#------------------------------------------------------------------------------
#$Date: 2013-03-27 08:32:40 +0000 (Wed, 27 Mar 2013) $
#$Revision: 77439 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/68/2206829.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2206829
loop_
_publ_author_name
'Chen, Guang'
'Zhao, Bin'
'Sun, Min'
'Qi, Wei'
_publ_section_title
'[<i>N</i>,<i>N</i>'-Bis(2-hydroxynaphthylmethylene)-1,2-ethanediaminato]zinc(II)'
_journal_coeditor_code           YA6260
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1869
_journal_page_last               m1870
_journal_volume                  61
_journal_year                    2005
_journal_paper_doi               10.1107/S1600536805026796
_chemical_formula_iupac          '[Zn (C24 H18 N2 O2)]'
_chemical_formula_moiety         'C24 H18 N2 O2 Zn'
_chemical_formula_sum            'C24 H18 N2 O2 Zn'
_chemical_formula_weight         431.77
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.920(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.6810(10)
_cell_length_b                   8.1840(10)
_cell_length_c                   12.9570(10)
_cell_measurement_reflns_used    2849
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.9
_cell_measurement_theta_min      2.7
_cell_volume                     1846.9(3)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Sheldrick, 1997b)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997a)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997a)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.061
_diffrn_reflns_av_sigmaI/netI    0.066
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9152
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.3
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.354
_exptl_absorpt_correction_T_max  0.755
_exptl_absorpt_correction_T_min  0.663
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.553
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             888
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.64
_refine_diff_density_min         -0.40
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.01
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     262
_refine_ls_number_reflns         4153
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.01
_refine_ls_R_factor_all          0.072
_refine_ls_R_factor_gt           0.051
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0753P)^2^] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.127
_refine_ls_wR_factor_ref         0.137
_reflns_number_gt                3029
_reflns_number_total             4153
_reflns_threshold_expression     I>2\s(I)
_[local]_cod_data_source_file    ya6260.cif
_[local]_cod_data_source_block   I
_[local]_cod_cif_authors_sg_H-M  'P 21/c'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_error_flag                  retracted
_cod_error_source                original
_cod_error_description
;
    This file does not describe any real compound and was retracted by
    the publisher. The previously deposited coordinates can be reviewed
