Crystallography Open Database

Information card for entry 2214529

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Coordinates	2214529.cif
Structure factors	2214529.hkl
Original IUCr paper	HTML

Structure parameters

Chemical name	catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato- κ^2^O,O')ytterbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)(Ag—W)-di-μ-sulfido]]
Formula	C24 H72 Ag N14 O10 P4 S4 W Yb
Calculated formula	C24 H72 Ag N14 O10 P4 S4 W Yb
SMILES	[Yb]12([O]=P(N(C)C)(N(C)C)N(C)C)([O]=P(N(C)C)(N(C)C)N(C)C)([O]=P(N(C)C)(N(C)C)N(C)C)([O]=P(N(C)C)(N(C)C)N(C)C)([O]=N(=O)O1)[O]=N(=O)O2.[Yb]12([O]=P(N(C)C)(N(C)C)N(C)C)([O]=P(N(C)C)(N(C)C)N(C)C)([O]=P(N(C)C)(N(C)C)N(C)C)([O]=P(N(C)C)(N(C)C)N(C)C)([O]=N(=O)O1)[O]=N(=O)O2.[Ag]1S[W](S1)(=[S]2)=[S][Ag]21S[W](S1)(=S)=S
Title of publication	<i>catena</i>-Poly[[tetrakis(hexamethylphosphoramide-κ<i>O</i>)bis(nitrato- κ^2^<i>O</i>,<i>O</i>')ytterbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)(<i>Ag</i>—<i>W</i>)-di-μ-sulfido]]
Authors of publication	Cao, Yuan; Zhang, Jin-Fang; Zhang, Chi
Journal of publication	Acta Crystallographica Section E
Year of publication	2007
Journal volume	63
Journal issue	8
Pages of publication	m2076 - m2077
a	15.7241 ± 0.0009 Å
b	29.528 ± 0.0018 Å
c	11.3464 ± 0.0007 Å
α	90°
β	90.798 ± 0.001°
γ	90°
Cell volume	5267.6 ± 0.5 Å³
Cell temperature	153 ± 2 K
Ambient diffraction temperature	153 ± 2 K
Number of distinct elements	9
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0354
Residual factor for significantly intense reflections	0.0325
Weighted residual factors for significantly intense reflections	0.0674
Weighted residual factors for all reflections included in the refinement	0.0686
Goodness-of-fit parameter for all reflections included in the refinement	1.179
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	Yes

Version history

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