data_2012415
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2002
_journal_volume  58
_journal_page_first  i16
_journal_page_last  i17
_publ_section_title
;
AgCo~3~PO~4~(HPO~4~)~2~
;
loop_
_publ_author_name
  'Guesmi, Abderrahmen'
  'Driss, Ahmed'
_chemical_formula_sum  'Ag Co3 H2 O12 P3'
_chemical_formula_structural  'Ag Co3 P O4 (H P O4)2'
_chemical_formula_iupac  'Ag Co3 P O4 (H P O4)2'
_chemical_formula_weight  571.59
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'C 2/c'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, y, -z+1/2'
  'x+1/2, y+1/2, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x, -y, z-1/2'
  '-x+1/2, -y+1/2, -z'
  'x+1/2, -y+1/2, z-1/2'
_cell_length_a  12.035(2)
_cell_length_b  12.235(2)
_cell_length_c  6.541(2)
_cell_angle_alpha  90
_cell_angle_beta  114.14(2)
_cell_angle_gamma  90
_cell_volume  878.9(3)
_cell_formula_units_Z  4
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  4.320
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ag  .0000  .47148(4)  .2500  .02258(19) Uani d S 1 . . Ag
  Co1  .29015(4)  .16196(4)  .37801(8)  .00841(18) Uani d . 1 . . Co
  Co2  .5000  .27873(5)  .2500  .0094(2) Uani d S 1 . . Co
  P1  .22255(8)  .38696(7)  .11416(14)  .0072(2) Uani d . 1 . . P
  P2  .0000  .18372(10)  .2500  .0073(3) Uani d S 1 . . P
  O1  .1068(2)  .1078(2)  .2663(4)  .0108(5) Uani d . 1 . . O
  O2  .0350(2)  .2557(2)  .4620(4)  .0092(5) Uani d . 1 . . O
  O3  .3443(2)  .1719(2)  .1121(4)  .0093(5) Uani d . 1 . . O
  O4  .2169(2)  .31838(19)  .3066(4)  .0090(5) Uani d . 1 . . O
  O5  .1628(2)  .4994(2)  .1069(4)  .0111(5) Uani d . 1 . . O
  O6  .3605(2)  .4057(2)  .1588(4)  .0105(5) Uani d D 1 . . O
  H  .384(6)  .467(2)  .193(12)  .050 Uiso d D 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ag  .0098(2)  .0393(3)  .0152(3)  .000  .00155(18)  .000
  Co1  .0084(3)  .0060(3)  .0109(3)  .00012(16)  .0040(2)  .00024(16)
  Co2  .0086(3)  .0086(3)  .0109(3)  .000  .0040(3)  .000
  P1  .0076(4)  .0046(4)  .0088(4)  -.0001(3)  .0027(3)  -.0003(3)
  P2  .0057(5)  .0058(5)  .0086(6)  .000  .0011(4)  .000
  O1  .0081(11)  .0069(11)  .0171(13)  .0008(9)  .0048(10)  -.0009(9)
  O2  .0072(11)  .0098(11)  .0092(11)  -.0010(9)  .0020(9)  -.0010(9)
  O3  .0092(11)  .0093(11)  .0083(11)  -.0014(9)  .0025(9)  -.0006(8)
  O4  .0100(11)  .0076(11)  .0097(11)  .0002(9)  .0045(9)  .0006(9)
  O5  .0100(11)  .0057(10)  .0168(13)  .0012(9)  .0045(10)  .0005(9)
  O6  .0078(11)  .0067(11)  .0160(12)  -.0015(9)  .0039(9)  -.0008(9)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ag O5 6_566 2.382(3) y
  Ag O5 5_565 2.382(3) y
  Ag O5 . 2.516(3) y
  Ag O5 2 2.516(3) y
  Co1 O5 4_545 2.059(3) y
  Co1 O4 . 2.079(2) y
  Co1 O3 . 2.096(3) y
  Co1 O4 7_556 2.113(2) y
  Co1 O1 . 2.126(2) y
  Co1 O2 7_556 2.176(2) y
  Co2 O2 7_556 2.134(2) y
  Co2 O2 8 2.134(2) y
  Co2 O3 . 2.156(2) y
  Co2 O3 2_655 2.156(2) y
  Co2 O6 2_655 2.184(3) y
  Co2 O6 . 2.184(3) y
  P1 O4 . 1.537(2) y
  P1 O3 7 1.543(3) y
  P1 O5 . 1.544(3) y
  P1 O6 . 1.581(3) y
  P2 O2 . 1.549(3) y
  P2 O2 2 1.549(3) y
  P2 O1 2 1.554(2) y
  P2 O1 . 1.554(2) y