#------------------------------------------------------------------------------
#$Date: 2013-12-28 13:58:47 +0000 (Sat, 28 Dec 2013) $
#$Revision: 91933 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/13/2101352.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2101352
loop_
_publ_author_name
'Sheikh-Ali, B. M.'
'Rapta, M.'
'Jameson, G. B.'
'Weiss, R. G.'
_publ_section_title
;
 Molecular conformations and crystal packing properties of five
 4-alkyl-<i>N</i>-(4-cyanophenyl)piperidines by X-ray diffraction: a
 surprising dependence upon alkyl chain length
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              823
_journal_page_last               835
_journal_volume                  51
_journal_year                    1995
_chemical_formula_sum            'C16 H22 N2'
_chemical_formula_weight         242.40
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2y1'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.43(3)
_cell_angle_gamma                90.0
_cell_formula_units_Z            8
_cell_length_a                   8.317(2)
_cell_length_b                   17.435(3)
_cell_length_c                   20.011(4)
_cell_volume                     2901.7(10)
_diffrn_radiation_type           Mo
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    0.065
_exptl_crystal_density_diffrn    1.110
_exptl_crystal_F_000             1056
_[local]_cod_data_source_file    gr0375.cif
_[local]_cod_data_source_block   gr0375a
_cod_database_code               2101352
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
N(1A) .1106(10) .8134(6) .2033(4) .084(3)
C(2A) .1130(11) .7495(7) .1880(5) .068(3)
C(3A) .1182(9) .6719(6) .1696(4) .059(2)
C(4A) .1222(9) .6495(6) .1037(4) .062(2)
C(5A) .1268(9) .5741(6) .0868(4) .057(2)
C(6A) .1269(9) .5135(7) .1325(4) .058(3)
C(7A) .1256(9) .5363(5) .2015(4) .060(2)
C(8A) .1232(9) .6133(6) .2187(4) .065(3)
N(9A) .1416(7) .4369(4) .1168(3) .053(2)
C(10A) .0957(9) .4152(6) .0470(4) .066(2)
C(11A) .1515(9) .3363(5) .0297(3) .059(2)
C(12A) .0985(8) .2748(5) .0794(4) .057(2)
C(13A) .1512(8) .2997(5) .1461(4) .052(2)
C(14A) .1015(10) .3789(5) .1662(4) .066(2)
C(15A) .1587(9) .1934(6) .0594(4) .067(2)
C(16A) .0892(10) .1283(6) .1000(4) .053(3)
C(17A) .1546(11) .0495(6) .0806(5) .073(3)
C(18A) .0792(14) -.0147(7) .1165(5) .078(4)
N(1D) -.1112(10) .5735(7) .4542(4) .087(3)
C(2D) -.1102(9) .6388(7) .4431(5) .062(3)
C(3D) -.1140(8) .7195(6) .4266(4) .058(2)
C(4D) -.1107(9) .7756(6) .4734(4) .063(2)
C(5D) -.1140(9) .8506(6) .4565(4) .062(3)
C(6D) -.1194(8) .8766(6) .3908(4) .046(2)
C(7D) -.1252(9) .8171(7) .3416(5) .068(3)
C(8D) -.1208(9) .7417(7) .3598(4) .067(3)
