#------------------------------------------------------------------------------
#$Date: 2010-01-30 13:59:17 +0000 (Sat, 30 Jan 2010) $
#$Revision: 966 $
#$URL: svn://www.crystallography.net/cod/cif/2/2012792.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2012792
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2002
_journal_volume  58
_journal_page_first  i87
_journal_page_last  i89
_publ_section_title
;
Sodium silver tricobalt diphosphate and sodium silver copper(II) diphosphate
;
loop_
_publ_author_name
  'Bennazha, J.'
  'Boukhari, Ali'
  'Holt, Elizabeth M.'
_chemical_name_common  'Sodium silver tricobalt diphosphate'
_chemical_formula_sum            'Ag0.58 Co3 Na1.42 O14 P4'
_[local]_cod_chemical_formula_sum_orig 'Ag0.58  Co3 Na1.42 O14 P4 '
_chemical_formula_structural  'Ag0.58  Na1.42 Co3 (P2 O7)2'
_chemical_formula_weight  619.88
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
_symmetry_space_group_name_Hall  '-P 1'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
_cell_length_a  5.296(2)
_cell_length_b  6.3590(10)
_cell_length_c  16.238(4)
_cell_angle_alpha  80.930(10)
_cell_angle_beta  81.80(3)
_cell_angle_gamma  72.92(2)
_cell_volume  513.5(2)
_cell_formula_units_Z  2
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  4.009
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Co1 1.23425(11) 0.96160(8) 0.34055(3) 0.00901(14) Uani d . 1 . . Co
  Co2 0.80340(12) 0.71808(9) 0.41125(4) 0.01018(14) Uani d . 1 . . Co
  Co3 0.96264(12) 0.36526(9) 0.19545(3) 0.00979(14) Uani d . 1 . . Co
  Na1 0.09797(17) 0.25188(14) 0.97986(5) 0.0217(3) Uani d P 0.659(3) . . Na
  Ag1 0.09797(17) 0.25188(14) 0.97986(5) 0.0217(3) Uani d P 0.341(3) . . Ag
  Na2 0.3906(2) 0.72922(16) 0.13722(6) 0.0197(3) Uani d P 0.765(3) . . Na
  Ag2 0.3906(2) 0.72922(16) 0.13722(6) 0.0197(3) Uani d P 0.235(3) . . Ag
  P1 0.8110(2) -0.09808(16) 0.21710(6) 0.00766(19) Uani d . 1 . . P
  O11 0.9431(6) -0.3030(5) 0.17431(18) 0.0129(6) Uani d . 1 . . O
  O12 0.6445(6) -0.1368(5) 0.29903(18) 0.0102(5) Uani d . 1 . . O
  O13 1.0115(6) 0.0257(5) 0.22299(19) 0.0108(5) Uani d . 1 . . O
  O14 0.5943(6) 0.0482(5) 0.1573(2) 0.0150(6) Uani d . 1 . . O
  P2 0.5659(2) 0.25057(17) 0.08228(6) 0.0097(2) Uani d . 1 . . P
  O21 0.7277(6) 0.3973(5) 0.09851(19) 0.0139(6) Uani d . 1 . . O
  O22 0.2705(6) 0.3568(5) 0.0910(2) 0.0153(6) Uani d . 1 . . O
  O23 0.6746(8) 0.1474(6) 0.0030(2) 0.0216(7) Uani d . 1 . . O
  P3 0.7048(2) 0.21744(16) 0.45848(6) 0.00687(19) Uani d . 1 . . P
  O31 0.8802(6) 0.0146(4) 0.41945(18) 0.0092(5) Uani d . 1 . . O
  O32 0.5896(6) 0.1575(5) 0.54735(17) 0.0099(5) Uani d . 1 . . O
  O33 0.8365(6) 0.3989(5) 0.4503(2) 0.0134(6) Uani d . 1 . . O
  O34 0.4405(6) 0.2999(5) 0.41178(18) 0.0132(6) Uani d . 1 . . O
  P4 0.3575(2) 0.42729(16) 0.32343(6) 0.00725(19) Uani d . 1 . . P
  O41 0.1744(6) 0.6529(5) 0.34236(19) 0.0101(5) Uani d . 1 . . O
  O42 0.2019(6) 0.2891(4) 0.29514(18) 0.0103(5) Uani d . 1 . . O
  O43 0.5949(7) 0.4470(5) 0.2654(2) 0.0161(6) Uani d . 1 . . O
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Co1 0.0097(3) 0.0065(2) 0.0105(3) -0.00272(19) 0.0005(2) -0.00060(18)