    in older revisions of this file or in the COD database retracted/
    subdirectory, http://www.crystallography.net/retracted/.

    The precise reasons for the retraction and other circumstances are
    extensively discussed in the Acta Cryst. E editorial:

    William T. A. Harrison, Jim Simpson and Matthias Weil, Acta
    Cryst. E 66 (2010) e1--e2

    http://journals.iucr.org/e/issues/2010/01/00/me0406/index.html
    http://journals.iucr.org/e/issues/2010/01/00/me0406/me0406.pdf
    doi:10.1107/S1600536809051757
    (http://dx.doi.org/10.1107/S1600536809051757)

    Saulius Gra\<zulis
    2011-04-19
;
_cod_database_code               2206829
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Zn1 0.022954(19) 0.33477(4) 0.07297(3) 0.03501(15) Uani d . 1 Zn
O1 0.09689(11) 0.4212(3) 0.17690(15) 0.0333(5) Uani d . 1 O
O2 -0.04847(11) 0.4332(3) 0.14147(14) 0.0324(5) Uani d . 1 O
N1 0.09373(14) 0.2323(3) 0.00696(18) 0.0318(5) Uani d . 1 N
N2 -0.05060(14) 0.2595(3) -0.03401(18) 0.0300(5) Uani d . 1 N
C1 0.21010(18) 0.3180(4) 0.1207(2) 0.0334(7) Uani d . 1 C
C2 0.17118(17) 0.4107(4) 0.1863(2) 0.0328(7) Uani d . 1 C
C3 0.21539(18) 0.5026(4) 0.2698(2) 0.0398(7) Uani d . 1 C
H3 0.1902 0.5695 0.3110 0.048 Uiso calc R 1 H
C4 0.29259(19) 0.4941(4) 0.2898(3) 0.0449(8) Uani d . 1 C
H4 0.3194 0.5548 0.3449 0.054 Uiso calc R 1 H
C5 0.33438(19) 0.3949(5) 0.2290(3) 0.0445(8) Uani d . 1 C
C6 0.4156(2) 0.3808(6) 0.2523(3) 0.0608(11) Uani d . 1 C
H6 0.4424 0.4371 0.3095 0.073 Uiso calc R 1 H
C7 0.4547(2) 0.2885(6) 0.1941(4) 0.0714(13) Uani d . 1 C
H7 0.5079 0.2803 0.2112 0.086 Uiso calc R 1 H
C8 0.4150(2) 0.2051(5) 0.1079(4) 0.0633(11) Uani d . 1 C
H8 0.4421 0.1414 0.0672 0.076 Uiso calc R 1 H
C9 0.3373(2) 0.2154(5) 0.0822(3) 0.0509(9) Uani d . 1 C
H9 0.3123 0.1596 0.0236 0.061 Uiso calc R 1 H
C10 0.29369(18) 0.3085(4) 0.1422(3) 0.0388(7) Uani d . 1 C
C11 0.16768(18) 0.2337(4) 0.0334(2) 0.0347(7) Uani d . 1 C
H11 0.1956 0.1743 -0.0083 0.042 Uiso calc R 1 H
C12 0.05967(19) 0.1355(4) -0.0862(3) 0.0393(7) Uani d . 1 C
H12A 0.0558 0.0215 -0.0673 0.047 Uiso calc R 1 H
H12B 0.0916 0.1430 -0.1398 0.047 Uiso calc R 1 H
C13 -0.01894(18) 0.2038(4) -0.1267(2) 0.0378(7) Uani d . 1 C
H13A -0.0155 0.2945 -0.1738 0.045 Uiso calc R 1 H
H13B -0.0516 0.1203 -0.1643 0.045 Uiso calc R 1 H
C14 -0.12390(18) 0.2639(4) -0.0405(2) 0.0342(7) Uani d . 1 C
H14 -0.1533 0.2178 -0.0998 0.041 Uiso calc R 1 H
C15 -0.16416(18) 0.3333(3) 0.0351(2) 0.0313(6) Uani d . 1 C
C16 -0.12240(17) 0.4222(4) 0.1194(2) 0.0321(6) Uani d . 1 C
C17 -0.16514(18) 0.5123(4) 0.1856(2) 0.0384(7) Uani d . 1 C
H17 -0.1386 0.5729 0.2410 0.046 Uiso calc R 1 H
C18 -0.24248(19) 0.5110(4) 0.1694(3) 0.0466(8) Uani d . 1 C
H18 -0.2679 0.5728 0.2131 0.056 Uiso calc R 1 H
C19 -0.28649(19) 0.4178(4) 0.0873(3) 0.0452(8) Uani d . 1 C
C20 -0.3675(2) 0.4170(5) 0.0708(3) 0.0600(11) Uani d . 1 C
H20 -0.3928 0.4788 0.1145 0.072 Uiso calc R 1 H
C21 -0.4088(2) 0.3293(6) -0.0065(4) 0.0721(14) Uani d . 1 C
H21 -0.4622 0.3300 -0.0161 0.087 Uiso calc R 1 H
