#------------------------------------------------------------------------------
#$Date: 2010-01-30 13:59:17 +0000 (Sat, 30 Jan 2010) $
#$Revision: 966 $
#$URL: svn://www.crystallography.net/cod/cif/2/2200381.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2200381
_journal_name_full  'Acta Crystallographica, Section E'
_journal_year  2001
_journal_volume  57
_journal_page_first  i55
_journal_page_last  i56
_publ_section_title
;
The new ternary compound Ce~2~Rh~15~Si~7~
;
loop_
_publ_author_name
  'Tursina, Anna I.'
  'Gribanov, Alexandr V.'
  'Seropegin, Yuri D.'
_chemical_formula_moiety  'Ce2 Rh15 Si7'
_chemical_formula_sum  'Ce2 Rh15 Si7'
_chemical_formula_iupac  'Ce2 Rh15 Si7'
_chemical_formula_weight  2020.52
_symmetry_cell_setting  cubic
_symmetry_space_group_name_H-M  'P m -3 m'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  'x, -y, -z'
  '-x, -y, z'
  '-x, y, -z'
  '-y, x, z'
  'y, x, -z'
  'y, -x, z'
  '-y, -x, -z'
  'y, z, x'
  '-y, -z, x'
  'y, -z, -x'
  '-y, z, -x'
  '-z, y, x'
  '-z, -y, -x'
  'z, -y, x'
  'z, y, -x'
  'z, x, y'
  '-z, x, -y'
  '-z, -x, y'
  'z, -x, -y'
  '-x, -z, -y'
  '-x, z, y'
  'x, -z, y'
  'x, z, -y'
  '-x, -y, -z'
  '-x, y, z'
  'x, y, -z'
  'x, -y, z'
  'y, -x, -z'
  '-y, -x, z'
  '-y, x, -z'
  'y, x, z'
  '-y, -z, -x'
  'y, z, -x'
  '-y, z, x'
  'y, -z, x'
  'z, -y, -x'
  'z, y, x'
  '-z, y, -x'
  '-z, -y, x'
  '-z, -x, -y'
  'z, -x, y'
  'z, x, -y'
  '-z, x, y'
  'x, z, y'
  'x, -z, -y'
  '-x, z, -y'
  '-x, -z, y'
_cell_length_a  8.8180(10)
_cell_length_b  8.8180(10)
_cell_length_c  8.8180(10)
_cell_angle_alpha  90.00
_cell_angle_beta  90.00
_cell_angle_gamma  90.00
_cell_volume  685.66(13)
_cell_formula_units_Z  2
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  9.787
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ce1  .5000  .5000  .5000  .0135(8) Uani d S 1 . . Ce
  Ce2  .5000  .0000  .0000  .0154(6) Uani d S 1 . . Ce
  Rh3  .2241(3)  .0000  .0000  .0137(5) Uani d S 1 . . Rh
  Rh4  .26211(14)  .26211(14)  .5000  .0127(4) Uani d S 1 . . Rh
  Rh5  .32339(14)  .32339(14)  .0000  .0133(4) Uani d S 1 . . Rh
  Si6  .1345(11)  .5000  .5000  .0147(16) Uani d S 1 . . Si
  Si7  .2130(6)  .2130(6)  .2130(6)  .0147(13) Uani d S 1 . . Si
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ce1  .0135(8)  .0135(8)  .0135(8)  .000  .000  .000
  Ce2  .0144(11)  .0159(8)  .0159(8)  .000  .000  .000
  Rh3  .0119(10)  .0146(6)  .0146(6)  .000  .000  .000
  Rh4  .0129(5)  .0129(5)  .0123(7)  .0014(5)  .000  .000
  Rh5  .0140(5)  .0140(5)  .0119(7)  -.0022(6)  .000  .000
  Si6  .010(3)  .017(2)  .017(2)  .000  .000  .000
  Si7  .0147(13)  .0147(13)  .0147(13)  .0019(16)  .0019(16)  .0019(16)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ce1 Rh4 37_566 2.9666(18) ?
  Ce1 Rh4 . 2.9666(18) ?
