#------------------------------------------------------------------------------
#$Date: 2011-09-10 04:16:28 +0100 (Sat, 10 Sep 2011) $
#$Revision: 25271 $
#$URL: svn://www.crystallography.net/cod/cif/2/2206829.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2206829
loop_
_publ_author_name
'Chen, Guang'
'Zhao, Bin'
'Sun, Min'
'Qi, Wei'
_publ_section_title
;
 [<i>N</i>,<i>N</i>'-Bis(2-hydroxynaphthylmethylene)-1,2-ethanediaminato]zinc(II)
;
_journal_coeditor_code           YA6260
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1869
_journal_page_last               m1870
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Zn (C24 H18 N2 O2)]'
_chemical_formula_moiety         'C24 H18 N2 O2 Zn'
_chemical_formula_sum            'C24 H18 N2 O2 Zn'
_chemical_formula_weight         431.77
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.920(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.6810(10)
_cell_length_b                   8.1840(10)
_cell_length_c                   12.9570(10)
_cell_measurement_reflns_used    2849
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.9
_cell_measurement_theta_min      2.7
_cell_volume                     1846.9(3)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Sheldrick, 1997b)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997a)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997a)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.061
_diffrn_reflns_av_sigmaI/netI    0.066
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9152
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.3
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.354
_exptl_absorpt_correction_T_max  0.755
_exptl_absorpt_correction_T_min  0.663
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.553
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             888
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.64
_refine_diff_density_min         -0.40
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.01
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     262
_refine_ls_number_reflns         4153
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.01
_refine_ls_R_factor_all          0.072
_refine_ls_R_factor_gt           0.051
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0753P)^2^] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.127
_refine_ls_wR_factor_ref         0.137
_reflns_number_gt                3029
_reflns_number_total             4153
_reflns_threshold_expression     I>2\s(I)
_[local]_cod_data_source_file    ya6260.cif
_[local]_cod_data_source_block   I
_[local]_cod_cif_authors_sg_H-M  'P 21/c'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2206829
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Zn1 0.022954(19) 0.33477(4) 0.07297(3) 0.03501(15) Uani d . 1 Zn