C22 -0.3710(2) 0.2374(6) -0.0722(3) 0.0614(11) Uani d . 1 C
H22 -0.3997 0.1767 -0.1259 0.074 Uiso calc R 1 H
C23 -0.2926(2) 0.2340(5) -0.0598(3) 0.0496(9) Uani d . 1 C
H23 -0.2688 0.1700 -0.1041 0.060 Uiso calc R 1 H
C24 -0.24742(18) 0.3271(4) 0.0200(3) 0.0372(7) Uani d . 1 C
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Zn1 0.0384(2) 0.0396(2) 0.0272(2) 0.00038(16) 0.00605(15) -0.00013(15)
O1 0.0340(11) 0.0419(12) 0.0236(10) 0.0007(9) 0.0038(8) -0.0029(9)
O2 0.0336(11) 0.0404(12) 0.0228(10) 0.0012(9) 0.0041(8) -0.0037(9)
N1 0.0410(14) 0.0326(13) 0.0226(12) 0.0007(11) 0.0080(10) 0.0000(11)
N2 0.0374(14) 0.0304(13) 0.0220(12) -0.0007(11) 0.0049(10) -0.0001(10)
C1 0.0357(16) 0.0351(16) 0.0301(16) 0.0000(13) 0.0069(12) 0.0066(13)
C2 0.0368(16) 0.0343(16) 0.0269(15) -0.0020(13) 0.0039(12) 0.0060(13)
C3 0.0465(19) 0.0407(18) 0.0320(17) -0.0055(15) 0.0060(14) -0.0034(14)
C4 0.0433(19) 0.050(2) 0.0388(18) -0.0114(16) 0.0004(14) -0.0026(16)
C5 0.0394(18) 0.046(2) 0.046(2) -0.0061(15) 0.0024(15) 0.0083(17)
C6 0.038(2) 0.073(3) 0.068(3) -0.0071(19) -0.0014(18) -0.002(2)
C7 0.0315(19) 0.082(3) 0.099(4) 0.003(2) 0.007(2) 0.001(3)
C8 0.042(2) 0.073(3) 0.077(3) 0.0123(19) 0.016(2) -0.001(2)
C9 0.043(2) 0.058(2) 0.053(2) 0.0048(17) 0.0122(17) 0.0010(19)
C10 0.0364(17) 0.0382(18) 0.0420(19) 0.0023(13) 0.0080(14) 0.0104(15)
C11 0.0400(17) 0.0374(17) 0.0286(16) 0.0048(14) 0.0116(13) 0.0027(13)
C12 0.0454(18) 0.0406(18) 0.0322(17) 0.0027(14) 0.0078(14) -0.0078(14)
C13 0.0485(19) 0.0433(19) 0.0213(15) -0.0043(14) 0.0057(13) -0.0070(13)
C14 0.0418(18) 0.0327(16) 0.0261(15) -0.0041(13) 0.0003(13) 0.0039(13)
C15 0.0364(16) 0.0292(15) 0.0279(15) 0.0001(12) 0.0043(12) 0.0053(12)
C16 0.0381(17) 0.0308(16) 0.0279(15) 0.0058(13) 0.0074(12) 0.0103(13)
C17 0.0434(18) 0.0383(18) 0.0342(17) 0.0073(14) 0.0084(13) -0.0004(14)
C18 0.0475(19) 0.045(2) 0.049(2) 0.0100(16) 0.0143(16) 0.0000(17)
C19 0.0374(18) 0.046(2) 0.053(2) 0.0054(15) 0.0111(15) 0.0129(17)
C20 0.043(2) 0.065(3) 0.074(3) 0.0098(19) 0.017(2) 0.011(2)
C21 0.0306(19) 0.081(3) 0.100(4) -0.002(2) 0.000(2) 0.019(3)
C22 0.047(2) 0.070(3) 0.064(3) -0.012(2) -0.0025(19) 0.003(2)
C23 0.0424(19) 0.055(2) 0.049(2) -0.0059(17) 0.0012(16) 0.0055(18)
C24 0.0379(17) 0.0372(17) 0.0350(17) -0.0015(13) 0.0027(13) 0.0100(14)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
N1 Zn1 N2 86.91(11) y
N1 Zn1 O1 93.49(10) y
N2 Zn1 O1 176.90(10) y
N1 Zn1 O2 178.54(10) y
N2 Zn1 O2 93.16(10) y
O1 Zn1 O2 86.52(9) y
C2 O1 Zn1 128.25(19) ?
C16 O2 Zn1 127.71(19) ?
C11 N1 C12 118.1(3) ?
C11 N1 Zn1 127.7(2) ?
C12 N1 Zn1 114.2(2) ?
C14 N2 C13 118.3(3) ?
C14 N2 Zn1 128.0(2) ?
C13 N2 Zn1 113.44(19) ?
C2 C1 C11 119.8(3) ?
C2 C1 C10 120.0(3) ?
C11 C1 C10 120.2(3) ?
O1 C2 C1 124.8(3) ?
O1 C2 C3 116.5(3) ?
C1 C2 C3 118.7(3) ?
C4 C3 C2 121.4(3) ?
C4 C3 H3 119.3 ?
C2 C3 H3 119.3 ?
C3 C4 C5 121.9(3) ?
C3 C4 H4 119.0 ?
C5 C4 H4 119.0 ?
C10 C5 C6 119.0(4) ?
C10 C5 C4 118.9(3) ?
C6 C5 C4 122.1(3) ?
C7 C6 C5 121.8(4) ?
C7 C6 H6 119.1 ?
C5 C6 H6 119.1 ?
C6 C7 C8 119.3(4) ?
C6 C7 H7 120.3 ?
C8 C7 H7 120.3 ?