  Co2 0.0103(3) 0.0064(2) 0.0132(3) -0.00295(19) 0.0018(2) -0.00095(18)
  Co3 0.0109(3) 0.0082(2) 0.0106(3) -0.0033(2) -0.0015(2) -0.00055(18)
  Na1 0.0231(5) 0.0296(5) 0.0156(4) -0.0115(3) 0.0004(3) -0.0062(3)
  Ag1 0.0231(5) 0.0296(5) 0.0156(4) -0.0115(3) 0.0004(3) -0.0062(3)
  Na2 0.0161(5) 0.0215(5) 0.0209(5) -0.0039(4) -0.0012(4) -0.0046(3)
  Ag2 0.0161(5) 0.0215(5) 0.0209(5) -0.0039(4) -0.0012(4) -0.0046(3)
  P1 0.0088(4) 0.0068(4) 0.0078(4) -0.0032(3) 0.0006(3) -0.0017(3)
  O11 0.0178(15) 0.0103(12) 0.0102(13) -0.0041(11) 0.0027(11) -0.0037(10)
  O12 0.0084(13) 0.0135(13) 0.0080(12) -0.0036(11) 0.0026(10) -0.0013(10)
  O13 0.0106(14) 0.0085(12) 0.0141(13) -0.0042(10) -0.0012(11) -0.0008(10)
  O14 0.0130(15) 0.0162(14) 0.0160(14) -0.0070(12) -0.0043(12) 0.0059(11)
  P2 0.0097(5) 0.0099(4) 0.0091(4) -0.0023(4) -0.0007(4) -0.0010(3)
  O21 0.0152(15) 0.0133(13) 0.0146(14) -0.0065(12) -0.0038(12) 0.0015(11)
  O22 0.0107(14) 0.0166(14) 0.0172(15) -0.0020(12) -0.0016(12) -0.0009(11)
  O23 0.030(2) 0.0205(16) 0.0161(15) -0.0106(15) 0.0030(14) -0.0068(12)
  P3 0.0074(4) 0.0057(4) 0.0070(4) -0.0016(3) 0.0006(3) -0.0008(3)
  O31 0.0084(13) 0.0065(12) 0.0123(13) -0.0011(10) 0.0001(10) -0.0027(10)
  O32 0.0111(14) 0.0117(12) 0.0060(12) -0.0040(11) 0.0012(10) 0.0009(10)
  O33 0.0143(14) 0.0082(12) 0.0182(14) -0.0059(11) 0.0023(12) -0.0008(11)
  O34 0.0110(14) 0.0148(13) 0.0115(13) -0.0017(11) -0.0034(11) 0.0033(11)
  P4 0.0078(4) 0.0058(4) 0.0078(4) -0.0017(3) 0.0001(3) -0.0011(3)
  O41 0.0099(13) 0.0066(12) 0.0145(13) -0.0025(10) -0.0016(11) -0.0027(10)
  O42 0.0138(14) 0.0080(12) 0.0119(13) -0.0069(11) -0.0022(11) -0.0014(10)
  O43 0.0149(15) 0.0175(14) 0.0163(14) -0.0077(12) 0.0078(12) -0.0056(11)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Co1 O42 1_665 2.062(3) yes
  Co1 O41 1_655 2.073(3) yes
  Co1 O31 1_565 2.086(3) yes
  Co1 O32 2_766 2.096(3) yes
  Co1 O12 1_665 2.117(3) yes
  Co1 O13 1_565 2.306(3) yes
  Co2 O33 . 1.992(3) yes
  Co2 O32 2_666 2.052(3) yes
  Co2 O31 1_565 2.070(3) yes
  Co2 O41 1_655 2.079(3) yes
  Co2 O12 1_565 2.081(3) yes
  Co3 O11 1_565 2.057(3) yes
  Co3 O13 . 2.081(3) yes
  Co3 O43 . 2.077(3) yes
  Co3 O21 . 2.092(3) yes
  Co3 O42 1_655 2.107(3) yes
  Co3 O22 1_655 2.174(3) yes
  Na1 O23 1_456 2.483(4) yes
  Na1 O11 2_656 2.506(3) yes
  Na1 O23 2_656 2.460(4) yes
  Na1 O22 1_556 2.397(3) yes
  Na1 O21 1_456 2.614(3) yes
  Na1 O21 2_666 2.725(3) yes
  Na1 O22 2_566 2.866(3) yes
  Na1 O23 1_556 2.994(3) yes
  Na2 O23 2_665 2.329(4) yes
  Na2 O11 1_465 2.421(3) yes
  Na2 O21 . 2.433(3) yes
  Na2 O14 1_565 2.642(3) yes
  Na2 O43 . 2.655(4) yes
  Na2 O13 1_465 2.708(3) yes
  Na2 O22 . 2.856(3) yes
  Na2 O11 1_565 3.013(4) yes
  P1 O11 . 1.510(3) no
  P1 O12 . 1.516(3) no
  P1 O13 . 1.517(3) no
  P1 O14 . 1.591(3) no
  O14 P2 . 1.614(3) no
  P2 O23 . 1.500(3) no
  P2 O22 . 1.506(3) no
  P2 O21 . 1.512(3) no
  P3 O33 . 1.495(3) no
  P3 O31 . 1.521(3) no
  P3 O32 . 1.521(3) no
  P3 O34 . 1.599(3) no
  O34 P4 . 1.585(3) no
  P4 O43 . 1.484(3) no
  P4 O41 . 1.527(3) no
  P4 O42 . 1.524(3) no
_cod_database_code 2012792