#------------------------------------------------------------------------------
#$Date: 2015-02-25 13:01:53 +0000 (Wed, 25 Feb 2015) $
#$Revision: 132410 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/49/2104987.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2104987
loop_
_publ_author_name
'Liu, Xiaogang'
'Cole, Jacqueline M.'
'Waddell, Paul G.'
'Lin, Tze-Chia'
_publ_section_title
;
 Molecular origins of commercial laser dye functionality in azacoumarins
 and 2-quinolones: LD 425, LD 489 and LD 473
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              560
_journal_page_last               568
_journal_volume                  67
_journal_year                    2011
_chemical_formula_moiety         'C15 H15 F3 N2 O2'
_chemical_formula_sum            'C15 H15 F3 N2 O2'
_chemical_formula_weight         312.29
_chemical_name_common            'LD 489'
_chemical_name_systematic        ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.537(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.9941(5)
_cell_length_b                   11.2954(6)
_cell_length_c                   14.3536(9)
_cell_measurement_reflns_used    11391
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      0.998
_cell_volume                     1423.44(14)
_computing_cell_refinement
;
;
_computing_data_collection       'COLLECT (Nonius BV, 1998)'
_computing_data_reduction
;
;
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      180(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_sigmaI/netI    0.0475
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            7357
_diffrn_reflns_theta_full        27.39
_diffrn_reflns_theta_max         27.39
_diffrn_reflns_theta_min         3.76
_exptl_absorpt_coefficient_mu    0.124
_exptl_absorpt_correction_T_max  0.998
_exptl_absorpt_correction_T_min  0.958
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Blessing, 1997)'
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    1.457
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Unknown
_exptl_crystal_F_000             648
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.311
_refine_diff_density_min         -0.252
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     259
_refine_ls_number_reflns         3199
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0758
_refine_ls_R_factor_gt           0.0476
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0596P)^2^+0.3202P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1131
_refine_ls_wR_factor_ref         0.1271
_reflns_number_gt                2235
_reflns_number_total             3199
_reflns_threshold_expression     >2sigma(I)
_iucr_refine_instructions_details
;
TITL jc0204 in P2(1)/c
CELL 0.71073   8.9941  11.2954  14.3536  90.000 102.537  90.000
ZERR    4.00   0.0005   0.0006   0.0009   0.000   0.003   0.000
