#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:53:41 +0000 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/52/2105243.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2105243
loop_
_publ_author_name
'Briggs, Naomi E. B.'
'Kennedy, Alan R.'
'Morrison, Catriona A.'
_publ_section_title
;
 42 salt forms of tyramine: structural comparison and the occurrence of
 hydrate formation
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              453
_journal_page_last               464
_journal_paper_doi               10.1107/S0108768112026456
_journal_volume                  68
_journal_year                    2012
_chemical_formula_sum            'C20 H32 N2 O9'
_chemical_formula_weight         444.48
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.160(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.8909(6)
_cell_length_b                   7.7956(4)
_cell_length_c                   11.9547(6)
_cell_measurement_reflns_used    4105
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      29.0713
_cell_measurement_theta_min      3.1282
_cell_volume                     1090.78(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Diffraction Gemini S'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0203
_diffrn_reflns_av_sigmaI/netI    0.0366
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7124
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.13
_exptl_absorpt_coefficient_mu    0.107
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.84028
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.353
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             476
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.157
_refine_diff_density_min         -0.206
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   1.9(10)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.964
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     340
_refine_ls_number_reflns         4027
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.964
_refine_ls_R_factor_all          0.0446
_refine_ls_R_factor_gt           0.0339
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0444P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0740
_refine_ls_wR_factor_ref         0.0769
_reflns_number_gt                3280
_reflns_number_total             4027
_reflns_threshold_expression     I>2/s(I)
_cod_data_source_file            ry5045.cif
_cod_data_source_block           tyrlmal
_cod_original_sg_symbol_H-M      P21
_cod_database_code               2105243
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_disorder_assembly
_atom_site_disorder_group
O O1 1.29514(14) 1.1782(2) 1.25471(12) 0.0325(4) Uani d . 1 1 . .
O O2 0.79534(15) 1.0576(2) 0.24675(11) 0.0334(4) Uani d . 1 1 . .
O O1W 0.89938(15) 0.8500(2) 0.81188(13) 0.0337(4) Uani d . 1 1 . .
O O3 1.43407(12) 1.0900(2) 1.05206(12) 0.0319(4) Uani d . 1 1 . .
O O2W 0.59796(15) 0.8958(2) 0.18607(13) 0.0333(4) Uani d . 1 1 . .
O O4 1.28497(12) 1.1747(2) 0.92678(14) 0.0369(4) Uani d . 1 1 . .
O O6 1.21169(13) 0.5362(2) 1.04839(15) 0.0408(4) Uani d . 1 1 A .
O O7 1.05549(11) 0.6710(2) 0.96627(11) 0.0279(3) Uani d . 1 1 A .
N N1 1.56306(16) 0.9568(3) 1.88411(15) 0.0255(4) Uani d . 1 1 . .
N N2 1.06840(17) 1.2926(3) 0.86934(16) 0.0265(4) Uani d . 1 1 . .
C C1 1.38643(17) 0.9926(3) 1.58497(16) 0.0241(5) Uani d . 1 1 . .
C C2 1.29444(17) 1.1022(3) 1.55718(17) 0.0257(5) Uani d . 1 1 . .
H H2 1.2529 1.1355 1.6146 0.031 Uiso calc R 1 1 . .
C C3 1.26099(18) 1.1650(3) 1.44769(16) 0.0256(5) Uani d . 1 1 . .
H H3 1.1968 1.2391 1.4302 0.031 Uiso calc R 1 1 . .
C C4 1.32228(17) 1.1184(3) 1.36441(16) 0.0243(5) Uani d . 1 1 . .
C C5 1.41515(18) 1.0097(3) 1.39057(18) 0.0289(5) Uani d . 1 1 . .
H H5 1.4575 0.9781 1.3334 0.035 Uiso calc R 1 1 . .
C C6 1.44633(18) 0.9472(3) 1.49963(18) 0.0291(5) Uani d . 1 1 . .
H H6 1.5098 0.8718 1.5166 0.035 Uiso calc R 1 1 . .
C C7 1.42138(18) 0.9276(3) 1.70531(16) 0.0294(5) Uani d . 1 1 . .
H H7A 1.4314 0.8016 1.7041 0.035 Uiso calc R 1 1 . .