N(9D) -.1173(7) .9509(5) .3727(3) .060(2)
C(10D) -.1665(9) 1.0109(6) .4217(4) .067(2)
C(11D) -.1181(9) 1.0878(6) .4052(4) .067(3)
C(12D) -.1601(9) 1.1160(6) .3336(4) .064(2)
C(13D) -.1069(10) 1.0546(7) .2858(4) .075(3)
C(14D) -.1522(11) .9742(6) .3027(4) .075(3)
C(15D) -.1027(8) 1.1924(6) .3157(4) .064(2)
C(16D) -.1653(8) 1.2622(6) .3536(4) .064(2)
C(17D) -.1058(11) 1.3370(7) .3322(5) .081(3)
C(18D) -.1653(13) 1.4082(7) .3684(5) .101(3)
N(1C) .6344(10) .0688(6) .0512(4) .080(2)
C(2C) .6348(9) .1336(7) .0628(5) .064(3)
C(3C) .6347(8) .2153(6) .0792(5) .062(3)
C(4C) .6289(9) .2716(6) .0319(4) .062(3)
C(5C) .6293(9) .3459(6) .0478(4) .059(2)
C(6C) .6302(8) .3722(6) .1139(4) .046(2)
C(7C) .6378(9) .3129(7) .1639(4) .061(3)
C(8C) .6406(9) .2367(7) .1467(4) .067(3)
N(9C) .6350(7) .4469(5) .1327(3) .052(2)
C(10C) .5962(10) .5040(6) .0824(4) .070(3)
C(11C) .6440(9) .5831(6) .0993(4) .067(3)
C(12C) .5919(8) .6112(5) .1708(3) .054(2)
C(13C) .6423(11) .5493(6) .2189(4) .079(3)
C(14C) .5904(9) .4705(5) .2003(3) .059(2)
C(15C) .6440(9) .6896(5) .1894(4) .063(2)
C(16C) .5883(8) .7568(5) .1483(4) .059(2)
C(17C) .6342(10) .8333(6) .1730(4) .068(3)
C(18C) .5688(12) .9004(6) .1334(5) .095(3)
N(1B) .3692(9) .3304(7) .2943(4) .082(2)
C(2B) .3717(11) .2682(7) .3078(5) .064(3)
C(3B) .3764(8) .1906(6) .3244(4) .054(2)
C(4B) .3781(8) .1639(6) .3906(4) .055(2)
C(5B) .3738(9) .0889(6) .4068(4) .059(3)
C(6B) .3756(9) .0316(6) .3592(4) .052(2)
C(7B) .3695(8) .0550(6) .2900(4) .055(2)
C(8B) .3700(8) .1316(6) .2744(4) .060(2)
N(9B) .3826(7) -.0465(5) .3753(3) .054(2)
C(10B) .3496(11) -.0668(6) .4447(4) .078(3)
C(11B) .4032(10) -.1461(6) .4622(4) .066(3)
C(12B) .3454(9) -.2084(5) .4129(4) .060(2)
C(13B) .3913(10) -.1848(6) .3441(4) .069(3)
C(14B) .3343(9) -.1033(5) .3266(4) .062(2)
C(15B) .4108(8) -.2868(6) .4332(4) .065(2)
C(16B) .3453(9) -.3528(6) .3917(4) .066(2)
C(17B) .3985(12) -.4323(7) .4169(5) .080(3)
C(18B) .3217(13) -.4975(7) .3839(5) .102(3)
C(16W) .187(15) .142(8) .119(9) .16(4)
C(18W) .22(2) -.013(10) .127(7) .22(6)
H(4AA) .1206(9) .6872(6) .0689(4) .075
H(5AA) .1256(9) .5600(6) .0405(4) .069
H(7AA) .1248(9) .4992(5) .2370(4) .072
H(8AA) .1260(9) .6278(6) .2650(4) .078
H(10A) .1431(9) .4511(6) .0167(4) .080
H(10B) -.0190(9) .4185(6) .0424(4) .080
H(11A) .2667(9) .3357(3) .0272(3) .071
H(11B) .1095(9) .3226(5) -.0134(3) .071
H(12A) -.0169(8) .2733(5) .0793(4) .068
H(13A) .2665(8) .2982(5) .1472(4) .062
H(13B) .1132(8) .2644(5) .1792(4) .062
H(14A) -.0135(10) .3795(5) .1696(4) .080
H(14B) .1453(10) .3916(5) .2093(4) .080
H(15A) .2738(9) .1930(6) .0631(4) .081
H(15B) .1310(9) .1839(6) .0135(4) .081
H(16A) -.0260(10) .1288(6) .0970(4) .063