O1 0.09689(11) 0.4212(3) 0.17690(15) 0.0333(5) Uani d . 1 O
O2 -0.04847(11) 0.4332(3) 0.14147(14) 0.0324(5) Uani d . 1 O
N1 0.09373(14) 0.2323(3) 0.00696(18) 0.0318(5) Uani d . 1 N
N2 -0.05060(14) 0.2595(3) -0.03401(18) 0.0300(5) Uani d . 1 N
C1 0.21010(18) 0.3180(4) 0.1207(2) 0.0334(7) Uani d . 1 C
C2 0.17118(17) 0.4107(4) 0.1863(2) 0.0328(7) Uani d . 1 C
C3 0.21539(18) 0.5026(4) 0.2698(2) 0.0398(7) Uani d . 1 C
H3 0.1902 0.5695 0.3110 0.048 Uiso calc R 1 H
C4 0.29259(19) 0.4941(4) 0.2898(3) 0.0449(8) Uani d . 1 C
H4 0.3194 0.5548 0.3449 0.054 Uiso calc R 1 H
C5 0.33438(19) 0.3949(5) 0.2290(3) 0.0445(8) Uani d . 1 C
C6 0.4156(2) 0.3808(6) 0.2523(3) 0.0608(11) Uani d . 1 C
H6 0.4424 0.4371 0.3095 0.073 Uiso calc R 1 H
C7 0.4547(2) 0.2885(6) 0.1941(4) 0.0714(13) Uani d . 1 C
H7 0.5079 0.2803 0.2112 0.086 Uiso calc R 1 H
C8 0.4150(2) 0.2051(5) 0.1079(4) 0.0633(11) Uani d . 1 C
H8 0.4421 0.1414 0.0672 0.076 Uiso calc R 1 H
C9 0.3373(2) 0.2154(5) 0.0822(3) 0.0509(9) Uani d . 1 C
H9 0.3123 0.1596 0.0236 0.061 Uiso calc R 1 H
C10 0.29369(18) 0.3085(4) 0.1422(3) 0.0388(7) Uani d . 1 C
C11 0.16768(18) 0.2337(4) 0.0334(2) 0.0347(7) Uani d . 1 C
H11 0.1956 0.1743 -0.0083 0.042 Uiso calc R 1 H
C12 0.05967(19) 0.1355(4) -0.0862(3) 0.0393(7) Uani d . 1 C
H12A 0.0558 0.0215 -0.0673 0.047 Uiso calc R 1 H
H12B 0.0916 0.1430 -0.1398 0.047 Uiso calc R 1 H
C13 -0.01894(18) 0.2038(4) -0.1267(2) 0.0378(7) Uani d . 1 C
H13A -0.0155 0.2945 -0.1738 0.045 Uiso calc R 1 H
H13B -0.0516 0.1203 -0.1643 0.045 Uiso calc R 1 H
C14 -0.12390(18) 0.2639(4) -0.0405(2) 0.0342(7) Uani d . 1 C
H14 -0.1533 0.2178 -0.0998 0.041 Uiso calc R 1 H
C15 -0.16416(18) 0.3333(3) 0.0351(2) 0.0313(6) Uani d . 1 C
C16 -0.12240(17) 0.4222(4) 0.1194(2) 0.0321(6) Uani d . 1 C
C17 -0.16514(18) 0.5123(4) 0.1856(2) 0.0384(7) Uani d . 1 C
H17 -0.1386 0.5729 0.2410 0.046 Uiso calc R 1 H
C18 -0.24248(19) 0.5110(4) 0.1694(3) 0.0466(8) Uani d . 1 C
H18 -0.2679 0.5728 0.2131 0.056 Uiso calc R 1 H
C19 -0.28649(19) 0.4178(4) 0.0873(3) 0.0452(8) Uani d . 1 C
C20 -0.3675(2) 0.4170(5) 0.0708(3) 0.0600(11) Uani d . 1 C
H20 -0.3928 0.4788 0.1145 0.072 Uiso calc R 1 H
C21 -0.4088(2) 0.3293(6) -0.0065(4) 0.0721(14) Uani d . 1 C
H21 -0.4622 0.3300 -0.0161 0.087 Uiso calc R 1 H
C22 -0.3710(2) 0.2374(6) -0.0722(3) 0.0614(11) Uani d . 1 C
H22 -0.3997 0.1767 -0.1259 0.074 Uiso calc R 1 H
C23 -0.2926(2) 0.2340(5) -0.0598(3) 0.0496(9) Uani d . 1 C
H23 -0.2688 0.1700 -0.1041 0.060 Uiso calc R 1 H
C24 -0.24742(18) 0.3271(4) 0.0200(3) 0.0372(7) Uani d . 1 C
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Zn1 0.0384(2) 0.0396(2) 0.0272(2) 0.00038(16) 0.00605(15) -0.00013(15)
O1 0.0340(11) 0.0419(12) 0.0236(10) 0.0007(9) 0.0038(8) -0.0029(9)