LATT 1
SYMM -X, 0.5+Y, 0.5-Z
SFAC C  H  O  N  F
UNIT 60 60 8 8 12
OMIT  0 1 1
OMIT  1 0 0
OMIT  1 1 0
OMIT  0 0 2
OMIT  0 2 0
OMIT  -1 1 1
OMIT  -1 0 2
OMIT      1   1   1
OMIT    0   1   2
L.S. 2
ACTA
BOND  $H
FMAP 2
PLAN 5
CONF
WGHT  0.059600  0.320200
FVAR  0.251510
TEMP -93
MOLE 1
C1     1   0.247701  0.789479  0.149852 11.000000  0.044830  0.032320 =
           0.043240 -0.001500  0.016270  0.005910
C2     1   0.808182  0.465231  0.073621 11.000000  0.026360  0.035160 =
           0.036360 -0.001290  0.007720  0.000730
C3     1   0.789766  0.559643  0.005175 11.000000  0.028020  0.039210 =
           0.033920 -0.000090  0.011200 -0.001750
C4     1   0.679159  0.641963  0.001193 11.000000  0.029170  0.029820 =
           0.028310 -0.001640  0.006690 -0.004600
C5     1   0.457574  0.716815  0.070803 11.000000  0.034570  0.024200 =
           0.032010  0.001760  0.008840 -0.001120
C6     1   0.368216  0.701969  0.135690 11.000000  0.032730  0.026000 =
           0.034470 -0.003050  0.010830 -0.000720
C7     1   0.395725  0.599134  0.195456 11.000000  0.032040  0.029910 =
           0.027350 -0.003580  0.009130 -0.004130
C8     1   0.594124  0.544200  0.130096 11.000000  0.026080  0.028310 =
           0.028130 -0.003230  0.004760 -0.001750
C9     1   0.576258  0.636786  0.064695 11.000000  0.028380  0.026050 =
           0.026220 -0.000380  0.005560 -0.001810
C10    1   0.122366  0.721984  0.182029 11.000000  0.033310  0.044080 =
           0.044940 -0.002000  0.014800  0.005730
C11    1   0.179469  0.648279  0.271116 11.000000  0.038390  0.042310 =
           0.040140 -0.005750  0.016690 -0.000990
C12    1   0.357133  0.480456  0.329470 11.000000  0.064840  0.051400 =
           0.053860  0.019950  0.031370  0.009950
C13    1   0.668244  0.741568 -0.069260 11.000000  0.040560  0.036990 =
           0.040040  0.003650  0.017690  0.000740
C14    1   0.186397  0.865478  0.062771 11.000000  0.054880  0.043610 =
           0.055120  0.010650  0.024500  0.018990
C15    1   0.051393  0.575484  0.295477 11.000000  0.043930  0.063820 =
           0.052400  0.002650  0.021470 -0.006520
F1     5   0.762676  0.729827 -0.127936 11.000000  0.063670  0.065770 =
           0.062270  0.025710  0.041860  0.015250
F2     5   0.701220  0.845482 -0.023971 11.000000  0.095940  0.034140 =
           0.065270  0.002140  0.027470 -0.016430
F3     5   0.528727  0.752676 -0.123636 11.000000  0.050760  0.054770 =
           0.046320  0.019360  0.011160  0.012570
H1     2   0.297851  0.844306  0.207205 11.000000  0.057150
H3     2   0.862643  0.563302 -0.034174 11.000000  0.034750
H5     2   0.440258  0.781186  0.028778 11.000000  0.033810
H11    2   0.219428  0.704826  0.327071 11.000000  0.053440
H10A   2   0.042599  0.773965  0.192704 11.000000  0.044630