C9 C8 C7 121.0(4) ?
C9 C8 H8 119.5 ?
C7 C8 H8 119.5 ?
C8 C9 C10 121.6(4) ?
C8 C9 H9 119.2 ?
C10 C9 H9 119.2 ?
C9 C10 C5 117.2(3) ?
C9 C10 C1 123.8(3) ?
C5 C10 C1 119.0(3) ?
N1 C11 C1 125.8(3) ?
N1 C11 H11 117.1 ?
C1 C11 H11 117.1 ?
N1 C12 C13 107.8(2) ?
N1 C12 H12A 110.1 ?
C13 C12 H12A 110.1 ?
N1 C12 H12B 110.1 ?
C13 C12 H12B 110.1 ?
H12A C12 H12B 108.5 ?
N2 C13 C12 106.7(2) ?
N2 C13 H13A 110.4 ?
C12 C13 H13A 110.4 ?
N2 C13 H13B 110.4 ?
C12 C13 H13B 110.4 ?
H13A C13 H13B 108.6 ?
N2 C14 C15 125.7(3) ?
N2 C14 H14 117.1 ?
C15 C14 H14 117.1 ?
C16 C15 C14 118.8(3) ?
C16 C15 C24 120.4(3) ?
C14 C15 C24 120.6(3) ?
O2 C16 C15 125.6(3) ?
O2 C16 C17 116.5(3) ?
C15 C16 C17 117.8(3) ?
C18 C17 C16 121.7(3) ?
C18 C17 H17 119.1 ?
C16 C17 H17 119.1 ?
C17 C18 C19 121.9(3) ?
C17 C18 H18 119.0 ?
C19 C18 H18 119.0 ?
C20 C19 C24 119.7(4) ?
C20 C19 C18 121.6(3) ?
C24 C19 C18 118.7(3) ?
C21 C20 C19 121.5(4) ?
C21 C20 H20 119.2 ?
C19 C20 H20 119.2 ?
C20 C21 C22 119.2(4) ?
C20 C21 H21 120.4 ?
C22 C21 H21 120.4 ?
C23 C22 C21 121.6(4) ?
C23 C22 H22 119.2 ?
C21 C22 H22 119.2 ?
C22 C23 C24 120.5(4) ?
C22 C23 H23 119.7 ?
C24 C23 H23 119.7 ?
C19 C24 C23 117.3(3) ?
C19 C24 C15 119.4(3) ?
C23 C24 C15 123.3(3) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Zn1 N1 1.836(2) y
Zn1 N2 1.836(2) y
Zn1 O1 1.848(2) y
Zn1 O2 1.849(2) y
O1 C2 1.301(3) ?
O2 C16 1.292(3) ?
N1 C11 1.293(4) ?
N1 C12 1.482(4) ?
N2 C14 1.285(4) ?
N2 C13 1.481(4) ?
C1 C2 1.404(4) ?
C1 C11 1.424(4) ?
C1 C10 1.458(4) ?
C2 C3 1.434(4) ?
C3 C4 1.347(4) ?
C3 H3 0.9300 ?
C4 C5 1.424(5) ?
C4 H4 0.9300 ?
C5 C10 1.415(5) ?
C5 C6 1.420(5) ?
C6 C7 1.341(6) ?
C6 H6 0.9300 ?
C7 C8 1.392(6) ?
C7 H7 0.9300 ?
C8 C9 1.360(5) ?
C8 H8 0.9300 ?
C9 C10 1.409(5) ?
C9 H9 0.9300 ?
C11 H11 0.9300 ?
C12 C13 1.506(4) ?
C12 H12A 0.9700 ?
C12 H12B 0.9700 ?
C13 H13A 0.9700 ?
C13 H13B 0.9700 ?
C14 C15 1.425(4) ?
C14 H14 0.9300 ?
C15 C16 1.410(4) ?
C15 C24 1.452(4) ?
C16 C17 1.440(4) ?
C17 C18 1.347(4) ?
C17 H17 0.9300 ?
C18 C19 1.427(5) ?
C18 H18 0.9300 ?
C19 C20 1.412(5) ?
C19 C24 1.412(5) ?
C20 C21 1.342(6) ?
C20 H20 0.9300 ?
C21 C22 1.391(6) ?
C21 H21 0.9300 ?
C22 C23 1.368(5) ?
C22 H22 0.9300 ?