O2 0.0336(11) 0.0404(12) 0.0228(10) 0.0012(9) 0.0041(8) -0.0037(9)
N1 0.0410(14) 0.0326(13) 0.0226(12) 0.0007(11) 0.0080(10) 0.0000(11)
N2 0.0374(14) 0.0304(13) 0.0220(12) -0.0007(11) 0.0049(10) -0.0001(10)
C1 0.0357(16) 0.0351(16) 0.0301(16) 0.0000(13) 0.0069(12) 0.0066(13)
C2 0.0368(16) 0.0343(16) 0.0269(15) -0.0020(13) 0.0039(12) 0.0060(13)
C3 0.0465(19) 0.0407(18) 0.0320(17) -0.0055(15) 0.0060(14) -0.0034(14)
C4 0.0433(19) 0.050(2) 0.0388(18) -0.0114(16) 0.0004(14) -0.0026(16)
C5 0.0394(18) 0.046(2) 0.046(2) -0.0061(15) 0.0024(15) 0.0083(17)
C6 0.038(2) 0.073(3) 0.068(3) -0.0071(19) -0.0014(18) -0.002(2)
C7 0.0315(19) 0.082(3) 0.099(4) 0.003(2) 0.007(2) 0.001(3)
C8 0.042(2) 0.073(3) 0.077(3) 0.0123(19) 0.016(2) -0.001(2)
C9 0.043(2) 0.058(2) 0.053(2) 0.0048(17) 0.0122(17) 0.0010(19)
C10 0.0364(17) 0.0382(18) 0.0420(19) 0.0023(13) 0.0080(14) 0.0104(15)
C11 0.0400(17) 0.0374(17) 0.0286(16) 0.0048(14) 0.0116(13) 0.0027(13)
C12 0.0454(18) 0.0406(18) 0.0322(17) 0.0027(14) 0.0078(14) -0.0078(14)
C13 0.0485(19) 0.0433(19) 0.0213(15) -0.0043(14) 0.0057(13) -0.0070(13)
C14 0.0418(18) 0.0327(16) 0.0261(15) -0.0041(13) 0.0003(13) 0.0039(13)
C15 0.0364(16) 0.0292(15) 0.0279(15) 0.0001(12) 0.0043(12) 0.0053(12)
C16 0.0381(17) 0.0308(16) 0.0279(15) 0.0058(13) 0.0074(12) 0.0103(13)
C17 0.0434(18) 0.0383(18) 0.0342(17) 0.0073(14) 0.0084(13) -0.0004(14)
C18 0.0475(19) 0.045(2) 0.049(2) 0.0100(16) 0.0143(16) 0.0000(17)
C19 0.0374(18) 0.046(2) 0.053(2) 0.0054(15) 0.0111(15) 0.0129(17)
C20 0.043(2) 0.065(3) 0.074(3) 0.0098(19) 0.017(2) 0.011(2)
C21 0.0306(19) 0.081(3) 0.100(4) -0.002(2) 0.000(2) 0.019(3)
C22 0.047(2) 0.070(3) 0.064(3) -0.012(2) -0.0025(19) 0.003(2)
C23 0.0424(19) 0.055(2) 0.049(2) -0.0059(17) 0.0012(16) 0.0055(18)
C24 0.0379(17) 0.0372(17) 0.0350(17) -0.0015(13) 0.0027(13) 0.0100(14)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
N1 Zn1 N2 86.91(11) y
N1 Zn1 O1 93.49(10) y
N2 Zn1 O1 176.90(10) y
N1 Zn1 O2 178.54(10) y
N2 Zn1 O2 93.16(10) y
O1 Zn1 O2 86.52(9) y
C2 O1 Zn1 128.25(19) ?
C16 O2 Zn1 127.71(19) ?
C11 N1 C12 118.1(3) ?
C11 N1 Zn1 127.7(2) ?
C12 N1 Zn1 114.2(2) ?
C14 N2 C13 118.3(3) ?
C14 N2 Zn1 128.0(2) ?
C13 N2 Zn1 113.44(19) ?
C2 C1 C11 119.8(3) ?
C2 C1 C10 120.0(3) ?
C11 C1 C10 120.2(3) ?
O1 C2 C1 124.8(3) ?
O1 C2 C3 116.5(3) ?
C1 C2 C3 118.7(3) ?
C4 C3 C2 121.4(3) ?
C4 C3 H3 119.3 ?
C2 C3 H3 119.3 ?
C3 C4 C5 121.9(3) ?
C3 C4 H4 119.0 ?
C5 C4 H4 119.0 ?
C10 C5 C6 119.0(4) ?
C10 C5 C4 118.9(3) ?
C6 C5 C4 122.1(3) ?
C7 C6 C5 121.8(4) ?
C7 C6 H6 119.1 ?
C5 C6 H6 119.1 ?
C6 C7 C8 119.3(4) ?
C6 C7 H7 120.3 ?
C8 C7 H7 120.3 ?
C9 C8 C7 121.0(4) ?
C9 C8 H8 119.5 ?
C7 C8 H8 119.5 ?
C8 C9 C10 121.6(4) ?
C8 C9 H9 119.2 ?
C10 C9 H9 119.2 ?
C9 C10 C5 117.2(3) ?
C9 C10 C1 123.8(3) ?
C5 C10 C1 119.0(3) ?