H12A   2   0.345937  0.508762  0.394604 11.000000  0.088050
H14A   2   0.102320  0.917481  0.072711 11.000000  0.067320
H15A   2  -0.035708  0.627904  0.294039 11.000000  0.070100
H10B   2   0.071328  0.663156  0.128822 11.000000  0.050930
H12B   2   0.458502  0.456098  0.328190 11.000000  0.116950
H14B   2   0.263538  0.918226  0.047769 11.000000  0.060150
H15B   2   0.080386  0.536967  0.359804 11.000000  0.066390
H12C   2   0.292083  0.418630  0.314936 11.000000  0.092280
H14C   2   0.139158  0.808380  0.008560 11.000000  0.090140
H15C   2   0.020929  0.507293  0.243015 11.000000  0.072090
N1     4   0.509780  0.523445  0.192482 11.000000  0.031890  0.029570 =
           0.031310  0.001980  0.010020  0.000580
N2     4   0.307194  0.572857  0.258043 11.000000  0.039470  0.034560 =
           0.037510  0.003130  0.018040  0.001910
O1     3   0.707631  0.461322  0.133958 11.000000  0.030230  0.033520 =
           0.036910  0.006630  0.011000  0.006140
O2     3   0.905599  0.388808  0.085032 11.000000  0.036130  0.043700 =
           0.054270  0.006600  0.014910  0.010320
HKLF 4
END
;
_[local]_cod_data_source_file    bk5105.cif
_[local]_cod_data_source_block   ld489
_[local]_cod_cif_authors_sg_H-M  P_21/c
_cod_database_code               2104987
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_symmetry_multiplicity
C C1 0.2477(2) 0.78948(17) 0.14985(14) 0.0391(4) Uani d 1 1
C C2 0.80818(19) 0.46523(15) 0.07362(12) 0.0325(4) Uani d 1 1
C C3 0.7898(2) 0.55964(16) 0.00517(13) 0.0330(4) Uani d 1 1
C C4 0.67916(19) 0.64196(14) 0.00119(12) 0.0290(4) Uani d 1 1
C C5 0.45757(19) 0.71682(15) 0.07080(12) 0.0300(4) Uani d 1 1
C C6 0.36822(19) 0.70197(14) 0.13569(12) 0.0305(4) Uani d 1 1
C C7 0.39573(19) 0.59913(14) 0.19546(12) 0.0294(4) Uani d 1 1
C C8 0.59412(18) 0.54420(14) 0.13010(11) 0.0277(4) Uani d 1 1
C C9 0.57626(18) 0.63679(14) 0.06469(11) 0.0269(4) Uani d 1 1
C C10 0.1224(2) 0.72198(18) 0.18203(15) 0.0398(5) Uani d 1 1
C C11 0.1795(2) 0.64828(17) 0.27112(14) 0.0390(4) Uani d 1 1
C C12 0.3571(3) 0.4805(2) 0.32947(19) 0.0539(6) Uani d 1 1
C C13 0.6682(2) 0.74157(16) -0.06926(13) 0.0378(4) Uani d 1 1
C C14 0.1864(3) 0.8655(2) 0.06277(17) 0.0493(6) Uani d 1 1
C C15 0.0514(3) 0.5755(2) 0.29548(18) 0.0517(6) Uani d 1 1
F F1 0.76268(15) 0.72983(11) -0.12794(9) 0.0596(4) Uani d 1 1
F F2 0.70122(17) 0.84548(10) -0.02397(10) 0.0636(4) Uani d 1 1
F F3 0.52873(13) 0.75268(10) -0.12364(8) 0.0505(3) Uani d 1 1
H H1 0.298(3) 0.844(2) 0.2072(17) 0.057(6) Uiso d 1 1
H H3 0.863(2) 0.5633(16) -0.0342(13) 0.035(5) Uiso d 1 1
H H5 0.440(2) 0.7812(17) 0.0288(14) 0.034(5) Uiso d 1 1
H H11 0.219(2) 0.705(2) 0.3271(16) 0.053(6) Uiso d 1 1
H H10A 0.043(2) 0.7740(18) 0.1927(14) 0.045(5) Uiso d 1 1
H H12A 0.346(3) 0.509(3) 0.395(2) 0.088(9) Uiso d 1 1
H H14A 0.102(3) 0.917(2) 0.0727(18) 0.067(7) Uiso d 1 1