H(16B) .1192(10) .1366(6) .1458(4) .063
H(17A) .2692(11) .0485(6) .0859(5) .088
H(17B) .1307(11) .0432(6) .0338(5) .088
H(18A) .1085(14) -.0622(7) .0956(5) .095
H(18B) -.0357(14) -.0097(7) .1163(5) .095
H(18C) .1185(14) -.0140(7) .1616(5) .095
H(4DA) -.1073(9) .7614(6) .5197(4) .076
H(5DA) -.1086(9) .8891(6) .4908(4) .074
H(7DA) -.1256(9) .8298(7) .2948(5) .082
H(8DA) -.1262(9) .7026(7) .3260(4) .081
H(10C) -.1223(9) .9969(6) .4644(4) .080
H(10D) -.2814(9) 1.0108(6) .4255(4) .080
H(11C) -.0033(9) 1.0902(6) .4101(4) .080
H(11D) -.1638(9) 1.1227(6) .4369(4) .080
H(12B) -.2753(9) 1.1172(6) .3308(4) .077
H(13C) -.1447(10) 1.0659(7) .2414(4) .090
H(13D) .0084(10) 1.0563(7) .2850(4) .090
H(14C) -.2659(11) .9696(6) .2954(4) .091
H(14D) -.0998(11) .9388(6) .2732(4) .091
H(15C) -.1259(8) 1.1997(6) .2691(4) .077
H(15D) .0122(8) 1.1923(6) .3206(4) .077
H(16C) -.2800(8) 1.2631(6) .3484(4) .077
H(16D) -.1423(8) 1.2554(6) .4003(4) .077
H(17C) -.1266(11) 1.3430(7) .2853(4) .097
H(17D) .0088(11) 1.3360(7) .3382(4) .097
H(18D) -.1142(12) 1.4533(6) .3509(5) .092
H(18E) -.1430(12) 1.4043(6) .4154(5) .092
H(18F) -.2794(12) 1.4118(6) .3613(5) .092
H(4CA) .6243(9) .2569(6) -.0143(4) .075
H(5CA) .6287(9) .3843(6) .0134(4) .071
H(7CA) .6437(9) .3270(7) .2103(4) .074
H(8CA) .6399(9) .1979(7) .1808(4) .080
H(10E) .4822(10) .5024(6) .0749(4) .084
H(10F) .6478(10) .4901(6) .0414(4) .084
H(11E) .5980(9) .6170(6) .0666(4) .080
H(11F) .7588(9) .5873(6) .0961(4) .080
H(12C) .4766(8) .6117(5) .1720(3) .065
H(13E) .6044(11) .5609(6) .2630(4) .095
H(13F) .7577(11) .5497(6) .2207(4) .095
H(14E) .6363(9) .4344(5) .2313(3) .070
H(14F) .4756(9) .4676(5) .2041(3) .070
H(15E) .6102(9) .6983(5) .2345(4) .076
H(15F) .7594(9) .6903(5) .1896(4) .076
H(16D2) .4729(8) .7549(5) .1480(4) .071
H(16E) .6232(8) .7495(5) .1031(4) .071
H(17E) .7493(10) .8360(6) .1729(4) .082
H(17F) .6000(10) .8381(6) .2185(4) .082
H(18G) .5937(12) .9469(6) .1568(5) .119
H(18H) .4542(12) .8956(6) .1285(5) .119
H(18I) .6170(12) .9016(6) .0899(5) .119
H(4BA) .3862(8) .2006(6) .4261(4) .066
H(5BA) .3696(9) .0735(6) .4528(4) .071
H(7B) .3646(8) .0167(6) .2556(4) .066
H(8BA) .3687(8) .1469(6) .2283(4) .072
H(10G) .2362(11) -.0640(6) .4526(4) .094
H(10H) .4024(11) -.0307(6) .4736(4) .094
H(11F2) .3720(10) -.1593(6) .5069(4) .079
H(11G) .5184(10) -.1462(6) .4607(4) .079
H(12D) .2302(9) -.2100(5) .4149(4) .072
H(13G) .3508(10) -.2207(6) .3116(4) .083
H(13H) .5064(10) -.1857(6) .3421(4) .083
H(14G) .3772(9) -.0891(5) .2840(4) .075
H(14H) .2193(9) -.1043(5) .3225(4) .075
H(15E2) .3885(8) -.2964(6) .4795(4) .078
H(15F2) .5254(8) -.2851(6) .4283(4) .078
H(16F) .3810(9) -.3477(5) .3464(4) .080