N1 C11 C1 125.8(3) ?
N1 C11 H11 117.1 ?
C1 C11 H11 117.1 ?
N1 C12 C13 107.8(2) ?
N1 C12 H12A 110.1 ?
C13 C12 H12A 110.1 ?
N1 C12 H12B 110.1 ?
C13 C12 H12B 110.1 ?
H12A C12 H12B 108.5 ?
N2 C13 C12 106.7(2) ?
N2 C13 H13A 110.4 ?
C12 C13 H13A 110.4 ?
N2 C13 H13B 110.4 ?
C12 C13 H13B 110.4 ?
H13A C13 H13B 108.6 ?
N2 C14 C15 125.7(3) ?
N2 C14 H14 117.1 ?
C15 C14 H14 117.1 ?
C16 C15 C14 118.8(3) ?
C16 C15 C24 120.4(3) ?
C14 C15 C24 120.6(3) ?
O2 C16 C15 125.6(3) ?
O2 C16 C17 116.5(3) ?
C15 C16 C17 117.8(3) ?
C18 C17 C16 121.7(3) ?
C18 C17 H17 119.1 ?
C16 C17 H17 119.1 ?
C17 C18 C19 121.9(3) ?
C17 C18 H18 119.0 ?
C19 C18 H18 119.0 ?
C20 C19 C24 119.7(4) ?
C20 C19 C18 121.6(3) ?
C24 C19 C18 118.7(3) ?
C21 C20 C19 121.5(4) ?
C21 C20 H20 119.2 ?
C19 C20 H20 119.2 ?
C20 C21 C22 119.2(4) ?
C20 C21 H21 120.4 ?
C22 C21 H21 120.4 ?
C23 C22 C21 121.6(4) ?
C23 C22 H22 119.2 ?
C21 C22 H22 119.2 ?
C22 C23 C24 120.5(4) ?
C22 C23 H23 119.7 ?
C24 C23 H23 119.7 ?
C19 C24 C23 117.3(3) ?
C19 C24 C15 119.4(3) ?
C23 C24 C15 123.3(3) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Zn1 N1 1.836(2) y
Zn1 N2 1.836(2) y
Zn1 O1 1.848(2) y
Zn1 O2 1.849(2) y
O1 C2 1.301(3) ?
O2 C16 1.292(3) ?
N1 C11 1.293(4) ?
N1 C12 1.482(4) ?
N2 C14 1.285(4) ?
N2 C13 1.481(4) ?
C1 C2 1.404(4) ?
C1 C11 1.424(4) ?
C1 C10 1.458(4) ?
C2 C3 1.434(4) ?
C3 C4 1.347(4) ?
C3 H3 0.9300 ?
C4 C5 1.424(5) ?
C4 H4 0.9300 ?
C5 C10 1.415(5) ?
C5 C6 1.420(5) ?
C6 C7 1.341(6) ?
C6 H6 0.9300 ?
C7 C8 1.392(6) ?
C7 H7 0.9300 ?
C8 C9 1.360(5) ?
C8 H8 0.9300 ?
C9 C10 1.409(5) ?
C9 H9 0.9300 ?
C11 H11 0.9300 ?
C12 C13 1.506(4) ?
C12 H12A 0.9700 ?
C12 H12B 0.9700 ?
C13 H13A 0.9700 ?
C13 H13B 0.9700 ?
C14 C15 1.425(4) ?
C14 H14 0.9300 ?
C15 C16 1.410(4) ?
C15 C24 1.452(4) ?
C16 C17 1.440(4) ?
C17 C18 1.347(4) ?
C17 H17 0.9300 ?
C18 C19 1.427(5) ?
C18 H18 0.9300 ?
C19 C20 1.412(5) ?
C19 C24 1.412(5) ?
C20 C21 1.342(6) ?
C20 H20 0.9300 ?
C21 C22 1.391(6) ?
C21 H21 0.9300 ?
C22 C23 1.368(5) ?
C22 H22 0.9300 ?
C23 C24 1.415(5) ?
C23 H23 0.9300 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
N1 Zn1 O1 C2 3.3(3) ?
O2 Zn1 O1 C2 -178.1(3) ?
