data_2202582
_journal_name_full  'Acta Crystallographica, Section E'
_journal_year  2003
_journal_volume  59
_journal_page_first  m906
_journal_page_last  m907
_publ_section_title
;
1,2-diaminoethanesilver(I) hexafluoroarsenate
;
loop_
_publ_author_name
  'Zhu, Hai-Liang'
  'Sun, Zhi-Yuan'
  'Rong, Na-Na'
  'Zhang, Biao'
  'Zhang, Min'
  'Li, Yong'
_chemical_formula_moiety  'C2 H8 Ag N2+, As F6-'
_chemical_formula_sum  'C2 H8 Ag As F6 N2'
_chemical_formula_iupac  '[Ag(C2 H8 N2)]AsF~6~'
_chemical_formula_weight  356.89
_symmetry_cell_setting  orthorhombic
_symmetry_space_group_name_H-M  'P n m a'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x+1/2, -y, z+1/2'
  '-x, y+1/2, -z'
  'x+1/2, -y+1/2, -z+1/2'
  '-x, -y, -z'
  'x-1/2, y, -z-1/2'
  'x, -y-1/2, z'
  '-x-1/2, y-1/2, z-1/2'
_cell_length_a  10.098(2)
_cell_length_b  10.477(2)
_cell_length_c  8.220(2)
_cell_angle_alpha  90.00
_cell_angle_beta  90.00
_cell_angle_gamma  90.00
_cell_volume  869.6(3)
_cell_formula_units_Z  4
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  2.726
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ag1 0.15803(7) 0.2500 0.09525(9) 0.0615(4) Uani d S 1 . . Ag
  As1 0.02978(9) 0.2500 0.55262(11) 0.0510(4) Uani d S 1 . . As
  F1 -0.0808(11) 0.3564(8) 0.6174(11) 0.162(3) Uani d . 1 . . F
  F2 0.1357(7) 0.3557(9) 0.4783(14) 0.178(4) Uani d . 1 . . F
  F3 -0.0514(7) 0.2500 0.3715(9) 0.129(4) Uani d S 1 . . F
  F4 0.1069(12) 0.2500 0.7323(13) 0.182(6) Uani d S 1 . . F
  N1 0.1579(5) 0.4559(6) 0.1025(7) 0.0619(15) Uani d . 1 . . N
  H1C 0.2411 0.4823 0.0824 0.080 Uiso d R 1 . . H
  H1D 0.1380 0.4796 0.2049 0.080 Uiso d R 1 . . H
  C1 0.0705(6) 0.5238(6) -0.0074(9) 0.0602(15) Uani d . 1 . . C
  H1A 0.1010 0.5140 -0.1173 0.080 Uiso d R 1 . . H
  H1B 0.0717 0.6131 0.0186 0.080 Uiso d R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ag1 0.0560(5) 0.0618(5) 0.0666(6) 0.000 0.0015(3) 0.000
  As1 0.0558(6) 0.0487(6) 0.0486(6) 0.000 -0.0008(4) 0.000
  F1 0.173(8) 0.163(8) 0.149(6) 0.067(6) 0.015(5) -0.053(6)
  F2 0.148(6) 0.202(8) 0.185(7) -0.121(6) -0.014(6) 0.044(7)
  F3 0.065(4) 0.258(13) 0.065(4) 0.000 -0.007(3) 0.000
  F4 0.133(9) 0.33(2) 0.081(6) 0.000 -0.045(6) 0.000
  N1 0.060(3) 0.058(3) 0.068(4) -0.007(2) -0.001(3) -0.006(3)
  C1 0.053(3) 0.062(4) 0.065(4) -0.006(3) 0.003(3) -0.002(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ag1 N1 7_565 2.158(6) ?
  Ag1 N1 . 2.158(6) ?
  As1 F2 . 1.656(6) ?
  As1 F2 7_565 1.656(6) ?
  As1 F1 7_565 1.665(7) ?
  As1 F1 . 1.665(7) ?
  As1 F4 . 1.669(9) ?
  As1 F3 . 1.700(7) ?
  N1 C1 . 1.449(8) ?
  N1 H1C . 0.9000 ?
  N1 H1D . 0.9000 ?
  C1 C1 5_565 1.514(12) ?
  C1 H1A . 0.9600 ?
  C1 H1B . 0.9600 ?