H H15A -0.036(3) 0.628(2) 0.2940(18) 0.070(8) Uiso d 1 1
H H10B 0.071(2) 0.6632(19) 0.1288(16) 0.051(6) Uiso d 1 1
H H12B 0.459(4) 0.456(3) 0.328(3) 0.117(12) Uiso d 1 1
H H14B 0.264(3) 0.918(2) 0.0478(16) 0.060(7) Uiso d 1 1
H H15B 0.080(3) 0.537(2) 0.3598(19) 0.066(7) Uiso d 1 1
H H12C 0.292(4) 0.419(3) 0.315(2) 0.092(10) Uiso d 1 1
H H14C 0.139(3) 0.808(3) 0.009(2) 0.090(9) Uiso d 1 1
H H15C 0.021(3) 0.507(2) 0.2430(18) 0.072(7) Uiso d 1 1
N N1 0.50978(16) 0.52345(12) 0.19248(10) 0.0304(3) Uani d 1 1
N N2 0.30719(17) 0.57286(13) 0.25804(11) 0.0357(4) Uani d 1 1
O O1 0.70763(13) 0.46132(10) 0.13396(8) 0.0330(3) Uani d 1 1
O O2 0.90560(14) 0.38881(12) 0.08503(10) 0.0439(4) Uani d 1 1
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
C1 0.0448(11) 0.0323(9) 0.0432(11) 0.0059(8) 0.0163(9) -0.0015(9)
C2 0.0264(8) 0.0352(9) 0.0364(9) 0.0007(7) 0.0077(7) -0.0013(8)
C3 0.0280(9) 0.0392(10) 0.0339(9) -0.0017(7) 0.0112(7) -0.0001(8)
C4 0.0292(8) 0.0298(9) 0.0283(8) -0.0046(7) 0.0067(7) -0.0016(7)
C5 0.0346(9) 0.0242(8) 0.0320(9) -0.0011(7) 0.0088(7) 0.0018(7)
C6 0.0327(9) 0.0260(8) 0.0345(9) -0.0007(7) 0.0108(7) -0.0031(7)
C7 0.0320(9) 0.0299(9) 0.0273(8) -0.0041(7) 0.0091(7) -0.0036(7)
C8 0.0261(8) 0.0283(8) 0.0281(8) -0.0017(7) 0.0048(7) -0.0032(7)
C9 0.0284(8) 0.0261(8) 0.0262(8) -0.0018(7) 0.0056(7) -0.0004(7)
C10 0.0333(10) 0.0441(11) 0.0449(11) 0.0057(9) 0.0148(8) -0.0020(10)
C11 0.0384(10) 0.0423(11) 0.0401(10) -0.0010(8) 0.0167(8) -0.0058(9)
C12 0.0648(16) 0.0514(14) 0.0539(14) 0.0100(12) 0.0314(12) 0.0199(12)
C13 0.0406(10) 0.0370(10) 0.0400(10) 0.0007(8) 0.0177(8) 0.0036(8)
C14 0.0549(14) 0.0436(12) 0.0551(13) 0.0190(11) 0.0245(11) 0.0107(11)
C15 0.0439(12) 0.0638(14) 0.0524(13) -0.0065(11) 0.0215(10) 0.0027(12)
F1 0.0637(8) 0.0658(8) 0.0623(8) 0.0152(6) 0.0419(7) 0.0257(7)
F2 0.0959(11) 0.0341(6) 0.0653(8) -0.0164(6) 0.0275(8) 0.0021(6)
F3 0.0508(7) 0.0548(7) 0.0463(6) 0.0126(5) 0.0112(5) 0.0194(6)
N1 0.0319(8) 0.0296(7) 0.0313(7) 0.0006(6) 0.0100(6) 0.0020(6)
N2 0.0395(8) 0.0346(8) 0.0375(8) 0.0019(6) 0.0180(7) 0.0031(7)
O1 0.0302(6) 0.0335(7) 0.0369(6) 0.0061(5) 0.0110(5) 0.0066(5)
O2 0.0361(7) 0.0437(8) 0.0543(8) 0.0103(6) 0.0149(6) 0.0066(7)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C6 C1 C10 108.34(15)
C6 C1 C14 113.68(16)
C10 C1 C14 112.00(18)
C6 C1 H1 107.0(12)
C10 C1 H1 106.2(12)
C14 C1 H1 109.2(12)
O2 C2 O1 116.33(15)
O2 C2 C3 126.35(16)
O1 C2 C3 117.31(14)
C4 C3 C2 120.92(16)
C4 C3 H3 122.5(11)
C2 C3 H3 116.4(11)
C3 C4 C9 120.98(15)
C3 C4 C13 118.88(15)
C9 C4 C13 120.11(15)
C6 C5 C9 121.79(16)
C6 C5 H5 119.6(11)
C9 C5 H5 118.6(11)
C5 C6 C7 117.18(15)
C5 C6 C1 123.78(16)
C7 C6 C1 118.99(15)
N1 C7 N2 116.36(15)
N1 C7 C6 122.05(15)
N2 C7 C6 121.59(15)
N1 C8 O1 112.57(14)
N1 C8 C9 126.49(15)
O1 C8 C9 120.94(14)
C8 C9 C5 114.60(15)
C8 C9 C4 117.62(15)
C5 C9 C4 127.77(15)