N2 Zn1 O2 C16 7.9(2) ?
O1 Zn1 O2 C16 -175.2(2) ?
N2 Zn1 N1 C11 176.3(3) ?
O1 Zn1 N1 C11 -0.6(3) ?
N2 Zn1 N1 C12 -4.8(2) ?
O1 Zn1 N1 C12 178.2(2) ?
N1 Zn1 N2 C14 170.6(3) ?
O2 Zn1 N2 C14 -7.9(3) ?
N1 Zn1 N2 C13 -16.2(2) ?
O2 Zn1 N2 C13 165.3(2) ?
Zn1 O1 C2 C1 -5.1(4) ?
Zn1 O1 C2 C3 174.4(2) ?
C11 C1 C2 O1 3.3(5) ?
C10 C1 C2 O1 -176.7(3) ?
C11 C1 C2 C3 -176.2(3) ?
C10 C1 C2 C3 3.8(4) ?
O1 C2 C3 C4 176.7(3) ?
C1 C2 C3 C4 -3.8(5) ?
C2 C3 C4 C5 0.5(5) ?
C3 C4 C5 C10 2.8(5) ?
C3 C4 C5 C6 -177.5(4) ?
C10 C5 C6 C7 0.3(6) ?
C4 C5 C6 C7 -179.3(4) ?
C5 C6 C7 C8 0.6(7) ?
C6 C7 C8 C9 -0.3(7) ?
C7 C8 C9 C10 -0.9(7) ?
C8 C9 C10 C5 1.7(5) ?
C8 C9 C10 C1 -177.3(4) ?
C6 C5 C10 C9 -1.4(5) ?
C4 C5 C10 C9 178.2(3) ?
C6 C5 C10 C1 177.6(3) ?
C4 C5 C10 C1 -2.7(5) ?
C2 C1 C10 C9 178.4(3) ?
C11 C1 C10 C9 -1.6(5) ?
C2 C1 C10 C5 -0.6(4) ?
C11 C1 C10 C5 179.4(3) ?
C12 N1 C11 C1 -179.3(3) ?
Zn1 N1 C11 C1 -0.5(5) ?
C2 C1 C11 N1 -0.4(5) ?
C10 C1 C11 N1 179.6(3) ?
C11 N1 C12 C13 -157.4(3) ?
Zn1 N1 C12 C13 23.7(3) ?
C14 N2 C13 C12 -153.9(3) ?
Zn1 N2 C13 C12 32.2(3) ?
N1 C12 C13 N2 -34.0(3) y
C13 N2 C14 C15 -171.5(3) ?
Zn1 N2 C14 C15 1.5(5) ?
N2 C14 C15 C16 7.8(5) ?
N2 C14 C15 C24 -178.5(3) ?
Zn1 O2 C16 C15 -1.5(4) ?
Zn1 O2 C16 C17 -179.86(19) ?
C14 C15 C16 O2 -7.8(4) ?
C24 C15 C16 O2 178.5(3) ?
C14 C15 C16 C17 170.6(3) ?
C24 C15 C16 C17 -3.1(4) ?
O2 C16 C17 C18 179.4(3) ?
C15 C16 C17 C18 0.9(4) ?
C16 C17 C18 C19 1.4(5) ?
C17 C18 C19 C20 180.0(3) ?
C17 C18 C19 C24 -1.3(5) ?
C24 C19 C20 C21 1.3(6) ?
C18 C19 C20 C21 180.0(4) ?
C19 C20 C21 C22 -0.2(7) ?
C20 C21 C22 C23 0.1(7) ?
C21 C22 C23 C24 -1.1(6) ?
C20 C19 C24 C23 -2.2(5) ?
C18 C19 C24 C23 179.1(3) ?
C20 C19 C24 C15 177.8(3) ?
C18 C19 C24 C15 -1.0(5) ?
C22 C23 C24 C19 2.1(5) ?
C22 C23 C24 C15 -177.8(3) ?
C16 C15 C24 C19 3.2(4) ?
C14 C15 C24 C19 -170.4(3) ?
C16 C15 C24 C23 -176.9(3) ?
C14 C15 C24 C23 9.5(5) ?