H(16G) .2300(9) -.3510(5) .3915(4) .080
H(17E2) .3730(12) -.4348(7) .4636(5) .096
H(17F2) .5131(12) -.4361(7) .4129(5) .096
H(18J) .3653(13) -.5440(7) .4022(5) .215
H(18K) .3440(13) -.4951(7) .3370(5) .215
H(18L) .2076(13) -.4964(7) .3906(5) .215
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
N(1A) C(2A) 1.16(2)
C(2A) C(3A) 1.40(2)
C(3A) C(4A) 1.375(11)
C(3A) C(8A) 1.420(13)
C(4A) C(5A) 1.355(14)
C(5A) C(6A) 1.400(14)
C(6A) N(9A) 1.377(13)
C(6A) C(7A) 1.437(12)
C(7A) C(8A) 1.386(13)
N(9A) C(14A) 1.454(10)
N(9A) C(10A) 1.492(9)
C(10A) C(11A) 1.492(13)
C(11A) C(12A) 1.529(11)
C(12A) C(13A) 1.466(10)
C(12A) C(15A) 1.559(12)
C(13A) C(14A) 1.499(12)
C(15A) C(16W) 1.55(12)
C(15A) C(16A) 1.512(13)
C(16A) C(16W) 0.93(12)
C(16A) C(17A) 1.527(14)
C(17A) C(18A) 1.473(14)
C(17A) C(18W) 1.5(2)
C(17A) C(16W) 1.81(13)
C(18A) C(18W) 1.2(2)
N(1D) C(2D) 1.16(2)
C(2D) C(3D) 1.45(2)
C(3D) C(4D) 1.355(13)
C(3D) C(8D) 1.394(12)
C(4D) C(5D) 1.351(14)
C(5D) C(6D) 1.392(12)
C(6D) N(9D) 1.347(12)
C(6D) C(7D) 1.428(14)
C(7D) C(8D) 1.37(2)
N(9D) C(14D) 1.485(10)
N(9D) C(10D) 1.492(11)
C(10D) C(11D) 1.437(14)
C(11D) C(12D) 1.552(11)
C(12D) C(15D) 1.459(13)
C(12D) C(13D) 1.504(13)
C(13D) C(14D) 1.49(2)
C(15D) C(16D) 1.526(12)
C(16D) C(17D) 1.460(14)
C(17D) C(18D) 1.52(2)
N(1C) C(2C) 1.154(14)
C(2C) C(3C) 1.46(2)
C(3C) C(4C) 1.364(13)
C(3C) C(8C) 1.403(12)
C(4C) C(5C) 1.334(13)
C(5C) C(6C) 1.400(11)
C(6C) N(9C) 1.359(11)
C(6C) C(7C) 1.438(14)
C(7C) C(8C) 1.37(2)
N(9C) C(10C) 1.450(11)
N(9C) C(14C) 1.465(9)
C(10C) C(11C) 1.472(14)
C(11C) C(12C) 1.577(11)
C(12C) C(15C) 1.480(12)
C(12C) C(13C) 1.503(12)
C(13C) C(14C) 1.489(13)
C(15C) C(16C) 1.504(11)
C(16C) C(17C) 1.470(13)
C(17C) C(18C) 1.513(13)
N(1B) C(2B) 1.118(14)
C(2B) C(3B) 1.39(2)
C(3B) C(4B) 1.402(11)
C(3B) C(8B) 1.436(12)
C(4B) C(5B) 1.347(14)
C(5B) C(6B) 1.383(13)
C(6B) N(9B) 1.398(12)
C(6B) C(7B) 1.443(11)
C(7B) C(8B) 1.373(14)
N(9B) C(14B) 1.445(10)
N(9B) C(10B) 1.461(10)
C(10B) C(11B) 1.491(14)
C(11B) C(12B) 1.541(11)
C(12B) C(13B) 1.489(10)
C(12B) C(15B) 1.525(12)
C(13B) C(14B) 1.538(13)
C(15B) C(16B) 1.516(12)
C(16B) C(17B) 1.539(14)
C(17B) C(18B) 1.458(14)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N(1A) C(2A) C(3A) 179.3(11)
C(4A) C(3A) C(2A) 121.9(9)
C(4A) C(3A) C(8A) 117.2(9)
C(2A) C(3A) C(8A) 120.9(9)
C(5A) C(4A) C(3A) 121.1(9)
C(4A) C(5A) C(6A) 124.8(9)
N(9A) C(6A) C(5A) 125.7(8)
N(9A) C(6A) C(7A) 119.4(9)
C(5A) C(6A) C(7A) 114.1(10)
C(8A) C(7A) C(6A) 120.6(9)
C(7A) C(8A) C(3A) 121.7(9)
C(6A) N(9A) C(14A) 119.7(7)
C(6A) N(9A) C(10A) 116.0(8)
C(14A) N(9A) C(10A) 113.7(7)
N(9A) C(10A) C(11A) 111.9(7)
C(10A) C(11A) C(12A) 113.8(6)
C(13A) C(12A) C(11A) 107.4(7)
C(13A) C(12A) C(15A) 114.1(7)