C1 C10 C11 113.25(17)
C1 C10 H10A 111.8(12)
C11 C10 H10A 109.1(12)
C1 C10 H10B 109.7(11)
C11 C10 H10B 106.4(11)
H10A C10 H10B 106.3(17)
N2 C11 C15 111.58(17)
N2 C11 C10 109.87(15)
C15 C11 C10 110.87(18)
N2 C11 H11 108.0(12)
C15 C11 H11 108.1(12)
C10 C11 H11 108.3(12)
N2 C12 H12A 110.1(16)
N2 C12 H12B 110(2)
H12A C12 H12B 113(3)
N2 C12 H12C 108(2)
H12A C12 H12C 105(2)
H12B C12 H12C 110(3)
F1 C13 F3 106.80(15)
F1 C13 F2 106.87(15)
F3 C13 F2 106.39(15)
F1 C13 C4 113.30(15)
F3 C13 C4 112.38(15)
F2 C13 C4 110.70(15)
C1 C14 H14A 111.6(14)
C1 C14 H14B 112.3(14)
H14A C14 H14B 105.8(19)
C1 C14 H14C 106.5(17)
H14A C14 H14C 106(2)
H14B C14 H14C 114(2)
C11 C15 H15A 108.2(15)
C11 C15 H15B 112.9(14)
H15A C15 H15B 109(2)
C11 C15 H15C 108.6(13)
H15A C15 H15C 110(2)
H15B C15 H15C 108.1(19)
C8 N1 C7 117.77(14)
C7 N2 C12 119.01(16)
C7 N2 C11 122.92(15)
C12 N2 C11 116.87(16)
C8 O1 C2 122.22(13)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C6 C7 1.433(2)
C7 N1 1.343(2)
C8 N1 1.314(2)
C8 C9 1.391(2)
C5 C9 1.416(2)
C5 C6 1.366(2)
C8 O1 1.377(2)
C2 O1 1.3820(19)
C2 C3 1.435(2)
C3 C4 1.354(2)
C4 C9 1.434(2)
C2 O2 1.215(2)
C7 N2 1.356(2)
C1 C6 1.513(2)
C1 C10 1.514(3)
C1 C14 1.518(3)
C1 H1 1.05(2)
C3 H3 0.954(19)
C4 C13 1.502(2)
C5 H5 0.936(19)
C10 C11 1.519(3)
C10 H10A 0.96(2)
C10 H10B 1.04(2)
C11 N2 1.475(2)
C11 C15 1.517(3)
C11 H11 1.03(2)
C12 N2 1.464(3)
C12 H12A 1.01(3)
C12 H12B 0.96(4)
C12 H12C 0.91(3)
C13 F1 1.326(2)
C13 F3 1.332(2)
C13 F2 1.343(2)
C14 H14A 0.99(3)
C14 H14B 0.97(2)
C14 H14C 1.03(3)
C15 H15A 0.98(3)
C15 H15B 1.00(3)
C15 H15C 1.07(3)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C6 C7 N2 C11 -1.4(3)
N1 C7 N2 C12 11.7(3)
O2 C2 C3 C4 -177.94(17)
O1 C2 C3 C4 0.8(2)
C2 C3 C4 C9 -0.5(3)
C2 C3 C4 C13 177.75(16)
C9 C5 C6 C7 -2.2(2)
C9 C5 C6 C1 175.43(17)
C10 C1 C6 C5 149.84(17)
C14 C1 C6 C5 24.6(3)
C10 C1 C6 C7 -32.5(2)
C14 C1 C6 C7 -157.71(18)
C5 C6 C7 N1 3.8(2)
C1 C6 C7 N1 -174.01(16)
C5 C6 C7 N2 -175.99(15)
C1 C6 C7 N2 6.2(3)
N1 C8 C9 C5 2.4(2)
O1 C8 C9 C5 -178.35(14)
N1 C8 C9 C4 -178.67(15)
O1 C8 C9 C4 0.6(2)
C6 C5 C9 C8 -0.6(2)
C6 C5 C9 C4 -179.36(16)
C3 C4 C9 C8 -0.1(2)
C13 C4 C9 C8 -178.40(15)
C3 C4 C9 C5 178.59(16)
C13 C4 C9 C5 0.3(3)
C6 C1 C10 C11 55.8(2)
C14 C1 C10 C11 -178.04(17)
C1 C10 C11 N2 -51.8(2)
C1 C10 C11 C15 -175.60(18)
C3 C4 C13 F1 6.6(2)
C9 C4 C13 F1 -175.14(15)
C3 C4 C13 F3 127.75(17)
C9 C4 C13 F3 -54.0(2)
C3 C4 C13 F2 -113.45(18)
C9 C4 C13 F2 64.8(2)
O1 C8 N1 C7 179.68(14)
C9 C8 N1 C7 -1.0(2)
N2 C7 N1 C8 177.59(14)
C6 C7 N1 C8 -2.2(2)
C6 C7 N2 C12 -168.50(19)
N1 C7 N2 C11 178.78(16)
C15 C11 N2 C7 147.17(18)
C10 C11 N2 C7 23.8(2)
C15 C11 N2 C12 -45.5(3)
C10 C11 N2 C12 -168.90(19)
N1 C8 O1 C2 179.03(14)
C9 C8 O1 C2 -0.3(2)
O2 C2 O1 C8 178.48(15)
C3 C2 O1 C8 -0.4(2)
_cod_database_fobs_code 2104987
_journal_paper_doi 10.1107/S0108768111037311