#------------------------------------------------------------------------------ #$Date: 2015-01-27 19:58:39 +0000 (Tue, 27 Jan 2015) $ #$Revision: 130149 $ #$URL: svn://www.crystallography.net/cod/cif/2/10/08/2100855.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2100855 loop_ _publ_author_name 'Watson, W. H.' 'Kashyap, R. P.' 'Krawiec, M.' 'Marchand, A. P.' 'Reddy, C. M.' 'Gadgil, V. R.' _publ_section_title ;meso- and D,L-D~3~-trishomocubylidene-D~3~-trishomocubane oxides and D,L-bi-D~3~-trishomocubyl ; _journal_issue 5 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 731 _journal_page_last 737 _journal_paper_doi 10.1107/S0108768192004178 _journal_volume 48 _journal_year 1992 _chemical_formula_sum 'C22 H24 O' _chemical_formula_weight 304.44 _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 1 21/a 1' _cell_angle_alpha 90 _cell_angle_beta 96.440(10) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 12.337(2) _cell_length_b 6.361(3) _cell_length_c 19.891(2) _cell_volume 1551.1(8) _diffrn_radiation_type Mo _diffrn_radiation_wavelength 0.71069 _exptl_absorpt_coefficient_mu 0.072 _exptl_crystal_density_diffrn 1.303 _exptl_crystal_F_000 656 _[local]_cod_data_source_file st0578.cif _[local]_cod_data_source_block st0578a _[local]_cod_cif_authors_sg_H-M 'P 21/a' _[local]_cod_chemical_formula_sum_orig 'C22 H24 O1' _cod_original_cell_volume 1551.1(9) _cod_database_code 2100855 loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z O(1) .5196(3) .3150(5) .26530(10) C(1) .4778(4) .1305(7) .2265(2) C(2) .5018(4) .1110(8) .1545(2) C(3) .4274(4) .2814(9) .1193(3) C(4) .4104(5) .2080(10) .0465(3) C(5) .3611(4) -.0010(10) .0632(3) C(6) .2631(4) .0610(10) .0973(3) C(7) .2416(5) -.1300(10) .1400(3) C(8) .3538(4) -.1271(9) .1795(3) C(9) .3575(4) .0899(8) .2129(2) C(10) .4364(4) -.0865(8) .1266(3) C(11) .3193(4) .2240(9) .1491(3) C(12) .5506(4) .1030(7) .2896(2) C(13) .5222(4) .0266(8) .3563(2) C(14) .5533(4) -.2053(8) .3544(2) C(15) .5738(5) -.2640(10) .4292(3) C(16) .6637(4) -.1028(8) .4447(2) C(17) .7477(4) -.1607(9) .3971(3) C(18) .8110(4) .0421(9) .3904(3) C(19) .7101(4) .1664(8) .3636(2) C(20) .6677(4) .0441(7) .2998(2) C(21) .6188(4) .1051(8) .4085(2) C(22) .6687(4) -.1829(8) .3299(2) H(2) .578(3) .122(6) .147(2) H(3) .453(3) .422(6) .129(2) H(4A) .479(3) .204(7) .023(2) H(4B) .350(4) .295(8) .014(2) H(5) .346(3) -.103(7) .025(2) H(6) .200(3) .112(7) .069(2) H(7A) .230(4) -.250(8) .111(3) H(7B) .183(3) -.105(6) .166(2) H(8) .379(3) -.240(7) .205(2) H(9) .318(3) .100(6) .251(2) H(10) .479(3) -.208(6) .116(2) H(11) .278(3) .333(6) .