H H7B 1.3602 0.9531 1.7492 0.035 Uiso calc R 1 1 . .
C C8 1.53245(16) 1.0110(3) 1.76322(16) 0.0248(5) Uani d . 1 1 . .
H H8A 1.5948 0.9787 1.7223 0.030 Uiso calc R 1 1 . .
H H8B 1.5241 1.1373 1.7595 0.030 Uiso calc R 1 1 . .
C C9 0.88340(17) 1.2552(3) 0.57380(16) 0.0243(5) Uani d . 1 1 . .
C C10 0.94259(18) 1.3004(3) 0.48804(18) 0.0266(5) Uani d . 1 1 . .
H H10 1.0051 1.3776 0.5045 0.032 Uiso calc R 1 1 . .
C C11 0.91278(18) 1.2358(3) 0.37954(17) 0.0279(5) Uani d . 1 1 . .
H H11 0.9543 1.2688 0.3220 0.034 Uiso calc R 1 1 . .
C C12 0.82169(17) 1.1224(3) 0.35480(16) 0.0245(5) Uani d . 1 1 . .
C C13 0.76022(18) 1.0781(3) 0.43846(16) 0.0258(5) Uani d . 1 1 . .
H H13 0.6965 1.0032 0.4214 0.031 Uiso calc R 1 1 . .
C C14 0.79190(17) 1.1433(3) 0.54726(17) 0.0259(5) Uani d . 1 1 . .
H H14 0.7502 1.1108 0.6047 0.031 Uiso calc R 1 1 . .
C C15 0.92083(17) 1.3202(3) 0.69424(15) 0.0259(5) Uani d . 1 1 . .
H H15A 0.9342 1.4454 0.6928 0.031 Uiso calc R 1 1 . .
H H15B 0.8595 1.2990 0.7388 0.031 Uiso calc R 1 1 . .
C C16 1.02848(17) 1.2315(3) 0.75029(15) 0.0268(5) Uani d . 1 1 . .
H H16A 1.0146 1.1063 0.7513 0.032 Uiso calc R 1 1 . .
H H16B 1.0893 1.2523 0.7050 0.032 Uiso calc R 1 1 . .
C C17 1.33061(19) 1.0783(3) 1.00698(18) 0.0272(5) Uani d . 1 1 A .
C C18 1.25508(19) 0.9420(3) 1.04364(19) 0.0287(5) Uani d . 1 1 . .
H H18A 1.1796 0.9638 1.0539 0.034 Uiso d R 1 1 A .
H H18B 1.2758 0.9251 1.1015 0.034 Uiso d PR 0.619(3) 1 . .
C C19 1.23611(18) 0.8018(3) 0.95533(18) 0.0290(5) Uani d . 1 1 A .
H H19A 1.1949 0.8324 0.8778 0.035 Uiso d R 1 1 . .
H H19B 1.3257 0.8094 0.9419 0.035 Uiso d PR 0.381(3) 1 . .
C C20 1.16293(18) 0.6587(3) 0.99285(17) 0.0252(5) Uani d . 1 1 . .
O O5A 1.34537(16) 0.7460(2) 0.94847(17) 0.0256(6) Uani d P 0.619(3) 1 A 1
H H5AH 1.3420 0.6739 0.8958 0.038 Uiso calc PR 0.619(3) 1 A 1
O O5B 1.3060(3) 0.8574(4) 1.1390(3) 0.0289(11) Uani d P 0.381(3) 1 A 2
H H5BH 1.3197 0.9268 1.1934 0.043 Uiso calc PR 0.381(3) 1 A 2
H H5N 1.153(2) 1.243(4) 0.901(2) 0.069(8) Uiso d . 1 1 . .
H H3N 1.6398(18) 0.995(3) 1.9136(16) 0.030(6) Uiso d . 1 1 . .
H H6N 1.0743(19) 1.413(4) 0.8703(19) 0.044(7) Uiso d . 1 1 . .
H H4N 1.0201(17) 1.244(3) 0.9188(17) 0.031(6) Uiso d . 1 1 . .
H H1N 1.5589(19) 0.845(4) 1.8947(19) 0.040(7) Uiso d . 1 1 . .
H H2N 1.516(2) 1.011(4) 1.935(2) 0.072(10) Uiso d . 1 1 . .