C23 C24 1.415(5) ?
C23 H23 0.9300 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
N1 Zn1 O1 C2 3.3(3) ?
O2 Zn1 O1 C2 -178.1(3) ?
N2 Zn1 O2 C16 7.9(2) ?
O1 Zn1 O2 C16 -175.2(2) ?
N2 Zn1 N1 C11 176.3(3) ?
O1 Zn1 N1 C11 -0.6(3) ?
N2 Zn1 N1 C12 -4.8(2) ?
O1 Zn1 N1 C12 178.2(2) ?
N1 Zn1 N2 C14 170.6(3) ?
O2 Zn1 N2 C14 -7.9(3) ?
N1 Zn1 N2 C13 -16.2(2) ?
O2 Zn1 N2 C13 165.3(2) ?
Zn1 O1 C2 C1 -5.1(4) ?
Zn1 O1 C2 C3 174.4(2) ?
C11 C1 C2 O1 3.3(5) ?
C10 C1 C2 O1 -176.7(3) ?
C11 C1 C2 C3 -176.2(3) ?
C10 C1 C2 C3 3.8(4) ?
O1 C2 C3 C4 176.7(3) ?
C1 C2 C3 C4 -3.8(5) ?
C2 C3 C4 C5 0.5(5) ?
C3 C4 C5 C10 2.8(5) ?
C3 C4 C5 C6 -177.5(4) ?
C10 C5 C6 C7 0.3(6) ?
C4 C5 C6 C7 -179.3(4) ?
C5 C6 C7 C8 0.6(7) ?
C6 C7 C8 C9 -0.3(7) ?
C7 C8 C9 C10 -0.9(7) ?
C8 C9 C10 C5 1.7(5) ?
C8 C9 C10 C1 -177.3(4) ?
C6 C5 C10 C9 -1.4(5) ?
C4 C5 C10 C9 178.2(3) ?
C6 C5 C10 C1 177.6(3) ?
C4 C5 C10 C1 -2.7(5) ?
C2 C1 C10 C9 178.4(3) ?
C11 C1 C10 C9 -1.6(5) ?
C2 C1 C10 C5 -0.6(4) ?
C11 C1 C10 C5 179.4(3) ?
C12 N1 C11 C1 -179.3(3) ?
Zn1 N1 C11 C1 -0.5(5) ?
C2 C1 C11 N1 -0.4(5) ?
C10 C1 C11 N1 179.6(3) ?
C11 N1 C12 C13 -157.4(3) ?
Zn1 N1 C12 C13 23.7(3) ?
C14 N2 C13 C12 -153.9(3) ?
Zn1 N2 C13 C12 32.2(3) ?
N1 C12 C13 N2 -34.0(3) y
C13 N2 C14 C15 -171.5(3) ?
Zn1 N2 C14 C15 1.5(5) ?
N2 C14 C15 C16 7.8(5) ?
N2 C14 C15 C24 -178.5(3) ?
Zn1 O2 C16 C15 -1.5(4) ?
Zn1 O2 C16 C17 -179.86(19) ?
C14 C15 C16 O2 -7.8(4) ?
C24 C15 C16 O2 178.5(3) ?
C14 C15 C16 C17 170.6(3) ?
C24 C15 C16 C17 -3.1(4) ?
O2 C16 C17 C18 179.4(3) ?
C15 C16 C17 C18 0.9(4) ?
C16 C17 C18 C19 1.4(5) ?
C17 C18 C19 C20 180.0(3) ?
C17 C18 C19 C24 -1.3(5) ?
C24 C19 C20 C21 1.3(6) ?
C18 C19 C20 C21 180.0(4) ?
C19 C20 C21 C22 -0.2(7) ?
C20 C21 C22 C23 0.1(7) ?
C21 C22 C23 C24 -1.1(6) ?
C20 C19 C24 C23 -2.2(5) ?
C18 C19 C24 C23 179.1(3) ?
C20 C19 C24 C15 177.8(3) ?
C18 C19 C24 C15 -1.0(5) ?
C22 C23 C24 C19 2.1(5) ?
C22 C23 C24 C15 -177.8(3) ?
C16 C15 C24 C19 3.2(4) ?
C14 C15 C24 C19 -170.4(3) ?
C16 C15 C24 C23 -176.9(3) ?
C14 C15 C24 C23 9.5(5) ?