158(2) H(13) .455(3) .054(5) .367(2) H(14) .506(3) -.286(6) .326(2) H(15A) .507(3) -.243(6) .458(2) H(15B) .605(3) -.413(7) .437(2) H(16) .697(3) -.085(6) .491(2) H(17) .790(3) -.271(7) .408(2) H(18A) .847(3) .096(7) .437(2) H(18B) .869(4) .031(7) .358(2) H(19) .716(3) .322(6) .352(2) H(20) .708(3) .065(6) .267(2) H(21) .596(3) .207(6) .444(2) H(22) .689(3) -.297(6) .301(2) loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C(2) C(1) C(9) 96.4(4) C(1) C(2) C(3) 101.9(4) C(1) C(2) C(10) 104.9(4) C(3) C(2) C(10) 98.5(4) C(2) C(3) C(4) 103.4(4) C(2) C(3) C(11) 98.8(4) C(4) C(3) C(11) 105.1(4) C(3) C(4) C(5) 94.3(4) C(4) C(5) C(6) 103.3(5) C(4) C(5) C(10) 105.3(4) C(6) C(5) C(10) 99.3(4) C(5) C(6) C(7) 103.9(5) C(5) C(6) C(11) 98.7(4) C(7) C(6) C(11) 104.6(4) C(6) C(7) C(8) 94.2(5) C(7) C(8) C(9) 102.6(5) C(7) C(8) C(10) 106.2(5) C(9) C(8) C(10) 98.4(4) C(8) C(9) C(1) 102.4(4) C(1) C(9) C(11) 104.8(4) C(8) C(9) C(11) 98.6(4) C(2) C(10) C(5) 104.9(4) C(2) C(10) C(8) 104.0(4) C(5) C(10) C(8) 103.0(4) C(3) C(11) C(6) 103.7(4) C(3) C(11) C(9) 104.1(4) C(6) C(11) C(9) 104.2(4) C(1) O(1) C(12) 60.1(2) O(1) C(1) C(12) 60.0(3) O(1) C(12) C(1) 59.8(3) C(13) C(12) C(20) 96.8(4) C(12) C(13) C(14) 102.1(4) C(12) C(13) C(21) 104.4(4) C(14) C(13) C(21) 98.6(4) C(13) C(14) C(15) 103.1(4) C(13) C(14) C(22) 99.2(4) C(15) C(14) C(22) 105.6(4) C(14) C(15) C(16) 94.1(4) C(15) C(16) C(17) 104.1(4) C(15) C(16) C(21) 105.2(4) C(17) C(16) C(21) 98.4(4) C(16) C(17) C(18) 103.9(4) C(16) C(17) C(22) 98.7(4) C(18) C(17) C(22) 106.1(4) C(17) C(18) C(19) 93.7(4) C(18) C(19) C(20) 102.5(4) C(18) C(19) C(21) 106.5(4) C(20) C(19) C(21) 98.4(4) C(19) C(20) C(12) 102.8(4) C(12) C(20) C(22) 104.6(4) C(19) C(20) C(22) 99.5(4) C(13) C(21) C(16) 103.7(4) C(13) C(21) C(19) 104.0(4) C(16) C(21) C(19) 103.4(4) C(14) C(22) C(17) 104.0(4) C(14) C(22) C(20) 103.6(4) C(17) C(22) C(20) 102.7(4) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance C(1) O(1) 1.466(5) C(1) C(2) 1.499(5) C(1) C(9) 1.500(6) C(2) C(3) 1.538(6) C(2) C(10) 1.561(6) C(3) C(4) 1.513(7) C(3) C(11) 1.562(7) C(4) C(5) 1.517(8) C(5) C(6) 1.504(7) C(5) C(10) 1.576(7) C(6) C(7) 1.524(8) C(6) C(11) 1.568(7) C(7) C(8) 1.513(7) C(8) C(9) 1.530(7) C(8) C(10) 1.567(7) C(9) C(11) 1.557(6) C(12) O(1) 1.469(5) C(12) C(13) 1.491(6) C(12) C(20) 1.484(6) C(13) C(14) 1.526(7) C(13) C(21) 1.571(6) C(14) C(15) 1.526(6) C(14) C(22) 1.563(6) C(15) C(16) 1.515(7) C(16) C(17) 1.526(7) C(16) C(21) 1.576(6) C(17) C(18) 1.521(7) C(17) C(22) 1.570(6) C(18) C(19) 1.520(7) C(19) C(20) 1.530(6) C(19) C(21) 1.564(6) C(20) C(22) 1.562(6)