H H1W 0.9528(18) 0.799(3) 0.8560(16) 0.022(6) Uiso d . 1 1 . .
H H2W 0.874(2) 0.910(4) 0.860(2) 0.044(8) Uiso d . 1 1 . .
H H2H 0.727(2) 0.989(4) 0.234(2) 0.078(11) Uiso d . 1 1 . .
H H1H 1.2316(16) 1.220(3) 1.2446(16) 0.020(6) Uiso d . 1 1 . .
H H3W 0.630(2) 0.811(4) 0.150(2) 0.066(10) Uiso d . 1 1 . .
H H4W 0.530(3) 0.954(5) 0.143(3) 0.120(14) Uiso d . 1 1 . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
O1 0.0329(9) 0.0401(10) 0.0248(8) 0.0009(9) 0.0055(7) 0.0027(8)
O2 0.0470(10) 0.0315(9) 0.0222(7) -0.0021(9) 0.0070(7) -0.0030(7)
O1W 0.0354(10) 0.0406(11) 0.0239(8) 0.0169(9) 0.0020(8) -0.0007(8)
O3 0.0225(8) 0.0283(8) 0.0431(8) 0.0027(7) 0.0009(6) -0.0020(7)
O2W 0.0292(10) 0.0409(11) 0.0289(8) 0.0074(9) 0.0024(7) -0.0068(9)
O4 0.0222(8) 0.0334(9) 0.0543(9) -0.0010(7) 0.0041(7) 0.0184(8)
O6 0.0235(8) 0.0388(9) 0.0586(10) -0.0002(8) 0.0027(7) 0.0269(8)
O7 0.0193(7) 0.0325(8) 0.0315(7) 0.0031(7) 0.0034(6) 0.0028(7)
N1 0.0206(10) 0.0235(11) 0.0306(10) 0.0003(9) -0.0005(8) 0.0000(9)
N2 0.0234(10) 0.0283(12) 0.0269(10) -0.0027(9) 0.0018(8) 0.0037(8)
C1 0.0203(11) 0.0252(12) 0.0260(10) -0.0058(10) 0.0018(8) -0.0037(9)
C2 0.0236(11) 0.0328(13) 0.0213(9) 0.0001(11) 0.0057(9) -0.0049(10)
C3 0.0240(11) 0.0240(11) 0.0286(11) 0.0011(11) 0.0035(9) -0.0057(10)
C4 0.0272(12) 0.0225(12) 0.0232(10) -0.0099(10) 0.0042(9) -0.0025(9)
C5 0.0284(12) 0.0294(13) 0.0318(11) 0.0020(12) 0.0133(10) -0.0040(11)
C6 0.0246(12) 0.0265(12) 0.0364(12) 0.0040(10) 0.0062(10) 0.0019(11)
C7 0.0267(13) 0.0325(14) 0.0278(10) -0.0010(11) 0.0013(9) 0.0052(10)
C8 0.0201(11) 0.0250(12) 0.0291(10) -0.0004(10) 0.0041(9) -0.0004(9)
C9 0.0258(11) 0.0238(12) 0.0236(10) 0.0057(11) 0.0049(9) -0.0019(9)
C10 0.0251(11) 0.0230(11) 0.0323(11) 0.0002(10) 0.0068(10) 0.0007(10)
C11 0.0345(13) 0.0256(12) 0.0268(10) 0.0024(12) 0.0140(9) 0.0028(10)
C12 0.0313(12) 0.0195(12) 0.0228(10) 0.0033(10) 0.0050(9) 0.0003(9)
C13 0.0238(11) 0.0261(12) 0.0276(10) 0.0010(10) 0.0045(9) 0.0005(10)
C14 0.0235(11) 0.0288(13) 0.0266(10) 0.0050(11) 0.0074(9) 0.0042(10)
C15 0.0222(11) 0.0293(13) 0.0261(10) 0.0047(10) 0.0042(9) -0.0011(10)
C16 0.0290(12) 0.0306(13) 0.0203(10) 0.0014(11) 0.0030(8) -0.0006(9)
C17 0.0216(12) 0.0206(12) 0.0388(12) 0.0022(10) 0.0042(10) -0.0004(11)