  Ce1 Rh4 13_655 2.9666(18) ?
  Ce1 Rh4 25_666 2.9666(18) ?
  Ce1 Rh4 33_666 2.9666(18) ?
  Ce1 Rh4 9 2.9666(18) ?
  Ce1 Rh4 39_656 2.9666(18) ?
  Ce1 Rh4 26_655 2.9666(18) ?
  Ce1 Rh4 10_665 2.9666(18) ?
  Ce1 Rh4 15_565 2.9666(18) ?
  Ce1 Rh4 34_556 2.9666(18) ?
  Ce1 Rh4 2_566 2.9666(18) ?
  Ce2 Rh3 25_655 2.433(3) ?
  Ce2 Rh3 . 2.433(3) ?
  Ce2 Rh5 10_655 3.2492(6) ?
  Ce2 Rh5 26_655 3.2492(6) ?
  Ce2 Rh5 34 3.2492(6) ?
  Ce2 Rh5 2 3.2492(6) ?
  Ce2 Rh5 . 3.2492(6) ?
  Ce2 Rh5 33_655 3.2492(6) ?
  Ce2 Rh5 25_655 3.2492(6) ?
  Ce2 Rh5 9 3.2492(6) ?
  Ce2 Rh4 37 3.2687(18) ?
  Ce2 Rh4 13_655 3.2687(18) ?
  Rh3 Si7 2 2.658(7) ?
  Rh3 Si7 . 2.658(7) ?
  Rh3 Si7 28 2.658(7) ?
  Rh3 Si7 27 2.658(7) ?
  Rh3 Rh3 29 2.794(4) ?
  Rh3 Rh3 33 2.794(4) ?
  Rh3 Rh3 5 2.794(4) ?
  Rh3 Rh3 9 2.794(4) ?
  Rh3 Rh5 9 2.9831(18) ?
  Rh3 Rh5 . 2.9831(18) ?
  Rh3 Rh5 2 2.9831(18) ?
  Rh4 Si6 5_655 2.380(4) ?
  Rh4 Si6 . 2.380(4) ?
  Rh4 Si7 . 2.604(7) ?
  Rh4 Si7 27_556 2.604(7) ?
  Rh4 Rh5 9 2.8389(9) ?
  Rh4 Rh5 13 2.8389(9) ?
  Rh4 Rh5 34_556 2.8389(9) ?
  Rh4 Rh5 39_556 2.8389(9) ?
  Rh4 Rh4 39_656 2.9666(18) ?
  Rh4 Rh4 34_556 2.9666(18) ?
  Rh4 Rh4 13_655 2.9666(18) ?
  Rh5 Si7 27 2.3287(10) ?
  Rh5 Si7 . 2.3287(10) ?
  Rh5 Si6 9 2.501(5) ?
  Rh5 Si6 33_665 2.501(5) ?
  Rh5 Rh4 13_655 2.8389(9) ?
  Rh5 Rh4 9 2.8389(9) ?
  Rh5 Rh4 39_655 2.8389(9) ?
  Rh5 Rh4 34 2.8389(9) ?
  Rh5 Rh3 5 2.9831(18) ?
  Rh5 Rh5 2_565 3.115(2) ?
  Rh5 Rh5 26_655 3.115(2) ?
  Si6 Si6 25_566 2.372(19) ?
  Si6 Rh4 34_556 2.380(4) ?
  Si6 Rh4 2_566 2.380(4) ?
  Si6 Rh4 9 2.380(4) ?
  Si6 Rh5 13 2.501(5) ?
  Si6 Rh5 37_566 2.501(5) ?
  Si6 Rh5 39_556 2.501(5) ?
  Si6 Rh5 15_565 2.501(5) ?
  Si7 Rh5 9 2.3287(10) ?
  Si7 Rh5 13 2.3287(10) ?
  Si7 Rh4 13_655 2.604(7) ?
  Si7 Rh4 9 2.604(7) ?
  Si7 Rh3 9 2.658(7) ?
  Si7 Rh3 5 2.658(7) ?
_cod_database_code 2200381