length_c  13.745(4)
_cell_angle_alpha  90
_cell_angle_beta  101.890(10)
_cell_angle_gamma  90
_cell_volume  1213.1(6)
_cell_formula_units_Z  4
_cell_measurement_temperature  150(2)
_exptl_crystal_density_diffrn  1.233
_diffrn_ambient_temperature  150(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  O1  .42227(14)  .12485(9)  .06615(7)  .0439(3) Uani d . 1 . . O
  C7  .56425(14)  .05279(10)  .32747(9)  .0213(3) Uani d . 1 . . C
  C8  .54862(14)  .04338(10)  .22396(8)  .0210(3) Uani d . 1 . . C
  C9  .63454(14)  -.04752(11)  .18415(9)  .0244(3) Uani d . 1 . . C
  C10  .73601(15)  -.12794(11)  .24583(10)  .0278(3) Uani d . 1 . . C
  C11  .75298(16)  -.11882(11)  .34807(10)  .0292(3) Uani d . 1 . . C
  C12  .66787(15)  -.02939(11)  .38835(9)  .0262(3) Uani d . 1 . . C
  C15  .44751(15)  .13117(11)  .15572(9)  .0246(3) Uani d . 1 . . C
  N1  .20131(12)  .07866(9)  .28372(7)  .0241(3) Uani d . 1 . . N
  C1  .47517(15)  .14762(10)  .37424(9)  .0218(3) Uani d . 1 . . C
  C2  .29921(15)  .15933(10)  .35281(8)  .0217(3) Uani d . 1 . . C
  C3  .22753(17)  .25411(11)  .39690(9)  .0281(3) Uani d . 1 . . C
  C4  .32549(19)  .33511(11)  .46071(10)  .0330(3) Uani d . 1 . . C
  C5  .49737(18)  .32245(12)  .48333(10)  .0326(3) Uani d . 1 . . C
  C6  .57074(16)  .22835(11)  .44111(9)  .0271(3) Uani d . 1 . . C
  C13  .20425(17)  -.04795(11)  .31544(11)  .0288(3) Uani d . 1 . . C
  C14  .03054(16)  .11710(13)  .24248(11)  .0324(3) Uani d . 1 . . C
  H9  .6203(18)  -.0522(13)  .1141(12)  .035(4) Uiso d . 1 . . H
  H10  .7969(18)  -.1918(14)  .2204(11)  .036(4) Uiso d . 1 . . H
  H11  .8247(18)  -.1752(13)  .3923(11)  .032(4) Uiso d . 1 . . H
  H12  .6787(18)  -.0250(13)  .4609(12)  .037(4) Uiso d . 1 . . H
  H15  .4016(17)  .2026(13)  .1863(10)  .029(3) Uiso d . 1 . . H
  H3  .1049(19)  .2629(12)  .3822(10)  .031(4) Uiso d . 1 . . H
  H4  .2765(19)  .4009(16)  .4897(11)  .045(4) Uiso d . 1 . . H
  H5  .5685(18)  .3803(13)  .5287(11)  .035(4) Uiso d . 1 . . H
  H6  .6931(19)  .2189(12)  .4568(10)  .028(3) Uiso d . 1 . . H
  H13X  .318(2)  -.0761(14)  .3438(11)  .036(4) Uiso d . 1 . . H
  H13Y  .1528(17)  -.0961(13)  .2544(11)  .033(4) Uiso d . 1 . . H
  H13Z  .1321(19)  -.0627(13)  .3654(11)  .035(4) Uiso d . 1 . . H
  H14X  -.0182(18)  .0609(14)  .1853(11)  .039(4) Uiso d . 1 . . H
  H14Y  -.0441(18)  .1154(12)  .2947(11)  .033(4) Uiso d . 1 . . H
  H14Z  .0307(17)  .1988(13)  .2156(10)  .032(4) Uiso d . 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  O1  .0557(7)  .0523(6)  .0205(5)  .0163(5)  .0005(5)  -.0001(4)
  C7  .0190(5)  .0223(6)  .0233(6)  -.0038(4)  .0057(5)  -.0005(4)
  C8  .0189(5)  .0219(5)  .0222(6)  -.0043(4)  .0041(5)  -.0013(4)
  C9  .0239(6)  .0267(6)  .0234(7)  -.0055(5)  .0067(5)  -.0042(5)
  C10  .0243(6)  .0247(6)  .0365(8)  .0014(5)  .0111(5)  -.0028(5)
  C11  .0246(6)  .0289(7)  .0346(7)  .0038(5)  .0073(5)  .0074(5)
  C12  .0253(6)  .0309(6)  .0226(6)  .0008(5)  .0053(5)  .0028(5)
  C15  .0260(6)  .0253(6)  .0227(7)  -.0022(5)  .0050(5)  -.0006(5)
  N1  .0227(5)  .0242(5)  .0249(5)  -.0013(4)  .0037(4)  .0005(4)
  C1  .0269(6)  .0215(5)  .0179(6)  -.0011(5)  .0064(5)  .0022(4)
  C2  .0266(6)  .0206(5)  .0185(6)  .0005(5)  .0063(5)  .0032(4)
  C3  .0318(7)  .0264(6)  .0274(7)  .0045(5)  .0095(5)  .0026(5)
  C4  .0482(8)  .0238(6)  .0302(7)  .0042(6)  .0151(6)  -.0034(5)
  C5  .0439(8)  .0290(6)  .0250(7)  -.0071(6)  .0078(6)  -.0064(5)
  C6  .0304(7)  .0298(6)  .0215(6)  -.0050(5)  .0063(5)  -.0009(5)
  C13  .0288(7)  .0236(6)  .0338(7)  -.0036(5)  .0061(6)  -.0004(5)
  C14  .0253(7)  .0369(8)  .0329(8)  .0009(6)  .0011(6)  .0046(6)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  O1 C15 . 1.2077(15) ?
  C7 C12 . 1.3959(17) ?
  C7 C8 . 1.4058(16) ?
  C7 C1 . 1.4939(16) ?
  C8 C9 . 1.3992(17) ?
  C8 C15 . 1.4773(17) ?
  C9 C10 . 1.3802(18) ?
  C10 C11 . 1.3870(19) ?
  C11 C12 . 1.3869(18) ?
  N1 C2 . 1.4220(15) ?
  N1 C14 . 1.4566(16) ?
  N1 C13 . 1.4632(16) ?
  C1 C6 . 1.3975(16) ?
  C1 C2 . 1.4124(17) ?
  C2 C3 . 1.3970(17) ?
  C3 C4 . 1.3858(19) ?
  C4 C5 . 1.381(2) ?
  C5 C6 . 1.3853(18) ?