C18 0.0278(13) 0.0265(13) 0.0315(11) -0.0004(11) 0.0047(10) 0.0076(11)
C19 0.0250(12) 0.0350(13) 0.0254(11) -0.0037(11) -0.0002(9) 0.0027(11)
C20 0.0238(12) 0.0257(12) 0.0260(11) -0.0005(11) 0.0040(9) 0.0026(11)
O5A 0.0276(12) 0.0199(11) 0.0323(12) 0.0064(9) 0.0132(9) -0.0030(9)
O5B 0.040(2) 0.0237(19) 0.0211(18) -0.0038(16) -0.0005(16) -0.0004(14)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C4 O1 H1H 109.5(14)
C12 O2 H2H 113.7(16)
H1W O1W H2W 99(2)
H3W O2W H4W 118(2)
C8 N1 H3N 108.8(12)
C8 N1 H1N 114.2(15)
H3N N1 H1N 109(2)
C8 N1 H2N 114.0(16)
H3N N1 H2N 104(2)
H1N N1 H2N 106(2)
C16 N2 H5N 109.6(14)
C16 N2 H6N 109.8(14)
H5N N2 H6N 107(2)
C16 N2 H4N 109.4(12)
H5N N2 H4N 105.4(18)
H6N N2 H4N 116(2)
C2 C1 C6 117.89(19)
C2 C1 C7 120.59(19)
C6 C1 C7 121.5(2)
C1 C2 C3 121.9(2)
C1 C2 H2 119.1
C3 C2 H2 119.1
C4 C3 C2 119.1(2)
C4 C3 H3 120.4
C2 C3 H3 120.4
O1 C4 C3 122.2(2)
O1 C4 C5 117.83(18)
C3 C4 C5 119.97(18)
C6 C5 C4 120.0(2)
C6 C5 H5 120.0
C4 C5 H5 120.0
C5 C6 C1 121.1(2)
C5 C6 H6 119.4
C1 C6 H6 119.4
C1 C7 C8 111.08(17)
C1 C7 H7A 109.4
C8 C7 H7A 109.4
C1 C7 H7B 109.4
C8 C7 H7B 109.4
H7A C7 H7B 108.0
N1 C8 C7 111.34(17)
N1 C8 H8A 109.4
C7 C8 H8A 109.4
N1 C8 H8B 109.4
C7 C8 H8B 109.4
H8A C8 H8B 108.0
C14 C9 C10 118.05(18)
C14 C9 C15 120.94(19)
C10 C9 C15 121.0(2)
C11 C10 C9 121.5(2)
C11 C10 H10 119.2
C9 C10 H10 119.2
C10 C11 C12 119.6(2)
C10 C11 H11 120.2
C12 C11 H11 120.2
O2 C12 C13 121.8(2)
O2 C12 C11 118.37(19)
C13 C12 C11 119.79(19)
C12 C13 C14 119.8(2)
C12 C13 H13 120.1
C14 C13 H13 120.1
C13 C14 C9 121.21(19)
C13 C14 H14 119.4
C9 C14 H14 119.4
C16 C15 C9 110.70(16)
C16 C15 H15A 109.5
C9 C15 H15A 109.5
C16 C15 H15B 109.5
C9 C15 H15B 109.5
H15A C15 H15B 108.1
N2 C16 C15 112.31(18)
N2 C16 H16A 109.1
C15 C16 H16A 109.1
N2 C16 H16B 109.1
C15 C16 H16B 109.1
H16A C16 H16B 107.9
O3 C17 O4 122.7(2)
O3 C17 C18 121.1(2)
O4 C17 C18 116.25(19)
O5B C18 C17 112.6(2)
O5B C18 C19 102.96(19)
C17 C18 C19 109.31(16)
O5B C18 H18A 105.8
C17 C18 H18A 122.8
C19 C18 H18A 101.1
O5B C18 H18B 20.2
C17 C18 H18B 107.2
C19 C18 H18B 122.3
H18A C18 H18B 94.7
O5A C19 C18 104.04(16)
O5A C19 C20 112.09(19)
C18 C19 C20 110.22(15)
O5A C19 H19A 109.4
C18 C19 H19A 117.7
C20 C19 H19A 103.6