C(11A) C(12A) C(15A) 112.2(6)
C(12A) C(13A) C(14A) 115.9(8)
N(9A) C(14A) C(13A) 113.1(7)
C(16W) C(15A) C(16A) 35(5)
C(16W) C(15A) C(12A) 112(5)
C(16A) C(15A) C(12A) 114.9(6)
C(16W) C(16A) C(15A) 75(8)
C(16W) C(16A) C(17A) 92(8)
C(15A) C(16A) C(17A) 113.6(7)
C(18A) C(17A) C(18W) 48(6)
C(18A) C(17A) C(16A) 114.0(8)
C(18W) C(17A) C(16A) 129(5)
C(18A) C(17A) C(16W) 121(4)
C(18W) C(17A) C(16W) 108(7)
C(16A) C(17A) C(16W) 31(4)
C(18W) C(18A) C(17A) 68(7)
N(1D) C(2D) C(3D) 177.3(11)
C(4D) C(3D) C(8D) 117.6(10)
C(4D) C(3D) C(2D) 123.0(9)
C(8D) C(3D) C(2D) 119.4(10)
C(5D) C(4D) C(3D) 121.8(9)
C(4D) C(5D) C(6D) 123.4(9)
N(9D) C(6D) C(5D) 124.4(9)
N(9D) C(6D) C(7D) 120.9(9)
C(5D) C(6D) C(7D) 114.7(10)
C(8D) C(7D) C(6D) 120.9(9)
C(7D) C(8D) C(3D) 121.6(10)
C(6D) N(9D) C(14D) 120.8(8)
C(6D) N(9D) C(10D) 119.7(7)
C(14D) N(9D) C(10D) 112.1(8)
C(11D) C(10D) N(9D) 115.1(7)
C(10D) C(11D) C(12D) 116.5(8)
C(15D) C(12D) C(13D) 113.2(7)
C(15D) C(12D) C(11D) 116.5(8)
C(13D) C(12D) C(11D) 107.2(8)
C(14D) C(13D) C(12D) 116.7(7)
N(9D) C(14D) C(13D) 115.0(8)
C(12D) C(15D) C(16D) 119.4(7)
C(17D) C(16D) C(15D) 116.7(7)
C(16D) C(17D) C(18D) 118.6(7)
N(1C) C(2C) C(3C) 178.6(12)
C(4C) C(3C) C(8C) 118.6(10)
C(4C) C(3C) C(2C) 123.0(10)
C(8C) C(3C) C(2C) 118.4(10)
C(5C) C(4C) C(3C) 122.2(9)
C(4C) C(5C) C(6C) 122.8(9)
N(9C) C(6C) C(5C) 125.0(9)
N(9C) C(6C) C(7C) 119.7(8)
C(5C) C(6C) C(7C) 115.1(9)
C(8C) C(7C) C(6C) 121.3(9)
C(7C) C(8C) C(3C) 119.9(10)
C(6C) N(9C) C(10C) 117.5(7)
C(6C) N(9C) C(14C) 121.1(7)
C(10C) N(9C) C(14C) 113.1(7)
N(9C) C(10C) C(11C) 115.1(7)
C(10C) C(11C) C(12C) 115.1(7)
C(15C) C(12C) C(13C) 115.0(7)
C(15C) C(12C) C(11C) 115.7(7)
C(13C) C(12C) C(11C) 106.3(7)
C(14C) C(13C) C(12C) 115.1(7)
N(9C) C(14C) C(13C) 114.5(7)
C(12C) C(15C) C(16C) 119.6(7)
C(17C) C(16C) C(15C) 116.3(6)
C(16C) C(17C) C(18C) 115.7(7)
N(1B) C(2B) C(3B) 179.4(11)
C(2B) C(3B) C(4B) 123.2(8)
C(2B) C(3B) C(8B) 122.0(8)
C(4B) C(3B) C(8B) 114.8(9)
C(5B) C(4B) C(3B) 123.4(9)
C(4B) C(5B) C(6B) 122.4(9)
C(5B) C(6B) N(9B) 123.1(8)
C(5B) C(6B) C(7B) 117.0(9)
N(9B) C(6B) C(7B) 119.9(9)
C(8B) C(7B) C(6B) 119.6(9)
C(7B) C(8B) C(3B) 122.7(8)
C(6B) N(9B) C(14B) 120.0(7)
C(6B) N(9B) C(10B) 116.7(8)
C(14B) N(9B) C(10B) 114.9(7)
N(9B) C(10B) C(11B) 113.1(8)
C(10B) C(11B) C(12B) 114.3(7)
C(13B) C(12B) C(15B) 113.6(7)
C(13B) C(12B) C(11B) 108.5(7)
C(15B) C(12B) C(11B) 110.7(7)
C(12B) C(13B) C(14B) 112.6(7)
N(9B) C(14B) C(13B) 113.4(7)
C(16B) C(15B) C(12B) 114.1(7)
C(15B) C(16B) C(17B) 113.8(7)
C(18B) C(17B) C(16B) 115.4(8)
C(16A) C(16W) C(15A) 70(7)
C(16A) C(16W) C(17A) 57(7)
C(15A) C(16W) C(17A) 98(6)
C(18A) C(18W) C(17A) 64(7)
_journal_paper_doi 10.1107/S0108768194013054