O5A C19 H19B 21.9
C18 C19 H19B 91.9
C20 C19 H19B 133.9
H19A C19 H19B 100.3
O6 C20 O7 123.2(2)
O6 C20 C19 118.67(19)
O7 C20 C19 118.2(2)
C19 O5A H19B 49.0
C19 O5A H5AH 109.5
H19B O5A H5AH 122.4
C18 O5B H18B 19.1
C18 O5B H5BH 109.5
H18B O5B H5BH 91.0
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O1 C4 1.375(2)
O1 H1H 0.814(19)
O2 C12 1.371(2)
O2 H2H 0.97(3)
O1W H1W 0.85(2)
O1W H2W 0.84(3)
O3 C17 1.256(3)
O2W H3W 0.91(3)
O2W H4W 0.99(4)
O4 C17 1.263(3)
O6 C20 1.246(3)
O7 C20 1.265(2)
N1 C8 1.488(3)
N1 H3N 0.96(2)
N1 H1N 0.88(3)
N1 H2N 0.99(3)
N2 C16 1.496(3)
N2 H5N 1.08(3)
N2 H6N 0.94(3)
N2 H4N 0.97(2)
C1 C2 1.382(3)
C1 C6 1.389(3)
C1 C7 1.513(3)
C2 C3 1.389(3)
C2 H2 0.9500
C3 C4 1.382(3)
C3 H3 0.9500
C4 C5 1.383(3)
C5 C6 1.380(3)
C5 H5 0.9500
C6 H6 0.9500
C7 C8 1.524(3)
C7 H7A 0.9900
C7 H7B 0.9900
C8 H8A 0.9900
C8 H8B 0.9900
C9 C14 1.387(3)
C9 C10 1.388(3)
C9 C15 1.517(3)
C10 C11 1.378(3)
C10 H10 0.9500
C11 C12 1.389(3)
C11 H11 0.9500
C12 C13 1.383(3)
C13 C14 1.385(3)
C13 H13 0.9500
C14 H14 0.9500
C15 C16 1.504(3)
C15 H15A 0.9900
C15 H15B 0.9900
C16 H16A 0.9900
C16 H16B 0.9900
C17 C18 1.505(3)
C18 O5B 1.363(4)
C18 C19 1.509(2)
C18 H18A 0.9427
C18 H18B 0.7042
C19 O5A 1.386(3)
C19 C20 1.530(3)
C19 H19A 0.9977
C19 H19B 1.1071
O5A H19B 0.5464
O5A H5AH 0.8400
O5B H18B 0.7427
O5B H5BH 0.8400
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C6 C1 C2 C3 0.6(3)
C7 C1 C2 C3 179.5(2)
C1 C2 C3 C4 -0.8(3)
C2 C3 C4 O1 -178.85(19)
C2 C3 C4 C5 0.4(3)
O1 C4 C5 C6 179.6(2)
C3 C4 C5 C6 0.3(3)
C4 C5 C6 C1 -0.6(4)
C2 C1 C6 C5 0.1(3)
C7 C1 C6 C5 -178.8(2)
C2 C1 C7 C8 -108.0(2)
C6 C1 C7 C8 70.8(3)
C1 C7 C8 N1 176.06(19)
C14 C9 C10 C11 -0.5(3)
C15 C9 C10 C11 176.9(2)
C9 C10 C11 C12 -0.2(3)
C10 C11 C12 O2 -178.7(2)
C10 C11 C12 C13 1.4(3)
O2 C12 C13 C14 178.30(19)
C11 C12 C13 C14 -1.8(3)
C12 C13 C14 C9 1.1(3)
C10 C9 C14 C13 0.0(3)
C15 C9 C14 C13 -177.4(2)
C14 C9 C15 C16 104.6(2)
C10 C9 C15 C16 -72.7(3)
C9 C15 C16 N2 179.8(2)
O3 C17 C18 O5B 9.7(3)
O4 C17 C18 O5B -172.5(2)
O3 C17 C18 C19 -104.1(2)
O4 C17 C18 C19 73.7(2)
O5B C18 C19 O5A -62.3(2)
C17 C18 C19 O5A 57.66(19)
O5B C18 C19 C20 58.1(2)
C17 C18 C19 C20 178.0(2)
O5A C19 C20 O6 24.1(3)
C18 C19 C20 O6 -91.3(2)
O5A C19 C20 O7 -156.21(19)
C18 C19 C20 O7 88.4(2)